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Title: Recent Progress in Biomass–Derived Electrode Materials for High Volumetric Performance Supercapacitors

Journal Article · · Advanced Energy Materials
 [1];  [1];  [2];  [3]; ORCiD logo [4];  [5]
  1. Wenzhou Univ., Zhejiang (China)
  2. Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Illinois at Chicago, Chicago, IL (United States)
  3. Univ. of Windsor, Windsor, ON (Canada)
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
  5. Wenzhou Univ., Zhejiang (China); Shihezi Univ., Xinjiang (China)

Abstract Tremendous efforts have been spent on the development of electrical energy storage (EES) systems with high volumetric performance in the past few years due to the evergrowing demand of miniaturized, portable electronic devices, and electric vehicles. Among all the EES devices, supercapacitors with electrode materials derived from biosources have attracted special attention due to their eco‐friendliness, natural abundance, their intrinsic porous structures as well as their renewable and sustainable features. However, the relatively low packing densities make their specific volumetric capacitance intrinsically low, which has largely limited their further application in the supercapacitors. To address these issues, various promising approaches ranging from structural manufacture to compositional design are applied and significant breakthroughs are witnessed in recent years. In this progress report, key factors influencing the volumetric performance of biomass‐derived electrode materials are systematically discussed with a particular focus spanning from fundamental to operational aspects. This work provides insights into the development of high‐volumetric‐performance biomass‐derived supercapacitors by comprehensively summarizing recent advances in the rational structural design and fabrication. Perspectives regarding the future challenges and promising research directions on the design of next‐generation EES devices are also provided.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1482202
Alternate ID(s):
OSTI ID: 1464430
Journal Information:
Advanced Energy Materials, Vol. 8, Issue 23; ISSN 1614-6832
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 264 works
Citation information provided by
Web of Science

References (115)

