Anisotropic moiré optical transitions in twisted monolayer/bilayer phosphorene heterostructures

Zhao, Shilong; Wang, Erqing; Üzer, Ebru Alime; Guo, Shuaifei; Qi, Ruishi; Tan, Junyang; Watanabe, Kenji; Taniguchi, Takashi; Nilges, Tom; Gao, Peng; Zhang, Yuanbo; Cheng, Hui-Ming; Liu, Bilu; Zou, Xiaolong; Wang, Feng

doi:10.1038/s41467-021-24272-9

Title: Anisotropic moiré optical transitions in twisted monolayer/bilayer phosphorene heterostructures

Journal Article · Thu Jun 24 00:00:00 EDT 2021 · Nature Communications

DOI:https://doi.org/10.1038/s41467-021-24272-9· OSTI ID:1815927

^[1]; Wang, Erqing ^[2]; Üzer, Ebru Alime ^[3]; Guo, Shuaifei ^[4]; Qi, Ruishi ^[5]; Tan, Junyang ^[2];

^[6];

^[6]; Nilges, Tom ^[3];

^[7]; Zhang, Yuanbo ^[4];

^[2];

^[8]

Tsinghua Univ., Beijing (China). Tsinghua-Berkeley Shenzhen Inst.; Univ. of California, Berkeley, CA (United States). Dept. of Physics
Tsinghua Univ., Beijing (China). Tsinghua-Berkeley Shenzhen Inst.
Technische Univ. Muenchen, Garching (Germany). Dept. of Chemistry
Fudan Univ., Shanghai (China). Dept. of Physics. State Key Lab. of Surface Physics
Univ. of California, Berkeley, CA (United States). Dept. of Physics; Peking Univ., Beijing (China). International Center for Quantum Materials. School of Physics. Electron Microscopy Lab.
National Inst. for Materials Science, Tsukuba (Japan)
Peking Univ., Beijing (China). International Center for Quantum Materials. School of Physics. Electron Microscopy Lab.; Collaborative Innovation Center of Quantum Matter, Beijing (China)
Univ. of California, Berkeley, CA (United States). Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division; Univ. of California, Berkeley, CA (United States). Kavli Energy NanoSciences Inst.

Moiré superlattices of van der Waals heterostructures provide a powerful way to engineer electronic structures of two-dimensional materials. Many novel quantum phenomena have emerged in graphene and transition metal dichalcogenide moiré systems. Twisted phosphorene offers another attractive system to explore moiré physics because phosphorene features an anisotropic rectangular lattice, different from isotropic hexagonal lattices previously reported. Here we report emerging anisotropic moiré optical transitions in twisted monolayer/bilayer phosphorenes. The optical resonances in phosphorene moiré superlattice depend sensitively on twist angle and are completely different from those in the constitute monolayer and bilayer phosphorene even for a twist angle as large as 19°. Our calculations reveal that the Γ-point direct bandgap and the rectangular lattice of phosphorene give rise to the remarkably strong moiré physics in large-twist-angle phosphorene heterostructures. This work highlights fresh opportunities to explore moiré physics in phosphorene and other van der Waals heterostructures with different lattice configurations.

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Sponsoring Organization:: USDOE Office of Science (SC); National Key Research and Development Program of China; Bureau of Industry and Information Technology of Shenzhen; National Natural Science Foundation of China (NSFC); Shenzhen Basic Research Projects; Guangdong Innovative and Entrepreneurial Research Team Program; Shanghai Municipal Science and Technology Commission; Chinese Academy of Sciences (CAS)

Grant/Contract Number:: AC02-05CH11231; 2018YFA0307200; 51722206; 51920105002; 201901171523; 2017YFB0701600; 11974197; JCYJ20170407155608882L 2017ZT07C341; 2016YFA0300703; 2018YFA0305600; U1732274; 11527805; 11421404; XDB30000000; JPMJCR15F3

OSTI ID:: 1815927

Journal Information:: Nature Communications, Vol. 12, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

