Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices
Abstract
This Letter describes strong coupling between a plasmonic nanoparticle (NP) lattice cavity and Soret excitons in a metal–organic framework (MOF) film. In optical transmission measurements, we observed a lower polariton mode that can be spectrally tuned by infiltrating MOF pores with solvents of different refractive index. Using transient absorption spectroscopy, both the lower and upper polariton modes can be resolved, with an estimated Rabi splitting of ~300 meV, nearly twice that of other plasmonic cavity–organic emitter systems. The polariton modes decay more rapidly than that of the uncoupled exciton. Furthermore, this hybrid system highlights the advantages of open plasmonic cavities for tunable coupling and the use of transient absorption spectroscopy to identify polariton modes.
- Authors:
-
- Northwestern University, Evanston, IL (United States)
- Northwestern University, Evanston, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 2001268
- Grant/Contract Number:
- SC0004752; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 126; Journal Issue: 44; Related Information: https://pubs.acs.org/doi/10.1021/acs.jpcc.2c05464.; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; Excitons; Lattices; Metal organic frameworks; Polaritons; Quantum mechanics
Citation Formats
Sample, Alexander D., Guan, Jun, Hu, Jingtian, Freire-Fernández, Francisco, Park, Sang-Min, Schaller, Richard D., Schatz, George C., and Odom, Teri W. Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices. United States: N. p., 2022.
Web. doi:10.1021/acs.jpcc.2c05464.
Sample, Alexander D., Guan, Jun, Hu, Jingtian, Freire-Fernández, Francisco, Park, Sang-Min, Schaller, Richard D., Schatz, George C., & Odom, Teri W. Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices. United States. https://doi.org/10.1021/acs.jpcc.2c05464
Sample, Alexander D., Guan, Jun, Hu, Jingtian, Freire-Fernández, Francisco, Park, Sang-Min, Schaller, Richard D., Schatz, George C., and Odom, Teri W. Fri .
"Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices". United States. https://doi.org/10.1021/acs.jpcc.2c05464. https://www.osti.gov/servlets/purl/2001268.
@article{osti_2001268,
title = {Polariton Formation from Soret Band Excitons in Metal–Organic Frameworks and Plasmonic Lattices},
author = {Sample, Alexander D. and Guan, Jun and Hu, Jingtian and Freire-Fernández, Francisco and Park, Sang-Min and Schaller, Richard D. and Schatz, George C. and Odom, Teri W.},
abstractNote = {This Letter describes strong coupling between a plasmonic nanoparticle (NP) lattice cavity and Soret excitons in a metal–organic framework (MOF) film. In optical transmission measurements, we observed a lower polariton mode that can be spectrally tuned by infiltrating MOF pores with solvents of different refractive index. Using transient absorption spectroscopy, both the lower and upper polariton modes can be resolved, with an estimated Rabi splitting of ~300 meV, nearly twice that of other plasmonic cavity–organic emitter systems. The polariton modes decay more rapidly than that of the uncoupled exciton. Furthermore, this hybrid system highlights the advantages of open plasmonic cavities for tunable coupling and the use of transient absorption spectroscopy to identify polariton modes.},
doi = {10.1021/acs.jpcc.2c05464},
journal = {Journal of Physical Chemistry. C},
number = 44,
volume = 126,
place = {United States},
year = {Fri Oct 28 00:00:00 EDT 2022},
month = {Fri Oct 28 00:00:00 EDT 2022}
}
Works referenced in this record:
Tilting a ground-state reactivity landscape by vibrational strong coupling
journal, February 2019
- Thomas, A.; Lethuillier-Karl, L.; Nagarajan, K.
- Science, Vol. 363, Issue 6427
Cavity-based quantum networks with single atoms and optical photons
journal, December 2015
- Reiserer, Andreas; Rempe, Gerhard
- Reviews of Modern Physics, Vol. 87, Issue 4
Experimental realization of a one-atom laser in the regime of strong coupling
journal, September 2003
- McKeever, J.; Boca, A.; Boozer, A. D.
