Superelasticity and cryogenic linear shape memory effects of CaFe2As2

Sypek, John T.; Yu, Hang; Dusoe, Keith J.; Drachuck, Gil; Patel, Hetal; Giroux, Amanda M.; Goldman, Alan I.; Kreyssig, Andreas; Canfield, Paul C.; Bud’ko, Sergey L.; Weinberger, Christopher R.; Lee, Seok-Woo

doi:10.1038/s41467-017-01275-z

Title: Superelasticity and cryogenic linear shape memory effects of CaFe₂As₂

Journal Article · Fri Oct 20 00:00:00 EDT 2017 · Nature Communications

DOI:https://doi.org/10.1038/s41467-017-01275-z· OSTI ID:1407487

Sypek, John T. ^[1]; Yu, Hang ^[2]; Dusoe, Keith J. ^[1]; Drachuck, Gil ^[3]; Patel, Hetal ^[1]; Giroux, Amanda M. ^[1];

^[3]; Kreyssig, Andreas ^[3]; Canfield, Paul C. ^[3]; Bud’ko, Sergey L. ^[3]; Weinberger, Christopher R. ^[4];

^[1]

Univ. of Connet. Dept. of Materials Science and Engineering, Inst. of Materials Science
Drexel Univ., Philadelphia, PA (United States). Dept. of Mechanical Engineering and Mechanics
Iowa State Univ., Ames, IA (United States). Ames Lab., Dept. of Physics and Astronomy
Drexel Univ., Philadelphia, PA (United States). Dept. of Mechanical Engineering and Mechanics; Colorado State Univ., Fort Collins, CO (United States). Dept. of Mechanical Engineering

Shape memory materials have the ability to recover their original shape after a significant amount of deformation when they are subjected to certain stimuli, for instance, heat or magnetic fields. But, their performance is often limited by the energetics and geometry of the martensitic-austenitic phase transformation. We report a unique shape memory behavior in CaFe₂As₂, which exhibits superelasticity with over 13% recoverable strain, over 3 GPa yield strength, repeatable stress–strain response even at the micrometer scale, and cryogenic linear shape memory effects near 50 K. These properties are acheived through a reversible uni-axial phase transformation mechanism, the tetragonal/orthorhombic-to-collapsed-tetragonal phase transformation. These results offer the possibility of developing cryogenic linear actuation technologies with a high precision and high actuation power per unit volume for deep space exploration, and more broadly, suggest a mechanistic path to a class of shape memory materials, ThCr₂Si₂-structured intermetallic compounds.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1407487

