Water‐Lubricated Intercalation in V 2 O 5 ·nH 2 O for High‐Capacity and High‐Rate Aqueous Rechargeable Zinc Batteries

Yan, Mengyu; He, Pan; Chen, Ying; Wang, Shanyu; Wei, Qiulong; Zhao, Kangning; Xu, Xu; An, Qinyou; Shuang, Yi; Shao, Yuyan; Mueller, Karl T.; Mai, Liqiang; Liu, Jun; Yang, Jihui

doi:10.1002/adma.201703725

Title: Water‐Lubricated Intercalation in V ₂ O ₅ ·nH ₂ O for High‐Capacity and High‐Rate Aqueous Rechargeable Zinc Batteries

Journal Article · Mon Nov 13 00:00:00 EST 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201703725· OSTI ID:1408543

Yan, Mengyu ^[1]; He, Pan ^[2]; Chen, Ying ^[3]; Wang, Shanyu ^[4]; Wei, Qiulong ^[2]; Zhao, Kangning ^[2]; Xu, Xu ^[2]; An, Qinyou ^[2]; Shuang, Yi ^[2]; Shao, Yuyan ^[3]; Mueller, Karl T. ^[3]; Mai, Liqiang ^[2]; Liu, Jun ^[3]; Yang, Jihui ^[4]

Materials Science and Engineering Department University of Washington Seattle WA 98195‐2120 USA, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China
Pacific Northwest National Laboratory Richland WA 99352 USA
Materials Science and Engineering Department University of Washington Seattle WA 98195‐2120 USA

Abstract Low‐cost, environment‐friendly aqueous Zn batteries have great potential for large‐scale energy storage, but the intercalation of zinc ions in the cathode materials is challenging and complex. Herein, the critical role of structural H ₂ O on Zn ²⁺ intercalation into bilayer V ₂ O ₅ ·nH ₂ O is demonstrated. The results suggest that the H ₂ O‐solvated Zn ²⁺ possesses largely reduced effective charge and thus reduced electrostatic interactions with the V ₂ O ₅ framework, effectively promoting its diffusion. Benefited from the “lubricating” effect, the aqueous Zn battery shows a specific energy of ≈144 Wh kg ⁻¹ at 0.3 A g ⁻¹ . Meanwhile, it can maintain an energy density of 90 Wh kg ⁻¹ at a high power density of 6.4 kW kg ⁻¹ (based on the cathode and 200% Zn anode), making it a promising candidate for high‐performance, low‐cost, safe, and environment‐friendly energy‐storage devices.

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Sponsoring Organization:: USDOE

OSTI ID:: 1408543

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Vol. 30 Journal Issue: 1; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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References (42)

