Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries

Li, Guoxing; Gao, Yue; He, Xin; Huang, Qingquan; Chen, Shuru; Kim, Seong H.; Wang, Donghai

doi:10.1038/s41467-017-00974-x

Title: Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries

Journal Article · Wed Oct 11 00:00:00 EDT 2017 · Nature Communications

DOI:https://doi.org/10.1038/s41467-017-00974-x· OSTI ID:1430243

Li, Guoxing ^[1];

^[1]; He, Xin ^[2]; Huang, Qingquan ^[1];

^[1]; Kim, Seong H. ^[2];

^[1]

Pennsylvania State Univ., University Park, PA (United States). Department of Mechanical and Nuclear Engineering
Pennsylvania State Univ., University Park, PA (United States). Department of Chemical Engineering

Lithium metal is a promising anode candidate for the next-generation rechargeable battery due to its highest specific capacity (3860 mA h g-1) and lowest potential, but low Coulombic efficiency and formation of lithium dendrites hinder its practical application. Here, we report a self-formed flexible hybrid solid-electrolyte interphase layer through co-deposition of organosulfides/organopolysulfides and inorganic lithium salts using sulfur-containing polymers as an additive in the electrolyte. The organosulfides/organopolysulfides serve as “plasticizer” in the solid-electrolyte interphase layer to improve its mechanical flexibility and toughness. The as-formed robust solid-electrolyte interphase layers enable dendrite-free lithium deposition and significantly improve Coulombic efficiency (99% over 400 cycles at a current density of 2mAcm-2). A lithium-sulfur battery based on this strategy exhibits long cycling life (1000 cycles) and good capacity retention. This study reveals an avenue to effectively fabricate stable solid-electrolyte interphase layer for solving the issues associated with lithium metal anodes.

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Research Organization:: Pennsylvania State Univ., University Park, PA (United States). Department of Mechanical and Nuclear Engineering; Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: EE0007795

OSTI ID:: 1430243

Alternate ID(s):: OSTI ID: 1435961

Report Number(s):: DOE-PENN STATE-0007795; DOE-PENNSTATE-0007795; PII: 974

Journal Information:: Nature Communications, Vol. 8, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 204 works

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Design Multifunctional Catalytic Interface: Toward Regulation of Polysulfide and Li ₂ S Redox Conversion in Li–S Batteries Fan, Shuang; Huang, Shaozhuan; Pam, Mei Er Small, Vol. 15, Issue 51 https://doi.org/10.1002/smll.201906132	journal	November 2019
Toward Better Lithium–Sulfur Batteries: Functional Non-aqueous Liquid Electrolytes Xiong, Shizhao; Regula, Michael; Wang, Donghai Electrochemical Energy Reviews, Vol. 1, Issue 3 https://doi.org/10.1007/s41918-018-0015-y	journal	August 2018
Expanding pore sizes of ZIF-8-derived nitrogen-doped microporous carbon via C ₆₀ embedding: toward improved anode performance for the lithium-ion battery Guan, Jian; Zhong, Xiongwu; Chen, Xiang Nanoscale, Vol. 10, Issue 5 https://doi.org/10.1039/c7nr07829c	journal	January 2018
Lithium anode stable in air for low-cost fabrication of a dendrite-free lithium battery Shen, Xiaowei; Li, Yutao; Qian, Tao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08767-0	journal	February 2019
Innenrücktitelbild: A Sustainable Solid Electrolyte Interphase for High‐Energy‐Density Lithium Metal Batteries Under Practical Conditions (Angew. Chem. 8/2020) Zhang, Xue‐Qiang; Li, Tao; Li, Bo‐Quan Angewandte Chemie, Vol. 132, Issue 8 https://doi.org/10.1002/ange.202000869	journal	January 2020
Electrokinetic Phenomena Enhanced Lithium‐Ion Transport in Leaky Film for Stable Lithium Metal Anodes Li, Guoxing; Liu, Zhe; Wang, Daiwei Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900704	journal	April 2019
Long Cycle Life Lithium Metal Batteries Enabled with Upright Lithium Anode Chen, Yuqing; Yue, Meng; Liu, Cuilian Advanced Functional Materials, Vol. 29, Issue 15 https://doi.org/10.1002/adfm.201806752	journal	February 2019
“Pea-pod-like” nitrogen-doped hollow porous carbon cathode hosts decorated with polar titanium dioxide nanocrystals as efficient polysulfide reservoirs for advanced lithium–sulfur batteries Yao, Weiqi; Chu, Chenjie; Zheng, Weizhong Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/c8ta06288a	journal	January 2018
Toward High Performance Lithium-Sulfur Batteries Based on Li ₂ S Cathodes and Beyond: Status, Challenges, and Perspectives Su, Dawei; Zhou, Dong; Wang, Chengyin Advanced Functional Materials, Vol. 28, Issue 38 https://doi.org/10.1002/adfm.201800154	journal	March 2018
Revisiting the positive roles of liquid polysulfides in alkali metal–sulfur electrochemistry: from electrolyte additives to active catholyte Chang, Caiyun; Pu, Xiong Nanoscale, Vol. 11, Issue 45 https://doi.org/10.1039/c9nr07416c	journal	January 2019
Spatial separation of lithiophilic surface and superior conductivity for advanced Li metal anode: the case of acetylene black and N-doped carbon spheres Liang, Feng; Lin, Liangdong; Feng, Zhenyu Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c9ta00742c	journal	January 2019
Artificial Solid‐Electrolyte Interphase Enabled High‐Capacity and Stable Cycling Potassium Metal Batteries Wang, Huwei; Hu, Junyang; Dong, Jiahui Advanced Energy Materials, Vol. 9, Issue 43 https://doi.org/10.1002/aenm.201902697	journal	September 2019
A functional-gradient-structured ultrahigh modulus solid polymer electrolyte for all-solid-state lithium metal batteries Liu, Jie; Zhou, Jinqiu; Wang, Mengfan Journal of Materials Chemistry A, Vol. 7, Issue 42 https://doi.org/10.1039/c9ta07876b	journal	January 2019

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