Report Number(s):: IS-J 9415; PII: 1275

Journal Information:: Nature Communications, Vol. 8, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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References (39)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Metallurgy: Extraordinary Alloys That Remember Their Past Robinson, A. L. Science, Vol. 191, Issue 4230 https://doi.org/10.1126/science.191.4230.934	journal	March 1976
Size effects in the deformation of sub-micron Au columns Volkert, C. A.; Lilleodden, E. T. Philosophical Magazine, Vol. 86, Issue 33-35 https://doi.org/10.1080/14786430600567739	journal	November 2006
Ferrous Polycrystalline Shape-Memory Alloy Showing Huge Superelasticity Tanaka, Y.; Himuro, Y.; Kainuma, R. Science, Vol. 327, Issue 5972 https://doi.org/10.1126/science.1183169	journal	March 2010
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Nanoscale shape-memory alloys for ultrahigh mechanical damping Juan, Jose San; Nó, Maria L.; Schuh, Christopher A. Nature Nanotechnology, Vol. 4, Issue 7 https://doi.org/10.1038/nnano.2009.142	journal	June 2009
The selection of mechanical actuators based on performance indices Huber, J. E.; Fleck, N. A.; Ashby, M. F. Proceedings of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 453, Issue 1965 https://doi.org/10.1098/rspa.1997.0117	journal	October 1997
Structural, magnetic and superconducting phase transitions in CaFe2As2 under ambient and applied pressure Canfield, P. C.; Bud'ko, S. L.; Ni, N. arXiv https://doi.org/10.48550/arxiv.0901.4672	text	January 2009
Size dependence of mechanical properties of gold at the micron scale in the absence of strain gradients Greer, Julia R.; Oliver, Warren C.; Nix, William D. Acta Materialia, Vol. 53, Issue 6 https://doi.org/10.1016/j.actamat.2004.12.031	journal	April 2005
NiTiHf-based shape memory alloys Karaca, H. E.; Acar, E.; Tobe, H. Materials Science and Technology, Vol. 30, Issue 13 https://doi.org/10.1179/1743284714y.0000000598	journal	July 2014
Growth of single crystals from metallic fluxes Canfield, P. C.; Fisk, Z. Philosophical Magazine B, Vol. 65, Issue 6 https://doi.org/10.1080/13642819208215073	journal	June 1992
Making and Breaking Bonds in the Solid State: The ThCr ₂ Si ₂ Structure Hoffmann, Roald; Zheng, Chong The Journal of Physical Chemistry, Vol. 89, Issue 20 https://doi.org/10.1021/j100266a007	journal	September 1985
Shape Memory and Superelastic Ceramics at Small Scales Lai, A.; Du, Z.; Gan, C. L. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1239745	journal	September 2013
Shape Memory Alloys Tadaki, T.; Otsuka, K.; Shimizu, K. Annual Review of Materials Science, Vol. 18, Issue 1 https://doi.org/10.1146/annurev.ms.18.080188.000325	journal	August 1988
Pressure induced superconductivity in CaFe$_2$As$_2$ Torikachvili, Milton S.; Bud'ko, Sergey L.; Ni, Ni arXiv https://doi.org/10.48550/arxiv.0807.0616	text	January 2008
Pressure Induced Superconductivity in ${CaFe}_{2} {As}_{2}$ Torikachvili, Milton S.; Bud’ko, Sergey L.; Ni, Ni Physical Review Letters, Vol. 101, Issue 5 https://doi.org/10.1103/PhysRevLett.101.057006	journal	July 2008
Enhanced reversibility and unusual microstructure of a phase-transforming material Song, Yintao; Chen, Xian; Dabade, Vivekanand Nature, Vol. 502, Issue 7469 https://doi.org/10.1038/nature12532	journal	October 2013
Anisotropic Three-Dimensional Magnetism in ${CaFe}_{2} {As}_{2}$ McQueeney, R. J.; Diallo, S. O.; Antropov, V. P. Physical Review Letters, Vol. 101, Issue 22 https://doi.org/10.1103/PhysRevLett.101.227205	journal	November 2008
Cycling of a Lithium-Ion Battery with a Silicon Anode Drives Large Mechanical Actuation Lang, Jialiang; Ding, Bin; Zhu, Ting Advanced Materials, Vol. 28, Issue 46 https://doi.org/10.1002/adma.201603061	journal	October 2016
Structural, magnetic and superconducting phase transitions in CaFe2As2 under ambient and applied pressure Canfield, P. C.; Bud’ko, S. L.; Ni, N. Physica C: Superconductivity, Vol. 469, Issue 9-12 https://doi.org/10.1016/j.physc.2009.03.033	journal	May 2009
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020
Bulk metallic glasses Wang, W. H.; Dong, C.; Shek, C. H. Materials Science and Engineering: R: Reports, Vol. 44, Issue 2-3 https://doi.org/10.1016/j.mser.2004.03.001	journal	June 2004
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Transformation-induced plasticity during pseudoelastic deformation in Ni–Ti microcrystals Norfleet, D. M.; Sarosi, P. M.; Manchiraju, S. Acta Materialia, Vol. 57, Issue 12 https://doi.org/10.1016/j.actamat.2009.04.009	journal	July 2009
Alloys with long memories Omori, Toshihiro; Kainuma, Ryosuke Nature, Vol. 502, Issue 7469 https://doi.org/10.1038/502042a	journal	October 2013
Bulk metallic glasses Schneider, Susanne Journal of Physics: Condensed Matter, Vol. 13, Issue 34 https://doi.org/10.1088/0953-8984/13/34/316	journal	August 2001
Anisotropic three-dimensional magnetism in CaFe2As2 McQueeney, R. J.; Diallo, S. O.; Antropov, V. P. arXiv https://doi.org/10.48550/arxiv.0809.1410	text	January 2008
Correlation effects in the tetragonal and collapsed-tetragonal phase of ${CaFe}_{2} {As}_{2}$ Diehl, Jean; Backes, Steffen; Guterding, Daniel Physical Review B, Vol. 90, Issue 8 https://doi.org/10.1103/PhysRevB.90.085110	journal	August 2014
Lattice collapse and quenching of magnetism in ${CaFe}_{2} {As}_{2}$ under pressure: A single-crystal neutron and x-ray diffraction investigation Goldman, A. I.; Kreyssig, A.; Prokeš, K. Physical Review B, Vol. 79, Issue 2 https://doi.org/10.1103/PhysRevB.79.024513	journal	January 2009
Correlation effects in the tetragonal and collapsed tetragonal phase of CaFe2As2 Diehl, Jean; Backes, Steffen; Guterding, Daniel arXiv https://doi.org/10.48550/arxiv.1406.1314	text	January 2014
Successive stress-induced martensitic transformations and associated transformation pseudoelasticity in Cu-Al-Ni alloys Otsuka, K.; Sakamoto, H.; Shimizu, K. Acta Metallurgica, Vol. 27, Issue 4 https://doi.org/10.1016/0001-6160(79)90011-7	journal	April 1979
First-principles study of CaFe $_{2}$ As $_{2}$ under pressure Widom, Michael; Quader, Khandker Physical Review B, Vol. 88, Issue 4 https://doi.org/10.1103/PhysRevB.88.045117	journal	July 2013
Uniaxial versus hydrostatic pressure-induced phase transitions in CaFe $_{2}$ As $_{2}$ and BaFe $_{2}$ As $_{2}$ Tomić, Milan; Valentí, Roser; Jeschke, Harald O. Physical Review B, Vol. 85, Issue 9 https://doi.org/10.1103/PhysRevB.85.094105	journal	March 2012
Sample Dimensions Influence Strength and Crystal Plasticity Uchic, M. D. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1098993	journal	August 2004
Stabilization of an ambient-pressure collapsed tetragonal phase in CaFe $_{2}$ As $_{2}$ and tuning of the orthorhombic-antiferromagnetic transition temperature by over 70 K via control of nanoscale precipitates Ran, S.; Bud’ko, S. L.; Pratt, D. K. Physical Review B, Vol. 83, Issue 14 https://doi.org/10.1103/PhysRevB.83.144517	journal	April 2011
Control of magnetic, nonmagnetic, and superconducting states in annealed Ca(Fe $_{1 - x}$ Co $_{x}$ ) $_{2}$ As $_{2}$ Ran, S.; Bud'ko, S. L.; Straszheim, W. E. Physical Review B, Vol. 85, Issue 22 https://doi.org/10.1103/PhysRevB.85.224528	journal	June 2012
Thermal expansion of CaFe $_{2}$ As $_{2}$ : Effect of cobalt doping and postgrowth thermal treatment Bud'ko, Sergey L.; Ran, Sheng; Canfield, Paul C. Physical Review B, Vol. 88, Issue 6 https://doi.org/10.1103/PhysRevB.88.064513	journal	August 2013
First-order structural phase transition in ${CaFe}_{2} {As}_{2}$ Ni, N.; Nandi, S.; Kreyssig, A. Physical Review B, Vol. 78, Issue 1 https://doi.org/10.1103/PhysRevB.78.014523	journal	July 2008
Structural and magnetic properties of CaFe $_{2}$ As $_{2}$ and BaFe $_{2}$ As $_{2}$ from first-principles density functional theory Colonna, Nicola; Profeta, Gianni; Continenza, Alessandra Physical Review B, Vol. 83, Issue 9 https://doi.org/10.1103/PhysRevB.83.094529	journal	March 2011

