Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices
Abstract
Strong coupling between light and matter can produce hybrid eigenstates known as exciton–polaritons. Although polariton dynamics are important photophysical properties, the relaxation pathways of polaritons in different coupling regimes have seen limited attention. This paper reports the dynamics of hybridized states from 2D Ruddlesden–Popper perovskites coupled to plasmonic nanoparticle lattices. The open cavity architecture of Al lattices enables the coupling strength to be modulated by varying either the lead halide perovskite film thickness or the superstrate refractive index. Both experiments and finite-difference time-domain simulations of the optical dispersion diagrams showed avoided crossings that are a signature of strong coupling. Our analytical model also elucidated the correlation between the exciton/plasmon mixing ratio and polariton coupling strength. Using fs-transient absorption spectroscopy, we found that both the upper and lower polaritons have shorter lifetimes than the excitons and that polaritons can show faster excited-state dynamics when they have access to additional energy transfer channels.
- Authors:
-
[1];
[2];
[2];
[2];
[3];
[2];
[2];
[2];
[2];
[2]
- Northwestern Univ., Evanston, IL (United States); Gwangju Institute of Science and Technology (GIST) (Korea, Republic of)
- Northwestern Univ., Evanston, IL (United States)
- Northwestern Univ., Evanston, IL (United States); Univ. of South Florida, Tampa, FL (United States)
- Publication Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States); Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); US DoD; US Department of the Navy, Office of Naval Research (ONR)
- OSTI Identifier:
- 1865235
- Alternate Identifier(s):
- OSTI ID: 1866210; OSTI ID: 1870319
- Grant/Contract Number:
- SC0012541; SC0021314; SC0004752; N00014-21-1-2289; N00014-17-13023; DMR-1720139; ECCS-2025633
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 16; Journal Issue: 3; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; strong coupling; polariton; plasmonic nanoparticle lattices; 2D perovskite; polariton dynamics; lattices; excitons; lipids; perovskites; strong coupling, polariton, plasmonic nanoparticle lattices, 2D perovskite, polariton dynamics
Citation Formats
Park, Jeong-Eun, López-Arteaga, Rafael, Sample, Alexander D., Cherqui, Charles R., Spanopoulos, Ioannis, Guan, Jun, Kanatzidis, Mercouri G., Schatz, George C., Weiss, Emily A., and Odom, Teri W. Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices. United States: N. p., 2022.
Web. doi:10.1021/acsnano.1c09296.
Park, Jeong-Eun, López-Arteaga, Rafael, Sample, Alexander D., Cherqui, Charles R., Spanopoulos, Ioannis, Guan, Jun, Kanatzidis, Mercouri G., Schatz, George C., Weiss, Emily A., & Odom, Teri W. Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices. United States. https://doi.org/10.1021/acsnano.1c09296
Park, Jeong-Eun, López-Arteaga, Rafael, Sample, Alexander D., Cherqui, Charles R., Spanopoulos, Ioannis, Guan, Jun, Kanatzidis, Mercouri G., Schatz, George C., Weiss, Emily A., and Odom, Teri W. Wed .
"Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices". United States. https://doi.org/10.1021/acsnano.1c09296. https://www.osti.gov/servlets/purl/1865235.
