Interfacial Engineering Enabled Novel Bi-Based Layered Oxide Supercells with Modulated Microstructures and Tunable Physical Properties

Li, Leigang; Cheng, Jianli; Wang, Hua; Huang, Jijie; Gao, Xingyao; Wang, Xuejing; Misra, Shikhar; Zhang, Bruce; Jian, Jie; Chen, Aiping; Lu, Ping; Qian, Xiaofeng; Yang, Kesong; Wang, Haiyan

doi:10.1021/acs.cgd.9b00938

Interfacial Engineering Enabled Novel Bi-Based Layered Oxide Supercells with Modulated Microstructures and Tunable Physical Properties

Journal Article · Thu Nov 07 00:00:00 EST 2019 · Crystal Growth and Design

DOI:https://doi.org/10.1021/acs.cgd.9b00938· OSTI ID:1760591

Li, Leigang ^[1]; ^[2]; Wang, Hua ^[3]; Huang, Jijie ^[4]; Gao, Xingyao ^[4]; Wang, Xuejing ^[4]; Misra, Shikhar ^[4]; Zhang, Bruce ^[4]; Jian, Jie ^[4]; ^[5]; Lu, Ping ^[6]; ^[3]; ^[2]; ^[4]

Purdue Univ., West Lafayette, IN (United States); Texas A & M Univ., College Station, TX (United States)
Univ. of California, San Diego, CA (United States)
Texas A & M Univ., College Station, TX (United States)
Purdue Univ., West Lafayette, IN (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Two-dimensional layered materials hold great significance to fundamental scientific research and future nanoscale device applications. Besides the well-studied graphene and dichalcogenides, oxide-based layered materials are another family attracting significant research interests, for example, the Bi-based Bi₃Fe₂Mn₂O_10-δ layered supercell (called BFMO322 SC) structure. BFMO322 SC is an excellent room-temperature multiferroic material, but its growth mechanism is unclear. In this work, Bi₂Fe_1–xMn_xO₆ thin films with different Fe/Mn molar ratios were deposited on CeO₂ buffer layers by pulsed laser deposition. By varying the Fe/Mn molar ratios, it has been determined that Mn can favor the growth of Bi-based layered structures, while Fe cannot facilitate the growth. A series of novel layered supercell structures can be obtained by manipulating the growth kinetics at the substrate/film interface, as achieved by precisely controlling the growth conditions. More interestingly, the magnetization and optical band gap of the Bi-based layered structures can be tuned by varying the Fe/Mn molar ratios. This original work has demonstrated the power of interfacial engineering in enabling new Bi-based layered structures and thus is of great significance for the design of new layered structures with multifunctionalities.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: National Science Foundation (NSF); US Department of the Navy, Office of Naval Research (ONR); USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: 89233218CNA000001; NA0003525

OSTI ID:: 1760591

Report Number(s):: LA-UR--20-24154

Journal Information:: Crystal Growth and Design, Journal Name: Crystal Growth and Design Journal Issue: 12 Vol. 19; ISSN 1528-7483

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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