High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)

Xu, Henghui; Chien, Po-Hsiu; Shi, Jianjian; Li, Yutao; Wu, Nan; Liu, Yuanyue; Hu, Yan-Yan; Goodenough, John B.

doi:10.1073/pnas.1907507116

Title: High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)

Journal Article · Thu Aug 29 00:00:00 EDT 2019 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1907507116· OSTI ID:1559398

; Chien, Po-Hsiu; Shi, Jianjian; Li, Yutao; Wu, Nan;

; Hu, Yan-Yan;

Flexible and low-cost poly(ethylene oxide) (PEO)-based electrolytes are promising for all-solid-state Li-metal batteries because of their compatibility with a metallic lithium anode. However, the low room-temperature Li-ion conductivity of PEO solid electrolytes and severe lithium-dendrite growth limit their application in high-energy Li-metal batteries. Here we prepared a PEO/perovskite Li _3/8 Sr _7/16 Ta _3/4 Zr _1/4 O ₃ composite electrolyte with a Li-ion conductivity of 5.4 × 10 ⁻⁵ and 3.5 × 10 ⁻⁴ S cm ⁻¹ at 25 and 45 °C, respectively; the strong interaction between the F ⁻ of TFSI ⁻ (bis-trifluoromethanesulfonimide) and the surface Ta ⁵⁺ of the perovskite improves the Li-ion transport at the PEO/perovskite interface. A symmetric Li/composite electrolyte/Li cell shows an excellent cyclability at a high current density up to 0.6 mA cm ⁻² . A solid electrolyte interphase layer formed in situ between the metallic lithium anode and the composite electrolyte suppresses lithium-dendrite formation and growth. All-solid-state Li|LiFePO ₄ and high-voltage Li|LiNi _0.8 Mn _0.1 Co _0.1 O ₂ batteries with the composite electrolyte have an impressive performance with high Coulombic efficiencies, small overpotentials, and good cycling stability.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Science Foundation (NSF); Welch Foundation

Grant/Contract Number:: EE000762; UTA17-001111; EE0007762; F-1959-20180324; DMR-1808517; DMR-1644779

OSTI ID:: 1559398

Alternate ID(s):: OSTI ID: 1614047

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Vol. 116 Journal Issue: 38; ISSN 0027-8424

Publisher:: National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 184 works

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References (43)

