Secondary Ion Mass Spectrometry (SIMS) for Chemical Characterization of Metal Halide Perovskites

Liu, Yongtao; Lorenz, Matthias; Ievlev, Anton; Ovchinnikova, Olga S.

doi:10.1002/adfm.202002201

Title: Secondary Ion Mass Spectrometry (SIMS) for Chemical Characterization of Metal Halide Perovskites

Journal Article · Thu Jun 18 00:00:00 EDT 2020 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202002201· OSTI ID:1661235

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Metal halide perovskite (MHP) solar cells have attracted much attention due to the rapidly growing power conversion efficiency that has reached 25.2% in a decade, comparable to established commercial photovoltaic modules. Compositional engineering is one of the most effective methods to boost the performance of MHP solar cells. Further improving the efficiency and the stability of MHP solar cells necessitates good understanding of the chemical–efficiency correlation and the chemical evolution during the degradation of MHP solar cells. In this regard, time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a powerful tool to investigate the chemical aspect of MHPs and has played an important role in advancing the development of MHP optoelectronics. However, up to date, a review that can guide future utilization of ToF-SIMS in the MHP development is missing. In this paper, the capabilities of ToF-SIMS in MHP investigations are summarized and analyzed from simple material synthesis and chemical distribution to more complicated device operation mechanism and stability. The strength of ToF-SIMS in resolving important issues in this field, such as interface composition, ion migration, and degradation in MHP is highlighted. Finally, an outlook with an emphasis on making the utmost of ToF-SIMS in developing MHP devices is provided.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1661235

Alternate ID(s):: OSTI ID: 1633838

Journal Information:: Advanced Functional Materials, Vol. 30, Issue 35; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 27 works

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References (191)

Suppressed Ion Migration in Reduced-Dimensional Perovskites Improves Operating Stability Huang, Ziru; Proppe, Andrew H.; Tan, Hairen ACS Energy Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsenergylett.9b00892	journal	June 2019
Exciton Binding Energy and the Nature of Emissive States in Organometal Halide Perovskites Zheng, Kaibo; Zhu, Qiushi; Abdellah, Mohamed The Journal of Physical Chemistry Letters, Vol. 6, Issue 15 https://doi.org/10.1021/acs.jpclett.5b01252	journal	July 2015
In Situ Passivation on Rear Perovskite Interface for Efficient and Stable Perovskite Solar Cells Wang, Gaoxiang; Wang, Lipeng; Qiu, Jianhang ACS Applied Materials & Interfaces, Vol. 12, Issue 6 https://doi.org/10.1021/acsami.9b18572	journal	January 2020
High Resolution Multimodal Chemical Imaging Platform for Organics and Inorganics Kim, Songkil; Trofimov, Artem; Khanom, Fouzia Analytical Chemistry, Vol. 91, Issue 19 https://doi.org/10.1021/acs.analchem.9b03377	journal	September 2019
Efficient Perovskite Solar Cells Fabricated by Co Partially Substituted Hybrid Perovskite Xu, Wenzhan; Zheng, Luyao; Zhang, Xiaotao Advanced Energy Materials, Vol. 8, Issue 14 https://doi.org/10.1002/aenm.201703178	journal	January 2018
Understanding the Role of Cesium and Rubidium Additives in Perovskite Solar Cells: Trap States, Charge Transport, and Recombination Hu, Yinghong; Hutter, Eline M.; Rieder, Philipp Advanced Energy Materials, Vol. 8, Issue 16 https://doi.org/10.1002/aenm.201703057	journal	January 2018
Strain–Chemical Gradient and Polarization in Metal Halide Perovskites Liu, Yongtao; Ievlev, Anton V.; Collins, Liam Advanced Electronic Materials, Vol. 6, Issue 4 https://doi.org/10.1002/aelm.201901235	journal	April 2020
Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells Zhao, Jingjing; Deng, Yehao; Wei, Haotong Science Advances, Vol. 3, Issue 11 https://doi.org/10.1126/sciadv.aao5616	journal	November 2017
High‐Performance Perovskite Solar Cells with Excellent Humidity and Thermo‐Stability via Fluorinated Perylenediimide Yang, Jia; Liu, Cong; Cai, Chunsheng Advanced Energy Materials, Vol. 9, Issue 18 https://doi.org/10.1002/aenm.201900198	journal	March 2019
Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S. Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0067-y	journal	January 2018
Highly efficient perovskite solar cells with a compositionally engineered perovskite/hole transporting material interface Cho, Kyung Taek; Paek, Sanghyun; Grancini, Giulia Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE03182J	journal	January 2017
Cesium Halides-Assisted Crystal Growth of Perovskite Films for Efficient Planar Heterojunction Solar Cells Liu, Tingting; Lai, Hongtao; Wan, Xiangjian Chemistry of Materials, Vol. 30, Issue 15 https://doi.org/10.1021/acs.chemmater.8b02002	journal	July 2018
Graded Bandgap Perovskite with Intrinsic n–p Homojunction Expands Photon Harvesting Range and Enables All Transport Layer‐Free Perovskite Solar Cells Sun, Haoxuan; Deng, Kaimo; Xiong, Jie Advanced Energy Materials, Vol. 10, Issue 8 https://doi.org/10.1002/aenm.201903347	journal	January 2020
Processing Solvent-Dependent Electronic and Structural Properties of Cesium Lead Triiodide Thin Films Ramadan, Alexandra J.; Rochford, Luke A.; Fearn, Sarah The Journal of Physical Chemistry Letters, Vol. 8, Issue 17 https://doi.org/10.1021/acs.jpclett.7b01677	journal	August 2017
Efficient, stable solar cells by using inherent bandgap of α-phase formamidinium lead iodide Min, Hanul; Kim, Maengsuk; Lee, Seung-Un Science, Vol. 366, Issue 6466 https://doi.org/10.1126/science.aay7044	journal	November 2019
Insights into the increased degradation rate of CH ₃ NH ₃ PbI ₃ solar cells in combined water and O ₂ environments Aristidou, Nick; Eames, Christopher; Islam, M. Saiful Journal of Materials Chemistry A, Vol. 5, Issue 48 https://doi.org/10.1039/C7TA06841G	journal	January 2017