@article{osti_1865235,
title = {Polariton Dynamics in Two-Dimensional Ruddlesden–Popper Perovskites Strongly Coupled with Plasmonic Lattices},
author = {Park, Jeong-Eun and López-Arteaga, Rafael and Sample, Alexander D. and Cherqui, Charles R. and Spanopoulos, Ioannis and Guan, Jun and Kanatzidis, Mercouri G. and Schatz, George C. and Weiss, Emily A. and Odom, Teri W.},
abstractNote = {Strong coupling between light and matter can produce hybrid eigenstates known as exciton–polaritons. Although polariton dynamics are important photophysical properties, the relaxation pathways of polaritons in different coupling regimes have seen limited attention. This paper reports the dynamics of hybridized states from 2D Ruddlesden–Popper perovskites coupled to plasmonic nanoparticle lattices. The open cavity architecture of Al lattices enables the coupling strength to be modulated by varying either the lead halide perovskite film thickness or the superstrate refractive index. Both experiments and finite-difference time-domain simulations of the optical dispersion diagrams showed avoided crossings that are a signature of strong coupling. Our analytical model also elucidated the correlation between the exciton/plasmon mixing ratio and polariton coupling strength. Using fs-transient absorption spectroscopy, we found that both the upper and lower polaritons have shorter lifetimes than the excitons and that polaritons can show faster excited-state dynamics when they have access to additional energy transfer channels.},
doi = {10.1021/acsnano.1c09296},
journal = {ACS Nano},
number = 3,
volume = 16,
place = {United States},
year = {Wed Mar 02 00:00:00 EST 2022},
month = {Wed Mar 02 00:00:00 EST 2022}
}
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Works referenced in this record:
Polarization-Dependent Lasing Behavior from Low-Symmetry Nanocavity Arrays
journal, April 2019
- Knudson, Michael P.; Li, Ran; Wang, Danqing
- ACS Nano, Vol. 13, Issue 7
Tunable Out-of-Plane Excitons in 2D Single-Crystal Perovskites
journal, September 2018
- Fieramosca, Antonio; De Marco, Luisa; Passoni, Marco
- ACS Photonics, Vol. 5, Issue 10
Electrical Tuning of Exciton–Plasmon Polariton Coupling in Monolayer MoS 2 Integrated with Plasmonic Nanoantenna Lattice
journal, June 2017
- Lee, Bumsu; Liu, Wenjing; Naylor, Carl H.
- Nano Letters, Vol. 17, Issue 7
Quantum Dot-Plasmon Lasing with Controlled Polarization Patterns
journal, February 2020
- Guan, Jun; Sagar, Laxmi Kishore; Li, Ran
- ACS Nano, Vol. 14, Issue 3
Enhanced Delayed Fluorescence in Tetracene Crystals by Strong Light‐Matter Coupling
journal, July 2019
- Berghuis, Anton Matthijs; Halpin, Alexei; Le‐Van, Quynh
- Advanced Functional Materials, Vol. 29, Issue 36
Two-dimensional hybrid perovskites sustaining strong polariton interactions at room temperature
journal, May 2019
- Fieramosca, A.; Polimeno, L.; Ardizzone, V.
- Science Advances, Vol. 5, Issue 5
Strongly Coupled Exciton–Surface Lattice Resonances Engineer Long-Range Energy Propagation
journal, May 2020
- Yadav, Ravindra Kumar; Otten, Matthew; Wang, Weijia
- Nano Letters, Vol. 20, Issue 7
Hierarchical Hybridization in Plasmonic Honeycomb Lattices
journal, August 2019
- Li, Ran; Bourgeois, Marc R.; Cherqui, Charles
- Nano Letters, Vol. 19, Issue 9
Room-Temperature Polariton Lasing in All-Inorganic Perovskite Nanoplatelets
journal, May 2017
- Su, Rui; Diederichs, Carole; Wang, Jun
- Nano Letters, Vol. 17, Issue 6
Strong Coupling Between Plasmons and Molecular Excitons in Metal–Organic Frameworks
journal, September 2021
- Sample, Alexander D.; Guan, Jun; Hu, Jingtian
- Nano Letters, Vol. 21, Issue 18
Plasmonic Surface Lattice Resonances at the Strong Coupling Regime
journal, December 2013
- Väkeväinen, A. I.; Moerland, R. J.; Rekola, H. T.