- Nature, Vol. 425, Issue 6955
Quantum Plasmonic Sensors
journal, March 2021
- Lee, Changhyoup; Lawrie, Benjamin; Pooser, Raphael
- Chemical Reviews, Vol. 121, Issue 8
Cavity-Enhanced Transport of Excitons
journal, May 2015
- Schachenmayer, Johannes; Genes, Claudiu; Tignone, Edoardo
- Physical Review Letters, Vol. 114, Issue 19
Strong-Coupling Theory of Periodically Driven Two-Level Systems
journal, January 2007
- Wu, Ying; Yang, Xiaoxue
- Physical Review Letters, Vol. 98, Issue 1
Dynamics of Strongly Coupled Hybrid States by Transient Absorption Spectroscopy
journal, August 2018
- Wang, Hai; Wang, Hai‐Yu; Sun, Hong‐Bo
- Advanced Functional Materials, Vol. 28, Issue 48
Origin of the asymmetric light emission from molecular exciton–polaritons
journal, January 2018
- Neuman, Tomáš; Aizpurua, Javier
- Optica, Vol. 5, Issue 10
Light–matter interaction in the strong coupling regime: configurations, conditions, and applications
journal, January 2018
- Dovzhenko, D. S.; Ryabchuk, S. V.; Rakovich, Yu. P.
- Nanoscale, Vol. 10, Issue 8
Ultrastrong coupling between light and matter
journal, January 2019
- Frisk Kockum, Anton; Miranowicz, Adam; De Liberato, Simone
- Nature Reviews Physics, Vol. 1, Issue 1
Strong coupling between surface plasmon polaritons and emitters: a review
journal, December 2014
- Törmä, P.; Barnes, W. L.
- Reports on Progress in Physics, Vol. 78, Issue 1
Novel Nanostructures and Materials for Strong Light–Matter Interactions
journal, October 2017
- Baranov, Denis G.; Wersäll, Martin; Cuadra, Jorge
- ACS Photonics, Vol. 5, Issue 1
Active Control of the Strong Coupling Regime between Porphyrin Excitons and Surface Plasmon Polaritons
journal, July 2011
- Berrier, Audrey; Cools, Ruud; Arnold, Christophe
- ACS Nano, Vol. 5, Issue 8
Oscillator strengths in porphyrins
journal, January 1971
- Hush, N. S.; Williams, M. L.
- Chemical Physics Letters, Vol. 8, Issue 2
Porphyrins XXIV. Energy, oscillator strength, and Zeeman splitting calculations (SCMO-CI) for phthalocyanine, porphyrins, and related ring systems
journal, December 1972
- McHugh, A. J.; Gouterman, Martin; Weiss, Charles
- Theoretica Chimica Acta, Vol. 24, Issue 4
Probing the role of oscillator strength and charge of exciton forming molecular J-aggregates in controlling nanoscale plasmon–exciton interactions
journal, January 2020
- Das, Kamalika; Dey, Jyotirban; Verma, Mrigank Singh
- Physical Chemistry Chemical Physics, Vol. 22, Issue 36
Plexcitons: The Role of Oscillator Strengths and Spectral Widths in Determining Strong Coupling
journal, January 2018
- Thomas, Reshmi; Thomas, Anoop; Pullanchery, Saranya
- ACS Nano, Vol. 12, Issue 1
Counterion-Dependent Excitonic Spectra of Tetra( p -carboxyphenyl)porphyrin Aggregates in Acidic Aqueous Solution
journal, January 2003
- Choi, Myong Yong; Pollard, Jennifer A.; Webb, M. Adam
- Journal of the American Chemical Society, Vol. 125, Issue 3
Strong coupling in porphyrin J-aggregate excitons and plasmons in nano-void arrays
journal, October 2017
- Ferdele, Stefano; Jose, Bincy; Foster, Robert
- Optical Materials, Vol. 72
Guest-responsive polaritons in a porous framework: chromophoric sponges in optical QED cavities
journal, January 2020
- Haldar, Ritesh; Fu, Zhihua; Joseph, Reetu
- Chemical Science, Vol. 11, Issue 30
Strong coupling in high-finesse organic semiconductor microcavities
journal, December 2003
- Connolly, L. G.; Lidzey, D. G.; Butté, R.