Molten salt synthesis of nitrogen-doped carbon with hierarchical pore structures for use as high-performance electrodes in supercapacitors journal November 2015
High-Performance Supercapacitor Electrode Materials Prepared from Various Pollens journal March 2013
Ultrahigh volumetric capacitance and cyclic stability of fluorine and nitrogen co-doped carbon microspheres journal September 2015
Recent Smart Methods for Achieving High-Energy Asymmetric Supercapacitors journal December 2017
A review of electrode materials for electrochemical supercapacitors journal January 2012
A porous biomass-based sandwich-structured Co3O4@Carbon Fiber@Co3O4 composite for high-performance supercapacitors journal April 2018
Carbon materials for high volumetric performance supercapacitors: design, progress, challenges and opportunities journal January 2016
Biomass-Derived Carbon Fiber Aerogel as a Binder-Free Electrode for High-Rate Supercapacitors journal January 2016
Boosting the Energy Density of Carbon-Based Aqueous Supercapacitors by Optimizing the Surface Charge journal March 2017
Preparation of highly porous binderless activated carbon electrodes from fibres of oil palm empty fruit bunches for application in supercapacitors journal March 2013
A Facile Molten-Salt Route to Graphene Synthesis journal July 2013
Biomass-derived hierarchical porous carbons: boosting the energy density of supercapacitors via an ionothermal approach journal January 2017
Lignin-derived interconnected hierarchical porous carbon monolith with large areal/volumetric capacitances for supercapacitor journal April 2016
Large area few-layer graphene with scalable preparation from waste biomass for high-performance supercapacitor journal November 2017
Biomass-Derived Activated Porous Carbon from Rice Straw for a High-Energy Symmetric Supercapacitor in Aqueous and Non-aqueous Electrolytes journal December 2016
Materials for electrochemical capacitors journal November 2008
Bio-inspired hollow activated carbon microtubes derived from willow catkins for supercapacitors with high volumetric performance journal July 2016
Efficient storage mechanisms for building better supercapacitors journal May 2016
Where Do Batteries End and Supercapacitors Begin? journal March 2014
Research progress on conducting polymer based supercapacitor electrode materials journal June 2017
Preparation of activated carbon from waste Camellia oleifera shell for supercapacitor application journal January 2012
A review on biomass as a fuel for boilers journal June 2011
Compressing Carbon Nanocages by Capillarity for Optimizing Porous Structures toward Ultrahigh-Volumetric-Performance Supercapacitors journal April 2017
Biomass-Derived Sponge-like Carbonaceous Hydrogels and Aerogels for Supercapacitors journal April 2013
High voltage supercapacitor built with seaweed carbons in neutral aqueous electrolyte journal December 2010
Nitrogen-Doped Aligned Carbon Nanotube/Graphene Sandwiches: Facile Catalytic Growth on Bifunctional Natural Catalysts and Their Applications as Scaffolds for High-Rate Lithium-Sulfur Batteries journal May 2014
Efficient Metal-Free Oxygen Reduction in Alkaline Medium on High-Surface-Area Mesoporous Nitrogen-Doped Carbons Made from Ionic Liquids and Nucleobases journal January 2011
Three-dimensional hierarchical and interconnected honeycomb-like porous carbon derived from pomelo peel for high performance supercapacitors journal January 2018
Electrochemical performance of activated carbons prepared from rice husk in different types of non-aqueous electrolytes journal December 2015
Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse journal February 2010
Biomass derived carbon for energy storage devices journal January 2017
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance journal November 2014
Enabling high-volumetric-energy-density supercapacitors: designing open, low-tortuosity heteroatom-doped porous carbon-tube bundle electrodes journal January 2017
Direct Synthesis of Highly Porous Interconnected Carbon Nanosheets and Their Application as High-Performance Supercapacitors journal April 2014
Preparation of capacitor’s electrode from cassava peel waste journal May 2010
Recent Breakthroughs in Supercapacitors Boosted by Nitrogen-Rich Porous Carbon Materials journal February 2017
Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review journal December 2015
Porous wood carbon monolith for high-performance supercapacitors journal January 2012
Biomass-derived nitrogen-doped porous carbons with tailored hierarchical porosity and high specific surface area for high energy and power density supercapacitors journal January 2018
Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries journal June 2013
Carbon-based materials as supercapacitor electrodes journal January 2009
Microtube Bundle Carbon Derived from Paulownia Sawdust for Hybrid Supercapacitor Electrodes journal May 2013
MnO 2 Nanowire/Biomass-Derived Carbon from Hemp Stem for High-Performance Supercapacitors journal May 2017
Nanoporous carbon electrode from waste coffee beans for high performance supercapacitors journal October 2008
Molten salt synthesis of nitrogen doped porous carbon: a new preparation methodology for high-volumetric capacitance electrode materials journal January 2016
Facile Ionothermal Synthesis of Microporous and Mesoporous Carbons from Task Specific Ionic Liquids journal April 2009
The role of graphene for electrochemical energy storage journal December 2014
Hierarchically porous carbon derived from polymers and biomass: effect of interconnected pores on energy applications journal January 2014
Activated carbon with high capacitance prepared by NaOH activation for supercapacitors journal November 2010
Carbons and Electrolytes for Advanced Supercapacitors journal February 2014
Functional Biomass Carbons with Hierarchical Porous Structure for Supercapacitor Electrode Materials journal October 2015
Promising Porous Carbon Derived from Celtuce Leaves with Outstanding Supercapacitance and CO 2 Capture Performance journal November 2012
Promising porous carbons derived from lotus seedpods with outstanding supercapacitance performance journal August 2016
Alloy Negative Electrodes for Li-Ion Batteries journal October 2014
Bamboo-based activated carbon for supercapacitor applications journal December 2014
Li–O2 and Li–S batteries with high energy storage journal January 2012
Designed formation of hollow particle-based nitrogen-doped carbon nanofibers for high-performance supercapacitors journal January 2017
A Metal-Free Supercapacitor Electrode Material with a Record High Volumetric Capacitance over 800 F cm −3 journal November 2015
Progress of Nanostructured Electrode Materials for Supercapacitors journal December 2017
