Rechargeable Aqueous Zn2+-Battery with High Power Density and Long Cycle-life

Wang, Fei; Hu, Enyuan; Sun, Wei; Gao, Tao; Ji, Xiao; Fan, Xiulin; Han, Fudong; Yang, Xiao -Qing; Xu, Kang; Wang, Chunsheng

doi:10.1039/C8EE01883A

Title: Rechargeable Aqueous Zn2+-Battery with High Power Density and Long Cycle-life

Journal Article · Wed Oct 03 00:00:00 EDT 2018 · Energy & Environmental Science

DOI:https://doi.org/10.1039/C8EE01883A· OSTI ID:1476764

Wang, Fei ^[1];

^[2]; Sun, Wei ^[3]; Gao, Tao ^[3]; Ji, Xiao ^[3]; Fan, Xiulin ^[3]; Han, Fudong ^[3]; Yang, Xiao -Qing ^[2]; Xu, Kang ^[4]; Wang, Chunsheng ^[3]

Univ. of Maryland, College Park, MD (United States); U.S. Army Research Lab., Adelphi, MD (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Maryland, College Park, MD (United States)
U.S. Army Research Lab., Adelphi, MD (United States)

Li-ion batteries (LIBs) are approaching their energy limits imposed by the intercalation chemistry nature. As alternatives, multivalent (MV) chemistries bring both promises and challenges, with the main obstacle being the sluggish diffusion of MV-cations due to their strong electrostatic interaction with host lattices. In this work, we demonstrated that polyanion based robust crystal architecture could enable the ultrafast and reversible Zn²⁺-intercalation and de-intercalation at a high working voltage. The nominal bivalence of Zn²⁺ was successfully delocalized by the multiple atoms through the p-d hybridization between the V-d and O-p orbitals, hence the inserted Zn²⁺ only bears an effective charge of 1.336, rendering its high mobility. The novel aqueous rechargeable 1.7 V Zn/LiV₂(PO₄)₃ cell based on such mechanism delivers a high power density (8000 W/kg at 60 C) comparable to supercapacitors, a high energy density (218 Wh/Kg at 1 C) close to LIBs, with extraordinary long cycle life of 4000 cycles. All of these parameters far exceed any Zn battery reported so far. The cell-level volumetric and specific energy densities of the Zn/LiV₂(PO₄)₃ cell are 320 Wh/L and 150 Wh/kg, respectively, which are even better than the first-generation LIBs. Furthermore, combining with the intrinsic safety of the aqueous chemistry and the wide working temperature range, this cell makes a strong candidate for automotive applications.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: SC0012704; AR0000389

OSTI ID:: 1476764

Alternate ID(s):: OSTI ID: 1477130

Report Number(s):: BNL-209154-2018-JAAM

Journal Information:: Energy & Environmental Science, Vol. 11, Issue 11; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 236 works

Citation information provided by
Web of Science

References (44)