Engineering Multiphase Metal Halide Perovskites Thin Films for Stable and Efficient Solar Cells Kim, Min; Figueroa‐Tapia, Jetsabel M.; Prato, Mirko Advanced Energy Materials, Vol. 10, Issue 8 https://doi.org/10.1002/aenm.201903221	journal	January 2020
The Second Spacer Cation Assisted Growth of a 2D Perovskite Film with Oriented Large Grain for Highly Efficient and Stable Solar Cells Lian, Xiaomei; Chen, Jiehuan; Qin, Minchao Angewandte Chemie International Edition, Vol. 58, Issue 28 https://doi.org/10.1002/anie.201902959	journal	May 2019
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design Saparov, Bayrammurad; Mitzi, David B. Chemical Reviews, Vol. 116, Issue 7 https://doi.org/10.1021/acs.chemrev.5b00715	journal	March 2016
A Printable Organic Electron Transport Layer for Low-Temperature-Processed, Hysteresis-Free, and Stable Planar Perovskite Solar Cells Lee, Jinho; Kim, Junghwan; Lee, Chang-Lyoul Advanced Energy Materials, Vol. 7, Issue 15 https://doi.org/10.1002/aenm.201700226	journal	April 2017
Mutual Insight on Ferroelectrics and Hybrid Halide Perovskites: A Platform for Future Multifunctional Energy Conversion Pandey, Richa; Vats, Gaurav; Yun, Jae Advanced Materials, Vol. 31, Issue 43 https://doi.org/10.1002/adma.201807376	journal	August 2019
Dimensional Engineering of a Graded 3D-2D Halide Perovskite Interface Enables Ultrahigh V _oc Enhanced Stability in the p-i-n Photovoltaics Bai, Yang; Xiao, Shuang; Hu, Chen Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701038	journal	July 2017
Direct Evidence of Ion-Migration-Induced Degradation of Ultrabright Perovskite Light-Emitting Diodes Lee, Hyunho; Ko, Donghyun; Lee, Changhee ACS Applied Materials & Interfaces, Vol. 11, Issue 12 https://doi.org/10.1021/acsami.8b22217	journal	March 2019
Thermodynamically stabilized β-CsPbI ₃ –based perovskite solar cells with efficiencies >18% Wang, Yong; Dar, M. Ibrahim; Ono, Luis K. Science, Vol. 365, Issue 6453 https://doi.org/10.1126/science.aav8680	journal	August 2019
Observation of Enhanced Hole Extraction in Br Concentration Gradient Perovskite Materials Kim, Min-cheol; Kim, Byeong Jo; Son, Dae-Yong Nano Letters, Vol. 16, Issue 9 https://doi.org/10.1021/acs.nanolett.6b02473	journal	August 2016
Direct Imaging of Current‐Induced Transformation of a Perovskite/Electrode Interface Drozdov, Mikhail N.; Yunin, Pavel A.; Travkin, Vlad V. Advanced Materials Interfaces, Vol. 6, Issue 12 https://doi.org/10.1002/admi.201900364	journal	April 2019
Novel Surface Passivation Technique for Low-Temperature Solution-Processed Perovskite PV Cells Tripathi, Neeti; Shirai, Yasuhiro; Yanagida, Masatoshi ACS Applied Materials & Interfaces, Vol. 8, Issue 7 https://doi.org/10.1021/acsami.5b11286	journal	February 2016
Catalytic metal-induced crystallization of sol–gel metal oxides for high-efficiency flexible perovskite solar cells Hou, Cheng-Hung; Shyue, Jing-Jong; Su, Wei-Fang Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/C8TA05973J	journal	January 2018
Spatially Resolved Carrier Dynamics at MAPbBr ₃ Single Crystal–Electrode Interface Ahmadi, Mahshid; Collins, Liam; Higgins, Kate ACS Applied Materials & Interfaces, Vol. 11, Issue 44 https://doi.org/10.1021/acsami.9b16287	journal	October 2019
FA _0.88 Cs _0.12 PbI ₃₋ _x (PF ₆ ) _x Interlayer Formed by Ion Exchange Reaction between Perovskite and Hole Transporting Layer for Improving Photovoltaic Performance and Stability Chen, Jiangzhao; Kim, Seul-Gi; Park, Nam-Gyu Advanced Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adma.201801948	journal	August 2018
Effect of Rubidium Incorporation on the Structural, Electrical, and Photovoltaic Properties of Methylammonium Lead Iodide-Based Perovskite Solar Cells Park, Ik Jae; Seo, Seongrok; Park, Min Ah ACS Applied Materials & Interfaces, Vol. 9, Issue 48 https://doi.org/10.1021/acsami.7b13947	journal	November 2017
Photoinduced Lattice Symmetry Enhancement in Mixed Hybrid Perovskites and Its Beneficial Effect on the Recombination Behavior Kim, Hui‐Seon; Hagfeldt, Anders Advanced Optical Materials, Vol. 7, Issue 9 https://doi.org/10.1002/adom.201801512	journal	February 2019
Carrier lifetimes of >1 μs in Sn-Pb perovskites enable efficient all-perovskite tandem solar cells Tong, Jinhui; Song, Zhaoning; Kim, Dong Hoe Science, Vol. 364, Issue 6439 https://doi.org/10.1126/science.aav7911	journal	April 2019
Perovskite solar cell towards lower toxicity: a theoretical study of physical lead reduction strategy Zheng, Yifan; Su, Rui; Xu, Zhaojian Science Bulletin, Vol. 64, Issue 17 https://doi.org/10.1016/j.scib.2019.06.006	journal	September 2019
Synthetic control over orientational degeneracy of spacer cations enhances solar cell efficiency in two-dimensional perovskites Hu, Jun; Oswald, Iain W. H.; Stuard, Samuel J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08980-x	journal	March 2019
Infiltration of methylammonium metal halide in highly porous membranes using sol-gel-derived coating method Kwon, Seung Lee; Jin, Young Un; Kim, Byeong Jo Applied Surface Science, Vol. 416 https://doi.org/10.1016/j.apsusc.2017.04.124	journal	September 2017
[6,6]-Phenyl-C ₆₁ -Butyric Acid Methyl Ester/Cerium Oxide Bilayer Structure as Efficient and Stable Electron Transport Layer for Inverted Perovskite Solar Cells Fang, Rui; Wu, Shaohang; Chen, Weitao ACS Nano, Vol. 12, Issue 3 https://doi.org/10.1021/acsnano.7b07754	journal	February 2018
General Post-annealing Method Enables High-Efficiency Two-Dimensional Perovskite Solar Cells Yan, Liang; Hu, Jun; Guo, Zhenkun ACS Applied Materials & Interfaces, Vol. 10, Issue 39 https://doi.org/10.1021/acsami.8b10230	journal	September 2018
Electroabsorption Spectroscopy Measurements of the Exciton Binding Energy, Electron–Hole Reduced Effective Mass, and Band Gap in the Perovskite CH ₃ NH ₃ PbI ₃ Ziffer, Mark E.; Mohammed, Joseph C.; Ginger, David S. ACS Photonics, Vol. 3, Issue 6 https://doi.org/10.1021/acsphotonics.6b00139	journal	April 2016
Electron-hole diffusion lengths > 175 μm in solution-grown CH ₃ NH ₃ PbI ₃ single crystals Dong, Qingfeng; Fang, Yanjun; Shao, Yuchuan Science, Vol. 347, Issue 6225 https://doi.org/10.1126/science.aaa5760	journal	January 2015
