Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode

Liu, Yayuan; Lin, Dingchang; Li, Yuzhang; Chen, Guangxu; Pei, Allen; Nix, Oliver; Li, Yanbin; Cui, Yi

doi:10.1038/s41467-018-06077-5

Title: Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode

Journal Article · Fri Sep 07 00:00:00 EDT 2018 · Nature Communications

DOI:https://doi.org/10.1038/s41467-018-06077-5· OSTI ID:1475484

^[1]; Lin, Dingchang ^[1]; Li, Yuzhang ^[1]; Chen, Guangxu ^[1];

^[1]; Nix, Oliver ^[1]; Li, Yanbin ^[1]; Cui, Yi ^[2]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Here, the physiochemical properties of the solid-electrolyte interphase, primarily governed by electrolyte composition, have a profound impact on the electrochemical cycling of metallic lithium. Herein, we discover that the effect of nitrate anions on regulating lithium deposition previously known in ether-based electrolytes can be extended to carbonate-based systems, which dramatically alters the nuclei from dendritic to spherical, albeit extremely limited solubility. This is attributed to the preferential reduction of nitrate during solid-electrolyte interphase formation, and the mechanisms behind which are investigated based on the structure, ion-transport properties, and charge transfer kinetics of the modified interfacial environment. To overcome the solubility barrier, a solubility-mediated sustained-release methodology is introduced, in which nitrate nanoparticles are encapsulated in porous polymer gel and can be steadily dissolved during battery operation to maintain a high concentration at the electroplating front. As such, effective dendrite suppression and remarkably enhanced cycling stability are achieved in corrosive carbonate electrolytes.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1475484

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 267 works

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