High-Pressure Hydrogen Interactions with Polyaminoborane and Polyiminoborane
Ammonia borane [NH3BH3, AB] is a prototypical Lewis acid (BH3)"Lewis base (NH3) adduct that is a stable molecular crystal at ambient temperature and pressure.[1] Upon heating, AB releases H2 in an exothermic reaction to form polyaminoborane [(NH2BH2)x, PAB] at temperatures below 1208C and decomposes further to polyiminoborane [(NHBH)x, PIB] above 1208C (Scheme S1, Supporting Information).[2-4] The structure and dynamics of AB, PAB and PIB is influenced by dihydrogen bonding (DHB)[5, 6] arising from the electrostatic interactions between protonic (Hd+) and hydridic (Hd*) H atoms and dative bonding due to donation of non-bonding lone pair on nitrogen to the empty p-orbital on boron.[7] Recently, it has been discovered that the presence of organic ligands on Lewis bases and/or donors creates steric hindrance resulting in a frustration of the dative bonding and termed as "frustrated Lewis pairs" (FLPs).[8] Early reports of phosphine-borane FLPs revealed a striking reactivity towards H2 activation[9, 10] and now seen in amine-borane FLPs as well.[11] We have recently reported on pressureinduced H2 interactions with AB resulting in the formation of AB*H2 complexes.[12] Herein, we demonstrate reactions of H2 and D2 with PAB and PIB in the 2-4 GPa pressure range and temperatures up to 2208C, in situ in a diamond anvil cell (DAC).[13] Isotopic scrambling of H2 and D2, when thermodynamics prevent reversible reactions,[4, 14] is proposed to occur by a mechanism involving "polymeric" FLPs. We thank the USDOE, Office of BES, for funding and NNSA (CDAC) and NSF-DMR for instrumentation support. PNNL is operated by Battelle.
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 978928
- Report Number(s):
- PNNL-SA-71060; EB4202000
- Journal Information:
- Chemphyschem, 11(1):93-96, Journal Name: Chemphyschem, 11(1):93-96 Journal Issue: 1 Vol. 11; ISSN CPCHFT; ISSN 1439-4235
- Country of Publication:
- United States
- Language:
- English
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