Layered VS ₂ Nanosheet-Based Aqueous Zn Ion Battery Cathode He, Pan; Yan, Mengyu; Zhang, Guobin Advanced Energy Materials, Vol. 7, Issue 11 https://doi.org/10.1002/aenm.201601920	journal	January 2017
Comparison of electrochemical performances of olivine NaFePO ₄ in sodium-ion batteries and olivine LiFePO ₄ in lithium-ion batteries Zhu, Yujie; Xu, Yunhua; Liu, Yihang Nanoscale, Vol. 5, Issue 2 https://doi.org/10.1039/C2NR32758A	journal	January 2013
Rhombohedral Form of Li ₃ V ₂ (PO ₄ ) ₃ as a Cathode in Li-Ion Batteries Gaubicher, J.; Wurm, C.; Goward, G. Chemistry of Materials, Vol. 12, Issue 11 https://doi.org/10.1021/cm000345g	journal	November 2000
Towards polyvalent ion batteries: A zinc-ion battery based on NASICON structured Na3V2(PO4)3 Li, Guolong; Yang, Ze; Jiang, Yan Nano Energy, Vol. 25 https://doi.org/10.1016/j.nanoen.2016.04.051	journal	July 2016
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
LiVPO4F/Li3V2(PO4)3 nanostructured composite cathode materials prepared via mechanochemical way Kosova, Nina V.; Devyatkina, Evgeniya T.; Slobodyuk, Arseny B. Journal of Solid State Electrochemistry, Vol. 18, Issue 5 https://doi.org/10.1007/s10008-013-2213-1	journal	August 2013
Materials Design Rules for Multivalent Ion Mobility in Intercalation Structures Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02342	journal	August 2015
Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode Alfaruqi, Muhammad H.; Mathew, Vinod; Song, Jinju Chemistry of Materials, Vol. 29, Issue 4 https://doi.org/10.1021/acs.chemmater.6b05092	journal	February 2017
Cation-Deficient Spinel ZnMn ₂ O ₄ Cathode in Zn(CF ₃ SO ₃ ) ₂ Electrolyte for Rechargeable Aqueous Zn-Ion Battery Zhang, Ning; Cheng, Fangyi; Liu, Yongchang Journal of the American Chemical Society, Vol. 138, Issue 39 https://doi.org/10.1021/jacs.6b05958	journal	September 2016
Rechargeable magnesium-ion battery based on a TiSe2-cathode with d-p orbital hybridized electronic structure Gu, Yunpeng; Katsura, Yukari; Yoshino, Takafumi Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12486	journal	July 2015
Electrochemical Zinc-Ion Intercalation Properties and Crystal Structures of ZnMo ₆ S ₈ and Zn ₂ Mo ₆ S ₈ Chevrel Phases in Aqueous Electrolytes Chae, Munseok S.; Heo, Jongwook W.; Lim, Sung-Chul Inorganic Chemistry, Vol. 55, Issue 7 https://doi.org/10.1021/acs.inorgchem.5b02362	journal	March 2016
Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Hannah, Daniel C. Chemical Reviews, Vol. 117, Issue 5 https://doi.org/10.1021/acs.chemrev.6b00614	journal	February 2017
Carbon-coated rhombohedral Li ₃ V ₂ (PO ₄ ) ₃ as both cathode and anode materials for lithium-ion batteries: electrochemical performance and lithium storage mechanism Jian, Zelang; Han, Wenze; Liang, Yanliang J. Mater. Chem. A, Vol. 2, Issue 47 https://doi.org/10.1039/C4TA04630G	journal	January 2014
Electrochemical Property: Structure Relationships in Monoclinic Li ₃ _- _y V ₂ (PO ₄ ) ₃ Yin, S. -C.; Grondey, H.; Strobel, P. Journal of the American Chemical Society, Vol. 125, Issue 34 https://doi.org/10.1021/ja034565h	journal	August 2003