Flexible, Scalable, and Highly Conductive Garnet-Polymer Solid Electrolyte Templated by Bacterial Cellulose Xie, Hua; Yang, Chunpeng; Fu, Kun Kelvin Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201703474	journal	March 2018
PVDF/Palygorskite Nanowire Composite Electrolyte for 4 V Rechargeable Lithium Batteries with High Energy Density Yao, Pengcheng; Zhu, Bin; Zhai, Haowei Nano Letters, Vol. 18, Issue 10 https://doi.org/10.1021/acs.nanolett.8b01421	journal	August 2018
Lithium Ion Conducting Poly(ethylene oxide)-Based Solid Electrolytes Containing Active or Passive Ceramic Nanoparticles Wang, Weimin; Yi, Eongyu; Fici, Anthony J. The Journal of Physical Chemistry C, Vol. 121, Issue 5 https://doi.org/10.1021/acs.jpcc.6b11136	journal	January 2017
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Lithium Ion Pathway within Li ₇ La ₃ Zr ₂ O ₁₂ -Polyethylene Oxide Composite Electrolytes Zheng, Jin; Tang, Mingxue; Hu, Yan-Yan Angewandte Chemie International Edition, Vol. 55, Issue 40 https://doi.org/10.1002/anie.201607539	journal	September 2016
Li ₃ N-Modified Garnet Electrolyte for All-Solid-State Lithium Metal Batteries Operated at 40 °C Xu, Henghui; Li, Yutao; Zhou, Aijun Nano Letters, Vol. 18, Issue 11 https://doi.org/10.1021/acs.nanolett.8b03902	journal	October 2018
Solid-State Lithium–Sulfur Batteries Operated at 37 °C with Composites of Nanostructured Li ₇ La ₃ Zr ₂ O ₁₂ /Carbon Foam and Polymer Tao, Xinyong; Liu, Yayuan; Liu, Wei Nano Letters, Vol. 17, Issue 5 https://doi.org/10.1021/acs.nanolett.7b00221	journal	April 2017
Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries Li, Yutao; Xu, Biyi; Xu, Henghui Angewandte Chemie International Edition, Vol. 56, Issue 3 https://doi.org/10.1002/anie.201608924	journal	December 2016
Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery Fan, Xiulin; Ji, Xiao; Han, Fudong Science Advances, Vol. 4, Issue 12 https://doi.org/10.1126/sciadv.aau9245	journal	December 2018
Enhancing ionic conductivity in composite polymer electrolytes with well-aligned ceramic nanowires Liu, Wei; Lee, Seok Woo; Lin, Dingchang Nature Energy, Vol. 2, Issue 5 https://doi.org/10.1038/nenergy.2017.35	journal	April 2017
Biocompatible and biodegradable solid polymer electrolytes for high voltage and high temperature lithium batteries Lin, Yue; Cheng, Yun; Li, Jie RSC Advances, Vol. 7, Issue 40 https://doi.org/10.1039/C7RA01601H	journal	January 2017
Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems Aurbach, D.; Zaban, A.; Ein-Eli, Y. Journal of Power Sources, Vol. 68, Issue 1 https://doi.org/10.1016/S0378-7753(97)02575-5	journal	September 1997
A Flexible Solid Composite Electrolyte with Vertically Aligned and Connected Ion-Conducting Nanoparticles for Lithium Batteries Zhai, Haowei; Xu, Pengyu; Ning, Mingqiang Nano Letters, Vol. 17, Issue 5 https://doi.org/10.1021/acs.nanolett.7b00715	journal	April 2017
New Insights into the Compositional Dependence of Li-Ion Transport in Polymer–Ceramic Composite Electrolytes Zheng, Jin; Hu, Yan-Yan ACS Applied Materials & Interfaces, Vol. 10, Issue 4 https://doi.org/10.1021/acsami.7b17301	journal	January 2018
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries Xue, Zhigang; He, Dan; Xie, Xiaolin Journal of Materials Chemistry A, Vol. 3, Issue 38 https://doi.org/10.1039/C5TA03471J	journal	January 2015
A Silica-Aerogel-Reinforced Composite Polymer Electrolyte with High Ionic Conductivity and High Modulus Lin, Dingchang; Yuen, Pak Yan; Liu, Yayuan Advanced Materials, Vol. 30, Issue 32 https://doi.org/10.1002/adma.201802661	journal	June 2018
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia Angewandte Chemie International Edition, Vol. 57, Issue 6 https://doi.org/10.1002/anie.201710806	journal	January 2018
At the polymer electrolyte interfaces: the role of the polymer host in interphase layer formation in Li-batteries Sun, Bing; Xu, Chao; Mindemark, Jonas Journal of Materials Chemistry A, Vol. 3, Issue 26 https://doi.org/10.1039/C5TA02485D	journal	January 2015
Flexible Composite Solid Electrolyte Facilitating Highly Stable “Soft Contacting” Li-Electrolyte Interface for Solid State Lithium-Ion Batteries Yang, Luyi; Wang, Zijian; Feng, Yancong Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701437	journal	September 2017
A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery Dong, Tiantian; Zhang, Jianjun; Xu, Gaojie Energy & Environmental Science, Vol. 11, Issue 5 https://doi.org/10.1039/C7EE03365F	journal	January 2018
PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic” Chen, Long; Li, Yutao; Li, Shuai-Peng Nano Energy, Vol. 46 https://doi.org/10.1016/j.nanoen.2017.12.037	journal	April 2018
Solid polymer electrolytes incorporating cubic Li7La3Zr2O12 for all-solid-state lithium rechargeable batteries Chen, Fei; Yang, Dunjie; Zha, Wenping Electrochimica Acta, Vol. 258 https://doi.org/10.1016/j.electacta.2017.11.164	journal	December 2017
Li-ion transport in a representative ceramic–polymer–plasticizer composite electrolyte: Li ₇ La ₃ Zr ₂ O ₁₂ –polyethylene oxide–tetraethylene glycol dimethyl ether Zheng, Jin; Dang, Heather; Feng, Xuyong Journal of Materials Chemistry A, Vol. 5, Issue 35 https://doi.org/10.1039/C7TA05832B	journal	January 2017
