Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

Chan, Amy Y.; Perry, Ian B.; Bissonnette, Noah B.; Buksh, Benito F.; Edwards, Grant A.; Frye, Lucas I.; Garry, Olivia L.; Lavagnino, Marissa N.; Li, Beryl X.; Liang, Yufan; Mao, Edna; Millet, Agustin; Oakley, James V.; Reed, Nicholas L.; Sakai, Holt A.; Seath, Ciaran P.; MacMillan, David C.

doi:10.1021/acs.chemrev.1c00383

Title: Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

Abstract

The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. Finally, this Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.

Authors:

Chan, Amy Y. ^[1]; Perry, Ian B. ^[1];

^[1]; Buksh, Benito F. ^[1]; Edwards, Grant A. ^[1];

^[1]; Garry, Olivia L. ^[1];

^[1]; Li, Beryl X. ^[1]; Liang, Yufan ^[1]; Mao, Edna ^[1]; Millet, Agustin ^[1]; Oakley, James V. ^[1];

^[1]; Sakai, Holt A. ^[1]; Seath, Ciaran P. ^[1];

^[1]

Princeton Univ., NJ (United States). Merck Center for Catalysis

Publication Date:: Thu Nov 18 00:00:00 EST 2021

Research Org.:: Princeton Univ., NJ (United States); Energy Frontier Research Centers (EFRC) (United States). Bio-inspired Light-Escalated Chemistry (BioLEC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institute of General Medical Sciences (NIGMS)

OSTI Identifier:: 2281322

Grant/Contract Number:: SC0019370; R35GM134897-01

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Reviews

Additional Journal Information:: Journal Volume: 122; Journal Issue: 2; Journal ID: ISSN 0009-2665

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Alkyls; Anions; Catalysis; Coupling reactions; Cross coupling reaction; metallophotoredox catalysis

Citation Formats


                    Chan, Amy Y., Perry, Ian B., Bissonnette, Noah B., Buksh, Benito F., Edwards, Grant A., Frye, Lucas I., Garry, Olivia L., Lavagnino, Marissa N., Li, Beryl X., Liang, Yufan, Mao, Edna, Millet, Agustin, Oakley, James V., Reed, Nicholas L., Sakai, Holt A., Seath, Ciaran P., and MacMillan, David C. Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.  United States: N. p., 2021. 
Web.  doi:10.1021/acs.chemrev.1c00383.

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                    Chan, Amy Y., Perry, Ian B., Bissonnette, Noah B., Buksh, Benito F., Edwards, Grant A., Frye, Lucas I., Garry, Olivia L., Lavagnino, Marissa N., Li, Beryl X., Liang, Yufan, Mao, Edna, Millet, Agustin, Oakley, James V., Reed, Nicholas L., Sakai, Holt A., Seath, Ciaran P., & MacMillan, David C. Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.  United States.  https://doi.org/10.1021/acs.chemrev.1c00383

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                    Chan, Amy Y., Perry, Ian B., Bissonnette, Noah B., Buksh, Benito F., Edwards, Grant A., Frye, Lucas I., Garry, Olivia L., Lavagnino, Marissa N., Li, Beryl X., Liang, Yufan, Mao, Edna, Millet, Agustin, Oakley, James V., Reed, Nicholas L., Sakai, Holt A., Seath, Ciaran P., and MacMillan, David C. Thu .  
"Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis".  United States.  https://doi.org/10.1021/acs.chemrev.1c00383.  https://www.osti.gov/servlets/purl/2281322.

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@article{osti_2281322,

  title        = {Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis},

  author       = {Chan, Amy Y. and Perry, Ian B. and Bissonnette, Noah B. and Buksh, Benito F. and Edwards, Grant A. and Frye, Lucas I. and Garry, Olivia L. and Lavagnino, Marissa N. and Li, Beryl X. and Liang, Yufan and Mao, Edna and Millet, Agustin and Oakley, James V. and Reed, Nicholas L. and Sakai, Holt A. and Seath, Ciaran P. and MacMillan, David C.},

  abstractNote = {The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. Finally, this Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.},

  doi          = {10.1021/acs.chemrev.1c00383},

  journal      = {Chemical Reviews},

  number       = 2,

  volume       = 122,

  place        = {United States},

  year         = {Thu Nov 18 00:00:00 EST 2021},

  month        = {Thu Nov 18 00:00:00 EST 2021}

}

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Works referenced in this record:

Palladium-Catalyzed Cross-Coupling Reactions in Total Synthesis
journal, July 2005

Nicolaou, K. C.; Bulger, Paul G.; Sarlah, David
Angewandte Chemie International Edition, Vol. 44, Issue 29
DOI: 10.1002/anie.200500368

Catalytic asymmetric hydrogenation employing a soluble, optically active, rhodium complex
journal, January 1968

Knowles, W. S.; Sabacky, M. J.
Chemical Communications (London), Issue 22
DOI: 10.1039/c19680001445

2, 2'-bis(diphenylphosphino)-1, 1'-binaphthyl(binap)
journal, January 1984

Miyashita, A.; Takaya, H.; Souchi, T.
Tetrahedron, Vol. 40, Issue 8
DOI: 10.1016/S0040-4020(01)82411-X

The first practical method for asymmetric epoxidation
journal, August 1980

Katsuki, Tsutomu; Sharpless, K. Barry
Journal of the American Chemical Society, Vol. 102, Issue 18
DOI: 10.1021/ja00538a077

Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques
journal, February 1971

Jean-Louis Hérisson, Par; Chauvin, Yves
Die Makromolekulare Chemie, Vol. 141, Issue 1, p. 161-176
DOI: 10.1002/macp.1971.021410112

Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstraction
journal, October 1974

Schrock, Richard R.
Journal of the American Chemical Society, Vol. 96, Issue 21
DOI: 10.1021/ja00828a061

Possible intermediate in the tungsten-catalyzed olefin metathesis reaction
journal, April 1972

Grubbs, Robert H.; Brunck, Terence K.
Journal of the American Chemical Society, Vol. 94, Issue 7
DOI: 10.1021/ja00762a073

Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives
journal, September 1968

Heck, Richard F.
Journal of the American Chemical Society, Vol. 90, Issue 20
DOI: 10.1021/ja01022a034

A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides
journal, October 1976

Baba, Shigeru; Negishi, Eiichi
Journal of the American Chemical Society, Vol. 98, Issue 21
DOI: 10.1021/ja00437a067

A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
journal, January 1979

Miyaura, Norio; Yamada, Kinji; Suzuki, Akira
Tetrahedron Letters, Vol. 20, Issue 36
DOI: 10.1016/S0040-4039(01)95429-2

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
journal, September 2016

Ruiz-Castillo, Paula; Buchwald, Stephen L.
Chemical Reviews, Vol. 116, Issue 19
DOI: 10.1021/acs.chemrev.6b00512

Reductive coupling of organometals induced by oxidation. Detection of metastable paramagnetic intermediates
journal, March 1978

Tsou, T. T.; Kochi, J. K.
Journal of the American Chemical Society, Vol. 100, Issue 5
DOI: 10.1021/ja00473a067

Oxygen-atom transfer from nitrous oxide to a nickel metallacycle. Synthesis, structure, and reactions of [cyclic] (2,2'-bipyridine)Ni(OCH2CH2CH2CH2)
journal, March 1993

Matsunaga, Phillip T.; Hillhouse, Gregory L.; Rheingold, Arnold L.
Journal of the American Chemical Society, Vol. 115, Issue 5
DOI: 10.1021/ja00058a085

Oxygen-atom transfer from nitrous oxide (NNO) to nickel alkyls. Syntheses and reactions of nickel(II) alkoxides
journal, January 1995

Matsunaga, Phillip T.; Mavropoulos, John C.; Hillhouse, Gregory L.
Polyhedron, Vol. 14, Issue 1
DOI: 10.1016/0277-5387(94)00330-H

Carbon−Oxygen Reductive-Elimination from Nickel(II) Oxametallacycles and Factors That Control Formation of Ether, Aldehyde, Alcohol, or Ester Products
journal, August 1997

Han, Runyu; Hillhouse, Gregory L.
Journal of the American Chemical Society, Vol. 119, Issue 34
DOI: 10.1021/ja9714999

New N- and O-arylations with phenylboronic acids and cupric acetate
journal, May 1998

Chan, Dominic M. T.; Monaco, Kevin L.; Wang, Ru-Ping
Tetrahedron Letters, Vol. 39, Issue 19
DOI: 10.1016/S0040-4039(98)00503-6

New aryl/heteroaryl CN bond cross-coupling reactions via arylboronic acid/cupric acetate arylation
journal, May 1998

Lam, Patrick Y. S.; Clark, Charles G.; Saubern, Simon
Tetrahedron Letters, Vol. 39, Issue 19
DOI: 10.1016/S0040-4039(98)00504-8

Synthesis of diaryl ethers through the copper-promoted arylation of phenols with arylboronic acids. An expedient synthesis of thyroxine
journal, May 1998

Evans, David A.; Katz, Jeffrey L.; West, Theodore R.
Tetrahedron Letters, Vol. 39, Issue 19
DOI: 10.1016/S0040-4039(98)00502-4

Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans
journal, August 2010

Wang, Xisheng; Lu, Yi; Dai, Hui-Xiong
Journal of the American Chemical Society, Vol. 132, Issue 35
DOI: 10.1021/ja105366u

High-valent organometallic copper and palladium in catalysis
journal, April 2012

Hickman, Amanda J.; Sanford, Melanie S.
Nature, Vol. 484, Issue 7393
DOI: 10.1038/nature11008

Catalyst Control of Site Selectivity in the Pd ^II/IV -Catalyzed Direct Arylation of Naphthalene
journal, January 2011

Hickman, Amanda J.; Sanford, Melanie S.
ACS Catalysis, Vol. 1, Issue 3
DOI: 10.1021/cs1001543

Chemische Lichtwirkungen
journal, May 1908

Ciamician, Giacomo; Silber, P.
Berichte der deutschen chemischen Gesellschaft, Vol. 41, Issue 2
DOI: 10.1002/cber.19080410272

Applications of functionalized transition metal complexes in photonic and optoelectronic devices
journal, October 1998

Kalyanasundaram, K.
Coordination Chemistry Reviews, Vol. 177, Issue 1
DOI: 10.1016/S0010-8545(98)00189-1

Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies
journal, February 2010

Takeda, Hiroyuki; Ishitani, Osamu
Coordination Chemistry Reviews, Vol. 254, Issue 3-4
DOI: 10.1016/j.ccr.2009.09.030

Synthetically Tailored Excited States: Phosphorescent, Cyclometalated Iridium(III) Complexes and Their Applications
journal, October 2006

Lowry, Michael S.; Bernhard, Stefan
Chemistry - A European Journal, Vol. 12, Issue 31
DOI: 10.1002/chem.200600618

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
journal, March 2013

Prier, Christopher K.; Rankic, Danica A.; MacMillan, David W. C.
Chemical Reviews, Vol. 113, Issue 7
DOI: 10.1021/cr300503r

Photoredox Catalysis in Organic Chemistry
journal, June 2016

Shaw, Megan H.; Twilton, Jack; MacMillan, David W. C.
The Journal of Organic Chemistry, Vol. 81, Issue 16
DOI: 10.1021/acs.joc.6b01449

Organic Photoredox Catalysis
journal, June 2016

Romero, Nathan A.; Nicewicz, David A.
Chemical Reviews, Vol. 116, Issue 17
DOI: 10.1021/acs.chemrev.6b00057

The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle: The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle
journal, March 2020

Capaldo, Luca; Ravelli, Davide
European Journal of Organic Chemistry, Vol. 2020, Issue 19
DOI: 10.1002/ejoc.202000144

The photophysics of photoredox catalysis: a roadmap for catalyst design
journal, January 2016

Arias-Rotondo, Daniela M.; McCusker, James K.
Chemical Society Reviews, Vol. 45, Issue 21
DOI: 10.1039/C6CS00526H

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis
journal, March 2014

Hopkinson, Matthew N.; Sahoo, Basudev; Li, Jun-Long
Chemistry - A European Journal, Vol. 20, Issue 14
DOI: 10.1002/chem.201304823

Dual Catalysis Strategies in Photochemical Synthesis
journal, April 2016

Skubi, Kazimer L.; Blum, Travis R.; Yoon, Tehshik P.
Chemical Reviews, Vol. 116, Issue 17
DOI: 10.1021/acs.chemrev.6b00018

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling
journal, May 2016

Levin, Mark D.; Kim, Suhong; Toste, F. Dean
ACS Central Science, Vol. 2, Issue 5
DOI: 10.1021/acscentsci.6b00090

The merger of transition metal and photocatalysis
journal, July 2017

Twilton, Jack; Le, Chi; Zhang, Patricia
Nature Reviews Chemistry, Vol. 1, Issue 7
DOI: 10.1038/s41570-017-0052

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
journal, May 2012

Johansson Seechurn, Carin C. C.; Kitching, Matthew O.; Colacot, Thomas J.
Angewandte Chemie International Edition, Vol. 51, Issue 21, p. 5062-5085
DOI: 10.1002/anie.201107017

Recent advances in homogeneous nickel catalysis
journal, May 2014

Tasker, Sarah Z.; Standley, Eric A.; Jamison, Timothy F.
Nature, Vol. 509, Issue 7500
DOI: 10.1038/nature13274

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore
journal, February 2014

Zuo, Zhiwei; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 136, Issue 14
DOI: 10.1021/ja501621q

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin
journal, July 2014

Chu, Lingling; Ohta, Chisa; Zuo, Zhiwei
Journal of the American Chemical Society, Vol. 136, Issue 31
DOI: 10.1021/ja505964r

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis
journal, April 2015

Ventre, Sandrine; Petronijevic, Filip R.; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 137, Issue 17
DOI: 10.1021/jacs.5b02244

Merging photoredox with nickel catalysis: Coupling of -carboxyl sp3-carbons with aryl halides
journal, June 2014

Zuo, Z.; Ahneman, D. T.; Chu, L.
Science, Vol. 345, Issue 6195
DOI: 10.1126/science.1255525

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis
journal, February 2016

Zuo, Zhiwei; Cong, Huan; Li, Wei
Journal of the American Chemical Society, Vol. 138, Issue 6
DOI: 10.1021/jacs.5b13211

On-DNA Decarboxylative Arylation: Merging Photoredox with Nickel Catalysis in Water
journal, June 2019

Kölmel, Dominik K.; Meng, Jiang; Tsai, Mei-Hsuan
ACS Combinatorial Science, Vol. 21, Issue 8
DOI: 10.1021/acscombsci.9b00076

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids
journal, May 2015

Chu, Lingling; Lipshultz, Jeffrey M.; MacMillan, David W. C.
Angewandte Chemie International Edition, Vol. 54, Issue 27
DOI: 10.1002/anie.201501908

Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides
journal, January 2015

Noble, Adam; McCarver, Stefan J.; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 137, Issue 2
DOI: 10.1021/ja511913h

Decarboxylative Hydroalkylation of Alkynes
journal, April 2018

Till, Nicholas A.; Smith, Russell T.; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 140, Issue 17
DOI: 10.1021/jacs.8b02834

Fragment Couplings via CO ₂ Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox
journal, September 2015

Le, Chi “Chip”; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 137, Issue 37
DOI: 10.1021/jacs.5b08304

Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones
journal, January 1980

Shimizu, Isao; Yamada, Toshiro; Tsuji, Jiro
Tetrahedron Letters, Vol. 21, Issue 33
DOI: 10.1016/S0040-4039(00)77444-2

Facile generation of a reactive palladium(II) enolate intermediate by the decarboxylation of palladium(II) .beta.-ketocarboxylate and its utilization in allylic acylation
journal, September 1980

Tsuda, Tetsuo; Chujo, Yoshiki; Nishi, Seiichi
Journal of the American Chemical Society, Vol. 102, Issue 20
DOI: 10.1021/ja00540a053

Cross-Couplings of Unactivated Secondary Alkyl Halides: Room-Temperature Nickel-Catalyzed Negishi Reactions of Alkyl Bromides and Iodides
journal, November 2003

Zhou, Jianrong (Steve); Fu, Gregory C.
Journal of the American Chemical Society, Vol. 125, Issue 48
DOI: 10.1021/ja0389366

Suzuki Cross-Couplings of Unactivated Secondary Alkyl Bromides and Iodides
journal, January 2004

Zhou, Jianrong (Steve); Fu, Gregory C.
Journal of the American Chemical Society, Vol. 126, Issue 5
DOI: 10.1021/ja039889k

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides
journal, August 2016

Johnston, Craig P.; Smith, Russell T.; Allmendinger, Simon
Nature, Vol. 536, Issue 7616
DOI: 10.1038/nature19056

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
journal, March 2011

Jana, Ranjan; Pathak, Tejas P.; Sigman, Matthew S.
Chemical Reviews, Vol. 111, Issue 3
DOI: 10.1021/cr100327p

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis
journal, June 2014

Tellis, J. C.; Primer, D. N.; Molander, G. A.
Science, Vol. 345, Issue 6195
DOI: 10.1126/science.1253647

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings
journal, April 2015

Gutierrez, Osvaldo; Tellis, John C.; Primer, David N.
Journal of the American Chemical Society, Vol. 137, Issue 15
DOI: 10.1021/ja513079r

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis
journal, November 2015

El Khatib, Mirna; Serafim, Ricardo Augusto Massarico; Molander, Gary A.
Angewandte Chemie International Edition, Vol. 55, Issue 1
DOI: 10.1002/anie.201506147

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers
journal, June 2015

Karakaya, Idris; Primer, David N.; Molander, Gary A.
Organic Letters, Vol. 17, Issue 13
DOI: 10.1021/acs.orglett.5b01463

Single-Electron Transmetalation: Photoredox/Nickel Dual Catalytic Cross-Coupling of Secondary Alkyl β-Trifluoroboratoketones and -esters with Aryl Bromides
journal, June 2016

Tellis, John C.; Amani, Javad; Molander, Gary A.
Organic Letters, Vol. 18, Issue 12
DOI: 10.1021/acs.orglett.6b01357

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp ² )-C(sp ³ ) Cross-Couplings in Flow
journal, October 2016

Lima, Fabio; Kabeshov, Mikhail A.; Tran, Duc N.
Angewandte Chemie International Edition, Vol. 55, Issue 45
DOI: 10.1002/anie.201605548

Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis
journal, May 2016

Karimi-Nami, Rahman; Tellis, John C.; Molander, Gary A.
Organic Letters, Vol. 18, Issue 11
DOI: 10.1021/acs.orglett.6b00911

Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling
journal, November 2017

Alam, Rauful; Molander, Gary A.
The Journal of Organic Chemistry, Vol. 82, Issue 24
DOI: 10.1021/acs.joc.7b02589

Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis
journal, January 2017

Amani, Javad; Molander, Gary A.
The Journal of Organic Chemistry, Vol. 82, Issue 3
DOI: 10.1021/acs.joc.6b02897

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides
journal, April 2017

Amani, Javad; Alam, Rauful; Badir, Shorouk
Organic Letters, Vol. 19, Issue 9
DOI: 10.1021/acs.orglett.7b00989

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso -Anhydrides
journal, February 2017

Stache, Erin E.; Rovis, Tomislav; Doyle, Abigail G.
Angewandte Chemie International Edition, Vol. 56, Issue 13
DOI: 10.1002/anie.201700097

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer
journal, July 2017

Primer, David N.; Molander, Gary A.
Journal of the American Chemical Society, Vol. 139, Issue 29
DOI: 10.1021/jacs.7b06288

On the Nature of C(sp ³ )–C(sp ² ) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides
journal, March 2020

Yuan, Mingbin; Song, Zhihui; Badir, Shorouk O.
Journal of the American Chemical Society, Vol. 142, Issue 15
DOI: 10.1021/jacs.0c02355

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling
journal, August 2015

Nawrat, Christopher C.; Jamison, Christopher R.; Slutskyy, Yuriy
Journal of the American Chemical Society, Vol. 137, Issue 35
DOI: 10.1021/jacs.5b07678

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp ³ –sp ² Cross-Coupling of Oxalates with Aryl Halides
journal, October 2016

Zhang, Xiaheng; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 138, Issue 42
DOI: 10.1021/jacs.6b09533

A new method for the deoxygenation of secondary alcohols
journal, January 1975

Barton, Derek H. R.; McCombie, Stuart W.
Journal of the Chemical Society, Perkin Transactions 1, Issue 16
DOI: 10.1039/p19750001574

O -Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp ³ –Csp ² Cross-Coupling
journal, May 2017

Vara, Brandon A.; Patel, Niki R.; Molander, Gary A.
ACS Catalysis, Vol. 7, Issue 6
DOI: 10.1021/acscatal.7b00772

Remote Nickel-Catalyzed Cross-Coupling Arylation via Proton-Coupled Electron Transfer-Enabled C–C Bond Cleavage
journal, February 2020

Huang, Long; Ji, Tengfei; Rueping, Magnus
Journal of the American Chemical Society, Vol. 142, Issue 7
DOI: 10.1021/jacs.9b12490

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O–H Bonds
journal, August 2016

Yayla, Hatice G.; Wang, Huaiju; Tarantino, Kyle T.
Journal of the American Chemical Society, Vol. 138, Issue 34
DOI: 10.1021/jacs.6b06517

Dual Catalytic Strategy for Forging sp ² – sp ³ and sp ³ – sp ³ Architectures via β - Scission of Aliphatic Alcohol Derivatives
journal, November 2020

Cong, Fei; Lv, Xin-Yang; Day, Craig S.
Journal of the American Chemical Society, Vol. 142, Issue 49
DOI: 10.1021/jacs.0c11172

Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis
journal, March 2021

Chen, Yuegang; Wang, Xin; He, Xu
Journal of the American Chemical Society, Vol. 143, Issue 13
DOI: 10.1021/jacs.1c00618

Photosubstitution of Dicyanoarenes by Hypervalent Allylsilicon Reagents via Photoinduced Electron Transfer
journal, April 2014

Matsuoka, Daisuke; Nishigaichi, Yutaka
Chemistry Letters, Vol. 43, Issue 4
DOI: 10.1246/cl.131132

Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds
journal, July 2015

Corcé, Vincent; Chamoreau, Lise‐Marie; Derat, Etienne
Angewandte Chemie International Edition, Vol. 54, Issue 39
DOI: 10.1002/anie.201504963

Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions
journal, January 2016

Lévêque, Christophe; Chenneberg, Ludwig; Corcé, Vincent
Organic Chemistry Frontiers, Vol. 3, Issue 4
DOI: 10.1039/C6QO00014B

Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates
journal, December 2015

Jouffroy, Matthieu; Primer, David N.; Molander, Gary A.
Journal of the American Chemical Society, Vol. 138, Issue 2
DOI: 10.1021/jacs.5b10963

Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis
journal, February 2016

Patel, Niki R.; Kelly, Christopher B.; Jouffroy, Matthieu
Organic Letters, Vol. 18, Issue 4
DOI: 10.1021/acs.orglett.6b00024

C(sp ³ )–C(sp ² ) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates
journal, January 2017

Vara, Brandon A.; Jouffroy, Matthieu; Molander, Gary A.
Chemical Science, Vol. 8, Issue 1
DOI: 10.1039/C6SC03236B

Photoredox/Nickel Dual Catalysis for the C(sp ³ )-C(sp ³ ) Cross-Coupling of Alkylsilicates with Alkyl Halides: Photoredox/Nickel Dual Catalysis for the C(sp ³ )-C(sp ³ ) Cross-Coupling of Alkylsilicates with Alkyl Halides
journal, March 2017

Lévêque, Christophe; Corcé, Vincent; Chenneberg, Ludwig
European Journal of Organic Chemistry, Vol. 2017, Issue 15
DOI: 10.1002/ejoc.201601571

Ru/Ni Dual Catalytic Desulfinative Photoredox C _{sp ²} –C _{sp ³} Cross-Coupling of Alkyl Sulfinate Salts and Aryl Halides
journal, November 2017

Knauber, Thomas; Chandrasekaran, Ramalakshmi; Tucker, Joseph W.
Organic Letters, Vol. 19, Issue 24
DOI: 10.1021/acs.orglett.7b03280

Transfer hydrogenation with Hantzsch esters and related organic hydride donors
journal, January 2012

Zheng, Chao; You, Shu-Li
Chemical Society Reviews, Vol. 41, Issue 6
DOI: 10.1039/c1cs15268h

Visible‐Light‐Mediated Aromatic Substitution Reactions of Cyanoarenes with 4‐Alkyl‐1,4‐dihydropyridines through Double Carbon–Carbon Bond Cleavage
journal, February 2016

Nakajima, Kazunari; Nojima, Sunao; Sakata, Ken
ChemCatChem, Vol. 8, Issue 6
DOI: 10.1002/cctc.201600037

Nickel- and Photoredox-Catalyzed Cross-Coupling Reactions of Aryl Halides with 4-Alkyl-1,4-dihydropyridines as Formal Nucleophilic Alkylation Reagents
journal, October 2016

Nakajima, Kazunari; Nojima, Sunao; Nishibayashi, Yoshiaki
Angewandte Chemie International Edition, Vol. 55, Issue 45
DOI: 10.1002/anie.201606513

Radical-Based C−C Bond-Forming Processes Enabled by the Photoexcitation of 4-Alkyl-1,4-dihydropyridines
journal, October 2017

Buzzetti, Luca; Prieto, Alexis; Roy, Sudipta Raha
Angewandte Chemie International Edition, Vol. 56, Issue 47
DOI: 10.1002/anie.201709571

Photochemical Asymmetric Nickel‐Catalyzed Acyl Cross‐Coupling
journal, November 2019

Gandolfo, Eugenio; Tang, Xinjun; Raha Roy, Sudipta
Angewandte Chemie International Edition, Vol. 58, Issue 47
DOI: 10.1002/anie.201910168

1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis
journal, October 2016

Gutiérrez-Bonet, Álvaro; Tellis, John C.; Matsui, Jennifer K.
ACS Catalysis, Vol. 6, Issue 12
DOI: 10.1021/acscatal.6b02786

Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insights
journal, November 2018

Matsui, Jennifer K.; Gutiérrez-Bonet, Álvaro; Rotella, Madeline
Angewandte Chemie International Edition, Vol. 57, Issue 48
DOI: 10.1002/anie.201809919

Amide Synthesis by Nickel/Photoredox‐Catalyzed Direct Carbamoylation of (Hetero)Aryl Bromides
journal, March 2020

Alandini, Nurtalya; Buzzetti, Luca; Favi, Gianfranco
Angewandte Chemie International Edition, Vol. 59, Issue 13
DOI: 10.1002/anie.202000224

Functionalization of C-H Bonds by Photoredox Catalysis
journal, January 2017

Qin, Qixue; Jiang, Heng; Hu, Zhentao
The Chemical Record, Vol. 17, Issue 8
DOI: 10.1002/tcr.201600125

Discovery of an -Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity
journal, November 2011

McNally, A.; Prier, C. K.; MacMillan, D. W. C.
Science, Vol. 334, Issue 6059
DOI: 10.1126/science.1213920

C–H functionalization of amines with aryl halides by nickel-photoredox catalysis
journal, January 2016

Ahneman, Derek T.; Doyle, Abigail G.
Chemical Science, Vol. 7, Issue 12
DOI: 10.1039/C6SC02815B

Arylation of Aniline C(sp ³ )−H Bonds with Phenols via an In Situ Activation Strategy
journal, October 2017

Gui, Yong-Yuan; Wang, Zi-Xiao; Zhou, Wen-Jun
Asian Journal of Organic Chemistry, Vol. 7, Issue 3
DOI: 10.1002/ajoc.201700450

Direct Acylation of C(sp ³ )−H Bonds Enabled by Nickel and Photoredox Catalysis
journal, February 2016

Joe, Candice L.; Doyle, Abigail G.
Angewandte Chemie International Edition, Vol. 55, Issue 12
DOI: 10.1002/anie.201511438

Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry
journal, January 1999

Roberts, Brian P.
Chemical Society Reviews, Vol. 28, Issue 1
DOI: 10.1039/a804291h

O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols
journal, September 2015

Jeffrey, Jenna L.; Terrett, Jack A.; MacMillan, David W. C.
Science, Vol. 349, Issue 6255
DOI: 10.1126/science.aac8555

The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis
journal, March 2015

Cuthbertson, James D.; MacMillan, David W. C.
Nature, Vol. 519, Issue 7541
DOI: 10.1038/nature14255

Native functionality in triple catalytic cross-coupling: sp3 C-H bonds as latent nucleophiles
journal, April 2016

Shaw, M. H.; Shurtleff, V. W.; Terrett, J. A.
Science, Vol. 352, Issue 6291
DOI: 10.1126/science.aaf6635

Selective sp3 C–H alkylation via polarity-match-based cross-coupling
journal, June 2017

Le, Chip; Liang, Yufan; Evans, Ryan W.
Nature, Vol. 547, Issue 7661
DOI: 10.1038/nature22813

Mechanistic Insight into the Photoredox-Nickel-HAT Triple Catalyzed Arylation and Alkylation of α-Amino C _sp3 –H Bonds
journal, September 2020

Maity, Bholanath; Zhu, Chen; Yue, Huifeng
Journal of the American Chemical Society, Vol. 142, Issue 40
DOI: 10.1021/jacs.0c05010

Direct Aldehyde C–H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis
journal, August 2017

Zhang, Xiaheng; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 139, Issue 33
DOI: 10.1021/jacs.7b07078

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis
journal, April 2018

Twilton, Jack; Christensen, Melodie; DiRocco, Daniel A.
Angewandte Chemie International Edition, Vol. 57, Issue 19
DOI: 10.1002/anie.201800749

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations
journal, September 2016

Heitz, Drew R.; Tellis, John C.; Molander, Gary A.
Journal of the American Chemical Society, Vol. 138, Issue 39
DOI: 10.1021/jacs.6b04789

Direct Cross-Coupling of Allylic C(sp ³ )−H Bonds with Aryl- and Vinylbromides by Combined Nickel and Visible-Light Catalysis
journal, July 2018

Huang, Long; Rueping, Magnus
Angewandte Chemie International Edition, Vol. 57, Issue 32
DOI: 10.1002/anie.201805118

Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes
journal, May 2015

Hwang, Seung Jun; Powers, David C.; Maher, Andrew G.
Journal of the American Chemical Society, Vol. 137, Issue 20
DOI: 10.1021/jacs.5b03192

Direct C(sp ³ )–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals
journal, September 2016

Shields, Benjamin J.; Doyle, Abigail G.
Journal of the American Chemical Society, Vol. 138, Issue 39
DOI: 10.1021/jacs.6b08397

Direct C–C Bond Formation from Alkanes Using Ni-Photoredox Catalysis
journal, October 2018

Ackerman, Laura K. G.; Martinez Alvarado, Jesus I.; Doyle, Abigail G.
Journal of the American Chemical Society, Vol. 140, Issue 43
DOI: 10.1021/jacs.8b09191

Mild, Redox-Neutral Formylation of Aryl Chlorides through the Photocatalytic Generation of Chlorine Radicals
journal, May 2017

Nielsen, Matthew K.; Shields, Benjamin J.; Liu, Junyi
Angewandte Chemie International Edition, Vol. 56, Issue 25
DOI: 10.1002/anie.201702079

Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions
journal, October 2013

Schönherr, Heike; Cernak, Tim
Angewandte Chemie International Edition, Vol. 52, Issue 47
DOI: 10.1002/anie.201303207

Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source
journal, April 2020

Kariofillis, Stavros K.; Shields, Benjamin J.; Tekle-Smith, Makeda A.
Journal of the American Chemical Society, Vol. 142, Issue 16
DOI: 10.1021/jacs.0c02805

Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α-Hetero C(sp ³ )–H Bonds
journal, September 2017

Deng, Hong-Ping; Fan, Xuan-Zi; Chen, Zhi-Hui
Journal of the American Chemical Society, Vol. 139, Issue 38
DOI: 10.1021/jacs.7b08158

Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis: Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis
journal, March 2017

Capaldo, Luca; Ravelli, Davide
European Journal of Organic Chemistry, Vol. 2017, Issue 15
DOI: 10.1002/ejoc.201601485

Unraveling the Key Features of the Reactive State of Decatungstate Anion in Hydrogen Atom Transfer (HAT) Photocatalysis
journal, September 2016

Waele, Vincent De; Poizat, Olivier; Fagnoni, Maurizio
ACS Catalysis, Vol. 6, Issue 10
DOI: 10.1021/acscatal.6b01984

Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope
journal, December 2017

Ravelli, Davide; Fagnoni, Maurizio; Fukuyama, Takahide
ACS Catalysis, Vol. 8, Issue 1
DOI: 10.1021/acscatal.7b03354

Direct arylation of strong aliphatic C–H bonds
journal, August 2018

Perry, Ian B.; Brewer, Thomas F.; Sarver, Patrick J.
Nature, Vol. 560, Issue 7716
DOI: 10.1038/s41586-018-0366-x

Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes
journal, January 2020

Fan, Pei; Lan, Yun; Zhang, Chang
Journal of the American Chemical Society, Vol. 142, Issue 5
DOI: 10.1021/jacs.9b12554

sp ³ C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts
journal, September 2018

Shen, Yangyang; Gu, Yiting; Martin, Ruben
Journal of the American Chemical Society, Vol. 140, Issue 38
DOI: 10.1021/jacs.8b07405

The Dual Role of Benzophenone in Visible-Light/Nickel Photoredox-Catalyzed C−H Arylations: Hydrogen-Atom Transfer and Energy Transfer
journal, February 2019

Dewanji, Abhishek; Krach, Patricia E.; Rueping, Magnus
Angewandte Chemie International Edition, Vol. 58, Issue 11
DOI: 10.1002/anie.201901327

Synthesis of unsymmetrical ketones by applying visible-light benzophenone/nickel dual catalysis for direct benzylic acylation
journal, January 2020

Krach, Patricia E.; Dewanji, Abhishek; Yuan, Tingting
Chemical Communications, Vol. 56, Issue 45
DOI: 10.1039/D0CC01480J

Carboxylation of Benzylic and Aliphatic C–H Bonds with CO ₂ Induced by Light/Ketone/Nickel
journal, November 2019

Ishida, Naoki; Masuda, Yusuke; Imamura, Yuuya
Journal of the American Chemical Society, Vol. 141, Issue 50
DOI: 10.1021/jacs.9b12529

Benzaldehyde- and Nickel-Catalyzed Photoredox C(sp ³ )–H Alkylation/Arylation with Amides and Thioethers
journal, August 2019

Si, Xiaojia; Zhang, Lumin; Hashmi, A. Stephen K.
Organic Letters, Vol. 21, Issue 16
DOI: 10.1021/acs.orglett.9b02226

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer
journal, October 2016

Choi, Gilbert J.; Zhu, Qilei; Miller, David C.
Nature, Vol. 539, Issue 7628
DOI: 10.1038/nature19811

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds
journal, October 2016

Chu, John C. K.; Rovis, Tomislav
Nature, Vol. 539, Issue 7628
DOI: 10.1038/nature19810

Regioselective Alkylative Cross-Coupling of Remote Unactivated C( sp ³ )–H Bonds
journal, September 2019

Thullen, Scott M.; Treacy, Sean M.; Rovis, Tomislav
Journal of the American Chemical Society, Vol. 141, Issue 36
DOI: 10.1021/jacs.9b07014

Replacing Conventional Carbon Nucleophiles with Electrophiles: Nickel-Catalyzed Reductive Alkylation of Aryl Bromides and Chlorides
journal, March 2012

Everson, Daniel A.; Jones, Brittany A.; Weix, Daniel J.
Journal of the American Chemical Society, Vol. 134, Issue 14
DOI: 10.1021/ja301769r

Reductive Cross-Coupling of Nonaromatic, Heterocyclic Bromides with Aryl and Heteroaryl Bromides
journal, June 2014

Molander, Gary A.; Traister, Kaitlin M.; O’Neill, Brian T.
The Journal of Organic Chemistry, Vol. 79, Issue 12
DOI: 10.1021/jo500905m

An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles
journal, December 2015

Bhonde, Vasudev R.; O'Neill, Brian T.; Buchwald, Stephen L.
Angewandte Chemie International Edition, Vol. 55, Issue 5
DOI: 10.1002/anie.201509341

Cross-Electrophile Coupling: Principles of Reactivity and Selectivity
journal, May 2014

Everson, Daniel A.; Weix, Daniel J.
The Journal of Organic Chemistry, Vol. 79, Issue 11
DOI: 10.1021/jo500507s