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery Xu, Chengjun; Li, Baohua; Du, Hongda Angewandte Chemie International Edition, Vol. 51, Issue 4 https://doi.org/10.1002/anie.201106307	journal	December 2011
Electrochemically Induced Structural Transformation in a γ-MnO ₂ Cathode of a High Capacity Zinc-Ion Battery System Alfaruqi, Muhammad H.; Mathew, Vinod; Gim, Jihyeon Chemistry of Materials, Vol. 27, Issue 10 https://doi.org/10.1021/cm504717p	journal	May 2015
Pyro-synthesis of a high rate nano-Li3V2(PO4)3/C cathode with mixed morphology for advanced Li-ion batteries Kang, Jungwon; Mathew, Vinod; Gim, Jihyeon Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04047	journal	February 2014
A better understanding of the capacity fading mechanisms of Li ₃ V ₂ (PO ₄ ) ₃ Wang, Liping; Xu, Jin; Wang, Chong RSC Advances, Vol. 5, Issue 88 https://doi.org/10.1039/C5RA11510H	journal	January 2015
Experimental visualization of lithium diffusion in LixFePO4 Nishimura, Shin-ichi; Kobayashi, Genki; Ohoyama, Kenji Nature Materials, Vol. 7, Issue 9 https://doi.org/10.1038/nmat2251	journal	August 2008
A High Power Rechargeable Nonaqueous Multivalent Zn/V ₂ O ₅ Battery Senguttuvan, Premkumar; Han, Sang-Don; Kim, Soojeong Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201600826	journal	August 2016
The electronic structure and band gap of LiFePO4 and LiMnPO4 Zhou, Fei; Kang, Kisuk; Maxisch, Thomas Solid State Communications, Vol. 132, Issue 3-4 https://doi.org/10.1016/j.ssc.2004.07.055	journal	October 2004
Todorokite-type MnO2 as a zinc-ion intercalating material Lee, Jonghyuk; Ju, Jeh Beck; Cho, Won Il Electrochimica Acta, Vol. 112 https://doi.org/10.1016/j.electacta.2013.08.136	journal	December 2013
Battery materials for ultrafast charging and discharging Kang, Byoungwoo; Ceder, Gerbrand Nature, Vol. 458, Issue 7235, p. 190-193 https://doi.org/10.1038/nature07853	journal	March 2009
Study on structure and electrochemical properties of carbon-coated monoclinic Li3V2(PO4)3 using synchrotron based in situ X-ray diffraction and absorption Yoon, Jeongbae; Muhammad, Shoaib; Jang, Donghyuk Journal of Alloys and Compounds, Vol. 569 https://doi.org/10.1016/j.jallcom.2013.03.188	journal	August 2013
Disulfide-Bridged (Mo ₃ S ₁₁ ) Cluster Polymer: Molecular Dynamics and Application as Electrode Material for a Rechargeable Magnesium Battery Truong, Quang Duc; Kempaiah Devaraju, Murukanahally; Nguyen, Duc N. Nano Letters, Vol. 16, Issue 9 https://doi.org/10.1021/acs.nanolett.6b02593	journal	August 2016
Nanostructured Composites: A High Capacity, Fast Rate Li3V2(PO4)3/Carbon Cathode for Rechargeable Lithium Batteries Huang, H.; Yin, S. -C.; Kerr, T. Advanced Materials, Vol. 14, Issue 21 https://doi.org/10.1002/1521-4095(20021104)14:21<1525::AID-ADMA1525>3.0.CO;2-3	journal	November 2002
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance Augustyn, Veronica; Come, Jérémy; Lowe, Michael A. Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3601	journal	April 2013