Lead-Free All-Inorganic Cesium Tin Iodide Perovskite for Filamentary and Interface-Type Resistive Switching toward Environment-Friendly and Temperature-Tolerant Nonvolatile Memories Han, Ji Su; Le, Quyet Van; Choi, Jaeho ACS Applied Materials & Interfaces, Vol. 11, Issue 8 https://doi.org/10.1021/acsami.8b15769	journal	January 2019
Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells Aristidou, Nicholas; Eames, Christopher; Sanchez-Molina, Irene Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15218	journal	May 2017
Degradation of Highly Alloyed Metal Halide Perovskite Precursor Inks: Mechanism and Storage Solutions Dou, Benjia; Wheeler, Lance M.; Christians, Jeffrey A. ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00305	journal	March 2018
A Mechanically Robust Conducting Polymer Network Electrode for Efficient Flexible Perovskite Solar Cells Hu, Xiaotian; Meng, Xiangchuan; Zhang, Lin Joule, Vol. 3, Issue 9 https://doi.org/10.1016/j.joule.2019.06.011	journal	September 2019
Spin control in reduced-dimensional chiral perovskites Long, Guankui; Jiang, Chongyun; Sabatini, Randy Nature Photonics, Vol. 12, Issue 9 https://doi.org/10.1038/s41566-018-0220-6	journal	August 2018
The Relationship between Chemical Flexibility and Nanoscale Charge Collection in Hybrid Halide Perovskites Luo, Yanqi; Aharon, Sigalit; Stuckelberger, Michael Advanced Functional Materials, Vol. 28, Issue 18 https://doi.org/10.1002/adfm.201706995	journal	March 2018
Interface and Composition Analysis on Perovskite Solar Cells Matteocci, Fabio; Busby, Yan; Pireaux, Jean-Jacques ACS Applied Materials & Interfaces, Vol. 7, Issue 47 https://doi.org/10.1021/acsami.5b08038	journal	November 2015
Metal/Ion Interactions Induced p–i–n Junction in Methylammonium Lead Triiodide Perovskite Single Crystals Wu, Ting; Mukherjee, Rupam; Ovchinnikova, Olga S. Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b10416	journal	November 2017
Synthesis and Characterization of Multiple-Cation Rb(MAFA)PbI3 Perovskite Single Crystals Kim, Hyojung; Byun, Hye Ryung; Jeong, Mun Seok Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-38947-3	journal	February 2019
Sulfamic Acid-Catalyzed Lead Perovskite Formation for Solar Cell Fabrication on Glass or Plastic Substrates Guo, Yunlong; Sato, Wataru; Shoyama, Kazutaka Journal of the American Chemical Society, Vol. 138, Issue 16 https://doi.org/10.1021/jacs.6b02130	journal	January 2016
Quantitative Electromechanical Atomic Force Microscopy Collins, Liam; Liu, Yongtao; Ovchinnikova, Olga S. ACS Nano, Vol. 13, Issue 7 https://doi.org/10.1021/acsnano.9b02883	journal	July 2019
Large formamidinium lead trihalide perovskite solar cells using chemical vapor deposition with high reproducibility and tunable chlorine concentrations Leyden, Matthew R.; Lee, Michael V.; Raga, Sonia R. Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/C5TA03577E	journal	January 2015
Multi-cation Synergy Suppresses Phase Segregation in Mixed-Halide Perovskites Dang, Hoang X.; Wang, Kai; Ghasemi, Masoud Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.05.016	journal	July 2019
Analysis of Ion-Diffusion-Induced Interface Degradation in Inverted Perovskite Solar Cells via Restoration of the Ag Electrode Lee, Hyunho; Lee, Changhee Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702197	journal	December 2017
Rational molecular passivation for high-performance perovskite light-emitting diodes Xu, Weidong; Hu, Qi; Bai, Sai Nature Photonics, Vol. 13, Issue 6 https://doi.org/10.1038/s41566-019-0390-x	journal	March 2019
High performance perovskites solar cells by hybrid perovskites co-crystallized with poly(ethylene oxide) Wang, Kai; Zheng, Luyao; Zhu, Tao Nano Energy, Vol. 67 https://doi.org/10.1016/j.nanoen.2019.104229	journal	January 2020
PbI ₂ platelets for inverted planar organolead Halide Perovskite solar cells via ultrasonic spray deposition Chai, Gaoda; Wang, Shizhen; Xia, Zhonggao Semiconductor Science and Technology, Vol. 32, Issue 7 https://doi.org/10.1088/1361-6641/aa6e47	journal	June 2017
Tuning spin-orbit coupling towards enhancing photocurrent in hybrid organic-inorganic perovskites by using mixed organic cations Dou, Yixuan; Xu, Hengxing; Liu, Yongtao Organic Electronics, Vol. 81 https://doi.org/10.1016/j.orgel.2020.105671	journal	June 2020
Not All That Glitters Is Gold: Metal-Migration-Induced Degradation in Perovskite Solar Cells Domanski, Konrad; Correa-Baena, Juan-Pablo; Mine, Nicolas ACS Nano, Vol. 10, Issue 6 https://doi.org/10.1021/acsnano.6b02613	journal	May 2016
Time resolved surface photovoltage measurements using a big data capture approach to KPFM Collins, Liam; Ahmadi, Mahshid; Qin, Jiajun Nanotechnology, Vol. 29, Issue 44 https://doi.org/10.1088/1361-6528/aad873	journal	September 2018
Correlated Materials Characterization via Multimodal Chemical and Functional Imaging Belianinov, Alex; Ievlev, Anton V.; Lorenz, Matthias ACS Nano, Vol. 12, Issue 12 https://doi.org/10.1021/acsnano.8b07292	journal	November 2018
Targeted Ligand-Exchange Chemistry on Cesium Lead Halide Perovskite Quantum Dots for High-Efficiency Photovoltaics Wheeler, Lance M.; Sanehira, Erin M.; Marshall, Ashley R. Journal of the American Chemical Society, Vol. 140, Issue 33 https://doi.org/10.1021/jacs.8b04984	journal	July 2018
Plasmon resonance scattering at perovskite CH ₃ NH ₃ PbI ₃ coated single gold nanoparticles: evidence for electron transfer Xu, Duo; Liu, Dong; Xie, Tao Chemical Communications, Vol. 52, Issue 64 https://doi.org/10.1039/C6CC04283J	journal	January 2016
Dynamic behavior of CH ₃ NH ₃ PbI ₃ perovskite twin domains Liu, Yongtao; Collins, Liam; Belianinov, Alex Applied Physics Letters, Vol. 113, Issue 7 https://doi.org/10.1063/1.5041256	journal	August 2018
The role of interface between electron transport layer and perovskite in halogen migration and stabilizing perovskite solar cells with Cs ₄ SnO ₄ Zhao, Bingxin; Niu, Guangda; Dong, Qingshun Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/C8TA09382B	journal	January 2018