Ionic Conductivity Enhancement of Polymer Electrolytes with Ceramic Nanowire Fillers Liu, Wei; Liu, Nian; Sun, Jie Nano Letters, Vol. 15, Issue 4, p. 2740-2745 https://doi.org/10.1021/acs.nanolett.5b00600	journal	March 2015
Hybrid Lithium-Sulfur Batteries with an Advanced Gel Cathode and Stabilized Lithium-Metal Anode Xu, Henghui; Wang, Shaofei; Manthiram, Arumugam Advanced Energy Materials, Vol. 8, Issue 23 https://doi.org/10.1002/aenm.201800813	journal	May 2018
High-performance Li6.4La3Zr1.4Ta0.6O12/Poly(ethylene oxide)/Succinonitrile composite electrolyte for solid-state lithium batteries Zha, Wenping; Chen, Fei; Yang, Dunjie Journal of Power Sources, Vol. 397 https://doi.org/10.1016/j.jpowsour.2018.07.005	journal	September 2018
Mechanism of Ion Transport in Amorphous Poly(ethylene oxide)/LiTFSI from Molecular Dynamics Simulations Borodin, Oleg; Smith, Grant D. Macromolecules, Vol. 39, Issue 4 https://doi.org/10.1021/ma052277v	journal	February 2006
Ultrahigh Performance All Solid-State Lithium Sulfur Batteries: Salt Anion’s Chemistry-Induced Anomalous Synergistic Effect Eshetu, Gebrekidan Gebresilassie; Judez, Xabier; Li, Chunmei Journal of the American Chemical Society, Vol. 140, Issue 31 https://doi.org/10.1021/jacs.8b04612	journal	July 2018
Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes Koerver, Raimund; Aygün, Isabel; Leichtweiß, Thomas Chemistry of Materials, Vol. 29, Issue 13 https://doi.org/10.1021/acs.chemmater.7b00931	journal	June 2017
Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi Proceedings of the National Academy of Sciences, Vol. 113, Issue 26 https://doi.org/10.1073/pnas.1600422113	journal	June 2016
Low Resistance-Integrated All-Solid-State Battery Achieved by Li ₇ La ₃ Zr ₂ O ₁₂ Nanowire Upgrading Polyethylene Oxide (PEO) Composite Electrolyte and PEO Cathode Binder Wan, Zipei; Lei, Danni; Yang, Wei Advanced Functional Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adfm.201805301	journal	October 2018
Stabilizing Li ₁₀ SnP ₂ S ₁₂ /Li Interface via an in Situ Formed Solid Electrolyte Interphase Layer Zheng, Bizhu; Zhu, Jianping; Wang, Hongchun ACS Applied Materials & Interfaces, Vol. 10, Issue 30 https://doi.org/10.1021/acsami.8b08860	journal	July 2018
High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide) Lin, Dingchang; Liu, Wei; Liu, Yayuan Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04117	journal	December 2015
Perovskite Membranes with Vertically Aligned Microchannels for All-Solid-State Lithium Batteries Jiang, Zhouyang; Xie, Huiqi; Wang, Suqing Advanced Energy Materials, Vol. 8, Issue 27 https://doi.org/10.1002/aenm.201801433	journal	August 2018
Interface layer formation in solid polymer electrolyte lithium batteries: an XPS study Xu, Chao; Sun, Bing; Gustafsson, Torbjörn J. Mater. Chem. A, Vol. 2, Issue 20 https://doi.org/10.1039/C4TA00214H	journal	January 2014
Ionic conductivity of composite electrolytes based on oligo(ethylene oxide) and fumed oxides Zhou, J. Solid State Ionics, Vol. 166, Issue 3-4 https://doi.org/10.1016/j.ssi.2003.11.017	journal	January 2004
Synergistic Coupling between Li _6.75 La ₃ Zr _1.75 Ta _0.25 O ₁₂ and Poly(vinylidene fluoride) Induces High Ionic Conductivity, Mechanical Strength, and Thermal Stability of Solid Composite Electrolytes Zhang, Xue; Liu, Ting; Zhang, Shuofeng Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b06364	journal	September 2017
An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life Zhang, Zhihua; Zhao, Yanran; Chen, Shaojie Journal of Materials Chemistry A, Vol. 5, Issue 32 https://doi.org/10.1039/C7TA04320A	journal	January 2017
Mg ₂ B ₂ O ₅ Nanowire Enabled Multifunctional Solid-State Electrolytes with High Ionic Conductivity, Excellent Mechanical Properties, and Flame-Retardant Performance Sheng, Ouwei; Jin, Chengbin; Luo, Jianmin Nano Letters, Vol. 18, Issue 5 https://doi.org/10.1021/acs.nanolett.8b00659	journal	April 2018
Oxygen Release and Its Effect on the Cycling Stability of LiNi _x Mn _y Co _z O ₂ (NMC) Cathode Materials for Li-Ion Batteries Jung, Roland; Metzger, Michael; Maglia, Filippo Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0021707jes	journal	January 2017
A Perovskite Electrolyte That Is Stable in Moist Air for Lithium-Ion Batteries Li, Yutao; Xu, Henghui; Chien, Po-Hsiu Angewandte Chemie International Edition, Vol. 57, Issue 28 https://doi.org/10.1002/anie.201804114	journal	June 2018
Polymer Electrolytes Containing Solvate Ionic Liquids: A New Approach To Achieve High Ionic Conductivity, Thermal Stability, and a Wide Potential Window Kitazawa, Yuzo; Iwata, Kaori; Kido, Ryosuke Chemistry of Materials, Vol. 30, Issue 1 https://doi.org/10.1021/acs.chemmater.7b04274	journal	December 2017
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing Proceedings of the National Academy of Sciences, Vol. 114, Issue 42 https://doi.org/10.1073/pnas.1708489114	journal	October 2017

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Title: High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)

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