Li 2 S 6 ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries

Fang, Ruyi; Xu, Biyi; Grundish, Nicholas S.; Xia, Yang; Li, Yutao; Lu, Chengwei; Liu, Yijie; Wu, Nan; Goodenough, John B.

doi:10.1002/anie.202106039

Title: Li ₂ S ₆ ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries

Journal Article · Wed Jun 30 00:00:00 EDT 2021 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202106039· OSTI ID:1997297

^[1]; Xu, Biyi ^[1]; Grundish, Nicholas S. ^[1]; Xia, Yang ^[2]; Li, Yutao ^[1]; Lu, Chengwei ^[2]; Liu, Yijie ^[1]; Wu, Nan ^[1];

^[1]

Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA
College of Materials Science and Engineering Zhejiang University of Technology Hangzhou 310014 China

Abstract The integration of Li ₂ S ₆ within a poly(ethylene oxide) (PEO)‐based polymer electrolyte is demonstrated to improve the polymer electrolyte's ionic conductivity because the strong interplay between O ²⁻ _(PEO) and Li ⁺ from Li ₂ S ₆ reduces the crystalline volume within the PEO. The Li/electrolyte interface is stabilized by the in situ formation of an ultra‐thin Li ₂ S/Li ₂ S ₂ layer via the reaction between Li ₂ S ₆ and lithium metal, which increases the ionic transport at the interface and suppresses lithium dendrite growth. A symmetric Li/Li cell with the Li ₂ S ₆ ‐integrated composite electrolyte has excellent cyclability and a high critical current density of 0.9 mA cm ⁻² at 40 °C. Impressive electrochemical performance is demonstrated with all‐solid‐state Li/LiFePO ₄ and high‐voltage Li/LiNi _0.8 Mn _0.1 Co _0.1 O ₂ cells at 40 °C.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0005397; EE0007762

OSTI ID:: 1997297

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 60 Journal Issue: 32; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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