Imaging Metal Halide Perovskites Material and Properties at the Nanoscale Howard, John M.; Lahoti, Richa; Leite, Marina S. Advanced Energy Materials https://doi.org/10.1002/aenm.201903161	journal	December 2019
Efficient Defect Passivation for Perovskite Solar Cells by Controlling the Electron Density Distribution of Donor‐π‐Acceptor Molecules Wu, Tianhao; Wang, Yanbo; Li, Xing Advanced Energy Materials, Vol. 9, Issue 17 https://doi.org/10.1002/aenm.201803766	journal	March 2019
Perovskite/Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] Bulk Heterojunction for High-Efficient Carbon-Based Large-Area Solar Cells by Gradient Engineering Han, Jianhua; Yin, Xuewen; Zhou, Yu ACS Applied Materials & Interfaces, Vol. 10, Issue 49 https://doi.org/10.1021/acsami.8b15399	journal	November 2018
Excitons versus free charges in organo-lead tri-halide perovskites D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4586	journal	April 2014
Light-induced lattice expansion leads to high-efficiency perovskite solar cells Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean-Christophe Science, Vol. 360, Issue 6384 https://doi.org/10.1126/science.aap8671	journal	April 2018
In Situ Back‐Contact Passivation Improves Photovoltage and Fill Factor in Perovskite Solar Cells Tan, Furui; Tan, Hairen; Saidaminov, Makhsud I. Advanced Materials, Vol. 31, Issue 14 https://doi.org/10.1002/adma.201807435	journal	February 2019
Introducing optically polarizable molecules into perovskite solar cells by simultaneously enhanced spin–orbital coupling, suppressed non-radiative recombination and improved transport balance towards enhancing photovoltaic actions Han, Changfeng; Yu, Haomiao; Duan, Jiashun Journal of Materials Chemistry C, Vol. 6, Issue 23 https://doi.org/10.1039/C8TC01033A	journal	January 2018
Ferroelastic Fingerprints in Methylammonium Lead Iodide Perovskite Hermes, Ilka M.; Bretschneider, Simon A.; Bergmann, Victor W. The Journal of Physical Chemistry C, Vol. 120, Issue 10 https://doi.org/10.1021/acs.jpcc.5b11469	journal	January 2016
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
Precursor purity effects on solution-based growth of MAPbBr ₃ single crystals towards efficient radiation sensing Tisdale, Jeremy T.; Smith, Travis; Salasin, John Robert CrystEngComm, Vol. 20, Issue 48 https://doi.org/10.1039/C8CE01498A	journal	January 2018
Direct Evidence of Ion Diffusion for the Silver-Electrode-Induced Thermal Degradation of Inverted Perovskite Solar Cells Li, Jiangwei; Dong, Qingshun; Li, Nan Advanced Energy Materials, Vol. 7, Issue 14 https://doi.org/10.1002/aenm.201602922	journal	March 2017
3D In Situ ToF-SIMS Imaging of Perovskite Films under Controlled Humidity Environmental Conditions Lin, Wei-Chun; Chang, Hsun-Yun; Abbasi, Kevin Advanced Materials Interfaces, Vol. 4, Issue 2 https://doi.org/10.1002/admi.201600673	journal	December 2016
Probing Perovskite Inhomogeneity beyond the Surface: TOF-SIMS Analysis of Halide Perovskite Photovoltaic Devices Harvey, Steven P.; Li, Zhen; Christians, Jeffrey A. ACS Applied Materials & Interfaces, Vol. 10, Issue 34 https://doi.org/10.1021/acsami.8b07937	journal	July 2018
In situ growth of perovskite stacking layers for high-efficiency carbon-based hole conductor free perovskite solar cells Liu, Jianhua; Zhou, Qisen; Thein, Nan Kyi Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/C9TA02772F	journal	January 2019
Probing Strain-Induced Band Gap Modulation in 2D Hybrid Organic–Inorganic Perovskites Tu, Qing; Spanopoulos, Ioannis; Hao, Shiqiang ACS Energy Letters, Vol. 4, Issue 3 https://doi.org/10.1021/acsenergylett.9b00120	journal	February 2019
High efficiency perovskite quantum dot solar cells with charge separating heterostructure Zhao, Qian; Hazarika, Abhijit; Chen, Xihan Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10856-z	journal	June 2019
Chemical nature of ferroelastic twin domains in CH3NH3PbI3 perovskite Liu, Yongtao; Collins, Liam; Proksch, Roger Nature Materials, Vol. 17, Issue 11 https://doi.org/10.1038/s41563-018-0152-z	journal	August 2018
Deciphering Halogen Competition in Organometallic Halide Perovskite Growth Yang, Bin; Keum, Jong; Ovchinnikova, Olga S. Journal of the American Chemical Society, Vol. 138, Issue 15 https://doi.org/10.1021/jacs.5b13254	journal	March 2016
Comparison of Recombination Dynamics in CH ₃ NH ₃ PbBr ₃ and CH ₃ NH ₃ PbI ₃ Perovskite Films: Influence of Exciton Binding Energy Yang, Ye; Yang, Mengjin; Li, Zhen The Journal of Physical Chemistry Letters, Vol. 6, Issue 23 https://doi.org/10.1021/acs.jpclett.5b02290	journal	November 2015
Twin domains modulate light-matter interactions in metal halide perovskites Liu, Yongtao; Li, Mingxing; Wang, Miaosheng APL Materials, Vol. 8, Issue 1 https://doi.org/10.1063/1.5127866	journal	January 2020
Reversible and Irreversible Electric Field Induced Morphological and Interfacial Transformations of Hybrid Lead Iodide Perovskites Luchkin, Sergey Yu.; Akbulatov, Azat F.; Frolova, Lyubov A. ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b01960	journal	April 2017
Compositional engineering of perovskite materials for high-performance solar cells Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok Nature, Vol. 517, Issue 7535 https://doi.org/10.1038/nature14133	journal	January 2015
Universal passivation strategy to slot-die printed SnO2 for hysteresis-free efficient flexible perovskite solar module Bu, Tongle; Li, Jing; Zheng, Fei Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07099-9	journal	November 2018
Combustion Synthesized Zinc Oxide Electron‐Transport Layers for Efficient and Stable Perovskite Solar Cells Zheng, Ding; Wang, Gang; Huang, Wei Advanced Functional Materials, Vol. 29, Issue 16 https://doi.org/10.1002/adfm.201900265	journal	February 2019
Doped hole transport layer for efficiency enhancement in planar heterojunction organolead trihalide perovskite solar cells Wang, Qi; Bi, Cheng; Huang, Jinsong Nano Energy, Vol. 15 https://doi.org/10.1016/j.nanoen.2015.04.029	journal	July 2015