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling
journal, June 2016

Zhang, Patricia; Le, Chi “Chip”; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 138, Issue 26
DOI: 10.1021/jacs.6b04818

Rate constants for the reactions of tris(trimethylsilyl)silyl radicals with organic halides
journal, May 1989

Chatgilialoglu, C.; Griller, D.; Lesage, M.
The Journal of Organic Chemistry, Vol. 54, Issue 10
DOI: 10.1021/jo00271a058

Bond dissociation energy values in silicon-containing compounds and some of their implications
journal, August 1981

Walsh, Robin
Accounts of Chemical Research, Vol. 14, Issue 8
DOI: 10.1021/ar00068a004

A Continuous Stirred-Tank Reactor (CSTR) Cascade for Handling Solid-Containing Photochemical Reactions
journal, November 2019

Pomberger, Alexander; Mo, Yiming; Nandiwale, Kakasaheb Y.
Organic Process Research & Development, Vol. 23, Issue 12
DOI: 10.1021/acs.oprd.9b00378

Photoredox cross-electrophile coupling in DNA-encoded chemistry
journal, December 2020

Kölmel, Dominik K.; Ratnayake, Anokha S.; Flanagan, Mark E.
Biochemical and Biophysical Research Communications, Vol. 533, Issue 2
DOI: 10.1016/j.bbrc.2020.04.028

Metallaphotoredox Difluoromethylation of Aryl Bromides
journal, August 2018

Bacauanu, Vlad; Cardinal, Sébastien; Yamauchi, Motoshi
Angewandte Chemie International Edition, Vol. 57, Issue 38
DOI: 10.1002/anie.201807629

Metallaphotoredox-Catalyzed Cross-Electrophile C _sp ³ –C _sp ³ Coupling of Aliphatic Bromides
journal, December 2018

Smith, Russell T.; Zhang, Xiaheng; Rincón, Juan A.
Journal of the American Chemical Society, Vol. 140, Issue 50
DOI: 10.1021/jacs.8b12025

A Metallaphotoredox Strategy for the Cross‐Electrophile Coupling of α‐Chloro Carbonyls with Aryl Halides
journal, September 2019

Chen, Tiffany Q.; MacMillan, David W. C.
Angewandte Chemie International Edition, Vol. 58, Issue 41
DOI: 10.1002/anie.201909072

Nickel/Photoredox‐Catalyzed Asymmetric Reductive Cross‐Coupling of Racemic α‐Chloro Esters with Aryl Iodides
journal, March 2020

Guan, Haixing; Zhang, Qianwen; Walsh, Patrick J.
Angewandte Chemie International Edition, Vol. 59, Issue 13
DOI: 10.1002/anie.201914175

Cross-Electrophile Coupling of Unactivated Alkyl Chlorides
journal, June 2020

Sakai, Holt A.; Liu, Wei; Le, Chi “Chip”
Journal of the American Chemical Society, Vol. 142, Issue 27
DOI: 10.1021/jacs.0c04812

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Alkyl Bromides: Et ₃ N as the Terminal Reductant
journal, July 2016

Duan, Zhengli; Li, Wu; Lei, Aiwen
Organic Letters, Vol. 18, Issue 16
DOI: 10.1021/acs.orglett.6b01837

Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl–Alkyl Cross-Couplings
journal, February 2017

Paul, Avishek; Smith, Mark D.; Vannucci, Aaron K.
The Journal of Organic Chemistry, Vol. 82, Issue 4
DOI: 10.1021/acs.joc.6b02830

Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides
journal, February 2020

Constantin, Timothée; Zanini, Margherita; Regni, Alessio
Science, Vol. 367, Issue 6481
DOI: 10.1126/science.aba2419

Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides
journal, January 2019

Yu, Weijie; Chen, Long; Tao, Jiasi
Chemical Communications, Vol. 55, Issue 42
DOI: 10.1039/C9CC00768G

Visible‐Light‐Enabled Stereodivergent Synthesis of E ‐ and Z ‐Configured 1,4‐Dienes by Photoredox/Nickel Dual Catalysis
journal, November 2019

Song, Fan; Wang, Fang; Guo, Lei
Angewandte Chemie International Edition, Vol. 59, Issue 1
DOI: 10.1002/anie.201909543

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation
journal, April 2017

Basch, Corey H.; Liao, Jennie; Xu, Jianyu
Journal of the American Chemical Society, Vol. 139, Issue 15
DOI: 10.1021/jacs.7b02389

Deaminative Strategy for the Visible-Light-Mediated Generation of Alkyl Radicals
journal, August 2017

Klauck, Felix J. R.; James, Michael J.; Glorius, Frank
Angewandte Chemie International Edition, Vol. 56, Issue 40
DOI: 10.1002/anie.201706896

Photoinduced Deaminative Borylation of Alkylamines
journal, July 2018

Wu, Jingjing; He, Lin; Noble, Adam
Journal of the American Chemical Society, Vol. 140, Issue 34
DOI: 10.1021/jacs.8b07103

Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis
journal, April 2019

Yi, Jun; Badir, Shorouk O.; Kammer, Lisa Marie
Organic Letters, Vol. 21, Issue 9
DOI: 10.1021/acs.orglett.9b01097

Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C─N bond activation
journal, June 2019

Ni, Shengyang; Li, Chun-Xiao; Mao, Yu
Science Advances, Vol. 5, Issue 6
DOI: 10.1126/sciadv.aaw9516

Nickel-catalyzed C–N bond activation: activated primary amines as alkylating reagents in reductive cross-coupling
journal, January 2019

Yue, Huifeng; Zhu, Chen; Shen, Li
Chemical Science, Vol. 10, Issue 16
DOI: 10.1039/C9SC00783K

Carboxylation of Aromatic and Aliphatic Bromides and Triflates with CO ₂ by Dual Visible-Light-Nickel Catalysis
journal, September 2017

Meng, Qing-Yuan; Wang, Shun; König, Burkhard
Angewandte Chemie International Edition, Vol. 56, Issue 43
DOI: 10.1002/anie.201706724

Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes with CO ₂ by Combining Visible Light and Nickel Catalysis
journal, February 2018

Meng, Qing-Yuan; Wang, Shun; Huff, Gregory S.
Journal of the American Chemical Society, Vol. 140, Issue 9
DOI: 10.1021/jacs.7b13448

Stereoselective Preparation of C ‐Aryl Glycosides via Visible‐Light‐Induced Nickel‐Catalyzed Reductive Cross‐Coupling of Glycosyl Chlorides and Aryl Bromides
journal, May 2021

Mou, Ze‐Dong; Wang, Jia‐Xi; Zhang, Xia
Advanced Synthesis & Catalysis, Vol. 363, Issue 12
DOI: 10.1002/adsc.202100343

An Efficient Intermolecular Palladium-Catalyzed Synthesis of Aryl Ethers
journal, October 2001

Torraca, Karen E.; Huang, Xiaohua; Parrish, Cynthia A.
Journal of the American Chemical Society, Vol. 123, Issue 43
DOI: 10.1021/ja016863p

Copper-Catalyzed Coupling of Aryl Iodides with Aliphatic Alcohols
journal, March 2002

Wolter, Martina; Nordmann, Gero; Job, Gabriel E.
Organic Letters, Vol. 4, Issue 6
DOI: 10.1021/ol025548k

Air Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C−C, C−N, and C−O Bond-Forming Cross-Couplings
journal, July 2002

Kataoka, Noriyasu; Shelby, Quinetta; Stambuli, James P.
The Journal of Organic Chemistry, Vol. 67, Issue 16
DOI: 10.1021/jo025732j

Aromatic Methoxylation and Hydroxylation by Organometallic High-Valent Nickel Complexes
journal, June 2015

Zhou, Wen; Schultz, Jason W.; Rath, Nigam P.
Journal of the American Chemical Society, Vol. 137, Issue 24
DOI: 10.1021/jacs.5b04082

Switching on elusive organometallic mechanisms with photoredox catalysis
journal, August 2015

Terrett, Jack A.; Cuthbertson, James D.; Shurtleff, Valerie W.
Nature, Vol. 524, Issue 7565
DOI: 10.1038/nature14875

General Paradigm in Photoredox Nickel‐Catalyzed Cross‐Coupling Allows for Light‐Free Access to Reactivity
journal, April 2020

Sun, Rui; Qin, Yangzhong; Nocera, Daniel G.
Angewandte Chemie International Edition, Vol. 59, Issue 24
DOI: 10.1002/anie.201916398

Photoredox Ni-catalyzed peptide C(sp ² )–O cross-coupling: from intermolecular reactions to side chain-to-tail macrocyclization
journal, January 2019

Lee, Hyelee; Boyer, Nicolas C.; Deng, Qiaolin
Chemical Science, Vol. 10, Issue 19
DOI: 10.1039/C9SC00694J

Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway
journal, November 2012

Creutz, S. E.; Lotito, K. J.; Fu, G. C.
Science, Vol. 338, Issue 6107
DOI: 10.1126/science.1226458

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light
journal, February 2016

Kainz, Q. M.; Matier, C. D.; Bartoszewicz, A.
Science, Vol. 351, Issue 6274
DOI: 10.1126/science.aad8313

Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)
journal, January 2017

Welin, Eric R.; Le, Chip; Arias-Rotondo, Daniela M.
Science, Vol. 355, Issue 6323
DOI: 10.1126/science.aal2490

Transient Absorption Spectroscopy Offers Mechanistic Insights for an Iridium/Nickel-Catalyzed C–O Coupling
journal, February 2020

Tian, Lei; Till, Nicholas A.; Kudisch, Bryan
Journal of the American Chemical Society, Vol. 142, Issue 10
DOI: 10.1021/jacs.9b12835

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis
journal, June 2016

Corcoran, Emily B.; Pirnot, Michael T.; Lin, Shishi
Science, Vol. 353, Issue 6296
DOI: 10.1126/science.aag0209

Chemistry informer libraries: a chemoinformatics enabled approach to evaluate and advance synthetic methods
journal, January 2016

Kutchukian, Peter S.; Dropinski, James F.; Dykstra, Kevin D.
Chem. Sci., Vol. 7, Issue 4
DOI: 10.1039/C5SC04751J

Photon Equivalents as a Parameter for Scaling Photoredox Reactions in Flow: Translation of Photocatalytic C−N Cross‐Coupling from Lab Scale to Multikilogram Scale
journal, May 2020

Corcoran, Emily B.; McMullen, Jonathan P.; Lévesque, François
Angewandte Chemie International Edition, Vol. 59, Issue 29
DOI: 10.1002/anie.201915412

Visible Light-Mediated (Hetero)aryl Amination Using Ni(II) Salts and Photoredox Catalysis in Flow: A Synthesis of Tetracaine
journal, January 2020

Park, Boyoung Y.; Pirnot, Michael T.; Buchwald, Stephen L.
The Journal of Organic Chemistry, Vol. 85, Issue 5
DOI: 10.1021/acs.joc.9b03107

Mechanistic Analysis of Metallaphotoredox C–N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity
journal, August 2020

Till, Nicholas A.; Tian, Lei; Dong, Zhe
Journal of the American Chemical Society, Vol. 142, Issue 37
DOI: 10.1021/jacs.0c05901

Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual Catalysis
journal, July 2015

Tasker, Sarah Z.; Jamison, Timothy F.
Journal of the American Chemical Society, Vol. 137, Issue 30
DOI: 10.1021/jacs.5b05597

The Heck Reaction as a Sharpening Stone of Palladium Catalysis
journal, August 2000

Beletskaya, Irina P.; Cheprakov, Andrei V.
Chemical Reviews, Vol. 100, Issue 8
DOI: 10.1021/cr9903048

Carbon–heteroatom bond formation catalysed by organometallic complexes
journal, September 2008

Hartwig, John F.
Nature, Vol. 455, Issue 7211
DOI: 10.1038/nature07369

Nickel Dual Photoredox Catalysis for the Synthesis of Aryl Amines
journal, April 2018

Key, Ryan J.; Vannucci, Aaron K.
Organometallics, Vol. 37, Issue 9
DOI: 10.1021/acs.organomet.8b00121

Nickel-Catalyzed Photoredox-Mediated Cross-Coupling of Aryl Electrophiles and Aryl Azides
journal, August 2018

Konev, Mikhail O.; McTeague, T. Andrew; Johannes, Jeffrey W.
ACS Catalysis, Vol. 8, Issue 10
DOI: 10.1021/acscatal.8b02954

Sulfonamidation of Aryl and Heteroaryl Halides through Photosensitized Nickel Catalysis
journal, February 2018

Kim, Taehoon; McCarver, Stefan J.; Lee, Chulbom
Angewandte Chemie International Edition, Vol. 57, Issue 13
DOI: 10.1002/anie.201800699

C–N Cross-Coupling via Photoexcitation of Nickel–Amine Complexes
journal, May 2018

Lim, Chern-Hooi; Kudisch, Max; Liu, Bin
Journal of the American Chemical Society, Vol. 140, Issue 24
DOI: 10.1021/jacs.8b03744

Energy Transfer to Ni-Amine Complexes in Dual Catalytic, Light-Driven C–N Cross-Coupling Reactions
journal, November 2019

Kudisch, Max; Lim, Chern-Hooi; Thordarson, Pall
Journal of the American Chemical Society, Vol. 141, Issue 49
DOI: 10.1021/jacs.9b11049

Photochemically Mediated Nickel-Catalyzed Synthesis of N -(Hetero)aryl Sulfamides
journal, April 2020

Simons, R. Thomas; Scott, Georgia E.; Kanegusuku, Anastasia Gant
The Journal of Organic Chemistry, Vol. 85, Issue 10
DOI: 10.1021/acs.joc.0c00139

Room Temperature CP Bond Formation Enabled by Merging Nickel Catalysis and Visible-Light-Induced Photoredox Catalysis
journal, February 2015

Xuan, Jun; Zeng, Ting-Ting; Chen, Jia-Rong
Chemistry - A European Journal, Vol. 21, Issue 13
DOI: 10.1002/chem.201500227

Phosphorylation of Alkenyl and Aryl C–O Bonds via Photoredox/Nickel Dual Catalysis
journal, July 2017

Liao, Li-Li; Gui, Yong-Yuan; Zhang, Xiao-Bo
Organic Letters, Vol. 19, Issue 14
DOI: 10.1021/acs.orglett.7b01561

Thioetherification via Photoredox/Nickel Dual Catalysis
journal, February 2016

Jouffroy, Matthieu; Kelly, Christopher B.; Molander, Gary A.
Organic Letters, Vol. 18, Issue 4
DOI: 10.1021/acs.orglett.6b00208

Photoredox Mediated Nickel Catalyzed Cross-Coupling of Thiols With Aryl and Heteroaryl Iodides via Thiyl Radicals
journal, February 2016

Oderinde, Martins S.; Frenette, Mathieu; Robbins, Daniel W.
Journal of the American Chemical Society, Vol. 138, Issue 6
DOI: 10.1021/jacs.5b11244

Merging Photoredox and Organometallic Catalysts in a Metal-Organic Framework Significantly Boosts Photocatalytic Activities
journal, October 2018

Zhu, Yuan-Yuan; Lan, Guangxu; Fan, Yingjie
Angewandte Chemie International Edition, Vol. 57, Issue 43
DOI: 10.1002/anie.201809493

Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations
journal, June 2020

Badir, Shorouk O.; Molander, Gary A.
Chem, Vol. 6, Issue 6
DOI: 10.1016/j.chempr.2020.05.013

Three-Component Olefin Dicarbofunctionalization Enabled by Nickel/Photoredox Dual Catalysis
journal, December 2019

Campbell, Mark W.; Compton, Jordan S.; Kelly, Christopher B.
Journal of the American Chemical Society, Vol. 141, Issue 51
DOI: 10.1021/jacs.9b08282

Site‐Selective 1,2‐Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis
journal, February 2020

Sun, Shang‐Zheng; Duan, Yaya; Mega, Riccardo S.
Angewandte Chemie International Edition, Vol. 59, Issue 11
DOI: 10.1002/anie.201916279

Selective, Intermolecular Alkylarylation of Alkenes via Photoredox/Nickel Dual Catalysis
journal, June 2019

Guo, Lei; Tu, Hai-Yong; Zhu, Shengqing
Organic Letters, Vol. 21, Issue 12
DOI: 10.1021/acs.orglett.9b01658

Dual Photoredox/Nickel‐Catalyzed Three‐Component Carbofunctionalization of Alkenes
journal, August 2019

García‐Domínguez, Andrés; Mondal, Rahul; Nevado, Cristina
Angewandte Chemie International Edition, Vol. 58, Issue 35
DOI: 10.1002/anie.201906692

Selective 1,2‐Aryl‐Aminoalkylation of Alkenes Enabled by Metallaphotoredox Catalysis
journal, August 2020

Zheng, Songlin; Chen, Zimin; Hu, Yuanyuan
Angewandte Chemie International Edition, Vol. 59, Issue 41
DOI: 10.1002/anie.202006439

General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis
journal, November 2020

Guo, Lei; Yuan, Mingbin; Zhang, Yanyan
Journal of the American Chemical Society, Vol. 142, Issue 48
DOI: 10.1021/jacs.0c08823

Photochemical C–H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization
journal, March 2021

Campbell, Mark W.; Yuan, Mingbin; Polites, Viktor C.
Journal of the American Chemical Society, Vol. 143, Issue 10
DOI: 10.1021/jacs.0c13077

Merging Photoredox PCET with Ni-Catalyzed Cross-Coupling: Cascade Amidoarylation of Unactivated Olefins
journal, February 2019

Zheng, Shuai; Gutiérrez-Bonet, Álvaro; Molander, Gary A.
Chem, Vol. 5, Issue 2
DOI: 10.1016/j.chempr.2018.11.014

Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization–Cross‐Coupling Cascade
journal, June 2019

Weires, Nicholas A.; Slutskyy, Yuriy; Overman, Larry E.
Angewandte Chemie International Edition, Vol. 58, Issue 25
DOI: 10.1002/anie.201903353

syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
journal, October 2018

Guo, Lei; Song, Fan; Zhu, Shengqing
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-06904-9

A multicomponent synthesis of stereodefined olefins via nickel catalysis and single electron/triplet energy transfer
journal, July 2019

Zhu, Chen; Yue, Huifeng; Maity, Bholanath
Nature Catalysis, Vol. 2, Issue 8
DOI: 10.1038/s41929-019-0311-x

Regioselective Hydroalkylation and Arylalkylation of Alkynes by Photoredox/Nickel Dual Catalysis: Application and Mechanism
journal, February 2020