High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials journal January 2018
Living healthy on a dying planet journal January 2009
Perspective: The energy-storage revolution journal October 2015
Sustainable Synthesis and Assembly of Biomass-Derived B/N Co-Doped Carbon Nanosheets with Ultrahigh Aspect Ratio for High-Performance Supercapacitors journal November 2015
Development of easy made low cost bindless monolithic electrodes from biomass with controlled properties to be used as electrochemical capacitors journal February 2011
3D Aperiodic Hierarchical Porous Graphitic Carbon Material for High-Rate Electrochemical Capacitive Energy Storage journal February 2009
Promising Carbons for Supercapacitors Derived from Fungi journal April 2011
A self-template synthesis of hierarchical porous carbon foams based on banana peel for supercapacitor electrodes journal July 2012
Oxygen and nitrogen co-doped porous carbon nanosheets derived from Perilla frutescens for high volumetric performance supercapacitors journal February 2017
Sustainable Low-Cost Green Electrodes with High Volumetric Capacitance for Aqueous Symmetric Supercapacitors with High Energy Density journal December 2015
Preparation of capacitor’s electrode from sunflower seed shell journal January 2011
Materials and Structures for Stretchable Energy Storage and Conversion Devices journal March 2014
Metal–organic frameworks and their derived nanostructures for electrochemical energy storage and conversion journal January 2015
Effect of Structure on the Fe[sup 3+]∕Fe[sup 2+] Redox Couple in Iron Phosphates journal January 1997
Opportunities and challenges for a sustainable energy future journal August 2012
Tuning Carbon Materials for Supercapacitors by Direct Pyrolysis of Seaweeds journal April 2009
A perspective: carbon nanotube macro-films for energy storage journal January 2013
From Rice Bran to High Energy Density Supercapacitors: A New Route to Control Porous Structure of 3D Carbon journal December 2014
From biomass with irregular structures to 1D carbon nanobelts: a stripping and cutting strategy to fabricate high performance supercapacitor materials journal January 2017
Scalable synthesis of hierarchically structured carbon nanotube–graphene fibres for capacitive energy storage journal May 2014
Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density journal October 2013
Oxygen- and Nitrogen-Enriched 3D Porous Carbon for Supercapacitors of High Volumetric Capacity journal October 2015
Molten salt activation for synthesis of porous carbon nanostructures and carbon sheets journal April 2014
Utilization of oil palm biodiesel solid residue as renewable sources for preparation of granular activated carbon by microwave induced KOH activation journal February 2013
From Dead Pine Needles to O, N Codoped Activated Carbons by a One-Step Carbonization for High Rate Performance Supercapacitors journal October 2017
Recent Progress in the Design of Advanced Cathode Materials and Battery Models for High-Performance Lithium-X (X = O 2 , S, Se, Te, I 2 , Br 2 ) Batteries journal May 2017
A Novel Exfoliation Strategy to Significantly Boost the Energy Storage Capability of Commercial Carbon Cloth journal May 2015
A honeycomb-like porous carbon derived from pomelo peel for use in high-performance supercapacitors journal January 2014
Porous layer-stacking carbon derived from in-built template in biomass for high volumetric performance supercapacitors journal March 2015
Mesoporous materials for energy conversion and storage devices journal May 2016
Biobased Nano Porous Active Carbon Fibers for High-Performance Supercapacitors journal June 2016
Strongly coupled inorganic–nano-carbon hybrid materials for energy storage journal January 2013
Energy storage applications of activated carbons: supercapacitors and hydrogen storage journal January 2014
Preparation of oil palm (Elaeis) empty fruit bunch activated carbon by microwave-assisted KOH activation for the adsorption of methylene blue journal July 2011
Carbon-Based Supercapacitors Produced by Activation of Graphene journal May 2011
Hollow carbon microtubes from kapok fiber: structural evolution and energy storage performance journal January 2018
3D Aperiodic Hierarchical Porous Graphitic Carbon Material for High-Rate Electrochemical Capacitive Energy Storage journal January 2008
Hierarchically porous nitrogen-doped carbon derived from the activation of agriculture waste by potassium hydroxide and urea for high-performance supercapacitors journal February 2018
Ionic Liquids as Versatile Precursors for Functionalized Porous Carbon and Carbon-Oxide Composite Materials by Confined Carbonization journal August 2010
Facile synthesis of functionalized porous carbon with three-dimensional interconnected pore structure for high volumetric performance supercapacitors journal November 2015
Building Three-Dimensional Graphene Frameworks for Energy Storage and Catalysis journal November 2014
Activated carbons from KOH-activation of argan (Argania spinosa) seed shells as supercapacitor electrodes journal May 2012
Facile and sustainable synthesis of sodium lignosulfonate derived hierarchical porous carbons for supercapacitors with high volumetric energy densities journal January 2017
Template-free fabrication of hierarchical porous carbon by constructing carbonyl crosslinking bridges between polystyrene chains journal January 2010
Bio-inspired beehive-like hierarchical nanoporous carbon derived from bamboo-based industrial by-product as a high performance supercapacitor electrode material journal January 2015
Fluidic Carbon Precursors for Formation of Functional Carbon under Ambient Pressure Based on Ionic Liquids journal December 2009
Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium-ion batteries journal June 2003
Activated carbon fiber paper with exceptional capacitive performance as a robust electrode for supercapacitors journal January 2016
Electrochemical capacitors: mechanism, materials, systems, characterization and applications journal January 2016
Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage journal December 2015
2D metal carbides and nitrides (MXenes) for energy storage journal January 2017
Preparation of nanodiamonds from carbon nanoparticles at atmospheric pressure journal January 2015
Recent Advances in Design and Fabrication of Electrochemical Supercapacitors with High Energy Densities journal December 2013
Toward Flexible Polymer and Paper-Based Energy Storage Devices journal February 2011
Ionic Liquids as Versatile Precursors for Functionalized Porous Carbon and Carbon-Oxide Composite Materials by Confined Carbonization journal August 2010
Boosting the Energy Density of Carbon-Based Aqueous Supercapacitors by Optimizing the Surface Charge journal March 2017

