High voltage stable cycling of all-solid-state lithium metal batteries enabled by top-down direct fluorinated poly (ethylene oxide)-based electrolytes

Yan, Hao; Wang, Tong; Liu, Lujuan; Song, Tinglu; Li, Chunli; Sun, Li; Wu, Lijun; Zheng, Jin-Cheng; Dai, Yang

doi:10.1016/j.jpowsour.2022.232559

High voltage stable cycling of all-solid-state lithium metal batteries enabled by top-down direct fluorinated poly (ethylene oxide)-based electrolytes

Journal Article · Tue Dec 20 23:00:00 EST 2022 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2022.232559· OSTI ID:1961785

Yan, Hao ^[1]; Wang, Tong ^[1]; Liu, Lujuan ^[1]; ^[2]; Li, Chunli ^[2]; Sun, Li ^[1]; ^[3]; Zheng, Jin-Cheng ^[4]; ^[1]

University of Shanghai (China)
Beijing Institute of Technology (China)
Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics
Xiamen University (China)

Poly (ethylene oxide) (PEO)-based solid-state polymer electrolytes (SPEs) show prospects in all-solid-state lithium metal batteries. However, they suffer from low ionic conductivity at room temperature and interfacial instability with high voltage cathodes for long-term cycling. In this work, top-down fluorinated PEOs (F-PEOs) for the all-solid-state electrolytes, which are scalable and cost-effective, are developed to improve the battery performance. We demonstrate, that by enhancing the disordering of the F-PEO matrix, the SPE achieves a maximum Li⁺ conductivity of 1.1 x 10^-4 S cm^-1 at 40 °C, which is 20 times higher than the baseline. By forming robust cathode/SPE and Li/SPE interfaces, the F-PEO-based SPEs demonstrate stable cycling in the LiFePO₄/Li and LiNi_0·8Mn_0·1Co_0·1O₂/Li (3-4.4 V, 500 cycles, capacity retention of 91.6%) based all-solid-state batteries at 40 °C. Therefore, our work highlights the significance of "disordering engineering" for energy storage materials.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; International Science & Technology Cooperation Program of China; National Natural Science Foundation of China; Beijing Natural Science Foundation; Guangdong Key Laboratory of Battery Safety; China Postdoctoral Science Foundation

Grant/Contract Number:: SC0012704

OSTI ID:: 1961785

Report Number(s):: BNL-224136-2023-JAAM

Journal Information:: Journal of Power Sources, Journal Name: Journal of Power Sources Vol. 557; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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High voltage stable cycling of all-solid-state lithium metal batteries enabled by top-down direct fluorinated poly (ethylene oxide)-based electrolytes

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