Effect of chemical pressure on the electronic phase transition in Ca 1-x Sr x Mn 7 O 12 films

Huon, A.; Lee, D.; Herklotz, A.; Fitzsimmons, M. R.; Lee, H. N.; May, S. J.

doi:10.1063/1.4994089

Title: Effect of chemical pressure on the electronic phase transition in Ca _1-x Sr _x Mn ₇ O ₁₂ films

Journal Article · Mon Sep 18 00:00:00 EDT 2017 · APL Materials

DOI:https://doi.org/10.1063/1.4994089· OSTI ID:1407986

Huon, A. ^[1];

^[2];

^[3];

^[2]; May, S. J. ^[1]

Drexel Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy

Here, we demonstrate how chemical pressure affects the structural and electronic phase transitions of the quadruple perovskite CaMn₇O₁₂ by Sr doping, a compound that exhibits a charge-ordering transition above room temperature making it a candidate for oxide electronics. We also have synthesized Ca_1-xSr_xMn₇O₁₂ (0 ≤ x ≤ 0.6) thin films by oxide molecular beam epitaxy on (LaAlO₃)_0.3(SrAl_0.5Ta_0.5O₃)_0.7 (LSAT) substrates. The substitution of Sr for Ca results in a linear expansion of the lattice, as revealed by X-ray diffraction. Temperature-dependent resistivity and X-ray diffraction measurements are used to demonstrate that the coupled charge-ordering and structural phase transitions can be tuned with Sr doping. An increase in Sr concentration acts to decrease the phase transition temperature (T*) from 426 K at x = 0 to 385 K at x = 0.6. Furthemore, the presence of a tunable electronic phase transition, above room temperature, points to the potential applicability of Ca_1-xSr_xMn₇O₁₂ in sensors or oxide electronics, for example, via charge doping.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC0014664

OSTI ID:: 1407986

Alternate ID(s):: OSTI ID: 1392139

Journal Information:: APL Materials, Vol. 5, Issue 9; ISSN 2166-532X

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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