Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries

Li, Yutao; Zhou, Weidong; Xin, Sen; Li, Shuai; Zhu, Jinlong; Lu, Xujie; Cui, Zhiming; Jia, Quanxi; Zhou, Jianshi; Zhao, Yusheng; Goodenough, John B.

doi:10.1002/anie.201604554

Title: Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries

Journal Article · Thu Jun 30 00:00:00 EDT 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201604554· OSTI ID:1414136

Li, Yutao ^[1]; Zhou, Weidong ^[1]; Xin, Sen ^[2]; Li, Shuai ^[3]; Zhu, Jinlong ^[3];

^[4]; Cui, Zhiming ^[1];

^[4]; Zhou, Jianshi ^[1]; Zhao, Yusheng ^[3]; Goodenough, John B. ^[1]

Univ. of Texas at Austin, Austin, TX (United States)
Univ. of Texas at Austin, Austin, TX (United States); Hefei Univ. of Technology, Anhui (People's Republic of China)
Univ. of Nevada, Las Vegas, NV (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

A fluorine-doped antiperovskite Li-ion conducto Li₂(OH)X (X=Cl, Br) is shown to be a promising candidat for a solid electrolyte in an all-solid-state Li-ion rechargeabl battery. Substitution of F¯ for OH¯ transforms orthorhombi Li₂OHCl to a room-temperature cubic phase, which show electrochemical stability to 9 V versus Li⁺/Li and two orders o magnitude higher Li-ion conductivity than that of orthorhombi Li₂OHCl. As a result, an all-solid-state Li/LiFePO₄ with F-dope Li₂OHCl as the solid electrolyte showed good cyclability an a high coulombic efficiency over 40 charge/discharge cycles

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC52-06NA25396; NA0001982

OSTI ID:: 1414136

Alternate ID(s):: OSTI ID: 1332392; OSTI ID: 1400457

Report Number(s):: LA-UR-17-20628

Journal Information:: Angewandte Chemie (International Edition), Vol. 55, Issue 34; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 175 works

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