Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions

Zhang, Dandan; Yang, Yiming; Bekenstein, Yehonadav; Yu, Yi; Gibson, Natalie A.; Wong, Andrew B.; Eaton, Samuel W.; Kornienko, Nikolay; Kong, Qiao; Lai, Minliang; Alivisatos, A. Paul; Leone, Stephen R.; Yang, Peidong

doi:10.1021/jacs.6b03134

Title: Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions

Journal Article · Mon May 23 00:00:00 EDT 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b03134· OSTI ID:1530244

Zhang, Dandan ^[1]; Yang, Yiming ^[1]; Bekenstein, Yehonadav ^[2]; Yu, Yi ^[1]; Gibson, Natalie A. ^[1]; Wong, Andrew B. ^[1]; Eaton, Samuel W. ^[3]; Kornienko, Nikolay ^[3]; Kong, Qiao ^[3]; Lai, Minliang ^[3]; Alivisatos, A. Paul ^[2]; Leone, Stephen R. ^[1]; Yang, Peidong ^[2]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Institute, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States)

In this paper, we demonstrate the successful synthesis of brightly emitting colloidal cesium lead halide (CsPbX₃, X = Cl, Br, I) nanowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr₃ NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX₃ alloy NWs with a wide range of alloy compositions can be achieved with well-preserved morphology and crystal structure. The NWs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20% to 80%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX₃ system. Finally, the wires increased functionality in the form of fast photoresponse rates and the low defect density suggest CsPbX₃ NWs as prospective materials for optoelectronic applications.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1530244

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 23; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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