A Crystalline Polyimide Porous Organic Framework for Selective Adsorption of Acetylene over Ethylene

Jiang, Lingchang; Tian, Yuyang; Sun, Tu; Zhu, Youliang; Ren, Hao; Zou, Xiaoqin; Ma, Yanhang; Meihaus, Katie R.; Long, Jeffrey R.; Zhu, Guangshan

doi:10.1021/jacs.8b08174

Title: A Crystalline Polyimide Porous Organic Framework for Selective Adsorption of Acetylene over Ethylene

Journal Article · Fri Oct 26 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b08174· OSTI ID:1566590

Jiang, Lingchang ^[1]; Tian, Yuyang ^[2]; Sun, Tu ^[3]; Zhu, Youliang ^[4]; Ren, Hao ^[1];

^[2]; Ma, Yanhang ^[3]; Meihaus, Katie R. ^[5];

^[5];

^[6]

Jilin Univ., Changchun (China)
Northeast Normal Univ., Changchun (China)
ShanghaiTech Univ., Shanghai (China)
Chinese Academy of Sciences, Changchun (China)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Jilin Univ., Changchun (China); Northeast Normal Univ., Changchun (China)

The separation of acetylene from ethylene is a crucial process in the petrochemical industry, as even small acetylene impurities can lead to premature termination of ethylene polymerization. Herein, we present the synthesis of a robust, crystalline naphthalene diimide porous aromatic framework via imidization of linear naphthalene-1,4,5,8-tetracarboxylic dianhydride and triangular tris(4-aminophenyl)amine. The resulting material, PAF-110, exhibits impressive thermal and long-term structural stability, as indicated by thermogravimetric analysis and powder X-ray diffraction characterization. Gas adsorption characterization reveals that PAF-110 has a capacity for acetylene that is more than twice its ethylene capacity at 273 K and 1 bar, and it exhibits a moderate acetylene selectivity of 3.9 at 298 K and 1 bar. Complementary computational investigation of each guest binding in PAF-110 suggests that this affinity and selectivity for acetylene arises from its stronger electrostatic interaction with the carbonyl oxygen atoms of the framework. As a result, to the best of our knowledge, PAF-110 is the first crystalline porous organic material to exhibit selective adsorption of acetylene over ethylene, and its properties may provide insight into the further optimized design of porous organic materials for this key gas separation.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001015

OSTI ID:: 1566590

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 46; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 153 works

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Title: A Crystalline Polyimide Porous Organic Framework for Selective Adsorption of Acetylene over Ethylene

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