Yue, Huifeng; Zhu, Chen; Kancherla, Rajesh
Angewandte Chemie International Edition, Vol. 59, Issue 14
DOI: 10.1002/anie.201914061

Beiträge zur Kenntniss des Acetenylbenzols
journal, January 1869

Glaser, C.
Berichte der deutschen chemischen Gesellschaft, Vol. 2, Issue 1
DOI: 10.1002/cber.186900201183

The Oxidation of free Radicals by Metal ions
journal, April 1961

De La Mare, H. E.; Kochi, J. K.; Rust, F. F.
Journal of the American Chemical Society, Vol. 83, Issue 8
DOI: 10.1021/ja01469a055

Emergence of Copper-Mediated Formation of C-C Bonds: Emergence of Copper-Mediated Formation of C-C Bonds
journal, July 2016

Maaliki, Carine; Thiery, Emilie; Thibonnet, Jérôme
European Journal of Organic Chemistry, Vol. 2017, Issue 2
DOI: 10.1002/ejoc.201600540

Catalysis for fluorination and trifluoromethylation
journal, May 2011

Furuya, Takeru; Kamlet, Adam S.; Ritter, Tobias
Nature, Vol. 473, Issue 7348
DOI: 10.1038/nature10108

The Many Roles for Fluorine in Medicinal Chemistry
journal, August 2008

Hagmann, William K.
Journal of Medicinal Chemistry, Vol. 51, Issue 15
DOI: 10.1021/jm800219f

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF ₃ I
journal, May 2012

Ye, Yingda; Sanford, Melanie S.
Journal of the American Chemical Society, Vol. 134, Issue 22
DOI: 10.1021/ja301553c

Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids
journal, November 2010

Chu, Lingling; Qing, Feng-Ling
Organic Letters, Vol. 12, Issue 21
DOI: 10.1021/ol1023135

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling
journal, February 2011

Senecal, Todd D.; Parsons, Andrew T.; Buchwald, Stephen L.
The Journal of Organic Chemistry, Vol. 76, Issue 4
DOI: 10.1021/jo1023377

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent
journal, January 2011

Xu, Jun; Luo, Dong-Fen; Xiao, Bin
Chemical Communications, Vol. 47, Issue 14
DOI: 10.1039/c1cc10359h

Merging photoredox with copper catalysis: decarboxylative difluoroacetylation of α,β-unsaturated carboxylic acids with ICF ₂ CO ₂ Et
journal, January 2016

Zhang, Heng-Rui; Chen, Dao-Qian; Han, Ya-Ping
Chemical Communications, Vol. 52, Issue 79
DOI: 10.1039/C6CC06284A

Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids
journal, May 2018

Kautzky, Jacob A.; Wang, Tao; Evans, Ryan W.
Journal of the American Chemical Society, Vol. 140, Issue 21
DOI: 10.1021/jacs.8b02650

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes
journal, May 2018

Le, Chip; Chen, Tiffany Q.; Liang, Tao
Science, Vol. 360, Issue 6392
DOI: 10.1126/science.aat4133

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions
journal, May 2010

Jones, Gavin O.; Liu, Peng; Houk, K. N.
Journal of the American Chemical Society, Vol. 132, Issue 17
DOI: 10.1021/ja100739h

Alternative Mechanistic Explanation for Ligand-Dependent Selectivities in Copper-Catalyzed N - and O -Arylation Reactions
journal, December 2010

Yu, Hai-Zhu; Jiang, Yuan-Ye; Fu, Yao
Journal of the American Chemical Society, Vol. 132, Issue 51
DOI: 10.1021/ja104264v

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides
journal, April 2019

Kornfilt, David J. P.; MacMillan, David W. C.
Journal of the American Chemical Society, Vol. 141, Issue 17
DOI: 10.1021/jacs.9b03024

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation
journal, March 2020

Sarver, Patrick J.; Bacauanu, Vlad; Schultz, Danielle M.
Nature Chemistry, Vol. 12, Issue 5
DOI: 10.1038/s41557-020-0436-1

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines
journal, January 1975

Sonogashira, Kenkichi; Tohda, Yasuo; Hagihara, Nobue
Tetrahedron Letters, Vol. 16, Issue 50
DOI: 10.1016/S0040-4039(00)91094-3

Highly Efficient Copper-Catalyzed Nitro-Mannich Type Reaction: Cross-Dehydrogenative-Coupling between sp ³ C−H Bond and sp ³ C−H Bond
journal, March 2005

Li, Zhiping; Li, Chao-Jun
Journal of the American Chemical Society, Vol. 127, Issue 11
DOI: 10.1021/ja050058j

Functionally Diverse Nucleophilic Trapping of Iminium Intermediates Generated Utilizing Visible Light
journal, December 2011

Freeman, David B.; Furst, Laura; Condie, Allison G.
Organic Letters, Vol. 14, Issue 1
DOI: 10.1021/ol202883v

Dual Catalysis: Combination of Photocatalytic Aerobic Oxidation and Metal Catalyzed Alkynylation Reactions-CC Bond Formation Using Visible Light
journal, March 2012

Rueping, Magnus; Koenigs, René M.; Poscharny, Konstantin
Chemistry - A European Journal, Vol. 18, Issue 17
DOI: 10.1002/chem.201200050

Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines
journal, January 2015

Perepichka, Inna; Kundu, Soumen; Hearne, Zoë
Organic & Biomolecular Chemistry, Vol. 13, Issue 2
DOI: 10.1039/C4OB02138J

Merging Photoredox with Copper Catalysis: Decarboxylative Alkynylation of α-Amino Acid Derivatives
journal, February 2017

Zhang, Hao; Zhang, Pengxiang; Jiang, Min
Organic Letters, Vol. 19, Issue 5
DOI: 10.1021/acs.orglett.6b03888

Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study
journal, January 2020

Mao, Yu; Zhao, Wenxuan; Lu, Shuo
Chemical Science, Vol. 11, Issue 19
DOI: 10.1039/D0SC02213F

Photo-Induced Sonogashira CC Coupling Reaction Catalyzed by Simple Copper(I) Chloride Salt at Room Temperature
journal, December 2012

Sagadevan, Arunachalam; Hwang, Kuo Chu
Advanced Synthesis & Catalysis, Vol. 354, Issue 18
DOI: 10.1002/adsc.201200683

Visible-light induced copper( i )-catalysed denitrogenative oxidative coupling of hydrazinylpyridines with terminal alkynes
journal, January 2018

Charpe, Vaibhav Pramod; Hande, Aniket A.; Sagadevan, Arunachalam
Green Chemistry, Vol. 20, Issue 21
DOI: 10.1039/C8GC01180J

Copper( i )-catalysed oxidative C–N coupling of 2-aminopyridine with terminal alkynes featuring a CC bond cleavage promoted by visible light
journal, January 2016

Ragupathi, Ayyakkannu; Sagadevan, Arunachalam; Lin, Chun-Cheng
Chemical Communications, Vol. 52, Issue 79
DOI: 10.1039/C6CC05506K

Visible Light Copper Photoredox-Catalyzed Aerobic Oxidative Coupling of Phenols and Terminal Alkynes: Regioselective Synthesis of Functionalized Ketones via C≡C Triple Bond Cleavage
journal, February 2017

Sagadevan, Arunachalam; Charpe, Vaibhav Pramod; Ragupathi, Ayyakkannu
Journal of the American Chemical Society, Vol. 139, Issue 8
DOI: 10.1021/jacs.6b13113

Copper( i ) chloride catalysed room temperature C _sp –C _sp homocoupling of terminal alkynes mediated by visible light
journal, January 2016

Sagadevan, Arunachalam; Charpe, Vaibhav Pramod; Hwang, Kuo Chu
Catalysis Science & Technology, Vol. 6, Issue 21
DOI: 10.1039/C6CY01400C

Visible-light-activated copper( i ) catalyzed oxidative C _sp –C _sp cross-coupling reaction: efficient synthesis of unsymmetrical conjugated diynes without ligands and base
journal, January 2016

Sagadevan, Arunachalam; Lyu, Ping-Chiang; Hwang, Kuo Chu
Green Chemistry, Vol. 18, Issue 16
DOI: 10.1039/C6GC01463A

Photoinduced Copper-Catalyzed Regioselective Synthesis of Indoles: Three-Component Coupling of Arylamines, Terminal Alkynes, and Quinones
journal, September 2015

Sagadevan, Arunachalam; Ragupathi, Ayyakkannu; Hwang, Kuo Chu
Angewandte Chemie International Edition, Vol. 54, Issue 47
DOI: 10.1002/anie.201506579

Copper Photoredox Catalyzed A3’ Coupling of Arylamines, Terminal Alkynes, and Alcohols through a Hydrogen Atom Transfer Process
journal, March 2019

Sagadevan, Arunachalam; Pampana, V. Kishore Kumar; Hwang, Kuo Chu
Angewandte Chemie International Edition, Vol. 58, Issue 12
DOI: 10.1002/anie.201813315

Photoinduced Copper-Catalyzed Coupling of Terminal Alkynes and Alkyl Iodides
journal, April 2018

Hazra, Avijit; Lee, Mitchell T.; Chiu, Justin F.
Angewandte Chemie International Edition, Vol. 57, Issue 19
DOI: 10.1002/anie.201801085

Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis
journal, October 2017

Wang, Dinghai; Zhu, Na; Chen, Pinhong
Journal of the American Chemical Society, Vol. 139, Issue 44
DOI: 10.1021/jacs.7b09802

Enantioselective cyanation via radical-mediated C–C single bond cleavage for synthesis of chiral dinitriles
journal, November 2019

Wang, Tao; Wang, Yi-Ning; Wang, Rui
Nature Communications, Vol. 10, Issue 1
DOI: 10.1038/s41467-019-13369-x

Enantioselective Remote C(sp ³ )–H Cyanation via Dual Photoredox and Copper Catalysis
journal, July 2020

Chen, Hui; Jin, Weiwei; Yu, Shouyun
Organic Letters, Vol. 22, Issue 15
DOI: 10.1021/acs.orglett.0c02008

Photoassisted C–C coupling via electron transfer to benzylic halides by a bis(di-imine) copper( I ) complex
journal, January 1987

Kern, Jean-Marc; Sauvage, Jean-Pierre
J. Chem. Soc., Chem. Commun., Issue 8
DOI: 10.1039/C39870000546

Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner-Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst
journal, April 2015

Bagal, Dattatraya B.; Kachkovskyi, Georgiy; Knorn, Matthias
Angewandte Chemie International Edition, Vol. 54, Issue 24
DOI: 10.1002/anie.201501880

Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts
journal, May 2012

Wallentin, Carl-Johan; Nguyen, John D.; Finkbeiner, Peter
Journal of the American Chemical Society, Vol. 134, Issue 21
DOI: 10.1021/ja300798k

Vicinal Difunctionalization of Alkenes: Chlorotrifluoromethylation with CF ₃ SO ₂ Cl by Photoredox Catalysis
journal, February 2014

Oh, Se Hwan; Malpani, Yashwardhan R.; Ha, Neul
Organic Letters, Vol. 16, Issue 5
DOI: 10.1021/ol403716t

Fluorinated free radicals
book, January 1997

Dolbier, William R.
Organofluorine Chemistry
DOI: 10.1007/BFb0119266

The Different Faces of Photoredox Catalysts: Visible-Light-Mediated Atom Transfer Radical Addition (ATRA) Reactions of Perfluoroalkyl Iodides with Styrenes and Phenylacetylenes
journal, April 2018

Rawner, Thomas; Lutsker, Eugen; Kaiser, Christian A.
ACS Catalysis, Vol. 8, Issue 5
DOI: 10.1021/acscatal.8b00847

Visible Light-Driven Azidation/Difunctionalization of Vinyl Arenes with Azidobenziodoxole under Copper Catalysis
journal, August 2019

Wu, Danhua; Cui, Shuang-Shuang; Lin, Yajun
The Journal of Organic Chemistry, Vol. 84, Issue 17
DOI: 10.1021/acs.joc.9b01569

Cu Photoredox Catalysts Supported by a 4,6-Disubstituted 2,2′-Bipyridine Ligand: Application in Chlorotrifluoromethylation of Alkenes
journal, October 2018

Alkan-Zambada, Murat; Hu, Xile
Organometallics, Vol. 37, Issue 21
DOI: 10.1021/acs.organomet.8b00585

Cu-Catalyzed Photoredox Chlorosulfonation of Alkenes and Alkynes
journal, March 2019

Alkan-Zambada, Murat; Hu, Xile
The Journal of Organic Chemistry, Vol. 84, Issue 7
DOI: 10.1021/acs.joc.9b00238

Photoredox-Catalyzed Bromodifluoromethylation of Alkenes with (Difluoromethyl)triphenylphosphonium Bromide
journal, May 2016

Lin, Qing-Yu; Ran, Yang; Xu, Xiu-Hua
Organic Letters, Vol. 18, Issue 10
DOI: 10.1021/acs.orglett.6b00935

Radical Carbofluorination of Unactivated Alkenes with Fluoride Ions
journal, April 2018

Liu, Zhonglin; Chen, He; Lv, Ying
Journal of the American Chemical Society, Vol. 140, Issue 19
DOI: 10.1021/jacs.8b03077

Visible-Light-Induced, Copper-Catalyzed Three-Component Coupling of Alkyl Halides, Olefins, and Trifluoromethylthiolate To Generate Trifluoromethyl Thioethers
journal, October 2018

He, Jian; Chen, Caiyou; Fu, Gregory C.
ACS Catalysis, Vol. 8, Issue 12
DOI: 10.1021/acscatal.8b04094

Reversing the Regioselectivity of Halofunctionalization Reactions through Cooperative Photoredox and Copper Catalysis
journal, January 2017

Griffin, Jeremy D.; Cavanaugh, Cortney L.; Nicewicz, David A.
Angewandte Chemie International Edition, Vol. 56, Issue 8
DOI: 10.1002/anie.201610722

Merging Photoredox and Copper Catalysis: Enantioselective Radical Cyanoalkylation of Styrenes
journal, July 2018

Sha, Wanxing; Deng, Lingling; Ni, Shengyang
ACS Catalysis, Vol. 8, Issue 8
DOI: 10.1021/acscatal.8b01863

Copper‐Catalyzed Radical Cross‐Coupling of Redox‐Active Oxime Esters, Styrenes, and Boronic Acids
journal, November 2018

Yu, Xiao‐Ye; Zhao, Quan‐Qing; Chen, Jun
Angewandte Chemie International Edition, Vol. 57, Issue 47
DOI: 10.1002/anie.201809820

Photoinduced, Copper-Catalyzed Radical Cross-Coupling of Cycloketone Oxime Esters, Alkenes, and Terminal Alkynes
journal, May 2019

Chen, Jun; He, Bin-Qing; Wang, Peng-Zi
Organic Letters, Vol. 21, Issue 11
DOI: 10.1021/acs.orglett.9b01529

Visible‐Light‐Accelerated Copper(II)‐Catalyzed Regio‐ and Chemoselective Oxo‐Azidation of Vinyl Arenes
journal, July 2018

Hossain, Asik; Vidyasagar, Adiyala; Eichinger, Christian
Angewandte Chemie International Edition, Vol. 57, Issue 27
DOI: 10.1002/anie.201801678

Visible-Light Induced and Oxygen-Promoted Oxidative Cyclization of Aromatic Enamines for the Synthesis of Quinolines Derivatives
journal, August 2017

Xia, Xiao-Feng; Zhang, Guo-Wei; Wang, Dawei
The Journal of Organic Chemistry, Vol. 82, Issue 16
DOI: 10.1021/acs.joc.7b01206

Merging visible-light photoredox and copper catalysis in catalytic aerobic oxidation of amines to nitriles
journal, January 2017

Tao, Chuanzhou; Wang, Bin; Sun, Lei
Organic & Biomolecular Chemistry, Vol. 15, Issue 2
DOI: 10.1039/C6OB02510B

Ru/Cu Photoredox or Cu/Ag Catalyzed C4–H Sulfonylation of 1-Naphthylamides at Room Temperature
journal, November 2017

Bai, Peirong; Sun, Suyan; Li, Zexian
The Journal of Organic Chemistry, Vol. 82, Issue 23
DOI: 10.1021/acs.joc.7b01917

Photoinduced synthesis of ( E )-vinyl sulfones through the insertion of sulfur dioxide
journal, January 2018

Liu, Tong; Ding, Yechun; Fan, Xiaona
Organic Chemistry Frontiers, Vol. 5, Issue 21
DOI: 10.1039/C8QO00965A

Transition‐Metal‐Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper‐Catalyzed Couplings of Carbazoles
journal, April 2013

Bissember, Alex C.; Lundgren, Rylan J.; Creutz, Sidney E.
Angewandte Chemie International Edition, Vol. 52, Issue 19
DOI: 10.1002/anie.201301202

A New Family of Nucleophiles for Photoinduced, Copper-Catalyzed Cross-Couplings via Single-Electron Transfer: Reactions of Thiols with Aryl Halides Under Mild Conditions (O °C)
journal, June 2013

Uyeda, Christopher; Tan, Yichen; Fu, Gregory C.
Journal of the American Chemical Society, Vol. 135, Issue 25
DOI: 10.1021/ja404050f

Oxygen nucleophiles as reaction partners in photoinduced, copper-catalyzed cross-couplings: O-arylations of phenols at room temperature
journal, January 2014

Tan, Yichen; Muñoz-Molina, José María; Fu, Gregory C.
Chem. Sci., Vol. 5, Issue 7
DOI: 10.1039/C4SC00368C

Copper-Catalyzed Alkylation of Aliphatic Amines Induced by Visible Light
journal, November 2017

Matier, Carson D.; Schwaben, Jonas; Peters, Jonas C.
Journal of the American Chemical Society, Vol. 139, Issue 49
DOI: 10.1021/jacs.7b09582

Design of a Photoredox Catalyst that Enables the Direct Synthesis of Carbamate-Protected Primary Amines via Photoinduced, Copper-Catalyzed N -Alkylation Reactions of Unactivated Secondary Halides
journal, November 2017

Ahn, Jun Myun; Peters, Jonas C.; Fu, Gregory C.
Journal of the American Chemical Society, Vol. 139, Issue 49
DOI: 10.1021/jacs.7b10907

Photoinduced, Copper-Catalyzed Decarboxylative C–N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement
journal, August 2017