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New materials physics Canfield, Paul C. Reports on Progress in Physics, Vol. 83, Issue 1 https://doi.org/10.1088/1361-6633/ab514b	journal	November 2019
Ultrahigh elastically compressible and strain-engineerable intermetallic compounds under uniaxial mechanical loading Song, Gyuho; Borisov, Vladislav; Meier, William R. APL Materials, Vol. 7, Issue 6 https://doi.org/10.1063/1.5087279	journal	June 2019
Trends in pressure-induced layer-selective half-collapsed tetragonal phases in the iron-based superconductor family $A e A {Fe}_{4} {As}_{4}$ Borisov, Vladislav; Canfield, Paul C.; Valentí, Roser Physical Review B, Vol. 98, Issue 6 https://doi.org/10.1103/physrevb.98.064104	journal	August 2018
Ultrahigh Elastically Compressible and Strain-Engineerable Intermetallic Compounds Under Uniaxial Mechanical Loading Song, Gyuho; Borisov, Vladislav; Meier, William R. arXiv https://doi.org/10.48550/arxiv.1904.02256	preprint	January 2019
Two types of magnetic shape-memory effects from twinned microstructure and magneto-structural coupling in Fe _{1+ y} Te Rößler, Sahana; Koz, Cevriye; Wang, Zhaosheng Proceedings of the National Academy of Sciences, Vol. 116, Issue 34 https://doi.org/10.1073/pnas.1905271116	journal	August 2019
A Nanoindentation Study of the Plastic Deformation and Fracture Mechanisms in Single-Crystalline CaFe2As2 Frawley, Keara G.; Bakst, Ian; Sypek, John T. JOM, Vol. 70, Issue 7 https://doi.org/10.1007/s11837-018-2851-y	journal	April 2018

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