Influence of LaFeO3 Surface Termination on Water Reactivity

Stoerzinger, Kelsey A.; Comes, Ryan; Spurgeon, Steven R.; Thevuthasan, Suntharampillai; Ihm, Kyuwook; Crumlin, Ethan J.; Chambers, Scott A.

doi:10.1021/acs.jpclett.7b00195

Title: Influence of LaFeO₃ Surface Termination on Water Reactivity

Journal Article · Thu Feb 16 00:00:00 EST 2017 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.7b00195· OSTI ID:1343949

^[1];

^[2];

^[1]; Thevuthasan, Suntharampillai ^[1]; Ihm, Kyuwook ^[3];

^[4]; Chambers, Scott A. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate; Auburn Univ., AL (United States). Dept. of Physics
Pohang Accelerator Lab. (PAL) (Korea, Republic of)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source

© 2017 American Chemical Society. The polarity of oxide surfaces can dramatically impact their surface reactivity, in particular, with polar molecules such as water. The surface species that result from this interaction change the oxide electronic structure and chemical reactivity in applications such as photoelectrochemistry but are challenging to probe experimentally. Here, we report a detailed study of the surface chemistry and electronic structure of the perovskite LaFeO 3 in humid conditions using ambient-pressure X-ray photoelectron spectroscopy. Comparing the two possible terminations of the polar (001)-oriented surface, we find that the LaO-terminated surface is more reactive toward water, forming hydroxyl species and adsorbing molecular water at lower relative humidity than its FeO 2 -terminated counterpart. However, the FeO 2 -terminated surface forms more hydroxyl species during water adsorption at higher humidity, suggesting that adsorbate-adsorbate interactions may impact reactivity. Our results demonstrate how the termination of a complex oxide can dramatically impact its reactivity, providing insight that can aid in the design of catalyst materials.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC0576RL01830; AC02-05CH11231

OSTI ID:: 1343949

Alternate ID(s):: OSTI ID: 1379758

Report Number(s):: PNNL-SA-123478

Journal Information:: Journal of Physical Chemistry Letters, Vol. 8, Issue 5; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 43 works

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Speciation and Electronic Structure of La1−xSrxCoO3−δ During Oxygen Electrolysis Stoerzinger, Kelsey A.; Renshaw Wang, Xiao; Hwang, Jonathan Topics in Catalysis, Vol. 61, Issue 20 https://doi.org/10.1007/s11244-018-1070-7	journal	October 2018
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