Zhao, Wei; Wurz, Ryan P.; Peters, Jonas C.
Journal of the American Chemical Society, Vol. 139, Issue 35
DOI: 10.1021/jacs.7b07546

Cross-Coupling of Alkyl Redox-Active Esters with Benzophenone Imines: Tandem Photoredox and Copper Catalysis
journal, June 2018

Mao, Runze; Balon, Jonathan; Hu, Xile
Angewandte Chemie International Edition, Vol. 57, Issue 30
DOI: 10.1002/anie.201804873

Decarboxylative C(sp3)–N cross-coupling via synergetic photoredox and copper catalysis
journal, February 2018

Mao, Runze; Frey, Adrian; Balon, Jonathan
Nature Catalysis, Vol. 1, Issue 2
DOI: 10.1038/s41929-017-0023-z

Tandem Photoredox and Copper-Catalyzed Decarboxylative C(sp ³ )–N Coupling of Anilines and Imines Using an Organic Photocatalyst
journal, June 2020

Barzanò, Guido; Mao, Runze; Garreau, Marion
Organic Letters, Vol. 22, Issue 14
DOI: 10.1021/acs.orglett.0c01769

Decarboxylative C(sp ³ )−O Cross-Coupling
journal, September 2018

Mao, Runze; Balon, Jonathan; Hu, Xile
Angewandte Chemie International Edition, Vol. 57, Issue 41
DOI: 10.1002/anie.201808024

Photocatalytic decarboxylative amidosulfonation enables direct transformation of carboxylic acids to sulfonamides
journal, January 2021

Nguyen, Vu T.; Haug, Graham C.; Nguyen, Viet D.
Chemical Science, Vol. 12, Issue 18
DOI: 10.1039/D1SC01389K

Visible-Light-Mediated Chan-Lam Coupling Reactions of Aryl Boronic Acids and Aniline Derivatives
journal, April 2015

Yoo, Woo-Jin; Tsukamoto, Tatsuhiro; Kobayashi, Shū
Angewandte Chemie International Edition, Vol. 54, Issue 22
DOI: 10.1002/anie.201500074

Visible Light-Mediated Ullmann-Type C–N Coupling Reactions of Carbazole Derivatives and Aryl Iodides
journal, June 2015

Yoo, Woo-Jin; Tsukamoto, Tatsuhiro; Kobayashi, Shu̅
Organic Letters, Vol. 17, Issue 14
DOI: 10.1021/acs.orglett.5b01645

Decarboxylative sp3 C–N coupling via dual copper and photoredox catalysis
journal, June 2018

Liang, Yufan; Zhang, Xiaheng; MacMillan, David W. C.
Nature, Vol. 559, Issue 7712
DOI: 10.1038/s41586-018-0234-8

Mechanistic Study on the Decarboxylative sp ³ C–N Cross-Coupling between Alkyl Carboxylic Acids and Nitrogen Nucleophiles via Dual Copper and Photoredox Catalysis
journal, September 2019

Zhao, Xia; Liu, Yanhong; Zhu, Rongxiu
Inorganic Chemistry, Vol. 58, Issue 19
DOI: 10.1021/acs.inorgchem.9b01477

Copper-mediated synthesis of drug-like bicyclopentanes
journal, February 2020

Zhang, Xiaheng; Smith, Russell T.; Le, Chip
Nature, Vol. 580, Issue 7802
DOI: 10.1038/s41586-020-2060-z

Recent Advances in the Synthetic Chemistry of Bicyclo[1.1.1]pentane
journal, November 2018

Kanazawa, Junichiro; Uchiyama, Masanobu
Synlett, Vol. 30, Issue 01
DOI: 10.1055/s-0037-1610314

Saturated bioisosteres of benzene: where to go next?
journal, January 2019

Mykhailiuk, Pavel K.
Organic & Biomolecular Chemistry, Vol. 17, Issue 11
DOI: 10.1039/C8OB02812E

HARC as an open-shell strategy to bypass oxidative addition in Ullmann–Goldberg couplings
journal, August 2020

Lavagnino, Marissa N.; Liang, Tao; MacMillan, David W. C.
Proceedings of the National Academy of Sciences, Vol. 117, Issue 35
DOI: 10.1073/pnas.2011831117

Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent
journal, January 2007

Osawa, Masahisa; Nagai, Hidetada; Akita, Munetaka
Dalton Transactions, Issue 8
DOI: 10.1039/b618007h

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis
journal, November 2011

Kalyani, Dipannita; McMurtrey, Kate B.; Neufeldt, Sharon R.
Journal of the American Chemical Society, Vol. 133, Issue 46
DOI: 10.1021/ja208068w

Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights
journal, May 2005

Kalyani, Dipannita; Deprez, Nicholas R.; Desai, Lopa V.
Journal of the American Chemical Society, Vol. 127, Issue 20
DOI: 10.1021/ja051402f

Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate
journal, August 2009

Deprez, Nicholas R.; Sanford, Melanie S.
Journal of the American Chemical Society, Vol. 131, Issue 31
DOI: 10.1021/ja904116k

Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed CH Arylation with Diaryliodonium Salts
journal, December 2012

Neufeldt, Sharon R.; Sanford, Melanie S.
Advanced Synthesis & Catalysis, Vol. 354, Issue 18
DOI: 10.1002/adsc.201200738

Visible-Light-Mediated Monoselective Ortho C–H Arylation of 6-Arylpurine Nucleosides with Diazonium Salts
journal, May 2017

Liang, Lei; Xie, Ming-Sheng; Wang, Hai-Xia
The Journal of Organic Chemistry, Vol. 82, Issue 11
DOI: 10.1021/acs.joc.7b00659

Visible-Light-Promoted C–H Arylation by Merging Palladium Catalysis with Organic Photoredox Catalysis
journal, March 2017

Jiang, Jian; Zhang, Wen-Man; Dai, Jian-Jun
The Journal of Organic Chemistry, Vol. 82, Issue 7
DOI: 10.1021/acs.joc.7b00140

A unified strategy for silver-, base-, and oxidant-free direct arylation of C–H bonds
journal, January 2017

Sahoo, Manoj K.; Midya, Siba P.; Landge, Vinod G.
Green Chemistry, Vol. 19, Issue 9
DOI: 10.1039/C6GC03438A

Combining Sanford Arylations on Benzodiazepines with the Nuisance Effect
journal, August 2017

Khan, Raysa; Boonseng, Sarote; Kemmitt, Paul D.
Advanced Synthesis & Catalysis, Vol. 359, Issue 18
DOI: 10.1002/adsc.201700626

Dual palladium–photoredox catalyzed chemoselective C–H arylation of phenylureas
journal, January 2020

Babu, Sakamuri Sarath; Shahid, M.; Gopinath, Purushothaman
Chemical Communications, Vol. 56, Issue 44
DOI: 10.1039/D0CC01443E

Dual Photoredox/Palladium-Catalyzed C–H Acylation of 2-Arylpyridines with Oxime Esters
journal, August 2020

He, Bin-Qing; Gao, Yuan; Wang, Peng-Zi
Synlett, Vol. 32, Issue 04
DOI: 10.1055/s-0040-1707252

Synthesis of Indoles Using Visible Light: Photoredox Catalysis for Palladium-Catalyzed CH Activation
journal, October 2014

Zoller, Jochen; Fabry, David C.; Ronge, Meria A.
Angewandte Chemie International Edition, Vol. 53, Issue 48
DOI: 10.1002/anie.201405478

Merging Photoredox with Palladium Catalysis: Decarboxylative ortho -Acylation of Acetanilides with α-Oxocarboxylic Acids under Mild Reaction Conditions
journal, December 2015

Zhou, Chao; Li, Pinhua; Zhu, Xianjin
Organic Letters, Vol. 17, Issue 24
DOI: 10.1021/acs.orglett.5b03192

Merging Visible-Light Photocatalysis and Palladium Catalysis for C−H Acylation of Azo- and Azoxybenzenes with α-Keto Acids
journal, January 2016

Xu, Ning; Li, Pinhua; Xie, Zuguang
Chemistry - A European Journal, Vol. 22, Issue 7
DOI: 10.1002/chem.201504530

Dual visible-light photoredox and palladium( ii ) catalysis for dehydrogenative C2-acylation of indoles at room temperature
journal, January 2017

Manna, Manash Kumar; Bairy, Gurupada; Jana, Ranjan
Organic & Biomolecular Chemistry, Vol. 15, Issue 28
DOI: 10.1039/C7OB01418J

Synthesis of Carbazoles by a Merged Visible Light Photoredox and Palladium-Catalyzed Process
journal, July 2015

Choi, Sungkyu; Chatterjee, Tanmay; Choi, Won Joon
ACS Catalysis, Vol. 5, Issue 8
DOI: 10.1021/acscatal.5b00817

A Highly Selective Catalytic Method for the Oxidative Functionalization of C−H Bonds
journal, March 2004

Dick, Allison R.; Hull, Kami L.; Sanford, Melanie S.
Journal of the American Chemical Society, Vol. 126, Issue 8
DOI: 10.1021/ja031543m

Metallaphotoredox-Mediated C _sp2 –H Hydroxylation of Arenes under Aerobic Conditions
journal, September 2018

Shah, Sk. Sheriff; Paul, Amrita; Bera, Manoranjan
Organic Letters, Vol. 20, Issue 18
DOI: 10.1021/acs.orglett.8b01973

Direct Oxygenation of C–H Bonds through Photoredox and Palladium Catalysis
journal, January 2020

Shah, Sk. Sheriff; Shee, Maniklal; Singh, Amit Kumar
The Journal of Organic Chemistry, Vol. 85, Issue 5
DOI: 10.1021/acs.joc.9b03197

Auxiliary-Directed C(sp ³ )−H Arylation by Synergistic Photoredox and Palladium Catalysis
journal, September 2017

Czyz, Milena L.; Lupton, David W.; Polyzos, Anastasios
Chemistry - A European Journal, Vol. 23, Issue 58
DOI: 10.1002/chem.201704045

Ligand-Free Heck Reactions of Aryl Iodides: Significant Acceleration of the Rate through Visible Light Irradiation at Ambient Temperature
journal, November 2016

Zhang, Heng; Huang, Xueliang
Advanced Synthesis & Catalysis, Vol. 358, Issue 23
DOI: 10.1002/adsc.201600704

Cis -Selective Decarboxylative Alkenylation of Aliphatic Carboxylic Acids with Vinyl Arenes Enabled by Photoredox/Palladium/Uphill Triple Catalysis
journal, April 2018

Zheng, Chao; Cheng, Wan-Min; Li, Hong-Lian
Organic Letters, Vol. 20, Issue 9
DOI: 10.1021/acs.orglett.8b00712

Organic syntheses by means of noble metal compounds XVII. Reaction of π-allylpalladium chloride with nucleophiles
journal, January 1965

Tsuji, Jiro; Takahashi, Hidetaka; Morikawa, Masanobu
Tetrahedron Letters, Vol. 6, Issue 49
DOI: 10.1016/S0040-4039(00)71674-1

New synthetic reactions. Allylic alkylation
journal, January 1973

Trost, Barry M.; Fullerton, Terry J.
Journal of the American Chemical Society, Vol. 95, Issue 1
DOI: 10.1021/ja00782a080

Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis
journal, August 2003

Trost, Barry M.; Crawley, Matthew L.
Chemical Reviews, Vol. 103, Issue 8
DOI: 10.1021/cr020027w

Decarboxylative Allylation of Amino Alkanoic Acids and Esters via Dual Catalysis
journal, September 2014

Lang, Simon B.; O’Nele, Kathryn M.; Tunge, Jon A.
Journal of the American Chemical Society, Vol. 136, Issue 39
DOI: 10.1021/ja508317j

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions
journal, January 2011

Weaver, Jimmie D.; Recio, Antonio; Grenning, Alexander J.
Chemical Reviews, Vol. 111, Issue 3
DOI: 10.1021/cr1002744

Catalytic radical generation of π-allylpalladium complexes
journal, March 2020

Huang, Huan-Ming; Koy, Maximilian; Serrano, Eloisa
Nature Catalysis, Vol. 3, Issue 4
DOI: 10.1038/s41929-020-0434-0

Three-component three-bond forming cascade via palladium photoredox catalysis
journal, January 2021

Bellotti, Peter; Koy, Maximilian; Gutheil, Christian
Chemical Science, Vol. 12, Issue 5
DOI: 10.1039/D0SC05551D

Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes
journal, March 2021

Zheng, Jun; Nikbakht, Ali; Breit, Bernhard
ACS Catalysis, Vol. 11, Issue 6
DOI: 10.1021/acscatal.1c00153

Redox-Neutral α-Allylation of Amines by Combining Palladium Catalysis and Visible-Light Photoredox Catalysis
journal, December 2014

Xuan, Jun; Zeng, Ting-Ting; Feng, Zhu-Jia
Angewandte Chemie International Edition, Vol. 54, Issue 5
DOI: 10.1002/anie.201409999

Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms
journal, November 2015

Lang, Simon B.; O'Nele, Kathryn M.; Douglas, Justin T.
Chemistry - A European Journal, Vol. 21, Issue 51
DOI: 10.1002/chem.201503644

Asymmetric Synthesis of Homoallylic Alcohols Featuring Vicinal Tetrasubstituted Carbon Centers via Dual Pd/Photoredox Catalysis
journal, May 2021

Xue, Sijing; Limburg, Bart; Ghorai, Debasish
Organic Letters, Vol. 23, Issue 11
DOI: 10.1021/acs.orglett.1c01380

Enantioselective Allylic Alkylation with 4-Alkyl-1,4-dihydro-pyridines Enabled by Photoredox/Palladium Cocatalysis
journal, November 2018

Zhang, Hong-Hao; Zhao, Jia-Jia; Yu, Shouyun
Journal of the American Chemical Society, Vol. 140, Issue 49
DOI: 10.1021/jacs.8b10766

Photoredox/palladium-cocatalyzed enantioselective alkylation of secondary benzyl carbonates with 4-alkyl-1,4-dihydropyridines
journal, April 2020

Shen, Xu; Qian, Linlin; Yu, Shouyun
Science China Chemistry, Vol. 63, Issue 5
DOI: 10.1007/s11426-019-9732-5

Enantioselective α-Allylation of Anilines Enabled by a Combined Palladium and Photoredox Catalytic System
journal, March 2020

Zhang, Hong-Hao; Zhao, Jia-Jia; Yu, Shouyun
ACS Catalysis, Vol. 10, Issue 8
DOI: 10.1021/acscatal.0c00871

Dehydrative Allylation of α C(sp ³ )–H Bonds of Alkylamines with Allylic Alcohols
journal, May 2020

Masuda, Yusuke; Ito, Misato; Murakami, Masahiro
Organic Letters, Vol. 22, Issue 11
DOI: 10.1021/acs.orglett.0c01464

Photoredox/palladium co-catalyzed propargylic benzylation with internal propargylic carbonates
journal, January 2020

Zhou, Zhao-Zhao; Jiao, Rui-Qiang; Yang, Ke
Chemical Communications, Vol. 56, Issue 85
DOI: 10.1039/D0CC04986G

Aerobic Oxidative Carbonylation of Enamides by Merging Palladium with Photoredox Catalysis
journal, July 2016

Liu, Kun; Zou, Minzhu; Lei, Aiwen
The Journal of Organic Chemistry, Vol. 81, Issue 16
DOI: 10.1021/acs.joc.6b00965

Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts
journal, July 2017

Shimomaki, Katsuya; Murata, Kei; Martin, Ruben
Journal of the American Chemical Society, Vol. 139, Issue 28
DOI: 10.1021/jacs.7b04838

Palladium-Catalyzed Direct Carboxylation of Aryl Bromides with Carbon Dioxide
journal, October 2009

Correa, Arkaitz; Martín, Rubén
Journal of the American Chemical Society, Vol. 131, Issue 44
DOI: 10.1021/ja905264a

Nickel-Catalyzed Carboxylation of Aryl and Vinyl Chlorides Employing Carbon Dioxide
journal, May 2012

Fujihara, Tetsuaki; Nogi, Keisuke; Xu, Tinghua
Journal of the American Chemical Society, Vol. 134, Issue 22
DOI: 10.1021/ja303514b

Palladium-Catalyzed Visible-Light-Driven Carboxylation of Aryl and Alkenyl Triflates by Using Photoredox Catalysts
journal, June 2019

Shimomaki, Katsuya; Nakajima, Tomoya; Caner, Joaquim
Organic Letters, Vol. 21, Issue 12
DOI: 10.1021/acs.orglett.9b01340

Carboxylation of Aryl Triflates with CO ₂ Merging Palladium and Visible-Light-Photoredox Catalysts
journal, June 2019

Bhunia, Samir Kumar; Das, Pritha; Nandi, Shantanu
Organic Letters, Vol. 21, Issue 12
DOI: 10.1021/acs.orglett.9b01532

Selective C–F bond carboxylation of gem -difluoroalkenes with CO ₂ by photoredox/palladium dual catalysis
journal, January 2019

Zhu, Chuan; Zhang, Yu-Feng; Liu, Ze-Yao
Chemical Science, Vol. 10, Issue 27
DOI: 10.1039/C9SC01336A

Gold-Catalyzed Organic Reactions
journal, July 2007

Hashmi, A. Stephen K.
Chemical Reviews, Vol. 107, Issue 7
DOI: 10.1021/cr000436x

Synthesis, structure and reactivity of organogold compounds of relevance to homogeneous gold catalysis
journal, February 2009

Hashmi, A. Stephen K.; Ramamurthi, Tanuja Dondeti; Rominger, Frank
Journal of Organometallic Chemistry, Vol. 694, Issue 4
DOI: 10.1016/j.jorganchem.2008.11.054

Fluorine-Enabled Cationic Gold Catalysis: Functionalized Hydration of Alkynes
journal, August 2010

Wang, Weibo; Jasinski, Jacek; Hammond, Gerald B.
Angewandte Chemie International Edition, Vol. 49, Issue 40
DOI: 10.1002/anie.201003593

AuI/AuIII Catalysis: An Alternative Approach for CC Oxidative Coupling
journal, June 2011

Hopkinson, Matthew N.; Gee, Antony D.; Gouverneur, Véronique
Chemistry - A European Journal, Vol. 17, Issue 30
DOI: 10.1002/chem.201100736

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes
journal, April 2013

Sahoo, Basudev; Hopkinson, Matthew N.; Glorius, Frank
Journal of the American Chemical Society, Vol. 135, Issue 15
DOI: 10.1021/ja400311h