Light–valley interactions in 2D semiconductors Mak, Kin Fai; Xiao, Di; Shan, Jie Nature Photonics, Vol. 12, Issue 8 https://doi.org/10.1038/s41566-018-0204-6	journal	July 2018
Infrared fingerprints of few-layer black phosphorus Zhang, Guowei; Huang, Shenyang; Chaves, Andrey Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14071	journal	January 2017
Two-dimensional material nanophotonics Xia, Fengnian; Wang, Han; Xiao, Di Nature Photonics, Vol. 8, Issue 12 https://doi.org/10.1038/nphoton.2014.271	journal	November 2014
Unconventional superconductivity in magic-angle graphene superlattices Cao, Yuan; Fatemi, Valla; Fang, Shiang Nature, Vol. 556, Issue 7699 https://doi.org/10.1038/nature26160	journal	March 2018
Interlayer electron–phonon coupling in WSe2/hBN heterostructures Jin, Chenhao; Kim, Jonghwan; Suh, Joonki Nature Physics, Vol. 13, Issue 2 https://doi.org/10.1038/nphys3928	journal	October 2016
Van der Waals density functionals applied to solids Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevB.83.195131	journal	May 2011
Emergent ferromagnetism near three-quarters filling in twisted bilayer graphene Sharpe, Aaron L.; Fox, Eli J.; Barnard, Arthur W. Science, Vol. 365, Issue 6453 https://doi.org/10.1126/science.aaw3780	journal	July 2019
Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus Kim, J.; Baik, S. S.; Ryu, S. H. Science, Vol. 349, Issue 6249 https://doi.org/10.1126/science.aaa6486	journal	August 2015
Evidence of a gate-tunable Mott insulator in a trilayer graphene moiré superlattice Chen, Guorui; Jiang, Lili; Wu, Shuang Nature Physics, Vol. 15, Issue 3 https://doi.org/10.1038/s41567-018-0387-2	journal	January 2019
Signatures of moiré-trapped valley excitons in MoSe2/WSe2 heterobilayers Seyler, Kyle L.; Rivera, Pasqual; Yu, Hongyi Nature, Vol. 567, Issue 7746 https://doi.org/10.1038/s41586-019-0957-1	journal	February 2019
A simple effective potential for exchange Becke, Axel D.; Johnson, Erin R. The Journal of Chemical Physics, Vol. 124, Issue 22 https://doi.org/10.1063/1.2213970	journal	June 2006
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Tunable correlated Chern insulator and ferromagnetism in a moiré superlattice Chen, Guorui; Sharpe, Aaron L.; Fox, Eli J. Nature, Vol. 579, Issue 7797 https://doi.org/10.1038/s41586-020-2049-7	journal	March 2020
Observation of moiré excitons in WSe2/WS2 heterostructure superlattices Jin, Chenhao; Regan, Emma C.; Yan, Aiming Nature, Vol. 567, Issue 7746 https://doi.org/10.1038/s41586-019-0976-y	journal	February 2019
Evidence for moiré excitons in van der Waals heterostructures Tran, Kha; Moody, Galan; Wu, Fengcheng Nature, Vol. 567, Issue 7746 https://doi.org/10.1038/s41586-019-0975-z	journal	February 2019
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus Qiao, Jingsi; Kong, Xianghua; Hu, Zhi-Xin Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5475	journal	July 2014
Moire bands in twisted double-layer graphene Bistritzer, R.; MacDonald, A. H. Proceedings of the National Academy of Sciences, Vol. 108, Issue 30 https://doi.org/10.1073/pnas.1108174108	journal	July 2011
Correlated insulator behaviour at half-filling in magic-angle graphene superlattices Cao, Yuan; Fatemi, Valla; Demir, Ahmet Nature, Vol. 556, Issue 7699 https://doi.org/10.1038/nature26154	journal	March 2018
One-Dimensional Electrical Contact to a Two-Dimensional Material Wang, L.; Meric, I.; Huang, P. Y. Science, Vol. 342, Issue 6158 https://doi.org/10.1126/science.1244358	journal	October 2013