Efficiently Improving the Stability of Inverted Perovskite Solar Cells by Employing Polyethylenimine-Modified Carbon Nanotubes as Electrodes Zhou, Yu; Yin, Xuewen; Luo, Qiang ACS Applied Materials & Interfaces, Vol. 10, Issue 37 https://doi.org/10.1021/acsami.8b10253	journal	August 2018
Determination of the exciton binding energy and effective masses for methylammonium and formamidinium lead tri-halide perovskite semiconductors Galkowski, Krzysztof; Mitioglu, Anatolie; Miyata, Atsuhiko Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03435C	journal	January 2016
Fullerene-Anchored Core-Shell ZnO Nanoparticles for Efficient and Stable Dual-Sensitized Perovskite Solar Cells Yao, Kai; Leng, Shifeng; Liu, Zhiliang Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2018.10.018	journal	February 2019
Small Cyclic Diammonium Cation Templated (110)-Oriented 2D Halide (X = I, Br, Cl) Perovskites with White-Light Emission Li, Xiaotong; Guo, Peijun; Kepenekian, Mikaël Chemistry of Materials, Vol. 31, Issue 9 https://doi.org/10.1021/acs.chemmater.9b01511	journal	April 2019
Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells Domanski, Konrad; Roose, Bart; Matsui, Taisuke Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE03352K	journal	January 2017
CH ₃ NH ₃ PbI ₃ perovskites: Ferroelasticity revealed Strelcov, Evgheni; Dong, Qingfeng; Li, Tao Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1602165	journal	April 2017
Transamidation of dimethylformamide during alkylammonium lead triiodide film formation for perovskite solar cells Lee, Michael V.; Raga, Sonia R.; Kato, Yuichi Journal of Materials Research, Vol. 32, Issue 1 https://doi.org/10.1557/jmr.2016.272	journal	July 2016
Stabilization of Precursor Solution and Perovskite Layer by Addition of Sulfur Min, Hanul; Kim, Gwisu; Paik, Min Jae Advanced Energy Materials, Vol. 9, Issue 17 https://doi.org/10.1002/aenm.201803476	journal	March 2019
Boosting the Efficiency of Perovskite Solar Cells with CsBr-Modified Mesoporous TiO ₂ Beads as Electron-Selective Contact Seo, Ji-Youn; Uchida, Ryusuke; Kim, Hui-Seon Advanced Functional Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adfm.201705763	journal	December 2017
Molecule-Doped Nickel Oxide: Verified Charge Transfer and Planar Inverted Mixed Cation Perovskite Solar Cell Chen, Wei; Zhou, Yecheng; Wang, Linjing Advanced Materials, Vol. 30, Issue 20 https://doi.org/10.1002/adma.201800515	journal	March 2018
Probing the Degradation Chemistry and Enhanced Stability of 2D Organolead Halide Perovskites Wygant, Bryan R.; Ye, Alexandre Z.; Dolocan, Andrei Journal of the American Chemical Society, Vol. 141, Issue 45 https://doi.org/10.1021/jacs.9b08895	journal	October 2019
Efficient and Stable CsPbI 3 Solar Cells via Regulating Lattice Distortion with Surface Organic Terminal Groups Wu, Tianhao; Wang, Yanbo; Dai, Zhensheng Advanced Materials https://doi.org/10.1002/adma.201900605	journal	April 2019
Efficient perovskite solar cells by hybrid perovskites incorporated with heterovalent neodymium cations Wang, Kai; Zheng, Luyao; Zhu, Tao Nano Energy, Vol. 61 https://doi.org/10.1016/j.nanoen.2019.04.073	journal	July 2019
Alkali Metal Halide Salts as Interface Additives to Fabricate Hysteresis-Free Hybrid Perovskite-Based Photovoltaic Devices Wang, Lili; Moghe, Dhanashree; Hafezian, Soroush ACS Applied Materials & Interfaces, Vol. 8, Issue 35 https://doi.org/10.1021/acsami.6b07368	journal	August 2016
ToF-SIMS Depth Profiling of Organic Delta Layers with Low-Energy Cesium Ions: Depth Resolution Assessment Noël, Céline; Busby, Yan; Mine, Nicolas Journal of The American Society for Mass Spectrometry, Vol. 30, Issue 8 https://doi.org/10.1007/s13361-019-02224-4	journal	May 2019
Polystyrene stabilized perovskite component, grain and microstructure for improved efficiency and stability of planar solar cells Zhang, Huiyin; Shi, Jiangjian; Zhu, Lifeng Nano Energy, Vol. 43 https://doi.org/10.1016/j.nanoen.2017.11.024	journal	January 2018
Highly Efficient and Stable Solar Cells Based on Crystalline Oriented 2D/3D Hybrid Perovskite Zhou, Tong; Lai, Hongtao; Liu, Tingting Advanced Materials https://doi.org/10.1002/adma.201901242	journal	June 2019
Protocols for Three-Dimensional Molecular Imaging Using Mass Spectrometry Wucher, Andreas; Cheng, Juan; Winograd, Nicholas Analytical Chemistry, Vol. 79, Issue 15 https://doi.org/10.1021/ac070692a	journal	August 2007
Identifying and controlling phase purity in 2D hybrid perovskite thin films Hu, Yinghong; Spies, Laura M.; Alonso-Álvarez, Diego Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/C8TA05475D	journal	January 2018
Relaying delivery of excited state electrons for fully printable perovskite solar cells via ultra-thin gradient PCBM/perovskite heterojunction Xu, Liang; Li, Chen; Zhong, Ya Solar Energy, Vol. 187 https://doi.org/10.1016/j.solener.2019.05.055	journal	July 2019
Interface‐Modification‐Induced Gradient Energy Band for Highly Efficient CsPbIBr ₂ Perovskite Solar Cells Subhani, Waqas Siddique; Wang, Kai; Du, Minyong Advanced Energy Materials, Vol. 9, Issue 21 https://doi.org/10.1002/aenm.201803785	journal	April 2019
Extrinsic ion migration in perovskite solar cells Li, Zhen; Xiao, Chuanxiao; Yang, Ye Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/C7EE00358G	journal	January 2017
Local Crystal Misorientation Influences Non-radiative Recombination in Halide Perovskites Jariwala, Sarthak; Sun, Hongyu; Adhyaksa, Gede W. P. Joule, Vol. 3, Issue 12 https://doi.org/10.1016/j.joule.2019.09.001	journal	December 2019
Colloidally prepared La-doped BaSnO ₃ electrodes for efficient, photostable perovskite solar cells Shin, Seong Sik; Yeom, Eun Joo; Yang, Woon Seok Science, Vol. 356, Issue 6334 https://doi.org/10.1126/science.aam6620	journal	March 2017
Highly Efficient and Stable Inverted Perovskite Solar Cell Obtained via Treatment by Semiconducting Chemical Additive Yu, Jae Choul; Badgujar, Sachin; Jung, Eui Dae Advanced Materials https://doi.org/10.1002/adma.201805554	journal	December 2018