- Applied Physics Letters, Vol. 83, Issue 26
Strong exciton–photon coupling in an organic semiconductor microcavity
journal, September 1998
- Lidzey, D. G.; Bradley, D. D. C.; Skolnick, M. S.
- Nature, Vol. 395, Issue 6697
Luminescent Functional Metal–Organic Frameworks
journal, June 2011
- Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong
- Chemical Reviews, Vol. 112, Issue 2
Spatially defined molecular emitters coupled to plasmonic nanoparticle arrays
journal, March 2019
- Liu, Jianxi; Wang, Weijia; Wang, Danqing
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 13
Sub-picosecond thermalization dynamics in condensation of strongly coupled lattice plasmons
journal, June 2020
- Väkeväinen, Aaro I.; Moilanen, Antti J.; Nečada, Marek
- Nature Communications, Vol. 11, Issue 1
Plasmonic Surface Lattice Resonances at the Strong Coupling Regime
journal, December 2013
- Väkeväinen, A. I.; Moerland, R. J.; Rekola, H. T.
- Nano Letters, Vol. 14, Issue 4
Programmable Soft Lithography: Solvent-Assisted Nanoscale Embossing
journal, February 2011
- Lee, Min Hyung; Huntington, Mark D.; Zhou, Wei
- Nano Letters, Vol. 11, Issue 2
Multiscale patterning of plasmonic metamaterials
journal, August 2007
- Henzie, Joel; Lee, Min Hyung; Odom, Teri W.
- Nature Nanotechnology, Vol. 2, Issue 9
Strong Coupling Between Plasmons and Molecular Excitons in Metal–Organic Frameworks
journal, September 2021
- Sample, Alexander D.; Guan, Jun; Hu, Jingtian
- Nano Letters, Vol. 21, Issue 18
Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
journal, May 2015
- Liu, Jinxuan; Zhou, Wencai; Liu, Jianxi
- Angewandte Chemie International Edition, Vol. 54, Issue 25
On the dielectric and optical properties of surface-anchored metal-organic frameworks: A study on epitaxially grown thin films
journal, August 2013
- Redel, Engelbert; Wang, Zhengbang; Walheim, Stefan
- Applied Physics Letters, Vol. 103, Issue 9
Geometry dependence of surface lattice resonances in plasmonic nanoparticle arrays
journal, April 2017
- Guo, R.; Hakala, T. K.; Törmä, P.
- Physical Review B, Vol. 95, Issue 15
Ultrafast Relaxation Dynamics in Zinc Tetraphenylporphyrin Surface-Mounted Metal Organic Framework
journal, December 2017
- Li, Xiaoxin; Gong, Chenghuan; Gurzadyan, Gagik G.
- The Journal of Physical Chemistry C, Vol. 122, Issue 1
Femtosecond to Microsecond Dynamics of Soret-Band Excited Corroles
journal, December 2015
- Raavi, Sai Santosh Kumar; Yin, Jun; Grancini, Giulia
- The Journal of Physical Chemistry C, Vol. 119, Issue 52
Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices
journal, March 2022
- Park, Jeong-Eun; López-Arteaga, Rafael; Sample, Alexander D.
- ACS Nano, Vol. 16, Issue 3
Realizing Strong Light-Matter Interactions between Single-Nanoparticle Plasmons and Molecular Excitons at Ambient Conditions
journal, April 2015
- Zengin, Gülis; Wersäll, Martin; Nilsson, Sara
- Physical Review Letters, Vol. 114, Issue 15
Tracking Polariton Relaxation with Multiscale Molecular Dynamics Simulations
journal, August 2019
- Groenhof, Gerrit; Climent, Clàudia; Feist, Johannes
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 18
Room Temperature Weak-to-Strong Coupling and the Emergence of Collective Emission from Quantum Dots Coupled to Plasmonic Arrays
journal, May 2020
- Yadav, Ravindra Kumar; Bourgeois, Marc R.; Cherqui, Charles
- ACS Nano, Vol. 14, Issue 6