Merging Visible Light Photoredox and Gold Catalysis
journal, September 2016

Hopkinson, Matthew N.; Tlahuext-Aca, Adrian; Glorius, Frank
Accounts of Chemical Research, Vol. 49, Issue 10
DOI: 10.1021/acs.accounts.6b00351

Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse ( C , N )-Cyclometalated Gold(III) Complexes
journal, July 2016

Tlahuext-Aca, Adrian; Hopkinson, Matthew N.; Daniliuc, Constantin G.
Chemistry - A European Journal, Vol. 22, Issue 33
DOI: 10.1002/chem.201602649

Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes
journal, September 2014

Hopkinson, Matthew N.; Sahoo, Basudev; Glorius, Frank
Advanced Synthesis & Catalysis, Vol. 356, Issue 13
DOI: 10.1002/adsc.201400580

Catalytic Cross-Coupling of Vinyl Golds with Diazonium Salts under Photoredox and Thermal Conditions
journal, August 2015

Patil, Dilip V.; Yun, Hokeun; Shin, Senghoon
Advanced Synthesis & Catalysis, Vol. 357, Issue 12
DOI: 10.1002/adsc.201500525

Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion
journal, April 2014

Shu, Xing-zhong; Zhang, Miao; He, Ying
Journal of the American Chemical Society, Vol. 136, Issue 16
DOI: 10.1021/ja500716j

Gold-Photoredox-Cocatalyzed Tandem Oxycyclization/Coupling Sequence of Allenols and Diazonium Salts with Visible Light Mediation
journal, August 2017

Alcaide, Benito; Almendros, Pedro; Aparicio, Borja
Advanced Synthesis & Catalysis, Vol. 359, Issue 16
DOI: 10.1002/adsc.201700598

Stable gold(III) catalysts by oxidative addition of a carbon–carbon bond
journal, January 2015

Wu, Chung-Yeh; Horibe, Takahiro; Jacobsen, Christian Borch
Nature, Vol. 517, Issue 7535
DOI: 10.1038/nature14104

Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis
journal, June 2017

Akram, Manjur O.; Mali, Pramod S.; Patil, Nitin T.
Organic Letters, Vol. 19, Issue 12
DOI: 10.1021/acs.orglett.7b01148

Dual gold/photoredox-catalyzed C(sp)–H arylation of terminal alkynes with diazonium salts
journal, January 2016

Tlahuext-Aca, Adrian; Hopkinson, Matthew N.; Sahoo, Basudev
Chemical Science, Vol. 7, Issue 1
DOI: 10.1039/C5SC02583D

Visible light-mediated gold-catalysed carbon(sp ² )–carbon(sp) cross-coupling
journal, January 2016

Kim, Suhong; Rojas-Martin, Jaime; Toste, F. Dean
Chemical Science, Vol. 7, Issue 1
DOI: 10.1039/C5SC03025K

Cross-Coupling of Meyer–Schuster Intermediates under Dual Gold–Photoredox Catalysis
journal, January 2016

Um, Jiwon; Yun, Hokeun; Shin, Seunghoon
Organic Letters, Vol. 18, Issue 3
DOI: 10.1021/acs.orglett.5b03531

Alkyne Difunctionalization by Dual Gold/Photoredox Catalysis
journal, March 2016

Tlahuext-Aca, Adrian; Hopkinson, Matthew N.; Garza-Sanchez, R. Aleyda
Chemistry - A European Journal, Vol. 22, Issue 17
DOI: 10.1002/chem.201600710

Domino Meyer-Schuster/Arylation Reaction of Alkynols or Alkynyl Hydroperoxides with Diazonium Salts Promoted by Visible Light under Dual Gold and Ruthenium Catalysis
journal, April 2016

Alcaide, Benito; Almendros, Pedro; Busto, Eduardo
Advanced Synthesis & Catalysis, Vol. 358, Issue 9
DOI: 10.1002/adsc.201600158

Photosensitizer-Free Visible-Light-Mediated Gold-Catalyzed 1,2-Difunctionalization of Alkynes
journal, March 2016

Huang, Long; Rudolph, Matthias; Rominger, Frank
Angewandte Chemie International Edition, Vol. 55, Issue 15
DOI: 10.1002/anie.201511487

Dual Photoredox/Gold Catalysis Arylative Cyclization of o -Alkynylphenols with Aryldiazonium Salts: A Flexible Synthesis of Benzofurans
journal, July 2016

Xia, Zhonghua; Khaled, Omar; Mouriès-Mansuy, Virginie
The Journal of Organic Chemistry, Vol. 81, Issue 16
DOI: 10.1021/acs.joc.6b01060

Photoinduced Gold-Catalyzed Domino C(sp) Arylation/Oxyarylation of TMS-Terminated Alkynols with Arenediazonium Salts
journal, February 2017

Alcaide, Benito; Almendros, Pedro; Busto, Eduardo
The Journal of Organic Chemistry, Vol. 82, Issue 4
DOI: 10.1021/acs.joc.6b03006

Gold-catalyzed reaction of alkynes with diazonium salts under photoirradiation revisited: New alkoxyarylation variant leading to enol ethers
journal, November 2020

Lázaro-Milla, Carlos; Busto, Eduardo; Burgos, Imanol
Journal of Catalysis, Vol. 391
DOI: 10.1016/j.jcat.2020.07.029

Photosensitized oxidative addition to gold(i) enables alkynylative cyclization of o-alkylnylphenols with iodoalkynes
journal, August 2019

Xia, Zhonghua; Corcé, Vincent; Zhao, Fen
Nature Chemistry, Vol. 11, Issue 9
DOI: 10.1038/s41557-019-0295-9

ortho ‐Oxygenative 1,2‐Difunctionalization of Diarylalkynes under Merged Gold/Organophotoredox Relay Catalysis
journal, October 2019

Sancheti, Shashank P.; Akram, Manjur O.; Roy, Rupam
Chemistry – An Asian Journal, Vol. 14, Issue 24
DOI: 10.1002/asia.201901275

Photopromoted Entry to Benzothiophenes, Benzoselenophenes, 3 H -Indoles, Isocoumarins, Benzosultams, and (Thio)flavones by Gold-Catalyzed Arylative Heterocyclization of Alkynes
journal, July 2017

Alcaide, Benito; Almendros, Pedro; Busto, Eduardo
Advanced Synthesis & Catalysis, Vol. 359, Issue 15
DOI: 10.1002/adsc.201700427

Gold-catalysed cross-coupling between aryldiazonium salts and arylboronic acids: probing the usefulness of photoredox conditions
journal, January 2016

Cornilleau, Thomas; Hermange, Philippe; Fouquet, Eric
Chemical Communications, Vol. 52, Issue 65
DOI: 10.1039/C6CC04239B

Dual gold photoredox C(sp ² )–C(sp ² ) cross couplings – development and mechanistic studies
journal, January 2016

Gauchot, Vincent; Lee, Ai-Lan
Chemical Communications, Vol. 52, Issue 66
DOI: 10.1039/C6CC05078F

A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis
journal, January 2015

He, Ying; Wu, Hongmiao; Toste, F. Dean
Chemical Science, Vol. 6, Issue 2
DOI: 10.1039/C4SC03092C

Understanding Thermal and Photochemical Aryl-Aryl Cross-Coupling by the Au ^I /Au ^III Redox Couple
journal, August 2018

Bhattacharjee, Rameswar; Datta, Ayan
Chemistry - A European Journal, Vol. 24, Issue 51
DOI: 10.1002/chem.201802634

Mechanism of the Visible Light-Mediated Gold-Catalyzed Oxyarylation Reaction of Alkenes
journal, January 2016

Zhang, Qi; Zhang, Zhen-Qi; Fu, Yao
ACS Catalysis, Vol. 6, Issue 2
DOI: 10.1021/acscatal.5b01971

Photosensitizer-Free, Gold-Catalyzed C-C Cross-Coupling of Boronic Acids and Diazonium Salts Enabled by Visible Light
journal, March 2017

Witzel, Sina; Xie, Jin; Rudolph, Matthias
Advanced Synthesis & Catalysis, Vol. 359, Issue 9
DOI: 10.1002/adsc.201700121

Light-Induced Gold-Catalyzed Hiyama Arylation: A Coupling Access to Biarylboronates
journal, November 2018

Xie, Jin; Sekine, Kohei; Witzel, Sina
Angewandte Chemie International Edition, Vol. 57, Issue 51
DOI: 10.1002/anie.201806427

Modular and Selective Arylation of Aryl Germanes (C−GeEt ₃ ) over C−Bpin, C−SiR ₃ and Halogens Enabled by Light‐Activated Gold Catalysis
journal, June 2020

Sherborne, Grant J.; Gevondian, Avetik G.; Funes‐Ardoiz, Ignacio
Angewandte Chemie International Edition, Vol. 59, Issue 36
DOI: 10.1002/anie.202005066

The Dual Role of Gold(I) Complexes in Photosensitizer‐Free Visible‐Light‐Mediated Gold‐Catalyzed 1,2‐Difunctionalization of Alkynes: A DFT Study
journal, August 2018

Liu, Yanhong; Yang, Yiying; Zhu, Rongxiu
Chemistry – A European Journal, Vol. 24, Issue 53
DOI: 10.1002/chem.201803075

DFT Study on Photosensitizer-Free Visible-Light-Mediated Au-Catalyzed cis -Difunctionalization of Alkynes: Mechanism and Selectivities as Compared to Rh Catalysis
journal, November 2019

Liu, Yanhong; Yang, Yiying; Zhu, Rongxiu
The Journal of Organic Chemistry, Vol. 84, Issue 24
DOI: 10.1021/acs.joc.9b02681

Light-Induced Mechanistic Divergence in Gold(I) Catalysis: Revisiting the Reactivity of Diazonium Salts
journal, October 2019

Taschinski, Svenja; Döpp, René; Ackermann, Martin
Angewandte Chemie International Edition, Vol. 58, Issue 47
DOI: 10.1002/anie.201908268

Visible‐Light‐Assisted Gold‐Catalyzed Fluoroarylation of Allenoates
journal, March 2020

Tang, Hai‐Jun; Zhang, Xinggui; Zhang, Yu‐Feng
Angewandte Chemie International Edition, Vol. 59, Issue 13
DOI: 10.1002/anie.201916471

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
journal, October 2014

Kärkäs, Markus D.; Verho, Oscar; Johnston, Eric V.
Chemical Reviews, Vol. 114, Issue 24
DOI: 10.1021/cr400572f

Cobalt complexes as artificial hydrogenases for the reductive side of water splitting
journal, August 2013

Eckenhoff, William T.; McNamara, William R.; Du, Pingwu
Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9
DOI: 10.1016/j.bbabio.2013.05.003

Cross-Coupling Hydrogen Evolution Reaction in Homogeneous Solution without Noble Metals
journal, March 2014

Zhong, Jian-Ji; Meng, Qing-Yuan; Liu, Bin
Organic Letters, Vol. 16, Issue 7
DOI: 10.1021/ol500534w

A Cascade Cross-Coupling Hydrogen Evolution Reaction by Visible Light Catalysis
journal, October 2013

Meng, Qing-Yuan; Zhong, Jian-Ji; Liu, Qiang
Journal of the American Chemical Society, Vol. 135, Issue 51
DOI: 10.1021/ja408486v

Visible Light Catalysis Assisted Site-Specific Functionalization of Amino Acid Derivatives by C–H Bond Activation without Oxidant: Cross-Coupling Hydrogen Evolution Reaction
journal, March 2015

Gao, Xue-Wang; Meng, Qing-Yuan; Li, Jia-Xin
ACS Catalysis, Vol. 5, Issue 4
DOI: 10.1021/acscatal.5b00093

Activation of CH Bonds through Oxidant-Free Photoredox Catalysis: Cross-Coupling Hydrogen-Evolution Transformation of Isochromans and β-Keto Esters
journal, October 2015

Xiang, Ming; Meng, Qing-Yuan; Li, Jia-Xin
Chemistry - A European Journal, Vol. 21, Issue 50
DOI: 10.1002/chem.201503361

Visible light-mediated oxidative C(sp ³ )–H phosphonylation for α-aminophosphonates under oxidant-free conditions
journal, January 2018

Niu, Linbin; Wang, Shengchun; Liu, Jiamei
Chemical Communications, Vol. 54, Issue 13
DOI: 10.1039/C7CC09624K

Visible‐Light‐Promoted Asymmetric Cross‐Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis
journal, February 2017

Yang, Qi; Zhang, Long; Ye, Chen
Angewandte Chemie International Edition, Vol. 56, Issue 13
DOI: 10.1002/anie.201700572

Photo-induced Decarboxylative Heck-Type Coupling of Unactivated Aliphatic Acids and Terminal Alkenes in the Absence of Sacrificial Hydrogen Acceptors
journal, November 2018

Cao, Hui; Jiang, Heming; Feng, Hongyu
Journal of the American Chemical Society, Vol. 140, Issue 47
DOI: 10.1021/jacs.8b11218

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids
journal, January 2016

Zhang, Guoting; Zhang, Lingling; Yi, Hong
Chemical Communications, Vol. 52, Issue 68
DOI: 10.1039/C6CC04109D

Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature
journal, December 2018

Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz
Synthesis, Vol. 51, Issue 05
DOI: 10.1055/s-0037-1611633

Visible-Light Photoredox-Catalyzed Decarboxylative Alkylation of Heteroarenes Using Carboxylic Acids with Hydrogen Release
journal, August 2019

Tian, Wan-Fa; Hu, Chun-Hong; He, Ke-Han
Organic Letters, Vol. 21, Issue 17
DOI: 10.1021/acs.orglett.9b02539

Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C–H Amination and Hydroxylation
journal, August 2016

Zheng, Yi-Wen; Chen, Bin; Ye, Pan
Journal of the American Chemical Society, Vol. 138, Issue 32
DOI: 10.1021/jacs.6b05498

Photoredox and cobalt co-catalyzed C(sp ² )–H functionalization/C–O bond formation for synthesis of lactones under oxidant- and acceptor-free conditions
journal, January 2018

Zhang, Muliang; Ruzi, Rehanguli; Li, Nan
Organic Chemistry Frontiers, Vol. 5, Issue 5
DOI: 10.1039/C7QO00795G

External Oxidant-Free Dehydrogenative Lactonization of 2-Arylbenzoic Acids via Visible-Light Photocatalysis
journal, March 2018

Shao, Ailong; Zhan, Jirui; Li, Na
The Journal of Organic Chemistry, Vol. 83, Issue 7
DOI: 10.1021/acs.joc.7b03195

Anti-Markovnikov Oxidation of β-Alkyl Styrenes with H ₂ O as the Terminal Oxidant
journal, September 2016

Zhang, Guoting; Hu, Xia; Chiang, Chien-Wei
Journal of the American Chemical Society, Vol. 138, Issue 37
DOI: 10.1021/jacs.6b07411

Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles
journal, February 2017

Niu, Linbin; Yi, Hong; Wang, Shengchun
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms14226

Photocatalytic Dehydrogenative Cross-Coupling of Alkenes with Alcohols or Azoles without External Oxidant
journal, December 2016

Yi, Hong; Niu, Linbin; Song, Chunlan
Angewandte Chemie International Edition, Vol. 56, Issue 4
DOI: 10.1002/anie.201609274

Visible-Light-Induced External Oxidant-Free Oxidative Phosphonylation of C(sp ² )–H Bonds
journal, September 2017

Niu, Linbin; Liu, Jiamei; Yi, Hong
ACS Catalysis, Vol. 7, Issue 11
DOI: 10.1021/acscatal.7b02418

Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions
journal, March 2018

Zhang, Guoting; Lin, Yulin; Luo, Xu
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-03534-z

External Oxidant-Free Oxidative Cross-Coupling: A Photoredox Cobalt-Catalyzed Aromatic C–H Thiolation for Constructing C–S Bonds
journal, July 2015

Zhang, Guoting; Liu, Chao; Yi, Hong
Journal of the American Chemical Society, Vol. 137, Issue 29
DOI: 10.1021/jacs.5b05665

A visible-light photocatalytic N-radical cascade of hydrazones for the synthesis of dihydropyrazole-fused benzosultams
journal, January 2016

Zhao, Quan-Qing; Hu, Xiao-Qiang; Yang, Meng-Nan
Chemical Communications, Vol. 52, Issue 86
DOI: 10.1039/C6CC05897C

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis
journal, December 2015

West, Julian G.; Huang, David; Sorensen, Erik J.
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms10093

Toward a mild dehydroformylation using base-metal catalysis
journal, January 2017

Abrams, Dylan J.; West, Julian G.; Sorensen, Erik J.
Chemical Science, Vol. 8, Issue 3
DOI: 10.1039/C6SC04607J

Acceptorless Dehydrogenation of N-Heterocycles by Merging Visible-Light Photoredox Catalysis and Cobalt Catalysis
journal, February 2017

He, Ke-Han; Tan, Fang-Fang; Zhou, Chao-Zheng
Angewandte Chemie International Edition, Vol. 56, Issue 11
DOI: 10.1002/anie.201612486

Room temperature catalytic dehydrogenation of cyclic amines with the liberation of H ₂ using water as a solvent
journal, January 2019

Sahoo, Manoj K.; Balaraman, Ekambaram
Green Chemistry, Vol. 21, Issue 8
DOI: 10.1039/C9GC00201D

Photocatalysis Enabling Acceptorless Dehydrogenation of Diaryl Hydrazines at Room Temperature
journal, July 2018

Sahoo, Manoj K.; Saravanakumar, Krishnasamy; Jaiswal, Garima
ACS Catalysis, Vol. 8, Issue 8
DOI: 10.1021/acscatal.8b01579

A photochemical dehydrogenative strategy for aniline synthesis
journal, August 2020

U. Dighe, Shashikant; Juliá, Fabio; Luridiana, Alberto
Nature, Vol. 584, Issue 7819
DOI: 10.1038/s41586-020-2539-7

Decarboxylative Elimination of N -Acyl Amino Acids via Photoredox/Cobalt Dual Catalysis
journal, October 2018

Cartwright, Kaitie C.; Tunge, Jon A.
ACS Catalysis, Vol. 8, Issue 12
DOI: 10.1021/acscatal.8b03282

Photoredox/Cobalt Dual‐Catalyzed Decarboxylative Elimination of Carboxylic Acids: Development and Mechanistic Insight
journal, September 2020

