Nanocrystalline iron oxide based electroactive materials in lithium ion batteries: the critical role of crystallite size, morphology, and electrode heterostructure on battery relevant electrochemistry

Bruck, Andrea M.; Cama, Christina A.; Gannett, Cara N.; Marschilok, Amy C.; Takeuchi, Esther S.; Takeuchi, Kenneth J.

doi:10.1039/C5QI00247H

Title: Nanocrystalline iron oxide based electroactive materials in lithium ion batteries: the critical role of crystallite size, morphology, and electrode heterostructure on battery relevant electrochemistry

Journal Article · Tue Dec 08 00:00:00 EST 2015 · Inorganic Chemistry Frontiers (Online)

DOI:https://doi.org/10.1039/C5QI00247H· OSTI ID:1387419

Bruck, Andrea M. ^[1]; Cama, Christina A. ^[1]; Gannett, Cara N. ^[2]; Marschilok, Amy C. ^[1]; Takeuchi, Esther S. ^[3]; Takeuchi, Kenneth J. ^[1]

Stony Brook Univ., NY (United States)
State Univ. of New York (SUNY), Geneseo, NY (United States); Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

The importance of crystallite size control and direct synthesis of materials with desirable properties is broadly applicable for the rational design and development of new active materials for energy storage. Recently, the use of nanoparticles and crystallite size control has redefined electrode design strategies, due in part to the large surface area/volume ratios providing more pathways for ion movement within the bulk electrode. This review is structured primarily as a case study, where reports involving a specific densely structured iron oxide, magnetite, Fe₃O₄, and its use as an electrode in LIBs are used as examples. Due to the high theoretical capacity (924 mA h g^–1), and opportunity for implementation of a low cost electrode material, magnetite was selected as the model material for this review. Notably, crystallite size, morphology, and electrode heterostructure can all play a critical role in battery relevant electrochemistry, particularly for crystallographically dense materials such as Fe₃O₄. Several examples of Fe₃O₄ based composites are described, incorporating different types of conductive materials such as carbons as part of the structure. Further, this review also provides a brief introduction to a newer iron oxide based material with a 2D layered structure, silver ferrite, where crystallite size control was synthetically achieved. By focusing on two specific iron oxide based nanoscale inorganic materials, this review highlights and distinguishes the contributions of electroactive material crystallite size, morphology and electrode heterostructure to electrochemical behavior, facilitating the future development of next generation of battery electrodes.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012673

OSTI ID:: 1387419

Journal Information:: Inorganic Chemistry Frontiers (Online), Vol. 3, Issue 1; Related Information: m2M partners with Stony Brook University (lead); Brookhaven National Laboratory; Columbia University; Georgia Institute of Technology; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; University of California, Berkeley; University of North Carolina at Chapel Hill; ISSN 2052-1553

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 71 works

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Dopamine as the coating agent and carbon precursor for the fabrication of N-doped carbon coated Fe3O4 composites as superior lithium ion anodes Lei, Cheng; Han, Fei; Li, Duo Nanoscale, Vol. 5, Issue 3 https://doi.org/10.1039/c2nr33043a	journal	January 2013
Lithium Batteries and Cathode Materials Whittingham, M. Stanley ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450266	journal	December 2004
Modeling the Mesoscale Transport of Lithium-Magnetite Electrodes Using Insight from Discharge and Voltage Recovery Experiments Knehr, K. W.; Brady, Nicholas William; Cama, Christina A. Columbia University https://doi.org/10.7916/d83r0tcd	text	January 2015

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Insights into Ionic Transport and Structural Changes in Magnetite during Multiple-Electron Transfer Reactions Zhang, Wei; Bock, David C.; Pelliccione, Christopher J. Advanced Energy Materials, Vol. 6, Issue 10 https://doi.org/10.1002/aenm.201502471	journal	March 2016
Magnetic Properties of Poly(trimethylene terephthalate‐ block ‐Poly(tetramethylene oxide) Copolymer Nanocomposites Reinforced by Graphene Oxide–Fe ₃ O ₄ Hybrid Nanoparticles Szymczyk, Anna; Paszkiewicz, Sandra; Typek, Janusz physica status solidi (a), Vol. 216, Issue 23 https://doi.org/10.1002/pssa.201900402	journal	October 2019
Natural Cellulose Derived Nanocomposites as Anodic Materials for Lithium‐Ion Batteries Lin, Zehao; Li, Shun; Huang, Jianguo The Chemical Record https://doi.org/10.1002/tcr.201900030	journal	July 2019
Multi-electron transfer enabled by topotactic reaction in magnetite Zhang, Wei; Li, Yan; Wu, Lijun Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09528-9	journal	April 2019
Self-recovery in Li-metal hybrid lithium-ion batteries via WO ₃ reduction Pathak, Rajesh; Gurung, Ashim; Elbohy, Hytham Nanoscale, Vol. 10, Issue 34 https://doi.org/10.1039/c8nr01507d	journal	January 2018
Three-dimensional iron oxyfluoride/N-doped carbon hybrid nanocomposites as high-performance cathodes for rechargeable Li-ion batteries Li, Xiaopeng; Zhang, Yongzhi; Meng, Yan Inorganic Chemistry Frontiers, Vol. 6, Issue 2 https://doi.org/10.1039/c8qi01057a	journal	January 2019
Disentangling the role of oxygen vacancies on the surface of Fe ₃ O ₄ and γ-Fe ₂ O ₃ Jian, Wei; Wang, Shi-Ping; Zhang, Hong-Xing Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00351g	journal	January 2019
Iron oxides with a reverse spinel structure: impact of active sites on molecule adsorption Jian, Wei; Jia, Ran; Wang, Jian Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00790c	journal	January 2019
Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes Zhang, Xiao; Bruck, Andrea M.; Zhu, Yue Nano Futures, Vol. 2, Issue 3 https://doi.org/10.1088/2399-1984/aada90	journal	August 2018
Controlling the Growth of Ni ₃ S ₂ Anode with Tunable Sodium Storage Song, Xiaosheng; Li, Xifei; Bai, Zhimin Advanced Materials Interfaces, Vol. 5, Issue 11 https://doi.org/10.1002/admi.201701684	journal	March 2018

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