Domain imaging in ferroelectric thin films via channeling-contrast backscattered electron microscopy

Ihlefeld, Jon F.; Michael, Joseph R.; McKenzie, Bonnie B.; Scrymgeour, David A.; Maria, Jon-Paul; Paisley, Elizabeth A.; Kitahara, Andrew R.

doi:10.1007/s10853-016-0402-x

Title: Domain imaging in ferroelectric thin films via channeling-contrast backscattered electron microscopy

Journal Article · Fri Sep 16 00:00:00 EDT 2016 · Journal of Materials Science

DOI:https://doi.org/10.1007/s10853-016-0402-x· OSTI ID:1338400

Ihlefeld, Jon F. ^[1]; Michael, Joseph R. ^[2]; McKenzie, Bonnie B. ^[2]; Scrymgeour, David A. ^[3]; Maria, Jon-Paul ^[4]; Paisley, Elizabeth A. ^[1]; Kitahara, Andrew R. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Electronic, Optical and Nano Materials Dept.
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Materials Performance and Characterization Dept.
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Microsystems Science and Technology Center
North Carolina State Univ., Raleigh, NC (United States). Dept. of Materials Science and Engineering

We report that ferroelastic domain walls provide opportunities for deterministically controlling mechanical, optical, electrical, and thermal energy. Domain wall characterization in micro- and nanoscale systems, where their spacing may be of the order of 100 nm or less is presently limited to only a few techniques, such as piezoresponse force microscopy and transmission electron microscopy. These respective techniques cannot, however, independently characterize domain polarization orientation and domain wall motion in technologically relevant capacitor structures or in a non-destructive manner, thus presenting a limitation of their utility. In this work, we show how backscatter scanning electron microscopy utilizing channeling contrast yield can image the ferroelastic domain structure of ferroelectric films with domain wall spacing as narrow as 10 nm.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000; DMR-1508191

OSTI ID:: 1338400

Report Number(s):: SAND-2016-12845J; 650062

Journal Information:: Journal of Materials Science, Vol. 52, Issue 2; ISSN 0022-2461

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 12 works

Citation information provided by
Web of Science

References (38)