Cartwright, Kaitie C.; Joseph, Ebbin; Comadoll, Chelsea G.
Chemistry – A European Journal, Vol. 26, Issue 54
DOI: 10.1002/chem.202001952

Catalytic dehydrogenative decarboxyolefination of carboxylic acids
journal, October 2018

Sun, Xiang; Chen, Junting; Ritter, Tobias
Nature Chemistry, Vol. 10, Issue 12
DOI: 10.1038/s41557-018-0142-4

Alkene Synthesis by Photocatalytic Chemoenzymatically Compatible Dehydrodecarboxylation of Carboxylic Acids and Biomass
journal, September 2019

Nguyen, Vu T.; Nguyen, Viet D.; Haug, Graham C.
ACS Catalysis, Vol. 9, Issue 10
DOI: 10.1021/acscatal.9b02951

A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System
journal, October 2017

Thullen, Scott M.; Rovis, Tomislav
Journal of the American Chemical Society, Vol. 139, Issue 43
DOI: 10.1021/jacs.7b09252

Controllable Isomerization of Alkenes by Dual Visible‐Light‐Cobalt Catalysis
journal, March 2019

Meng, Qing‐Yuan; Schirmer, Tobias E.; Katou, Kousuke
Angewandte Chemie International Edition, Vol. 58, Issue 17
DOI: 10.1002/anie.201900849

Photoredox/Cobalt Dual Catalysis for Visible-Light-Mediated Alkene–Alkyne Coupling
journal, May 2019

Rai, Pramod; Maji, Kakoli; Maji, Biplab
Organic Letters, Vol. 21, Issue 10
DOI: 10.1021/acs.orglett.9b01201

Visible Light-Gated Cobalt Catalysis for a Spatially and Temporally Resolved [2+2+2] Cycloaddition
journal, November 2016

Ruhl, Kyle E.; Rovis, Tomislav
Journal of the American Chemical Society, Vol. 138, Issue 48
DOI: 10.1021/jacs.6b08792

External Regulation of Cobalt-Catalyzed Cycloaddition Polymerization with Visible Light
journal, May 2018

Ravetz, Benjamin D.; Ruhl, Kyle E.; Rovis, Tomislav
ACS Catalysis, Vol. 8, Issue 6
DOI: 10.1021/acscatal.8b01431

Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II)
journal, November 2018

Ravetz, Benjamin D.; Wang, Jason Y.; Ruhl, Kyle E.
ACS Catalysis, Vol. 9, Issue 1
DOI: 10.1021/acscatal.8b04326

Visible-Light-Driven Alkyne Hydro-/Carbocarboxylation Using CO ₂ via Iridium/Cobalt Dual Catalysis for Divergent Heterocycle Synthesis
journal, March 2018

Hou, Jing; Ee, Aloysius; Feng, Wei
Journal of the American Chemical Society, Vol. 140, Issue 15
DOI: 10.1021/jacs.8b01561

Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis
journal, July 2018

Kalsi, Deepti; Dutta, Subhradeep; Barsu, Nagaraju
ACS Catalysis, Vol. 8, Issue 9
DOI: 10.1021/acscatal.8b02118

C–H and N–H bond annulation of aryl amides with unactivated olefins by merging cobalt( iii ) and photoredox catalysis
journal, January 2019

Kalsi, Deepti; Barsu, Nagaraju; Chakrabarti, Sagnik
Chemical Communications, Vol. 55, Issue 77
DOI: 10.1039/C9CC05744G

Cobalt‐Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis
journal, May 2019

Takizawa, Koji; Sekino, Tomoyuki; Sato, Shunta
Angewandte Chemie International Edition, Vol. 58, Issue 27
DOI: 10.1002/anie.201902509

Asymmetric Rhodium-Catalyzed Allylic Substitution Reactions: Discovery, Development and Applications to Target-Directed Synthesis
journal, September 2018

Turnbull, Ben W. H.; Evans, P. Andrew
The Journal of Organic Chemistry, Vol. 83, Issue 19
DOI: 10.1021/acs.joc.8b00583

Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination
journal, July 2019

Ghorai, Samir; Chirke, Sahadev Shrihari; Xu, Wen-Bin
Journal of the American Chemical Society, Vol. 141, Issue 29
DOI: 10.1021/jacs.9b06035

Angle-Dependent Optical Effects Deriving from Submicron Structures of Films and Pigments
journal, June 1999

Pfaff, Gerhard; Reynders, Peter
Chemical Reviews, Vol. 99, Issue 7
DOI: 10.1021/cr970075u

Composite Titanium Dioxide Nanomaterials
journal, May 2014

Dahl, Michael; Liu, Yiding; Yin, Yadong
Chemical Reviews, Vol. 114, Issue 19
DOI: 10.1021/cr400634p

Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations
journal, May 2014

Ma, Yi; Wang, Xiuli; Jia, Yushuai
Chemical Reviews, Vol. 114, Issue 19
DOI: 10.1021/cr500008u

New, Efficient Method for the Synthesis of Allyltitanium Compounds from Allyl Halides or Allyl Alcohol Derivatives via Oxidative Addition. A Highly Efficient and Practical Synthesis of Homoallyl Alcohols
journal, April 1995

Kasatkin, Aleksandr; Nakagawa, Takashi; Okamoto, Sentaro
Journal of the American Chemical Society, Vol. 117, Issue 13
DOI: 10.1021/ja00118a030

Emergence of a Novel Catalytic Radical Reaction: Titanocene-Catalyzed Reductive Opening of Epoxides
journal, November 1998

Gansäuer, Andreas; Bluhm, Harald; Pierobon, Marianna
Journal of the American Chemical Society, Vol. 120, Issue 49
DOI: 10.1021/ja981635p

Visible-light-driven spirocyclization of epoxides via dual titanocene and photoredox catalysis
journal, January 2020

Lin, Shuangjie; Chen, Yuqing; Li, Fusheng
Chemical Science, Vol. 11, Issue 3
DOI: 10.1039/C9SC05601G

Visible-light-mediated Barbier allylation of aldehydes and ketones via dual titanium and photoredox catalysis
journal, January 2020

Li, Fu-sheng; Chen, Yu-qing; Lin, Shuang-jie
Organic Chemistry Frontiers, Vol. 7, Issue 21
DOI: 10.1039/D0QO00171F

Cp ₂ TiCl ₂ -Catalyzed Photoredox Allylation of Aldehydes with Visible Light
journal, February 2020

Gualandi, Andrea; Calogero, Francesco; Mazzarini, Martino
ACS Catalysis, Vol. 10, Issue 6
DOI: 10.1021/acscatal.0c00348

Photocatalytic Generation of π‐Allyltitanium Complexes via Radical Intermediates
journal, November 2020

Li, Fusheng; Lin, Shuangjie; Chen, Yuqing
Angewandte Chemie International Edition, Vol. 60, Issue 3
DOI: 10.1002/anie.202010780

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis
journal, May 2020

Parasram, Marvin; Shields, Benjamin J.; Ahmad, Omar
ACS Catalysis, Vol. 10, Issue 10
DOI: 10.1021/acscatal.0c01199

Grignard-type carbonyl addition of allyl halides by means of chromous salt. A chemospecific synthesis of homoallyl alcohols
journal, April 1977

Okude, Yoshitaka; Hirano, Shigeo; Hiyama, Tamejiro
Journal of the American Chemical Society, Vol. 99, Issue 9
DOI: 10.1021/ja00451a061

Nozaki−Hiyama−Kishi Reactions Catalytic in Chromium
journal, January 1996

Fürstner, Alois; Shi, Nongyuan
Journal of the American Chemical Society, Vol. 118, Issue 49
DOI: 10.1021/ja9625236

Diastereoselective Allylation of Aldehydes by Dual Photoredox and Chromium Catalysis
journal, September 2018

Schwarz, J. Luca; Schäfers, Felix; Tlahuext-Aca, Adrian
Journal of the American Chemical Society, Vol. 140, Issue 40
DOI: 10.1021/jacs.8b08052

Catalytic Allylation of Aldehydes Using Unactivated Alkenes
journal, July 2020

Tanabe, Shun; Mitsunuma, Harunobu; Kanai, Motomu
Journal of the American Chemical Society, Vol. 142, Issue 28
DOI: 10.1021/jacs.0c04735

Dialkylation of 1,3-Dienes by Dual Photoredox and Chromium Catalysis
journal, December 2019

Schwarz, J. Luca; Huang, Huan-Ming; Paulisch, Tiffany O.
ACS Catalysis, Vol. 10, Issue 2
DOI: 10.1021/acscatal.9b04222

Radical Carbonyl Propargylation by Dual Catalysis
journal, December 2020

Huang, Huan‐Ming; Bellotti, Peter; Daniliuc, Constantin G.
Angewandte Chemie International Edition, Vol. 60, Issue 5
DOI: 10.1002/anie.202011996

1,2-Amino Alcohols via Cr/Photoredox Dual-Catalyzed Addition of α-Amino Carbanion Equivalents to Carbonyls
journal, January 2020

Schwarz, J. Luca; Kleinmans, Roman; Paulisch, Tiffany O.
Journal of the American Chemical Society, Vol. 142, Issue 5
DOI: 10.1021/jacs.9b12053

Direct Access to Monoprotected Homoallylic 1,2-Diols via Dual Chromium/Photoredox Catalysis
journal, September 2020

Schäfers, Felix; Quach, Linda; Schwarz, J. Luca
ACS Catalysis, Vol. 10, Issue 20
DOI: 10.1021/acscatal.0c03697

Coupling Reaction between Aldehydes and Non-Activated Hydrocarbons via the Reductive Radical-Polar Crossover Pathway
journal, January 2020

Yahata, Kenzo; Sakurai, Shu; Hori, Shuhei
Organic Letters, Vol. 22, Issue 3
DOI: 10.1021/acs.orglett.0c00096

Modern Rhodium‐Catalyzed Organic Reactions
book, January 2005

Evans, P. Andrew
Wiley-VCH Verlag GmbH & Co. KGaA
DOI: 10.1002/3527604693

A Rhodium Catalyst Superior to Iridium Congeners for Enantioselective Radical Amination Activated by Visible Light
journal, May 2016

Shen, Xiaodong; Harms, Klaus; Marsch, Michael
Chemistry - A European Journal, Vol. 22, Issue 27
DOI: 10.1002/chem.201601572

Asymmetric photoredox transition-metal catalysis activated by visible light
journal, November 2014

Huo, Haohua; Shen, Xiaodong; Wang, Chuanyong
Nature, Vol. 515, Issue 7525
DOI: 10.1038/nature13892

Direct Visible-Light-Excited Asymmetric Lewis Acid Catalysis of Intermolecular [2+2] Photocycloadditions
journal, June 2017

Huang, Xiaoqiang; Quinn, Taylor R.; Harms, Klaus
Journal of the American Chemical Society, Vol. 139, Issue 27
DOI: 10.1021/jacs.7b04363

Catalytic asymmetric synthesis of a nitrogen heterocycle through stereocontrolled direct photoreaction from electronically excited state
journal, December 2017

Huang, Xiaoqiang; Li, Xinyao; Xie, Xiulan
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/s41467-017-02148-1

Visible-Light-Activated Asymmetric β-C–H Functionalization of Acceptor-Substituted Ketones with 1,2-Dicarbonyl Compounds
journal, November 2017

Ma, Jiajia; Rosales, Anthony R.; Huang, Xiaoqiang
Journal of the American Chemical Society, Vol. 139, Issue 48
DOI: 10.1021/jacs.7b09152

Bis‐Cyclometalated Indazole Chiral‐at‐Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations
journal, November 2019

Steinlandt, Philipp S.; Zuo, Wei; Harms, Klaus
Chemistry – A European Journal, Vol. 25, Issue 67
DOI: 10.1002/chem.201903369

Asymmetric Photocatalysis with Bis-cyclometalated Rhodium Complexes
journal, March 2019

Huang, Xiaoqiang; Meggers, Eric
Accounts of Chemical Research, Vol. 52, Issue 3
DOI: 10.1021/acs.accounts.9b00028

Visible Light Induced Rhodium(I)‐Catalyzed C−H Borylation
journal, October 2019

Thongpaen, Jompol; Manguin, Romane; Dorcet, Vincent
Angewandte Chemie International Edition, Vol. 58, Issue 43
DOI: 10.1002/anie.201905924

Tris(2,2'-bipyridine)ruthenium(2+)-mediated photoreduction of olefins with 1-benzyl-1,4-dihydronicotinamide: a mechanistic probe for electron-transfer reactions of NAD(P)H-model compounds
journal, October 1981

Pac, Chyongjin; Ihama, Mikio; Yasuda, Masahide
Journal of the American Chemical Society, Vol. 103, Issue 21
DOI: 10.1021/ja00411a040

Photo-oxidation of some carbinols by the Ru(II) polypyridyl complex-aryl diazonium salt system
journal, January 1984

Cano-Yelo, Herminia; Deronzier, Alain
Tetrahedron Letters, Vol. 25, Issue 48
DOI: 10.1016/S0040-4039(01)81614-2

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
journal, October 2008

Nicewicz, D. A.; MacMillan, D. W. C.
Science, Vol. 322, Issue 5898
DOI: 10.1126/science.1161976

Efficient Visible Light Photocatalysis of [2+2] Enone Cycloadditions
journal, October 2008

Ischay, Michael A.; Anzovino, Mary E.; Du, Juana
Journal of the American Chemical Society, Vol. 130, Issue 39
DOI: 10.1021/ja805387f

Electron-Transfer Photoredox Catalysis: Development of a Tin-Free Reductive Dehalogenation Reaction
journal, July 2009

Narayanam, Jagan M. R.; Tucker, Joseph W.; Stephenson, Corey R. J.
Journal of the American Chemical Society, Vol. 131, Issue 25
DOI: 10.1021/ja9033582

Visible‐Light‐Enabled Ruthenium‐Catalyzed meta ‐C−H Alkylation at Room Temperature
journal, July 2019

Gandeepan, Parthasarathy; Koeller, Julian; Korvorapun, Korkit
Angewandte Chemie International Edition, Vol. 58, Issue 29
DOI: 10.1002/anie.201902258

meta ‐Selective C−H Activation of Arenes at Room Temperature Using Visible Light: Dual‐Function Ruthenium Catalysis
journal, July 2019

Sagadevan, Arunachalam; Greaney, Michael F.
Angewandte Chemie International Edition, Vol. 58, Issue 29
DOI: 10.1002/anie.201904288

Iron Dihydride Complex as the Pre-catalyst for Efficient Hydrosilylation of Aldehydes and Ketones Under Visible Light Activation
journal, May 2011

Castro, Luis C. Misal; Bézier, David; Sortais, Jean-Baptiste
Advanced Synthesis & Catalysis, Vol. 353, Issue 8
DOI: 10.1002/adsc.201000676

Visible-light-driven methane formation from CO2 with a molecular iron catalyst
journal, July 2017

Rao, Heng; Schmidt, Luciana C.; Bonin, Julien
Nature, Vol. 548, Issue 7665
DOI: 10.1038/nature23016

Visible-Light-Driven Conversion of CO ₂ to CH ₄ with an Organic Sensitizer and an Iron Porphyrin Catalyst
journal, December 2018

Rao, Heng; Lim, Chern-Hooi; Bonin, Julien
Journal of the American Chemical Society, Vol. 140, Issue 51
DOI: 10.1021/jacs.8b09740

Visible‐Light‐Promoted Iron‐Catalyzed C(sp ² )–C(sp ³ ) Kumada Cross‐Coupling in Flow
journal, July 2019

Wei, Xiao‐Jing; Abdiaj, Irini; Sambiagio, Carlo
Angewandte Chemie International Edition, Vol. 58, Issue 37
DOI: 10.1002/anie.201906462

Visible-Light-Driven Iron-Promoted Thiocarboxylation of Styrenes and Acrylates with CO ₂
journal, October 2017

Ye, Jian-Heng; Miao, Meng; Huang, He
Angewandte Chemie International Edition, Vol. 56, Issue 48
DOI: 10.1002/anie.201707862

Three-component difluoroalkylation–thiolation of alkenes by iron-facilitated visible-light photoredox catalysis
journal, January 2019

Xu, Rui; Cai, Chun
Chemical Communications, Vol. 55, Issue 30
DOI: 10.1039/C9CC00730J

Intermolecular dialkylation of alkenes with two distinct C(sp ³ )─H bonds enabled by synergistic photoredox catalysis and iron catalysis
journal, March 2019

Ouyang, Xuan-Hui; Li, Yang; Song, Ren-Jie
Science Advances, Vol. 5, Issue 3
DOI: 10.1126/sciadv.aav9839

Sonochemistry of dimanganese decacarbonyl (Mn2(CO)10) and dirhenium decacarbonyl (Re2(CO)10)
journal, September 1983

Suslick, Kenneth S.; Schubert, Paul F.
Journal of the American Chemical Society, Vol. 105, Issue 19
DOI: 10.1021/ja00357a014

Visible-Light-Initiated Manganese Catalysis for C−H Alkylation of Heteroarenes: Applications and Mechanistic Studies
journal, October 2017

Nuhant, Philippe; Oderinde, Martins S.; Genovino, Julien
Angewandte Chemie International Edition, Vol. 56, Issue 48
DOI: 10.1002/anie.201707958

Ketyl radical reactivity via atom transfer catalysis
journal, October 2018

Wang, Lu; Lear, Jeremy M.; Rafferty, Sean M.
Science, Vol. 362, Issue 6411
DOI: 10.1126/science.aau1777

Visible-Light-Promoted Manganese-Catalyzed Atom Transfer Radical Cyclization of Unactivated Alkyl Iodides
journal, June 2019

Weng, Wei-Zhi; Liang, Hao; Liu, Run-Zhou
Organic Letters, Vol. 21, Issue 14
DOI: 10.1021/acs.orglett.9b01918

Generation and Reactivity of Amidyl Radicals: Manganese‐Mediated Atom‐Transfer Reaction
journal, January 2020

Liu, Run‐Zhou; Li, Jinxia; Sun, Jun
Angewandte Chemie International Edition, Vol. 59, Issue 11
DOI: 10.1002/anie.201913042

Visible-Light-Mediated Manganese-Catalyzed Allylation Reactions of Unactivated Alkyl Iodides
journal, May 2020

Wang, Xiaochen; Dong, Jianyang; Li, Yongqiang
The Journal of Organic Chemistry, Vol. 85, Issue 11
DOI: 10.1021/acs.joc.0c00861

