Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy

Luo, Jiawei; Smith, Nicholas J.; Pantano, Carlo G.; Kim, Seong H.

doi:10.1016/j.jnoncrysol.2018.04.050

Title: Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy

Journal Article · Mon May 07 00:00:00 EDT 2018 · Journal of Non-Crystalline Solids

DOI:https://doi.org/10.1016/j.jnoncrysol.2018.04.050· OSTI ID:1600990

Luo, Jiawei ^[1]; Smith, Nicholas J. ^[2]; Pantano, Carlo G. ^[1];

^[1]

Pennsylvania State Univ., University Park, PA (United States)
Corning Inc., Corning, NY (United States)

A novel mathematical algorithm was developed to calculate refractive index (n + ik) from specular reflectance infrared (SR-IR) spectra in the strongly-absorbing glass network vibration region. The method is named as two-angle SR-IR (TASR-IR), since it is based on the Fresnel equations of specular reflectance at two incidence angles (10° and 45°). The results obtained from TASR-IR are comparable with the values obtained from spectroscopic ellipsometry. The TASR-IR method allows one to obtain the peak positions and intensities of fundamental network vibration modes of glass from the imaginary component (k) of complex refractive index without convolutions from the dispersion effect due to chains in the real component (n) of refractive index. The TASR-IR method is applied to silica, silicate, borosilicate, and boroaluminosilicate glasses; tentative peak assignments of glass network vibrations are proposed. The origin and concept of peaks in the vibrational spectra of glasses is discussed.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD); Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016584

OSTI ID:: 1600990

Alternate ID(s):: OSTI ID: 1582895

Journal Information:: Journal of Non-Crystalline Solids, Vol. 494, Issue C; ISSN 0022-3093

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 31 works

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