Investigation of Electrode Electrochemical Reactions in CH ₃ NH ₃ PbBr ₃ Perovskite Single‐Crystal Field‐Effect Transistors Wang, Junzhan; Senanayak, Satyaprasad P.; Liu, Jie Advanced Materials, Vol. 31, Issue 35 https://doi.org/10.1002/adma.201902618	journal	July 2019
Diversity of band gap and photoluminescence properties of lead halide perovskite: A halogen-dependent spectroscopic study Yu, Wenlei; Jiang, Yunfeng; Zhu, Xiuwei Chemical Physics Letters, Vol. 699 https://doi.org/10.1016/j.cplett.2018.03.052	journal	May 2018
Highly Efficient Sn/Pb Binary Perovskite Solar Cell via Precursor Engineering: A Two-Step Fabrication Process Lian, Xiaomei; Chen, Jiehuan; Zhang, Yingzhu Advanced Functional Materials, Vol. 29, Issue 5 https://doi.org/10.1002/adfm.201807024	journal	December 2018
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
Unravelling the Improved Electronic and Structural Properties of Methylammonium Lead Iodide Deposited from Acetonitrile Ramadan, Alexandra J.; Noel, Nakita K.; Fearn, Sarah Chemistry of Materials, Vol. 30, Issue 21 https://doi.org/10.1021/acs.chemmater.8b03084	journal	October 2018
Heterogeneity at multiple length scales in halide perovskite semiconductors Tennyson, Elizabeth M.; Doherty, Tiarnan A. S.; Stranks, Samuel D. Nature Reviews Materials, Vol. 4, Issue 9 https://doi.org/10.1038/s41578-019-0125-0	journal	July 2019
Ion-Migration Inhibition by the Cation-π Interaction in Perovskite Materials for Efficient and Stable Perovskite Solar Cells Wei, Dong; Ma, Fusheng; Wang, Rui Advanced Materials, Vol. 30, Issue 31 https://doi.org/10.1002/adma.201707583	journal	June 2018
Mobile-Ion-Induced Degradation of Organic Hole-Selective Layers in Perovskite Solar Cells Zhao, Yicheng; Zhou, Wenke; Tan, Hairen The Journal of Physical Chemistry C, Vol. 121, Issue 27 https://doi.org/10.1021/acs.jpcc.7b04684	journal	June 2017
Efficient Perovskite Solar Cells Fabricated Through CsCl-Enhanced PbI ₂ Precursor via Sequential Deposition Li, Qi; Zhao, Yicheng; Fu, Rui Advanced Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adma.201803095	journal	August 2018
Light and elevated temperature induced degradation (LeTID) in perovskite solar cells and development of stable semi-transparent cells Duong, The; Wu, YiLiang; Shen, Heping Solar Energy Materials and Solar Cells, Vol. 188 https://doi.org/10.1016/j.solmat.2018.08.017	journal	December 2018
Time-Resolved Electrical Scanning Probe Microscopy of Layered Perovskites Reveals Spatial Variations in Photoinduced Ionic and Electronic Carrier Motion Giridharagopal, Rajiv; Precht, Jake T.; Jariwala, Sarthak ACS Nano, Vol. 13, Issue 3 https://doi.org/10.1021/acsnano.8b08390	journal	February 2019
High-efficiency large-area perovskite photovoltaic modules achieved via electrochemically assembled metal-filamentary nanoelectrodes Hong, Soonil; Lee, Jinho; Kang, Hongkyu Science Advances, Vol. 4, Issue 8 https://doi.org/10.1126/sciadv.aat3604	journal	August 2018
Investigating the Effects of Chemical Gradients on Performance and Reliability within Perovskite Solar Cells with TOF-SIMS Harvey, Steven P.; Messinger, Jonah; Zhu, Kai Advanced Energy Materials https://doi.org/10.1002/aenm.201903674	journal	February 2020
High Efficiency Perovskite‐Silicon Tandem Solar Cells: Effect of Surface Coating versus Bulk Incorporation of 2D Perovskite Duong, The; Pham, Huyen; Kho, Teng Choon Advanced Energy Materials, Vol. 10, Issue 9 https://doi.org/10.1002/aenm.201903553	journal	January 2020
Photostability of MAPbI ₃ Perovskite Solar Cells by Incorporating Black Phosphorus Wang, Yong; Zhang, Haijuan; Zhang, Taiyang Solar RRL, Vol. 3, Issue 9 https://doi.org/10.1002/solr.201900197	journal	May 2019
A chemically inert bismuth interlayer enhances long-term stability of inverted perovskite solar cells Wu, Shaohang; Chen, Rui; Zhang, Shasha Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09167-0	journal	March 2019
Imaging and Mapping Characterization Tools for Perovskite Solar Cells Hidalgo, Juanita; Castro‐Méndez, Andrés‐Felipe; Correa‐Baena, Juan‐Pablo Advanced Energy Materials, Vol. 9, Issue 30 https://doi.org/10.1002/aenm.201900444	journal	July 2019
Planar perovskite solar cells with long-term stability using ionic liquid additives Bai, Sai; Da, Peimei; Li, Cheng Nature, Vol. 571, Issue 7764 https://doi.org/10.1038/s41586-019-1357-2	journal	July 2019
Induced charge transfer bridge by non-fullerene surface treatment for high-performance perovskite solar cells Wang, Kai-Li; Lou, Yan-Hui; Li, Meng Applied Physics Letters, Vol. 115, Issue 18 https://doi.org/10.1063/1.5124539	journal	October 2019
Room Temperature Phase Transition in Methylammonium Lead Iodide Perovskite Thin Films Induced by Hydrohalic Acid Additives Soe, Chan Myae Myae; Stoumpos, Constantinos C.; Harutyunyan, Boris ChemSusChem, Vol. 9, Issue 18, p. 2656-2665 https://doi.org/10.1002/cssc.201600879	journal	September 2016
A Gradient Heterostructure Based on Tolerance Factor in High-Performance Perovskite Solar Cells with 0.84 Fill Factor Qiao, Hong Wei; Yang, Shuang; Wang, Yun Advanced Materials, Vol. 31, Issue 5 https://doi.org/10.1002/adma.201804217	journal	November 2018
Novel Molecular Doping Mechanism for n‐Doping of SnO ₂ via Triphenylphosphine Oxide and Its Effect on Perovskite Solar Cells Tu, Bao; Shao, Yangfan; Chen, Wei Advanced Materials, Vol. 31, Issue 15 https://doi.org/10.1002/adma.201805944	journal	January 2019
Pinning Down the Anomalous Light Soaking Effect toward High-Performance and Fast-Response Perovskite Solar Cells: The Ion-Migration-Induced Charge Accumulation Zhang, Teng; Cheung, Sin Hang; Meng, Xiangyue The Journal of Physical Chemistry Letters, Vol. 8, Issue 20 https://doi.org/10.1021/acs.jpclett.7b02160	journal	October 2017
Quantifying SIMS of Organic Mixtures and Depth Profiles—Characterizing Matrix Effects of Fragment Ions Seah, M. P.; Havelund, R.; Spencer, S. J. Journal of The American Society for Mass Spectrometry, Vol. 30, Issue 2 https://doi.org/10.1007/s13361-018-2086-8	journal	October 2018
Temperature Gradient-Induced Instability of Perovskite via Ion Transport Wang, Xinwei; Liu, Hong; Zhou, Feng ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b17798	journal	December 2017