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Atomistic Simulation Study of Monoclinic Li ₃ V ₂ (PO ₄ ) ₃ as a Cathode Material for Lithium Ion Battery: Structure, Defect Chemistry, Lithium Ion Transport Pathway, and Dynamics Lee, Sanghun; Park, Sung Soo The Journal of Physical Chemistry C, Vol. 116, Issue 48 https://doi.org/10.1021/jp306105g	journal	November 2012
Enhancement of electronic conductivity of ${LiFePO}_{4}$ by Cr doping and its identification by first-principles calculations Shi, Siqi; Liu, Lijun; Ouyang, Chuying Physical Review B, Vol. 68, Issue 19 https://doi.org/10.1103/PhysRevB.68.195108	journal	November 2003
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System Zhang, Leyuan; Chen, Liang; Zhou, Xufeng Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201400930	journal	September 2014
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode Kundu, Dipan; Adams, Brian D.; Duffort, Victor Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.119	journal	August 2016
Novel Rechargeable M3V2(PO4)3//Zinc (M = Li, Na) Hybrid Aqueous Batteries with Excellent Cycling Performance Zhao, H. B.; Hu, C. J.; Cheng, H. W. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep25809	journal	May 2016
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions Pan, Huilin; Shao, Yuyan; Yan, Pengfei Nature Energy, Vol. 1, Issue 5 https://doi.org/10.1038/nenergy.2016.39	journal	April 2016
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
Highly reversible zinc metal anode for aqueous batteries Wang, Fei; Borodin, Oleg; Gao, Tao Nature Materials, Vol. 17, Issue 6 https://doi.org/10.1038/s41563-018-0063-z	journal	April 2018
Rechargeable nickel–3D zinc batteries: An energy-dense, safer alternative to lithium-ion Parker, Joseph F.; Chervin, Christopher N.; Pala, Irina R. Science, Vol. 356, Issue 6336 https://doi.org/10.1126/science.aak9991	journal	April 2017
Zinc-Iron Flow Batteries with Common Electrolyte Selverston, S.; Savinell, R. F.; Wainright, J. S. Journal of The Electrochemical Society, Vol. 164, Issue 6 https://doi.org/10.1149/2.0591706jes	journal	January 2017
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte Luo, Jia-Yan; Cui, Wang-Jun; He, Ping Nature Chemistry, Vol. 2, Issue 9 https://doi.org/10.1038/nchem.763	journal	August 2010
Nanostructured Composites: A High Capacity, Fast Rate Li3V2(PO4)3/Carbon Cathode for Rechargeable Lithium Batteries. Huang, Huan; Yin, Shieh-Chieh; Kerr, Tracy ChemInform, Vol. 34, Issue 3 https://doi.org/10.1002/chin.200303011	journal	January 2003
Electrochemical Property: Structure Relationships in Monoclinic Li3-yV2(PO4)3. Yin, S. -C.; Grondey, H.; Strobel, P. ChemInform, Vol. 34, Issue 46 https://doi.org/10.1002/chin.200346017	journal	November 2003
The electronic structure and band gap of LiFePO4 and LiMnPO4 Zhou, Fei; Kang, Kisuk; Maxisch, Thomas arXiv https://doi.org/10.48550/arxiv.cond-mat/0506125	text	January 2005