Nanostructured high-energy cathode materials for advanced lithium batteries Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo Nature Materials, Vol. 11, Issue 11 https://doi.org/10.1038/nmat3435	journal	October 2012
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Single-Crystalline Bilayered V ₂ O ₅ Nanobelts for High-Capacity Sodium-Ion Batteries Su, Dawei; Wang, Guoxiu ACS Nano, Vol. 7, Issue 12 https://doi.org/10.1021/nn405014d	journal	November 2013
Advances in the Application of Silicon and Germanium Nanowires for High-Performance Lithium-Ion Batteries Kennedy, Tadhg; Brandon, Michael; Ryan, Kevin M. Advanced Materials, Vol. 28, Issue 27 https://doi.org/10.1002/adma.201503978	journal	February 2016
Aqueous Cathode for Next-Generation Alkali-Ion Batteries Lu, Yuhao; Goodenough, John B.; Kim, Youngsik Journal of the American Chemical Society, Vol. 133, Issue 15 https://doi.org/10.1021/ja201118f	journal	April 2011
Electrochemical Insertion of Magnesium in Metal Oxides and Sulfides from Aprotic Electrolytes Novák, Petr Journal of The Electrochemical Society, Vol. 140, Issue 1 https://doi.org/10.1149/1.2056075	journal	January 1993
Copper hexacyanoferrate with a well-defined open framework as a positive electrode for aqueous zinc ion batteries Jia, Zhijun; Wang, Baoguo; Wang, Yi Materials Chemistry and Physics, Vol. 149-150 https://doi.org/10.1016/j.matchemphys.2014.11.014	journal	January 2015
An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate Trócoli, Rafael; La Mantia, Fabio ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201403143	journal	December 2014
Graphene decorated vanadium oxide nanowire aerogel for long-cycle-life magnesium battery cathodes An, Qinyou; Li, Yifei; Deog Yoo, Hyun Nano Energy, Vol. 18 https://doi.org/10.1016/j.nanoen.2015.10.029	journal	November 2015
On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials ^† Levi, E.; Gofer, Y.; Aurbach, D. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm9016497	journal	February 2010
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Insertion Electrode Materials for Rechargeable Lithium Batteries Winter, Martin; Besenhard, Jürgen O.; Spahr, Michael E. Advanced Materials, Vol. 10, Issue 10 https://doi.org/10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z	journal	July 1998
Aqueous Lithium-ion Battery LiTi2(PO4)3/LiMn2O4 with High Power and Energy Densities as well as Superior Cycling Stability** Luo, J. -Y.; Xia, Y. -Y. Advanced Functional Materials, Vol. 17, Issue 18 https://doi.org/10.1002/adfm.200700638	journal	December 2007
Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host Kim, Chunjoong; Phillips, Patrick J.; Key, Baris Advanced Materials, Vol. 27, Issue 22 https://doi.org/10.1002/adma.201500083	journal	April 2015
Nanostructured Bilayered Vanadium Oxide Electrodes for Rechargeable Sodium-Ion Batteries Tepavcevic, Sanja; Xiong, Hui; Stamenkovic, Vojislav R. ACS Nano, Vol. 6, Issue 1 https://doi.org/10.1021/nn203869a	journal	December 2011
The Lithium future-resources, recycling, and the environment: The Lithium future Wanger, Thomas Cherico Conservation Letters, Vol. 4, Issue 3 https://doi.org/10.1111/j.1755-263X.2011.00166.x	journal	March 2011
Structure of V ₂ O ₅ · n H ₂ O Xerogel Solved by the Atomic Pair Distribution Function Technique Petkov, Valeri; Trikalitis, Pantelis N.; Bozin, Emil S. Journal of the American Chemical Society, Vol. 124, Issue 34 https://doi.org/10.1021/ja026143y	journal	August 2002
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x Kim, Hyung-Seok; Cook, John B.; Lin, Hao Nature Materials, Vol. 16, Issue 4 https://doi.org/10.1038/nmat4810	journal	December 2016
Hyper-dendritic nanoporous zinc foam anodes Chamoun, Mylad; Hertzberg, Benjamin J.; Gupta, Tanya NPG Asia Materials, Vol. 7, Issue 4 https://doi.org/10.1038/am.2015.32	journal	April 2015
Organic electrolyte-based rechargeable zinc-ion batteries using potassium nickel hexacyanoferrate as a cathode material Chae, Munseok S.; Heo, Jongwook W.; Kwak, Hunho H. Journal of Power Sources, Vol. 337 https://doi.org/10.1016/j.jpowsour.2016.10.083	journal	January 2017
Electrospun Ultralong Hierarchical Vanadium Oxide Nanowires with High Performance for Lithium Ion Batteries Mai, Liqiang; Xu, Lin; Han, Chunhua Nano Letters, Vol. 10, Issue 11 https://doi.org/10.1021/nl103343w	journal	November 2010
