New Phases and Dissociation-Recombination of Hydrogen Deuteride to 3.4 Mbar

Dias, Ranga P.; Noked, Ori; Silvera, Isaac Franklin

doi:10.1103/PhysRevLett.116.145501

Title: New Phases and Dissociation-Recombination of Hydrogen Deuteride to 3.4 Mbar

Journal Article · Fri Apr 08 00:00:00 EDT 2016 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.116.145501· OSTI ID:1439437

Dias, Ranga P. ^[1]; Noked, Ori ^[1]; Silvera, Isaac Franklin ^[1]

Harvard Univ., Cambridge, MA (United States)

We present infrared absorption studies of solid hydrogen deuteride to pressures as high as 340 GPa (100 GPa =1 Mbar) in a diamond anvil cell and temperatures in the range 5–295 K. Above 198 GPa the HD sample transforms to a mixture of HD, H2, and D2, interpreted as a process of dissociation and recombination. Three new phase lines are observed, two of which differ remarkably from those of the high-pressure homonuclear species, but none are metallic. The time-dependent spectral changes are analyzed to determine the molecular concentrations as a function of time; the nucleon exchange achieves steady state concentrations in ~20 h at ~200 GPa.

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Research Organization:: Harvard Univ., Cambridge, MA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP)

Grant/Contract Number:: NA0001990; NA0003346

OSTI ID:: 1439437

Alternate ID(s):: OSTI ID: 1246515; OSTI ID: 1798848

Journal Information:: Physical Review Letters, Vol. 116, Issue 14; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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Commensurate-incommensurate phase transition of dense potassium simulated by machine-learned interatomic potential Zhao, Long; Zong, Hongxiang; Ding, Xiangdong Physical Review B, Vol. 100, Issue 22 https://doi.org/10.1103/physrevb.100.220101	journal	December 2019
Nature of the metallization transition in solid hydrogen Azadi, Sam; Drummond, N. D.; Foulkes, W. M. C. Physical Review B, Vol. 95, Issue 3 https://doi.org/10.1103/physrevb.95.035142	journal	January 2017
Quantum molecular dynamics study on the proton exchange, ionic structures, and transport properties of warm dense hydrogen-deuterium mixtures Liu, Lei; Li, Zhi-Guo; Dai, Jia-Yu Physical Review E, Vol. 97, Issue 6 https://doi.org/10.1103/physreve.97.063204	journal	June 2018
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Infrared Peak-Splitting from phonon localization in Solid Hydrogen Magdău, Ioan B.; Ackland, Graeme J. arXiv https://doi.org/10.48550/arxiv.1609.01518	text	January 2016
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The role of van der Waals and exchange interactions in high-pressure solid hydrogen Azadi, Sam; Ackland, Graeme J. arXiv https://doi.org/10.48550/arxiv.1708.01075	text	January 2017

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