Cited By (15)

ZnCl ₂ “Water‐in‐Salt” Electrolyte Transforms the Performance of Vanadium Oxide as a Zn Battery Cathode Zhang, Lu; Rodríguez‐Pérez, Ismael A.; Jiang, Heng Advanced Functional Materials, Vol. 29, Issue 30 https://doi.org/10.1002/adfm.201902653	journal	May 2019
Toward High‐Performance Hybrid Zn‐Based Batteries via Deeply Understanding Their Mechanism and Using Electrolyte Additive Hao, Junnan; Long, Jun; Li, Bo Advanced Functional Materials, Vol. 29, Issue 34 https://doi.org/10.1002/adfm.201903605	journal	June 2019
Electronic Structure Regulation of Layered Vanadium Oxide via Interlayer Doping Strategy toward Superior High‐Rate and Low‐Temperature Zinc‐Ion Batteries Geng, Hongbo; Cheng, Min; Wang, Bo Advanced Functional Materials, Vol. 30, Issue 6 https://doi.org/10.1002/adfm.201907684	journal	November 2019
Recent Advances and Prospects of Cathode Materials for Rechargeable Aqueous Zinc‐Ion Batteries Chen, Lineng; An, Qinyou; Mai, Liqiang Advanced Materials Interfaces, Vol. 6, Issue 17 https://doi.org/10.1002/admi.201900387	journal	July 2019
A Room‐Temperature Molten Hydrate Electrolyte for Rechargeable Zinc–Air Batteries Chen, Chih‐Yao; Matsumoto, Kazuhiko; Kubota, Keigo Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900196	journal	April 2019
An Ultrastable Presodiated Titanium Disulfide Anode for Aqueous “Rocking‐Chair” Zinc Ion Battery Li, Wei; Wang, Kangli; Cheng, Shijie Advanced Energy Materials, Vol. 9, Issue 27 https://doi.org/10.1002/aenm.201900993	journal	June 2019
A Flexible Solid‐State Aqueous Zinc Hybrid Battery with Flat and High‐Voltage Discharge Plateau Liu, Zhuoxin; Yang, Qi; Wang, Donghong Advanced Energy Materials, Vol. 9, Issue 46 https://doi.org/10.1002/aenm.201902473	journal	October 2019
Inhibiting VOPO ₄ ⋅ x H ₂ O Decomposition and Dissolution in Rechargeable Aqueous Zinc Batteries to Promote Voltage and Capacity Stabilities Shi, Hua‐Yu; Song, Yu; Qin, Zengming Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201908853	journal	November 2019
Mn ₂ O ₃ /Al ₂ O ₃ cathode material derived from a metal–organic framework with enhanced cycling performance for aqueous zinc-ion batteries Gou, Lei; Mou, Ke-Liang; Fan, Xiao-Yong Dalton Transactions, Vol. 49, Issue 3 https://doi.org/10.1039/c9dt03995c	journal	January 2020
Expanded hydrated vanadate for high-performance aqueous zinc-ion batteries Liu, Chaofeng; Neale, Zachary; Zheng, Jiqi Energy & Environmental Science, Vol. 12, Issue 7 https://doi.org/10.1039/c9ee00956f	journal	January 2019
Issues and opportunities facing aqueous zinc-ion batteries Tang, Boya; Shan, Lutong; Liang, Shuquan Energy & Environmental Science, Vol. 12, Issue 11 https://doi.org/10.1039/c9ee02526j	journal	January 2019
Rod-like anhydrous V ₂ O ₅ assembled by tiny nanosheets as a high-performance cathode material for aqueous zinc-ion batteries Zhou, Weijun; Chen, Jizhang; Chen, Minfeng RSC Advances, Vol. 9, Issue 52 https://doi.org/10.1039/c9ra06143f	journal	January 2019
Anchoring V ₂ O ₅ nanosheets on hierarchical titanium nitride nanowire arrays to form core–shell heterostructures as a superior cathode for high-performance wearable aqueous rechargeable zinc-ion batteries Li, Qiulong; Zhang, Qichong; Liu, Chenglong Journal of Materials Chemistry A, Vol. 7, Issue 21 https://doi.org/10.1039/c9ta03330k	journal	January 2019
A high energy efficiency and long life aqueous Zn–I ₂ battery Li, Wei; Wang, Kangli; Jiang, Kai Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/c9ta13081k	journal	January 2020
Inhibiting VOPO ₄ ⋅ x H ₂ O Decomposition and Dissolution in Rechargeable Aqueous Zinc Batteries to Promote Voltage and Capacity Stabilities Shi, Hua‐Yu; Song, Yu; Qin, Zengming Angewandte Chemie, Vol. 131, Issue 45 https://doi.org/10.1002/ange.201908853	journal	September 2019

Figures / Tables (4)

Similar Records

Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility

Journal Article · Wed May 31 00:00:00 EDT 2017 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1476764

Yang, Chongyin; Suo, Liumin; Borodin, Oleg; +9 more

Ultrahigh energy density Li-ion batteries based on cathodes of 1D metals with –Li–N–B–N– repeating units in α-Li{sub x}BN{sub 2} (1 ⩽ x ⩽ 3)

Journal Article · Thu Aug 07 00:00:00 EDT 2014 · Journal of Chemical Physics · OSTI ID:1476764

Németh, Károly

Water‐Lubricated Intercalation in V ₂ O ₅ ·nH ₂ O for High‐Capacity and High‐Rate Aqueous Rechargeable Zinc Batteries

Journal Article · Mon Nov 13 00:00:00 EST 2017 · Advanced Materials · OSTI ID:1476764

Yan, Mengyu; He, Pan; Chen, Ying; +11 more

Related Subjects

25 ENERGY STORAGE