- Nano Letters, Vol. 14, Issue 4
Spatially defined molecular emitters coupled to plasmonic nanoparticle arrays
journal, March 2019
- Liu, Jianxi; Wang, Weijia; Wang, Danqing
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 13
Engineering Directionality in Quantum Dot Shell Lasing Using Plasmonic Lattices
journal, January 2020
- Guan, Jun; Sagar, Laxmi Kishore; Li, Ran
- Nano Letters, Vol. 20, Issue 2
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises
journal, November 2018
- Mao, Lingling; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Journal of the American Chemical Society, Vol. 141, Issue 3
Recent progress of the optoelectronic properties of 2D Ruddlesden-Popper perovskites
journal, April 2019
- Wang, Haizhen; Fang, Chen; Luo, Hongmei
- Journal of Semiconductors, Vol. 40, Issue 4
Direct Evidence for Surface Plasmon-Mediated Enhanced Light Transmission through Metallic Nanohole Arrays
journal, September 2006
- Gao, Hanwei; Henzie, Joel; Odom, Teri W.
- Nano Letters, Vol. 6, Issue 9, p. 2104-2108
Strong exciton–photon coupling at room temperature in microcavities containing two-dimensional layered perovskite compounds
journal, June 2008
- Lanty, G.; Bréhier, A.; Parashkov, R.
- New Journal of Physics, Vol. 10, Issue 6
Spatial Coherence Properties of Organic Molecules Coupled to Plasmonic Surface Lattice Resonances in the Weak and Strong Coupling Regimes
journal, April 2014
- Shi, L.; Hakala, T. K.; Rekola, H. T.
- Physical Review Letters, Vol. 112, Issue 15
Dynamics of Strongly Coupled Hybrid States by Transient Absorption Spectroscopy
journal, August 2018
- Wang, Hai; Wang, Hai‐Yu; Sun, Hong‐Bo
- Advanced Functional Materials, Vol. 28, Issue 48
Ultrafast Manipulation of Strong Coupling in Metal−Molecular Aggregate Hybrid Nanostructures
journal, November 2010
- Vasa, P.; Pomraenke, R.; Cirmi, G.
- ACS Nano, Vol. 4, Issue 12
Polariton Transitions in Femtosecond Transient Absorption Studies of Ultrastrong Light–Molecule Coupling
journal, March 2020
- DelPo, Courtney A.; Kudisch, Bryan; Park, Kyu Hyung
- The Journal of Physical Chemistry Letters, Vol. 11, Issue 7
Dynamics of Strong Coupling between J-Aggregates and Surface Plasmon Polaritons in Subwavelength Hole Arrays
journal, June 2016
- Wang, Hai; Wang, Hai-Yu; Bozzola, Angelo
- Advanced Functional Materials, Vol. 26, Issue 34
Energy transfer mechanisms in layered 2D perovskites
journal, April 2018
- Williams, Olivia F.; Guo, Zhenkun; Hu, Jun
- The Journal of Chemical Physics, Vol. 148, Issue 13
Uniaxial Expansion of the 2D Ruddlesden–Popper Perovskite Family for Improved Environmental Stability
journal, March 2019
- Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun
- Journal of the American Chemical Society, Vol. 141, Issue 13
Two Dimensions Are Better for Perovskites
journal, September 2019
- Zheng, Kaibo; Pullerits, Tönu
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 19
Geometry dependence of surface lattice resonances in plasmonic nanoparticle arrays
journal, April 2017
- Guo, R.; Hakala, T. K.; Törmä, P.
- Physical Review B, Vol. 95, Issue 15
The rich photonic world of plasmonic nanoparticle arrays
journal, April 2018
- Wang, Weijia; Ramezani, Mohammad; Väkeväinen, Aaro I.
- Materials Today, Vol. 21, Issue 3
Ultranarrow plasmon resonances from annealed nanoparticle lattices
journal, September 2020
- Deng, Shikai; Li, Ran; Park, Jeong-Eun
- Proceedings of the National Academy of Sciences, Vol. 117, Issue 38
Optical studies of semiconductor perovskite nanocrystals for classical optoelectronic applications and quantum information technologies: a review
journal, September 2020
- Cao, Zengle; Hu, Fengrui; Zhang, Chunfeng
- Advanced Photonics, Vol. 2, Issue 05
Understanding the Defect Properties of Quasi-2D Halide Perovskites for Photovoltaic Applications
journal, April 2020
- Liu, Na; Liu, Pengfei; Zhou, Huanping
- The Journal of Physical Chemistry Letters, Vol. 11, Issue 9
Transient exciton-polariton dynamics in WSe 2 by ultrafast near-field imaging
journal, February 2019
- Mrejen, M.; Yadgarov, L.; Levanon, A.