Probing Ferroelectrics Using Optical Second Harmonic Generation Denev, Sava A.; Lummen, Tom T. A.; Barnes, Eftihia Journal of the American Ceramic Society, Vol. 94, Issue 9 https://doi.org/10.1111/j.1551-2916.2011.04740.x	journal	August 2011
Phonon scattering from ferroelectric domain walls: Phonon imaging in KDP Weilert, M. A.; Msall, M. E.; Anderson, A. C. Physical Review Letters, Vol. 71, Issue 5 https://doi.org/10.1103/PhysRevLett.71.735	journal	August 1993
Modes of Domain Wall Motion and Polarization of Lead Zirconate Titanate Polycrystals Omori, Minoru; Mishima, Tsuneo; Fujimoto, Tetsuro Japanese Journal of Applied Physics, Vol. 50, Issue 9S2 https://doi.org/10.7567/JJAP.50.09NC03	journal	September 2011
Observation of Nanoscale $180 °$ Stripe Domains in Ferroelectric ${P b T i O}_{3}$ Thin Films Streiffer, S. K.; Eastman, J. A.; Fong, D. D. Physical Review Letters, Vol. 89, Issue 6 https://doi.org/10.1103/PhysRevLett.89.067601	journal	July 2002
Direct evaluation of domain‐wall and intrinsic contributions to the dielectric and piezoelectric response and their temperature dependence on lead zirconate‐titanate ceramics Zhang, Q. M.; Wang, H.; Kim, N. Journal of Applied Physics, Vol. 75, Issue 1 https://doi.org/10.1063/1.355874	journal	January 1994
Room temperature concurrent formation of ultra-dense arrays of ferroelectric domain walls Mtebwa, Mahamudu; Feigl, Ludwig; Yudin, Petr Applied Physics Letters, Vol. 107, Issue 14 https://doi.org/10.1063/1.4932524	journal	October 2015
Spatial inhomogeneity of imprint and switching behavior in ferroelectric capacitors Gruverman, A.; Rodriguez, B. J.; Kingon, A. I. Applied Physics Letters, Vol. 82, Issue 18 https://doi.org/10.1063/1.1570942	journal	May 2003
Piezoresponse Force Microscopy Studies of Switching Behavior of Ferroelectric Capacitors on a 100-ns Time Scale Gruverman, A.; Wu, D.; Scott, J. F. Physical Review Letters, Vol. 100, Issue 9 https://doi.org/10.1103/PhysRevLett.100.097601	journal	March 2008
Ferroelectric ceramic electrooptic materials and devices Land, C. E.; Thacher, P. D. Proceedings of the IEEE, Vol. 57, Issue 5 https://doi.org/10.1109/PROC.1969.7070	journal	January 1969
Contribution of the irreversible displacement of domain walls to the piezoelectric effect in barium titanate and lead zirconate titanate ceramics Damjanovic, Dragan; Demartin, Marlyse Journal of Physics: Condensed Matter, Vol. 9, Issue 23 https://doi.org/10.1088/0953-8984/9/23/018	journal	June 1997
Study of ferroelectric and ferroelastic domain structures by scanning electron microscopy Le Bihan, R. Ferroelectrics, Vol. 97, Issue 1 https://doi.org/10.1080/00150198908018081	journal	September 1989
Room-Temperature Voltage Tunable Phonon Thermal Conductivity via Reconfigurable Interfaces in Ferroelectric Thin Films Ihlefeld, Jon F.; Foley, Brian M.; Scrymgeour, David A. Nano Letters, Vol. 15, Issue 3, p. 1791-1795 https://doi.org/10.1021/nl504505t	journal	February 2015
Penetration and energy-loss theory of electrons in solid targets Kanaya, K.; Okayama, S. Journal of Physics D: Applied Physics, Vol. 5, Issue 1 https://doi.org/10.1088/0022-3727/5/1/308	journal	January 1972
Conduction at domain walls in oxide multiferroics Seidel, J.; Martin, L. W.; He, Q. Nature Materials, Vol. 8, Issue 3 https://doi.org/10.1038/nmat2373	journal	January 2009
Phonon transport in barium titanate Mante, A. J. H.; Volger, J. Physica, Vol. 52, Issue 4 https://doi.org/10.1016/0031-8914(71)90164-9	journal	April 1971
Labile Ferroelastic Nanodomains in Bilayered Ferroelectric Thin Films Anbusathaiah, Varatharajan; Kan, Daisuke; Kartawidjaja, Fransiska C. Advanced Materials, Vol. 21, Issue 34 https://doi.org/10.1002/adma.200803701	journal	September 2009
Proton and carbon-13 NMR investigations of lead zirconate titanate (Pb(Zr,Ti)O3) thin-film precursor solutions Assink, R. A.; Schwartz, R. W. Chemistry of Materials, Vol. 5, Issue 4 https://doi.org/10.1021/cm00028a019	journal	April 1993
Effects of coherent ferroelastic domain walls on the thermal conductivity and Kapitza conductance in bismuth ferrite Hopkins, Patrick E.; Adamo, Carolina; Ye, Linghan Applied Physics Letters, Vol. 102, Issue 12 https://doi.org/10.1063/1.4798497	journal	March 2013
Chemically Homogeneous Complex Oxide Thin Films Via Improved Substrate Metallization Shelton, Christopher T.; Kotula, Paul G.; Brennecka, Geoff L. Advanced Functional Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adfm.201103077	journal	March 2012
Fractal Dimension and Size Scaling of Domains in Thin Films of Multiferroic ${BiFeO}_{3}$ Catalan, G.; Béa, H.; Fusil, S. Physical Review Letters, Vol. 100, Issue 2 https://doi.org/10.1103/PhysRevLett.100.027602	journal	January 2008
A Review of Domain Modelling and Domain Imaging Techniques in Ferroelectric Crystals Potnis, Prashant; Tsou, Nien-Ti; Huber, John Materials, Vol. 4, Issue 2 https://doi.org/10.3390/ma4020417	journal	February 2011
Nanoscale Observation of Time-Dependent Domain Wall Pinning as the Origin of Polarization Fatigue Yang, Sang Mo; Kim, Tae Heon; Yoon, Jong-Gul Advanced Functional Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adfm.201102685	journal	March 2012
Direct observation of ferroelectric domain formation by environmental scanning electron microscopy Reichmann, A.; Zankel, A.; Reingruber, H. Journal of the European Ceramic Society, Vol. 31, Issue 15 https://doi.org/10.1016/j.jeurceramsoc.2011.05.043	journal	December 2011
Ferroelastic domain wall dynamics in ferroelectric bilayers Anbusathaiah, V.; Jesse, S.; Arredondo, M. A. Acta Materialia, Vol. 58, Issue 16 https://doi.org/10.1016/j.actamat.2010.06.004	journal	September 2010
Conduction at Domain Walls in Insulating Pb(Zr0.2Ti0.8)O3 Thin Films Guyonnet, Jill; Gaponenko, Iaroslav; Gariglio, Stefano Advanced Materials, Vol. 23, Issue 45 https://doi.org/10.1002/adma.201102254	journal	September 2011
Direct Observation of Ferroelectric Domains in LiTa $O_{3}$ Using Environmental Scanning Electron Microscopy Zhu, Shining; Cao, Wenwu Physical Review Letters, Vol. 79, Issue 13 https://doi.org/10.1103/PhysRevLett.79.2558	journal	September 1997
Dielectric properties of fine‐grained barium titanate ceramics Arlt, G.; Hennings, D.; de With, G. Journal of Applied Physics, Vol. 58, Issue 4 https://doi.org/10.1063/1.336051	journal	August 1985
Ultrafast switching of ferroelastic nanodomains in bilayered ferroelectric thin films Ehara, Y.; Yasui, S.; Nagata, J. Applied Physics Letters, Vol. 99, Issue 18, Article No. 182906 https://doi.org/10.1063/1.3657468	journal	October 2011
Observation of inhomogeneous domain nucleation in epitaxial Pb(Zr,Ti)O3 capacitors Kim, D. J.; Jo, J. Y.; Kim, T. H. Applied Physics Letters, Vol. 91, Issue 13 https://doi.org/10.1063/1.2790485	journal	September 2007
Universality of Polarization Switching Dynamics in Ferroelectric Capacitors Revealed by 5D Piezoresponse Force Microscopy Kim, Yunseok; Lu, Xiaoli; Jesse, Stephen Advanced Functional Materials, Vol. 23, Issue 32 https://doi.org/10.1002/adfm.201300079	journal	April 2013
Visualization of ferroelectric domains in bulk single crystals Soergel, E. Applied Physics B, Vol. 81, Issue 6 https://doi.org/10.1007/s00340-005-1989-9	journal	October 2005
Bundles of polytwins as meta-elastic domains in the thin polycrystalline simple multi-ferroic system PZT Ivry, Yachin; Chu, D. P.; Durkan, Colm Nanotechnology, Vol. 21, Issue 6 https://doi.org/10.1088/0957-4484/21/6/065702	journal	January 2010
Electromechanical Imaging and Spectroscopy of Ferroelectric and Piezoelectric Materials: State of the Art and Prospects for the Future Balke, Nina; Bdikin, Igor; Kalinin, Sergei V. Journal of the American Ceramic Society, Vol. 92, Issue 8 https://doi.org/10.1111/j.1551-2916.2009.03240.x	journal	August 2009
Impact of elasticity on the piezoresponse of adjacent ferroelectric domains investigated by scanning force microscopy Jungk, Tobias; Hoffmann, Ákos; Soergel, Elisabeth Journal of Applied Physics, Vol. 102, Issue 8 https://doi.org/10.1063/1.2795680	journal	October 2007
Dynamics of ferroelastic domains in ferroelectric thin films Nagarajan, V.; Roytburd, A.; Stanishevsky, A. Nature Materials, Vol. 2, Issue 1 https://doi.org/10.1038/nmat800	journal	December 2002
Orientation, stress, and strain in an (001) barium titanate single crystal with 90° lamellar domains determined using electron backscatter diffraction Howell, Jane A.; Vaudin, Mark D.; Cook, Robert F. Journal of Materials Science, Vol. 49, Issue 5 https://doi.org/10.1007/s10853-013-7915-3	journal	December 2013
Direct Scanning Electron Microscopy Imaging of Ferroelectric Domains After Ion Milling GrÃ¼ner, Daniel; Shen, Zhijian Journal of the American Ceramic Society, Vol. 93, Issue 1 https://doi.org/10.1111/j.1551-2916.2009.03392.x	journal	January 2010
Observation of the domain structure of ferroelectrics with the scanning electron microscope Sogr, A. A.; Kopylova, I. B. Ferroelectrics, Vol. 191, Issue 1 https://doi.org/10.1080/00150199708015638	journal	January 1997