Correlation of annealing time with crystal structure, composition, and electronic properties of CH ₃ NH ₃ PbI _3−x Cl _x mixed-halide perovskite films Ralaiarisoa, Maryline; Busby, Yan; Frisch, Johannes Physical Chemistry Chemical Physics, Vol. 19, Issue 1 https://doi.org/10.1039/C6CP06347K	journal	January 2017
Efficient lateral-structure perovskite single crystal solar cells with high operational stability Song, Yilong; Bi, Weihui; Wang, Anran Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13998-2	journal	January 2020
Compositionally Graded Absorber for Efficient and Stable Near-Infrared-Transparent Perovskite Solar Cells Fu, Fan; Pisoni, Stefano; Weiss, Thomas P. Advanced Science, Vol. 5, Issue 3 https://doi.org/10.1002/advs.201700675	journal	January 2018
Homogenizing the sulfonic acid distribution of DMF-modified PEDOT:PSS films and perovskite solar cells Li, Hongliang; Zhang, Cuiling; Ma, Yunping Journal of Energy Chemistry, Vol. 32 https://doi.org/10.1016/j.jechem.2018.06.013	journal	May 2019
Solution-Processed Polymeric Thin Film as the Transparent Electrode for Flexible Perovskite Solar Cells Zhu, Tao; Yang, Yongrui; Yao, Xiang ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b22891	journal	March 2020
Hybrid Perovskites Depth Profiling with Variable-Size Argon Clusters and Monatomic Ions Beams Noël, Céline; Pescetelli, Sara; Agresti, Antonio Materials, Vol. 12, Issue 5 https://doi.org/10.3390/ma12050726	journal	March 2019
Hybrid Inorganic Electron-Transporting Layer Coupled with a Halogen-Resistant Electrode in CsPbI ₂ Br-Based Perovskite Solar Cells to Achieve Robust Long-Term Stability Zhang, Shasha; Chen, Weitao; Wu, Shaohang ACS Applied Materials & Interfaces, Vol. 11, Issue 46 https://doi.org/10.1021/acsami.9b17464	journal	October 2019
Correlative Microscopy in 3D: Helium Ion Microscopy-Based Photogrammetric Topography Reconstruction Combined with in situ Secondary Ion Mass Spectrometry Vollnhals, Florian; Wirtz, Tom Analytical Chemistry, Vol. 90, Issue 20 https://doi.org/10.1021/acs.analchem.8b02530	journal	September 2018
Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells Ke, Weijun; Xiao, Chuanxiao; Wang, Changlei Advanced Materials, Vol. 28, Issue 26 https://doi.org/10.1002/adma.201600594	journal	May 2016
Flower-like MoS ₂ nanocrystals: a powerful sorbent of Li ⁺ in the Spiro-OMeTAD layer for highly efficient and stable perovskite solar cells Jiang, Lu-Lu; Wang, Zhao-Kui; Li, Meng Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/C8TA11800K	journal	January 2019
Intrinsic Halide Segregation at Nanometer Scale Determines the High Efficiency of Mixed Cation/Mixed Halide Perovskite Solar Cells Gratia, Paul; Grancini, Giulia; Audinot, Jean-Nicolas Journal of the American Chemical Society, Vol. 138, Issue 49 https://doi.org/10.1021/jacs.6b10049	journal	December 2016
Light‐Ferroic Interaction in Hybrid Organic–Inorganic Perovskites Liu, Yongtao; Ievlev, Anton V.; Collins, Liam Advanced Optical Materials, Vol. 7, Issue 23 https://doi.org/10.1002/adom.201901451	journal	September 2019
Perovskite solar cells with 18.21% efficiency and area over 1 cm2 fabricated by heterojunction engineering Wu, Yongzhen; Yang, Xudong; Chen, Wei Nature Energy, Vol. 1, Issue 11 https://doi.org/10.1038/nenergy.2016.148	journal	September 2016
Photo-induced halide redistribution in organic–inorganic perovskite films deQuilettes, Dane W.; Zhang, Wei; Burlakov, Victor M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11683	journal	May 2016
Unveiling a Key Intermediate in Solvent Vapor Postannealing to Enlarge Crystalline Domains of Organometal Halide Perovskite Films Xiao, Shuang; Bai, Yang; Meng, Xiangyue Advanced Functional Materials, Vol. 27, Issue 12 https://doi.org/10.1002/adfm.201604944	journal	February 2017
MAPbI ₃ Solar Cells with Absorber Deposited by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation Dunlap-Shohl, Wiley A.; Barraza, E. Tomas; Barrette, Andrew ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01144	journal	January 2018
Environmental Gating and Galvanic Effects in Single Crystals of Organic–Inorganic Halide Perovskites Ahmadi, Mahshid; Muckley, Eric S.; Ivanov, Ilia N. ACS Applied Materials & Interfaces, Vol. 11, Issue 16 https://doi.org/10.1021/acsami.8b21112	journal	April 2019
Three-Dimensional Lead Iodide Perovskitoid Hybrids with High X-ray Photoresponse Li, Xiaotong; He, Yihui; Kepenekian, Mikaël Journal of the American Chemical Society, Vol. 142, Issue 14 https://doi.org/10.1021/jacs.0c00101	journal	March 2020
Reply to: On the ferroelectricity of CH3NH3PbI3 perovskites Liu, Yongtao; Collins, Liam; Proksch, Roger Nature Materials, Vol. 18, Issue 10 https://doi.org/10.1038/s41563-019-0481-6	journal	September 2019
Chemical Approaches for Stabilizing Perovskite Solar Cells Lee, Jin‐Wook; Park, Nam‐Gyu Advanced Energy Materials, Vol. 10, Issue 1 https://doi.org/10.1002/aenm.201903249	journal	November 2019
Breaking the Time Barrier in Kelvin Probe Force Microscopy: Fast Free Force Reconstruction Using the G-Mode Platform Collins, Liam; Ahmadi, Mahshid; Wu, Ting ACS Nano, Vol. 11, Issue 9 https://doi.org/10.1021/acsnano.7b02114	journal	August 2017
Critical Role of Organic Spacers for Bright 2D Layered Perovskites Light‐Emitting Diodes Tsai, Hsinhan; Liu, Cunming; Kinigstein, Eli Advanced Science, Vol. 7, Issue 7 https://doi.org/10.1002/advs.201903202	journal	February 2020
Compositional Engineering for Thermally Stable, Highly Efficient Perovskite Solar Cells Exceeding 20% Power Conversion Efficiency with 85 °C/85% 1000 h Stability Matsui, Taisuke; Yamamoto, Teruaki; Nishihara, Takashi Advanced Materials, Vol. 31, Issue 10 https://doi.org/10.1002/adma.201806823	journal	January 2019
Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance De Wolf, Stefaan; Holovsky, Jakub; Moon, Soo-Jin The Journal of Physical Chemistry Letters, Vol. 5, Issue 6 https://doi.org/10.1021/jz500279b	journal	March 2014
