Influence of LaFeO 3 Surface Termination on Water Reactivity

Stoerzinger, Kelsey A.; Comes, Ryan; Spurgeon, Steven R.; Thevuthasan, Suntharampillai; Ihm, Kyuwook; Crumlin, Ethan J.; Chambers, Scott A.

doi:10.1021/acs.jpclett.7b00195

Influence of LaFeO ₃ Surface Termination on Water Reactivity

Journal Article · Fri Feb 17 04:00:00 UTC 2017 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.7b00195· OSTI ID:1347856

; ; ; Thevuthasan, Suntharampillai; Ihm, Kyuwook; ; Chambers, Scott A.

The polarity of oxide surfaces can dramatically impact their surface reactivity, in particular with polar molecules such as water. The surface species that result from this interaction change the oxide electronic structure and chemical reactivity in applications such as photoelectrochemistry, but are challenging to probe experimentally with atomic-scale understanding. Here we report a detailed study of the surface chemistry and electronic structure of the perovskite LaFeO3 in humid conditions using ambient pressure X-ray photoelectron spectroscopy. Comparing the two possible terminations of the polar (001)-oriented surface, we find that the LaO surface is more reactive toward water, forming hydroxyl species and adsorbing molecular water at lower relative humidity than its FeO2-terminated counterpart. Our results demonstrate how the termination of a complex oxide can dramatically impact its reactivity, providing insight into the design of catalyst materials.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1347856

Report Number(s):: PNNL-SA-123478; 49306

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 5 Vol. 8; ISSN 1948-7185

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

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Chemical and electronic structure analysis of a SrTiO3 (001)/p-Ge (001) hydrogen evolution photocathode Stoerzinger, Kelsey A.; Du, Yingge; Spurgeon, Steven R. MRS Communications, Vol. 8, Issue 02 https://doi.org/10.1557/mrc.2018.38	journal	March 2018
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Water adsorption, dissociation and oxidation on SrTiO ₃ and ferroelectric surfaces revealed by ambient pressure X-ray photoelectron spectroscopy Domingo, Neus; Pach, Elzbieta; Cordero-Edwards, Kumara Physical Chemistry Chemical Physics, Vol. 21, Issue 9 https://doi.org/10.1039/c8cp07632d	journal	January 2019
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