Cited By (18)

Facile preparation of functionalized hierarchical porous carbon from bean dregs for high-performance supercapacitors journal November 2019
Tailoring porous carbon aerogels from bamboo cellulose fibers for high-performance supercapacitors journal June 2019
High‐Stability MnO x Nanowires@C@MnO x Nanosheet Core–Shell Heterostructure Pseudocapacitance Electrode Based on Reversible Phase Transition Mechanism journal April 2019
Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors journal January 2019
In Situ Encapsulation of Iron Complex Nanoparticles into Biomass-Derived Heteroatom-Enriched Carbon Nanotubes for High-Performance Supercapacitors journal December 2018
High-Performance Organic Electric Double-Layer Capacitors Using Allergen-Derived Activated Carbons journal January 2019
Size‐Related Electrochemical Performance in Active Carbon Nanostructures: A MOFs‐Derived Carbons Case Study journal August 2019
Superior Multifunctional Activity of Nanoporous Carbons with Widely Tunable Porosity: Enhanced Storage Capacities for Carbon‐Dioxide, Hydrogen, Water, and Electric Charge journal January 2020
N, O and P co-doped honeycomb-like hierarchical porous carbon derived from Sophora japonica for high performance supercapacitors journal January 2019
Design of NiO Flakes@CoMoO4 Nanosheets Core-Shell Architecture on Ni Foam for High-Performance Supercapacitors journal July 2019
Porous Carbons Derived from Collagen‐Enriched Biomass: Tailored Design, Synthesis, and Application in Electrochemical Energy Storage and Conversion journal September 2019
3D Laser Scribed Graphene Derived from Carbon Nanospheres: An Ultrahigh‐Power Electrode for Supercapacitors journal January 2019
Defect Rich Hierarchical Porous Carbon for High Power Supercapacitors journal February 2020
Biomass‐Derived Carbon: A Value‐Added Journey Towards Constructing High‐Energy Supercapacitors in an Asymmetric Fashion journal August 2019
Size Effects on the Mechanical Properties of Nanoporous Graphene Networks journal March 2019
Three-dimensional self-doped hierarchical porous mussel nacre-derived carbons for high performance supercapacitors journal July 2019
Shape-stabilized phase-change materials supported by eggplant-derived porous carbon for efficient solar-to-thermal energy conversion and storage journal January 2020
Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes journal October 2019

Figures / Tables (14)