Van der Waals Density Functional for General Geometries Dion, M.; Rydberg, H.; Schröder, E. Physical Review Letters, Vol. 92, Issue 24 https://doi.org/10.1103/PhysRevLett.92.246401	journal	June 2004
Strain-tunable van der Waals interactions in few-layer black phosphorus Huang, Shenyang; Zhang, Guowei; Fan, Fengren Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10483-8	journal	June 2019
Au ₃ SnP ₇ @Black Phosphorus: An Easy Access to Black Phosphorus Lange, Stefan; Schmidt, Peer; Nilges, Tom Inorganic Chemistry, Vol. 46, Issue 10 https://doi.org/10.1021/ic062192q	journal	May 2007
Direct observation of the layer-dependent electronic structure in phosphorene Li, Likai; Kim, Jonghwan; Jin, Chenhao Nature Nanotechnology, Vol. 12, Issue 1 https://doi.org/10.1038/nnano.2016.171	journal	September 2016
Observation of fractional Chern insulators in a van der Waals heterostructure Spanton, Eric M.; Zibrov, Alexander A.; Zhou, Haoxin Science, Vol. 360, Issue 6384 https://doi.org/10.1126/science.aan8458	journal	March 2018
Tuning superconductivity in twisted bilayer graphene Yankowitz, Matthew; Chen, Shaowen; Polshyn, Hryhoriy Science, Vol. 363, Issue 6431 https://doi.org/10.1126/science.aav1910	journal	January 2019
Phosphorene: from theory to applications Carvalho, Alexandra; Wang, Min; Zhu, Xi Nature Reviews Materials, Vol. 1, Issue 11 https://doi.org/10.1038/natrevmats.2016.61	journal	August 2016
Signatures of tunable superconductivity in a trilayer graphene moiré superlattice Chen, Guorui; Sharpe, Aaron L.; Gallagher, Patrick Nature, Vol. 572, Issue 7768 https://doi.org/10.1038/s41586-019-1393-y	journal	July 2019
Two-dimensional van der Waals materials Ajayan, Pulickel; Kim, Philip; Banerjee, Kaustav Physics Today, Vol. 69, Issue 9 https://doi.org/10.1063/PT.3.3297	journal	September 2016
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility Liu, Han; Neal, Adam T.; Zhu, Zhen ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn501226z	journal	March 2014
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Accurate Band Gaps of Semiconductors and Insulators with a Semilocal Exchange-Correlation Potential Tran, Fabien; Blaha, Peter Physical Review Letters, Vol. 102, Issue 22 https://doi.org/10.1103/PhysRevLett.102.226401	journal	June 2009
Access and in situ growth of phosphorene-precursor black phosphorus Köpf, Marianne; Eckstein, Nadine; Pfister, Daniela Journal of Crystal Growth, Vol. 405 https://doi.org/10.1016/j.jcrysgro.2014.07.029	journal	November 2014
The Atomic Distribution in Red and Black Phosphorus and the Crystal Structure of Black Phosphorus Hultgren, Ralph; Gingrich, N. S.; Warren, B. E. The Journal of Chemical Physics, Vol. 3, Issue 6 https://doi.org/10.1063/1.1749671	journal	June 1935
Probing Symmetry Properties of Few-Layer MoS ₂ and h-BN by Optical Second-Harmonic Generation Li, Yilei; Rao, Yi; Mak, Kin Fai Nano Letters, Vol. 13, Issue 7 https://doi.org/10.1021/nl401561r	journal	June 2013
Black phosphorus field-effect transistors Li, Likai; Yu, Yijun; Ye, Guo Jun Nature Nanotechnology, Vol. 9, Issue 5 https://doi.org/10.1038/nnano.2014.35	journal	March 2014
Resonantly hybridized excitons in moiré superlattices in van der Waals heterostructures Alexeev, Evgeny M.; Ruiz-Tijerina, David A.; Danovich, Mark Nature, Vol. 567, Issue 7746 https://doi.org/10.1038/s41586-019-0986-9	journal	March 2019
Simulations of twisted bilayer orthorhombic black phosphorus Pan, Douxing; Wang, Tzu-Chiang; Xiao, Wende Physical Review B, Vol. 96, Issue 4 https://doi.org/10.1103/PhysRevB.96.041411	journal	July 2017

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