Cited By (1)

Domain structure evolution in relaxor PLZT 8/65/35 ceramics after chemical etching and electron beam irradiation Gimadeeva, L. V.; Shikhova, V. A.; Chezganov, D. S. Ferroelectrics, Vol. 525, Issue 1 https://doi.org/10.1080/00150193.2018.1432933	journal	March 2018

Similar Records

Highly mobile ferroelastic domain walls in compositionally graded ferroelectric thin films

Journal Article · Mon Feb 15 00:00:00 EST 2016 · Nature Materials · OSTI ID:1338400

Damodaran, Anoop; Okatan, M. B.; Kacher, J.; +10 more

Structure and Dynamics of Domains in Ferroelectric Nanostructures – Phase-Field Modeling (Final Technical Report)

Technical Report · Mon Jun 15 00:00:00 EDT 2020 · OSTI ID:1338400

Chen, Long-Qing; Cheng, Xiao-Xing; Zorn, Jacob

Exploring Physics of Ferroelectric Domain Walls in Real Time: Deep Learning Enabled Scanning Probe Microscopy

Journal Article · Mon Sep 05 00:00:00 EDT 2022 · Advanced Science · OSTI ID:1338400

Liu, Yongtao; Kelley, Kyle P.; Funakubo, Hiroshi; +2 more

Related Subjects

47 OTHER INSTRUMENTATION

Title: Domain imaging in ferroelectric thin films via channeling-contrast backscattered electron microscopy

Citation Formats

References (38)

Cited By (1)

Similar Records

Related Subjects