Network structure in alteration layer of boroaluminosilicate glass formed by aqueous corrosion

Kaya, Huseyin; Ngo, Dien; Smith, Nicholas J.; Gin, Stéphane; Kim, Seong H.

doi:10.1016/j.jnoncrysol.2020.120494

Network structure in alteration layer of boroaluminosilicate glass formed by aqueous corrosion

Journal Article · Wed Oct 21 00:00:00 EDT 2020 · Journal of Non-Crystalline Solids

DOI:https://doi.org/10.1016/j.jnoncrysol.2020.120494· OSTI ID:1865522

Kaya, Huseyin ^[1]; ^[2]; ^[3]; ^[4]; ^[2]

Pennsylvania State Univ., University Park, PA (United States); Pennsylvania State University
Pennsylvania State Univ., University Park, PA (United States)
Corning Incorporated, Corning, NY (United States)
Univ. of Montpellier, Bagnols sur Ceze (France)

Exogenously-added LiCl has been shown to slightly accelerate the corrosion rate of a boroaluminosilicate glass called International Simple Glass (ISG) in aqueous solutions over forward- and residual-rate regimes, while KCl and CsCl impede. To understand the effect of exogenously added electrolytes on resulting hydrous species and the network structure of alteration layers, infrared spectroscopy was implemented. It was found that the fraction of molecular water relative to the surface-bound hydroxyl species is lower in the KCl and CsCl conditions compared to the LiCl and pure water conditions. An approximation for the spectral features of the thin surface films from an experimentally-obtained specular-reflectance infrared (SR-IR) spectrum was proposed; results indicate no significant difference in the Si-O bonding network of the alteration layers formed in the presence of exogenously added LiCl, KCl and CsCl. Furthermore, the observed change in corrosion rates might be linked to the relative abundance of molecular water species in the porous network, rather than the silicate bonding structure.

View Accepted Manuscript (DOE)

Research Organization:: Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016584

OSTI ID:: 1865522

Alternate ID(s):: OSTI ID: 1775976

Journal Information:: Journal of Non-Crystalline Solids, Journal Name: Journal of Non-Crystalline Solids Vol. 553; ISSN 0022-3093

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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