Visible-Light-Initiated Manganese-Catalyzed E -Selective Hydrosilylation and Hydrogermylation of Alkynes
journal, April 2019

Liang, Hao; Ji, Yun-Xing; Wang, Rui-Han
Organic Letters, Vol. 21, Issue 8
DOI: 10.1021/acs.orglett.9b00701

Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF ₃ SO ₂ Na
journal, January 2020

Long, Wenhao; Lian, Pengcheng; Li, Jingjing
Organic & Biomolecular Chemistry, Vol. 18, Issue 33
DOI: 10.1039/D0OB01322F

Kinetics and mechanism of apparent alkyl transfer from alkylcobaloximes to cobaloxime(I), cobaloxime(II), and cobaloxime(III) reagents
journal, May 1977

Dodd, David; Johnson, Michael D.; Lockman, Bill L.
Journal of the American Chemical Society, Vol. 99, Issue 11
DOI: 10.1021/ja00453a026

Bimolecular homolytic displacement of transition-metal complexes from carbon
journal, September 1983

Johnson, Michael D.
Accounts of Chemical Research, Vol. 16, Issue 9
DOI: 10.1021/ar00093a005

Connecting Organometallic Ni(III) and Ni(IV): Reactions of Carbon-Centered Radicals with High-Valent Organonickel Complexes
journal, May 2019

Bour, James R.; Ferguson, Devin M.; McClain, Edward J.
Journal of the American Chemical Society, Vol. 141, Issue 22
DOI: 10.1021/jacs.9b02411

Reductive radical-polar crossover: traditional electrophiles in modern radical reactions
journal, January 2019

Pitzer, Lena; Schwarz, J. Luca; Glorius, Frank
Chemical Science, Vol. 10, Issue 36
DOI: 10.1039/C9SC03359A

Catalytic Carbocation Generation Enabled by the Mesolytic Cleavage of Alkoxyamine Radical Cations
journal, July 2016

Zhu, Qilei; Gentry, Emily C.; Knowles, Robert R.
Angewandte Chemie International Edition, Vol. 55, Issue 34
DOI: 10.1002/anie.201604619

Spin-Selective Generation of Triplet Nitrenes: Olefin Aziridination through Visible-Light Photosensitization of Azidoformates
journal, January 2016

Scholz, Spencer O.; Farney, Elliot P.; Kim, Sangyun
Angewandte Chemie International Edition, Vol. 55, Issue 6
DOI: 10.1002/anie.201510868

Microenvironment mapping via Dexter energy transfer on immune cells
journal, March 2020

Geri, Jacob B.; Oakley, James V.; Reyes-Robles, Tamara
Science, Vol. 367, Issue 6482
DOI: 10.1126/science.aay4106

Photoredox-Assisted Gold-Catalyzed Arylative Alkoxycyclization of 1,6-Enynes
journal, April 2020

Mayans, Joan G.; Suppo, Jean-Simon; Echavarren, Antonio M.
Organic Letters, Vol. 22, Issue 8
DOI: 10.1021/acs.orglett.0c00799

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Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp³)–H Cross-Coupling

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In recent years, the development of light-driven reactions has contributed numerous advances in synthetic organic chemistry. A particularly active research area combines photoredox catalysis with nickel catalysis to accomplish otherwise inaccessible cross-coupling reactions. In these reactions, the photoredox catalyst absorbs light to generate an electronically excited charge-transfer state that can engage in electron or energy transfer with a substrate and the nickel catalyst. Our group questioned whether photoinduced activation of the nickel catalyst itself could also contribute new approaches to cross-coupling. Over the past five years, we have sought to advance this hypothesis for the development of a suite ofmore »« less
https://doi.org/10.1021/acs.accounts.0c00694

Full Text Available
³d-d Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications

Journal Article Ting, Stephen I. ; Garakyaraghi, Sofia ; Taliaferro, Chelsea M. ; ... - Journal of the American Chemical Society

Synthetic organic chemistry has seen major advances due to the merger of nickel and photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve generation of excited nickel species, sometimes even in the absence of a photoredox catalyst. To gain insights about these excited states, two of our groups previously studied the photophysics of Ni(^t-Bubpy)(o-Tol)Cl, which is representative of proposed intermediates in many Ni-photoredox reactions. This complex was found to have a long-lived excited state (τ = 4 ns), which was computationally assigned as a metal-to-ligand charge transfer (MLCT) state with an energy of 1.6 eV (38 kcal/mol).more »« less
Cited by 103
https://doi.org/10.1021/jacs.0c00781

Full Text Available
Mechanistic Origin of Photoredox Catalysis Involving Iron(II) Polypyridyl Chromophores

Journal Article Woodhouse, Matthew D. ; McCusker, James K. - Journal of the American Chemical Society

Photoredox catalysis employing ruthenium- and iridium-based chromophores have been the subject of considerable research. However, the natural abundance of these elements are among the lowest on the periodic table, a fact that has led to an interest in developing chromophores based on earth-abundant transition metals that can perform the same function. There have been reports of using Fe^II-based polypyridyl complexes as photocatalysts, but there is limited mechanistic information pertaining to the nature of their reactivity in the context of photoredox chemistry. Herein, we report the results of bimolecular quenching studies between [Fe(tren(py)₃)]²⁺ (where tren(py)₃ = tris(2-pyridyl-methylimino-ethyl)amine) and a series ofmore »« less
https://doi.org/10.1021/jacs.0c08389

Full Text Available
Direct Evidence for Excited Ligand Field State-based Oxidative Photoredox Chemistry of a Cobalt(III) Polypyridyl Photosensitizer

Journal Article Alowakennu, Micheal M. ; Ghosh, Atanu ; McCusker, James K. - Journal of the American Chemical Society

Increasing interest in sustainable chemistry coupled with the quest to explore new reactivity has spurred research on first-row transition metal complexes for potential applications in a variety of settings. One of the more active areas of research is photoredox catalysis, where the synthetically tunable nature of their electronic structures provides a rich palette of options for tailoring their reactivity to a desired chemical transformation. Understanding the mechanism of excited-state reactivity is critical for the informed development of next-generation catalysts, which in turn requires information concerning the propensity of their electronic excited states to engage in the desired electron or energymore »« less
https://doi.org/10.1021/jacs.3c09374
Direct Evidence of Visible Light-Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II)

Journal Article Fayad, Remi ; Engl, Sebastian ; Danilov, Evgeny O. ; ... - Journal of Physical Chemistry Letters

Developments in the field of photoredox catalysis that leveraged the long-lived excited states of Ir(III) and Ru(II) photosensi-tizers to enable radical coupling processes, paved the way for explorations of synthetic transformations that would otherwise remain unrealized. While first row transition metal photocatalysts have not been as extensively investigated, valuable syn-thetic transformations covering broad scopes of olefin functionalization have been recently reported featuring photoactivated chlorobis(phenanthroline) Cu(II) complexes. In the current study, the photochemical processes underpinning the catalytic activity of [Cu(dmp)2Cl]Cl (dmp = 2,9-dimethyl-1,10-phenanthroline) were investigated. The combined results from static spectroscopic investigations and conventional photochemistry, ultrafast transient absorption, and electron paramagneticmore »« less
Cited by 30
https://doi.org/10.1021/acs.jpclett.0c01601

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Title: Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

Abstract

Citation Formats

Palladium-Catalyzed Cross-Coupling Reactions in Total Synthesis journal, July 2005

Catalytic asymmetric hydrogenation employing a soluble, optically active, rhodium complex journal, January 1968

2, 2'-bis(diphenylphosphino)-1, 1'-binaphthyl(binap) journal, January 1984

The first practical method for asymmetric epoxidation journal, August 1980

Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques journal, February 1971

Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstraction journal, October 1974

Possible intermediate in the tungsten-catalyzed olefin metathesis reaction journal, April 1972

Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives journal, September 1968

A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides journal, October 1976

A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides journal, January 1979

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions journal, September 2016

Reductive coupling of organometals induced by oxidation. Detection of metastable paramagnetic intermediates journal, March 1978

Oxygen-atom transfer from nitrous oxide to a nickel metallacycle. Synthesis, structure, and reactions of [cyclic] (2,2'-bipyridine)Ni(OCH2CH2CH2CH2) journal, March 1993

Oxygen-atom transfer from nitrous oxide (NNO) to nickel alkyls. Syntheses and reactions of nickel(II) alkoxides journal, January 1995

Carbon−Oxygen Reductive-Elimination from Nickel(II) Oxametallacycles and Factors That Control Formation of Ether, Aldehyde, Alcohol, or Ester Products journal, August 1997

New N- and O-arylations with phenylboronic acids and cupric acetate journal, May 1998

New aryl/heteroaryl CN bond cross-coupling reactions via arylboronic acid/cupric acetate arylation journal, May 1998

Synthesis of diaryl ethers through the copper-promoted arylation of phenols with arylboronic acids. An expedient synthesis of thyroxine journal, May 1998

Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans journal, August 2010

High-valent organometallic copper and palladium in catalysis journal, April 2012

Catalyst Control of Site Selectivity in the Pd II/IV -Catalyzed Direct Arylation of Naphthalene journal, January 2011

Chemische Lichtwirkungen journal, May 1908

Applications of functionalized transition metal complexes in photonic and optoelectronic devices journal, October 1998

Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies journal, February 2010

Synthetically Tailored Excited States: Phosphorescent, Cyclometalated Iridium(III) Complexes and Their Applications journal, October 2006

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis journal, March 2013

Photoredox Catalysis in Organic Chemistry journal, June 2016

Organic Photoredox Catalysis journal, June 2016

The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle: The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle journal, March 2020

The photophysics of photoredox catalysis: a roadmap for catalyst design journal, January 2016

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis journal, March 2014

Dual Catalysis Strategies in Photochemical Synthesis journal, April 2016

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling journal, May 2016

The merger of transition metal and photocatalysis journal, July 2017

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize journal, May 2012

Recent advances in homogeneous nickel catalysis journal, May 2014

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore journal, February 2014

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin journal, July 2014

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis journal, April 2015

Merging photoredox with nickel catalysis: Coupling of -carboxyl sp3-carbons with aryl halides journal, June 2014

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis journal, February 2016

On-DNA Decarboxylative Arylation: Merging Photoredox with Nickel Catalysis in Water journal, June 2019

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids journal, May 2015

Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides journal, January 2015

Decarboxylative Hydroalkylation of Alkynes journal, April 2018

Fragment Couplings via CO 2 Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox journal, September 2015

Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones journal, January 1980

Facile generation of a reactive palladium(II) enolate intermediate by the decarboxylation of palladium(II) .beta.-ketocarboxylate and its utilization in allylic acylation journal, September 1980

Cross-Couplings of Unactivated Secondary Alkyl Halides: Room-Temperature Nickel-Catalyzed Negishi Reactions of Alkyl Bromides and Iodides journal, November 2003

Suzuki Cross-Couplings of Unactivated Secondary Alkyl Bromides and Iodides journal, January 2004

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides journal, August 2016

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners journal, March 2011

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis journal, June 2014

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings journal, April 2015

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis journal, November 2015

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers journal, June 2015

Single-Electron Transmetalation: Photoredox/Nickel Dual Catalytic Cross-Coupling of Secondary Alkyl β-Trifluoroboratoketones and -esters with Aryl Bromides journal, June 2016

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp 2 )-C(sp 3 ) Cross-Couplings in Flow journal, October 2016

Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis journal, May 2016

Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling journal, November 2017

Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis journal, January 2017

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides journal, April 2017

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso -Anhydrides journal, February 2017

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer journal, July 2017

On the Nature of C(sp 3 )–C(sp 2 ) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides journal, March 2020

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling journal, August 2015

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp 3 –sp 2 Cross-Coupling of Oxalates with Aryl Halides journal, October 2016

A new method for the deoxygenation of secondary alcohols journal, January 1975

O -Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp 3 –Csp 2 Cross-Coupling journal, May 2017

Remote Nickel-Catalyzed Cross-Coupling Arylation via Proton-Coupled Electron Transfer-Enabled C–C Bond Cleavage journal, February 2020

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O–H Bonds journal, August 2016

Dual Catalytic Strategy for Forging sp 2 – sp 3 and sp 3 – sp 3 Architectures via β - Scission of Aliphatic Alcohol Derivatives journal, November 2020

Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis journal, March 2021

Photosubstitution of Dicyanoarenes by Hypervalent Allylsilicon Reagents via Photoinduced Electron Transfer journal, April 2014

Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds journal, July 2015

Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions journal, January 2016

Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates journal, December 2015

Palladium-Catalyzed Cross-Coupling Reactions in Total Synthesis
journal, July 2005

Catalytic asymmetric hydrogenation employing a soluble, optically active, rhodium complex
journal, January 1968

2, 2'-bis(diphenylphosphino)-1, 1'-binaphthyl(binap)
journal, January 1984

The first practical method for asymmetric epoxidation
journal, August 1980

Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques
journal, February 1971

Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstraction
journal, October 1974

Possible intermediate in the tungsten-catalyzed olefin metathesis reaction
journal, April 1972

Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives
journal, September 1968

A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides
journal, October 1976

A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
journal, January 1979

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
journal, September 2016

Reductive coupling of organometals induced by oxidation. Detection of metastable paramagnetic intermediates
journal, March 1978

Oxygen-atom transfer from nitrous oxide to a nickel metallacycle. Synthesis, structure, and reactions of [cyclic] (2,2'-bipyridine)Ni(OCH2CH2CH2CH2)
journal, March 1993

Oxygen-atom transfer from nitrous oxide (NNO) to nickel alkyls. Syntheses and reactions of nickel(II) alkoxides
journal, January 1995

Carbon−Oxygen Reductive-Elimination from Nickel(II) Oxametallacycles and Factors That Control Formation of Ether, Aldehyde, Alcohol, or Ester Products
journal, August 1997

New N- and O-arylations with phenylboronic acids and cupric acetate
journal, May 1998

New aryl/heteroaryl CN bond cross-coupling reactions via arylboronic acid/cupric acetate arylation
journal, May 1998

Synthesis of diaryl ethers through the copper-promoted arylation of phenols with arylboronic acids. An expedient synthesis of thyroxine
journal, May 1998

Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans
journal, August 2010

High-valent organometallic copper and palladium in catalysis
journal, April 2012

Catalyst Control of Site Selectivity in the Pd ^II/IV -Catalyzed Direct Arylation of Naphthalene
journal, January 2011

Chemische Lichtwirkungen
journal, May 1908

Applications of functionalized transition metal complexes in photonic and optoelectronic devices
journal, October 1998

Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies
journal, February 2010

Synthetically Tailored Excited States: Phosphorescent, Cyclometalated Iridium(III) Complexes and Their Applications
journal, October 2006

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
journal, March 2013

Photoredox Catalysis in Organic Chemistry
journal, June 2016

Organic Photoredox Catalysis
journal, June 2016

The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle: The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle
journal, March 2020

The photophysics of photoredox catalysis: a roadmap for catalyst design
journal, January 2016

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis
journal, March 2014

Dual Catalysis Strategies in Photochemical Synthesis
journal, April 2016

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling
journal, May 2016

The merger of transition metal and photocatalysis
journal, July 2017

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
journal, May 2012

Recent advances in homogeneous nickel catalysis
journal, May 2014

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore
journal, February 2014

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin
journal, July 2014

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis
journal, April 2015

Merging photoredox with nickel catalysis: Coupling of -carboxyl sp3-carbons with aryl halides
journal, June 2014

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis
journal, February 2016

On-DNA Decarboxylative Arylation: Merging Photoredox with Nickel Catalysis in Water
journal, June 2019

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids
journal, May 2015

Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides
journal, January 2015

Decarboxylative Hydroalkylation of Alkynes
journal, April 2018

Fragment Couplings via CO ₂ Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox
journal, September 2015

Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones
journal, January 1980

Facile generation of a reactive palladium(II) enolate intermediate by the decarboxylation of palladium(II) .beta.-ketocarboxylate and its utilization in allylic acylation
journal, September 1980

Cross-Couplings of Unactivated Secondary Alkyl Halides: Room-Temperature Nickel-Catalyzed Negishi Reactions of Alkyl Bromides and Iodides
journal, November 2003

Suzuki Cross-Couplings of Unactivated Secondary Alkyl Bromides and Iodides
journal, January 2004

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides
journal, August 2016

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
journal, March 2011

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis
journal, June 2014

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings
journal, April 2015

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis
journal, November 2015

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers
journal, June 2015

Single-Electron Transmetalation: Photoredox/Nickel Dual Catalytic Cross-Coupling of Secondary Alkyl β-Trifluoroboratoketones and -esters with Aryl Bromides
journal, June 2016

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp ² )-C(sp ³ ) Cross-Couplings in Flow
journal, October 2016

Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis
journal, May 2016

Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling
journal, November 2017

Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis
journal, January 2017

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides
journal, April 2017

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso -Anhydrides
journal, February 2017

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer
journal, July 2017

On the Nature of C(sp ³ )–C(sp ² ) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides
journal, March 2020

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling
journal, August 2015

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp ³ –sp ² Cross-Coupling of Oxalates with Aryl Halides
journal, October 2016

A new method for the deoxygenation of secondary alcohols
journal, January 1975

O -Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp ³ –Csp ² Cross-Coupling
journal, May 2017

Remote Nickel-Catalyzed Cross-Coupling Arylation via Proton-Coupled Electron Transfer-Enabled C–C Bond Cleavage
journal, February 2020

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O–H Bonds
journal, August 2016

Dual Catalytic Strategy for Forging sp ² – sp ³ and sp ³ – sp ³ Architectures via β - Scission of Aliphatic Alcohol Derivatives
journal, November 2020

Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis
journal, March 2021

Photosubstitution of Dicyanoarenes by Hypervalent Allylsilicon Reagents via Photoinduced Electron Transfer
journal, April 2014

Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds
journal, July 2015

Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions
journal, January 2016

Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates
journal, December 2015

Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis
journal, February 2016

C(sp ³ )–C(sp ² ) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates
journal, January 2017

Photoredox/Nickel Dual Catalysis for the C(sp ³ )-C(sp ³ ) Cross-Coupling of Alkylsilicates with Alkyl Halides: Photoredox/Nickel Dual Catalysis for the C(sp ³ )-C(sp ³ ) Cross-Coupling of Alkylsilicates with Alkyl Halides
journal, March 2017