- Science Advances, Vol. 5, Issue 2
Exciton-Polariton Properties in Planar Microcavity of Millimeter-Sized Two-Dimensional Perovskite Sheet
journal, January 2020
- Zhang, Xiaoli; Shi, Huafeng; Dai, Haitao
- ACS Applied Materials & Interfaces, Vol. 12, Issue 4
Novel Nanostructures and Materials for Strong Light–Matter Interactions
journal, October 2017
- Baranov, Denis G.; Wersäll, Martin; Cuadra, Jorge
- ACS Photonics, Vol. 5, Issue 1
Real-time tunable lasing from plasmonic nanocavity arrays
journal, April 2015
- Yang, Ankun; Hoang, Thang B.; Dridi, Montacer
- Nature Communications, Vol. 6, Issue 1
Room Temperature Coherently Coupled Exciton–Polaritons in Two-Dimensional Organic–Inorganic Perovskite
journal, July 2018
- Wang, Jun; Su, Rui; Xing, Jun
- ACS Nano, Vol. 12, Issue 8
Perovskite semiconductors for room-temperature exciton-polaritonics
journal, July 2021
- Su, Rui; Fieramosca, Antonio; Zhang, Qing
- Nature Materials, Vol. 20, Issue 10
Strong Exciton–Plasmon Coupling in MoS 2 Coupled with Plasmonic Lattice
journal, January 2016
- Liu, Wenjing; Lee, Bumsu; Naylor, Carl H.
- Nano Letters, Vol. 16, Issue 2
Ultrafast Dynamics of Lattice Plasmon Lasers
journal, May 2019
- Wang, Weijia; Watkins, Nicolas; Yang, Ankun
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 12
Hetero-oligomer Nanoparticle Arrays for Plasmon-Enhanced Hydrogen Sensing
journal, July 2014
- Yang, Ankun; Huntington, Mark D.; Cardinal, M. Fernanda
- ACS Nano, Vol. 8, Issue 8
Impact of microstructure on local carrier lifetime in perovskite solar cells
journal, April 2015
- de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D.
- Science, Vol. 348, Issue 6235
Strongly Coupled Hybrid States: Dynamics of Strongly Coupled Hybrid States by Transient Absorption Spectroscopy (Adv. Funct. Mater. 48/2018)
journal, October 2018
- Wang, Hai; Wang, Hai‐Yu; Sun, Hong‐Bo
- Advanced Functional Materials, Vol. 28, Issue 48
Scaling law for excitons in 2D perovskite quantum wells
journal, June 2018
- Blancon, J. -C.; Stier, A. V.; Tsai, H.
- Nature Communications, Vol. 9, Issue 1
Programmable and reversible plasmon mode engineering
journal, November 2016
- Yang, Ankun; Hryn, Alexander J.; Bourgeois, Marc R.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 50
Relaxation bottleneck and its suppression in semiconductor microcavities
journal, July 2000
- Tartakovskii, A. I.; Emam-Ismail, M.; Stevenson, R. M.
- Physical Review B, Vol. 62, Issue 4
Perovskite energy funnels for efficient light-emitting diodes
journal, June 2016
- Yuan, Mingjian; Quan, Li Na; Comin, Riccardo
- Nature Nanotechnology, Vol. 11, Issue 10
The role of Rabi splitting tuning in the dynamics of strongly coupled J-aggregates and surface plasmon polaritons in nanohole arrays
journal, January 2016
- Wang, Hai; Toma, Andrea; Wang, Hai-Yu
- Nanoscale, Vol. 8, Issue 27
Bottleneck effects in the relaxation and photoluminescence of microcavity polaritons
journal, September 1997
- Tassone, F.; Piermarocchi, C.; Savona, V.