Bimolecular Additives Improve Wide-Band-Gap Perovskites for Efficient Tandem Solar Cells with CIGS Kim, Dong Hoe; Muzzillo, Christopher P.; Tong, Jinhui Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.04.012	journal	July 2019
Mitigating Measurement Artifacts in TOF-SIMS Analysis of Perovskite Solar Cells Harvey, Steven P.; Zhang, Fei; Palmstrom, Axel ACS Applied Materials & Interfaces, Vol. 11, Issue 34 https://doi.org/10.1021/acsami.9b09445	journal	August 2019
Poly(ethylene oxide)-assisted energy funneling for efficient perovskite light emission Xu, Tianfei; Meng, Yan; Wang, Miaosheng Journal of Materials Chemistry C, Vol. 7, Issue 27 https://doi.org/10.1039/C9TC01906E	journal	January 2019
Lattice strain causes non-radiative losses in halide perovskites Jones, Timothy W.; Osherov, Anna; Alsari, Mejd Energy & Environmental Science, Vol. 12, Issue 2 https://doi.org/10.1039/C8EE02751J	journal	January 2019
Perovskite seeding growth of formamidinium-lead-iodide-based perovskites for efficient and stable solar cells Zhao, Yicheng; Tan, Hairen; Yuan, Haifeng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04029-7	journal	April 2018
Enhanced photovoltage for inverted planar heterojunction perovskite solar cells Luo, Deying; Yang, Wenqiang; Wang, Zhiping Science, Vol. 360, Issue 6396 https://doi.org/10.1126/science.aap9282	journal	June 2018
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Imaging mass spectrometry McDonnell, Liam A.; Heeren, Ron M. A. Mass Spectrometry Reviews, Vol. 26, Issue 4 https://doi.org/10.1002/mas.20124	journal	January 2007
Progress of Surface Science Studies on ABX ₃ ‐Based Metal Halide Perovskite Solar Cells Qiu, Longbin; He, Sisi; Ono, Luis K. Advanced Energy Materials, Vol. 10, Issue 13 https://doi.org/10.1002/aenm.201902726	journal	April 2020
Enhancing charge transport in an organic photoactive layer via vertical component engineering for efficient perovskite/organic integrated solar cells Wang, Chenyun; Bai, Yiming; Guo, Qiang Nanoscale, Vol. 11, Issue 9 https://doi.org/10.1039/C8NR09467E	journal	January 2019
In situ and real-time ToF-SIMS analysis of light-induced chemical changes in perovskite CH ₃ NH ₃ PbI ₃ Xu, Duo; Hua, Xin; Liu, Shao-Chuang Chemical Communications, Vol. 54, Issue 43 https://doi.org/10.1039/C8CC01606B	journal	January 2018
Mesoscopic Perovskite Light-Emitting Diodes Palma, Alessandro Lorenzo; Cinà, Lucio; Busby, Yan ACS Applied Materials & Interfaces, Vol. 8, Issue 40 https://doi.org/10.1021/acsami.6b07750	journal	September 2016
Unravelling additive-based nanocrystal pinning for high efficiency organic-inorganic halide perovskite light-emitting diodes Park, Min-Ho; Jeong, Su-Hun; Seo, Hong-Kyu Nano Energy, Vol. 42 https://doi.org/10.1016/j.nanoen.2017.10.012	journal	December 2017
Interaction of oxygen with halide perovskites Senocrate, Alessandro; Acartürk, Tolga; Kim, Gee Yeong Journal of Materials Chemistry A, Vol. 6, Issue 23 https://doi.org/10.1039/C8TA04537B	journal	January 2018
A generic interface to reduce the efficiency-stability-cost gap of perovskite solar cells Hou, Yi; Du, Xiaoyan; Scheiner, Simon Science, Vol. 358, Issue 6367 https://doi.org/10.1126/science.aao5561	journal	November 2017
The influence of DMSO and ether via fast-dipping treatment for a perovskite solar cell Hwang, Ki-Hwan; Nam, Sang Hun; Kim, Dong In Solar Energy Materials and Solar Cells, Vol. 180 https://doi.org/10.1016/j.solmat.2017.10.024	journal	June 2018
Cation and anion immobilization through chemical bonding enhancement with fluorides for stable halide perovskite solar cells Li, Nengxu; Tao, Shuxia; Chen, Yihua Nature Energy, Vol. 4, Issue 5 https://doi.org/10.1038/s41560-019-0382-6	journal	May 2019
Integrated Perovskite/Bulk‐Heterojunction Organic Solar Cells Liu, Yongsheng; Chen, Yongsheng Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201805843	journal	February 2019
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells McMeekin, D. P.; Sadoughi, G.; Rehman, W. Science, Vol. 351, Issue 6269 https://doi.org/10.1126/science.aad5845	journal	January 2016
Unraveling the Impacts Induced by Organic and Inorganic Hole Transport Layers in Inverted Halide Perovskite Solar Cells Khadka, Dhruba B.; Shirai, Yasuhiro; Yanagida, Masatoshi ACS Applied Materials & Interfaces, Vol. 11, Issue 7 https://doi.org/10.1021/acsami.8b20924	journal	January 2019
Ferroic twin domains in metal halide perovskites Liu, Yongtao; Belianinov, Alex; Collins, Liam MRS Advances https://doi.org/10.1557/adv.2019.358	journal	September 2019
Additive-Assisted Crystallization Dynamics in Two-Step Fabrication of Perovskite Solar Cells Abzieher, Tobias; Mathies, Florian; Hetterich, Michael physica status solidi (a), Vol. 214, Issue 12 https://doi.org/10.1002/pssa.201700509	journal	October 2017
I ₂ vapor-induced degradation of formamidinium lead iodide based perovskite solar cells under heat–light soaking conditions Fu, Fan; Pisoni, Stefano; Jeangros, Quentin Energy & Environmental Science, Vol. 12, Issue 10 https://doi.org/10.1039/C9EE02043H	journal	January 2019
Effect of Electron-Transport Material on Light-Induced Degradation of Inverted Planar Junction Perovskite Solar Cells Akbulatov, Azat F.; Frolova, Lyubov A.; Griffin, Monroe P. Advanced Energy Materials, Vol. 7, Issue 19 https://doi.org/10.1002/aenm.201700476	journal	June 2017
Temperature Dependence of the Urbach Energy in Lead Iodide Perovskites Ledinsky, Martin; Schönfeldová, Tereza; Holovský, Jakub The Journal of Physical Chemistry Letters, Vol. 10, Issue 6 https://doi.org/10.1021/acs.jpclett.9b00138	journal	February 2019
Strain engineering in perovskite solar cells and its impacts on carrier dynamics Zhu, Cheng; Niu, Xiuxiu; Fu, Yuhao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08507-4	journal	February 2019
Improved efficiency and reduced hysteresis in ultra-stable fully printable mesoscopic perovskite solar cells through incorporation of CuSCN into the perovskite layer Zimmermann, Iwan; Gratia, Paul; Martineau, David Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/C9TA00669A	journal	January 2019

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