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries Naguib, Michael; Halim, Joseph; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja405735d	journal	October 2013
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
Improving the cycle life of a high-rate, high-potential aqueous dual-ion battery using hyper-dendritic zinc and copper hexacyanoferrate Gupta, Tanya; Kim, Andrew; Phadke, Satyajit Journal of Power Sources, Vol. 305 https://doi.org/10.1016/j.jpowsour.2015.11.065	journal	February 2016
Lithium batteries: To the limits of lithium Evarts, Eric C. Nature, Vol. 526, Issue 7575 https://doi.org/10.1038/526S93a	journal	October 2015
Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid Liu, Jun; Zhang, Ji-Guang; Yang, Zhenguo Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200690	journal	June 2012
Towards greener and more sustainable batteries for electrical energy storage Larcher, D.; Tarascon, J-M. Nature Chemistry, Vol. 7, Issue 1 https://doi.org/10.1038/nchem.2085	journal	November 2014
Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System Zhang, Leyuan; Chen, Liang; Zhou, Xufeng Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201400930	journal	September 2014
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode Kundu, Dipan; Adams, Brian D.; Duffort, Victor Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.119	journal	August 2016
In operando observation of temperature-dependent phase evolution in lithium-incorporation olivine cathode Yan, Mengyu; Zhang, Guobin; Wei, Qiulong Nano Energy, Vol. 22 https://doi.org/10.1016/j.nanoen.2016.01.031	journal	April 2016
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage Pasta, Mauro; Wessells, Colin D.; Huggins, Robert A. Nature Communications, Vol. 3, Issue 1, Article No. 1149 https://doi.org/10.1038/ncomms2139	journal	January 2012
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions Pan, Huilin; Shao, Yuyan; Yan, Pengfei Nature Energy, Vol. 1, Issue 5 https://doi.org/10.1038/nenergy.2016.39	journal	April 2016
Nanostructured Vanadium Oxide Electrodes for Enhanced Lithium-Ion Intercalation Wang, Y.; Takahashi, K.; Lee, K. H. Advanced Functional Materials, Vol. 16, Issue 9, p. 1133-1144 https://doi.org/10.1002/adfm.200500662	journal	June 2006
How Electrolytes Influence Battery Safety Roth, E. P.; Orendorff, C. J. Interface magazine, Vol. 21, Issue 2 https://doi.org/10.1149/2.F04122if	journal	January 2012
Copper hexacyanoferrate battery electrodes with long cycle life and high power Wessells, Colin D.; Huggins, Robert A.; Cui, Yi Nature Communications, Vol. 2, Article No. 550 https://doi.org/10.1038/ncomms1563	journal	November 2011
Rechargeable Lithium Batteries with Aqueous Electrolytes Li, W.; Dahn, J. R.; Wainwright, D. S. Science, Vol. 264, Issue 5162, p. 1115-1118 https://doi.org/10.1126/science.264.5162.1115	journal	May 1994
The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries Nam, Kwan Woo; Kim, Sangryun; Lee, Soyeon Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/acs.nanolett.5b01109	journal	May 2015
An electrochemical investigation of the aging of copper hexacyanoferrate during the operation in zinc-ion batteries Kasiri, Ghoncheh; Trócoli, Rafael; Bani Hashemi, Amir Electrochimica Acta, Vol. 222 https://doi.org/10.1016/j.electacta.2016.10.155	journal	December 2016
Nanowire Templated Semihollow Bicontinuous Graphene Scrolls: Designed Construction, Mechanism, and Enhanced Energy Storage Performance Yan, Mengyu; Wang, Fengchao; Han, Chunhua Journal of the American Chemical Society, Vol. 135, Issue 48 https://doi.org/10.1021/ja409027s	journal	November 2013
Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials Tripathi, Rajesh; Ramesh, T. N.; Ellis, Brian L. Angewandte Chemie, Vol. 122, Issue 46 https://doi.org/10.1002/ange.201003743	journal	October 2010
Structural Evolution of Reversible Mg Insertion into a Bilayer Structure of V ₂ O ₅ · n H ₂ O Xerogel Material Sa, Niya; Kinnibrugh, Tiffany L.; Wang, Hao Chemistry of Materials, Vol. 28, Issue 9 https://doi.org/10.1021/acs.chemmater.6b00026	journal	April 2016
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte Luo, Jia-Yan; Cui, Wang-Jun; He, Ping Nature Chemistry, Vol. 2, Issue 9 https://doi.org/10.1038/nchem.763	journal	August 2010

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