- Physical Review B, Vol. 56, Issue 12
Programmable Soft Lithography: Solvent-Assisted Nanoscale Embossing
journal, February 2011
- Lee, Min Hyung; Huntington, Mark D.; Zhou, Wei
- Nano Letters, Vol. 11, Issue 2
Perovskite—Cavity Complex: the Modulated Optical Characteristics of Organometallic Halide Perovskite CH 3 NH 3 PbI x Cl 3– x Doped in Length Tunable Optical Microcavities
journal, June 2016
- Zhang, Zhen-Yu; Wang, Hai-Yu; Li, Kai-Jiao
- The Journal of Physical Chemistry C, Vol. 120, Issue 24
Stretchable Nanolasing from Hybrid Quadrupole Plasmons
journal, June 2018
- Wang, Danqing; Bourgeois, Marc R.; Lee, Won-Kyu
- Nano Letters, Vol. 18, Issue 7
Dispersion Anisotropy of Plasmon–Exciton–Polaritons in Lattices of Metallic Nanoparticles
journal, November 2017
- Ramezani, Mohammad; Halpin, Alexei; Feist, Johannes
- ACS Photonics, Vol. 5, Issue 1
Room Temperature Weak-to-Strong Coupling and the Emergence of Collective Emission from Quantum Dots Coupled to Plasmonic Arrays
journal, May 2020
- Yadav, Ravindra Kumar; Bourgeois, Marc R.; Cherqui, Charles
- ACS Nano, Vol. 14, Issue 6
Sub-picosecond thermalization dynamics in condensation of strongly coupled lattice plasmons
journal, June 2020
- Väkeväinen, Aaro I.; Moilanen, Antti J.; Nečada, Marek
- Nature Communications, Vol. 11, Issue 1
Light–matter interactions with photonic quasiparticles
journal, September 2020
- Rivera, Nicholas; Kaminer, Ido
- Nature Reviews Physics, Vol. 2, Issue 10
Surface lattice resonances strongly coupled to Rhodamine 6G excitons: tuning the plasmon-exciton-polariton mass and composition
journal, January 2013
- Rodriguez, S. R. K.; Rivas, J. Gómez
- Optics Express, Vol. 21, Issue 22
Quantum Control of Ultrafast Internal Conversion Using Nanoconfined Virtual Photons
journal, January 2020
- Avramenko, Aleksandr G.; Rury, Aaron S.
- The Journal of Physical Chemistry Letters, Vol. 11, Issue 3
Correction: Polariton chemistry: controlling molecular dynamics with optical cavities
journal, January 2019
- Ribeiro, Raphael F.; Martínez-Martínez, Luis A.; Du, Matthew
- Chemical Science, Vol. 10, Issue 46
Strong light-matter coupling in quantum chemistry and quantum photonics
journal, September 2018
- Flick, Johannes; Rivera, Nicholas; Narang, Prineha
- Nanophotonics, Vol. 7, Issue 9
Accelerated Carrier Relaxation through Reduced Coulomb Screening in Two-Dimensional Halide Perovskite Nanoplatelets
journal, September 2018
- Hintermayr, Verena A.; Polavarapu, Lakshminarayana; Urban, Alexander S.
- ACS Nano, Vol. 12, Issue 10
Limits to Strong Coupling of Excitons in Multilayer WS 2 with Collective Plasmonic Resonances
journal, February 2019
- Wang, Shaojun; Le-Van, Quynh; Vaianella, Fabio
- ACS Photonics, Vol. 6, Issue 2
Mesoscale Metallic Pyramids with Nanoscale Tips
journal, July 2005
- Henzie, Joel; Kwak, Eun-Soo; Odom, Teri W.
- Nano Letters, Vol. 5, Issue 7