Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks

Abstract

Robust and versatile metal–organic frameworks (MOFs) have emerged as sophisticated scaffolds to meet the critical needs of the nuclear community, but their performance depends on their underexplored structural integrities in high- radiation fields. The contributions of selected metal nodes in the radiation stability of MOFs within the isostructural M-UiO-66 series (where M = Zr, Ce, Hf, Th, and Pu; Zr-UiO-66 experiments were executed in a previous work) have been determined. Ce-, Hf-, and Th-UiO-66 MOF samples were irradiated via gamma and He-ion methodologies to obtain doses up to 3 MGy and 85 MGy, respectively, the latter strikingly higher than that obtained in most other studies. Appreciable self-irradiation constituted the total absorbed doses, up to 31 MGy of the gamma-irradiated Pu-UiO-66 samples. Structural degradation was ascertained by powder X-ray diffraction, X-ray total scattering, vibrational spectroscopy, and, where possible, N2 physisorption isotherms. Diffuse reflectance infrared Fourier transform spectroscopy provided atomic-level mechanistic insights to reveal that the node-linker connection was most susceptible to radiation damage. Density functional theory calculations were performed on cluster models to evaluate the binding energy of the linkers to each metal node. Here, while the isostructures disclosed the same breakdown signatures, distinct radiation sensitivity as a function of metalmore » selection was evident and followed the trend Hf-UiO-66 ~ Zr-UiO-66 > Th-UiO-66 > Pu-UiO-66 > Ce-UiO-66. We anticipate that these endeavors will contribute to the rational design of radiation-resistant materials for targeted applications.« less

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4];  [1];  [5];  [5]; ORCiD logo [3]; ORCiD logo [5]; ORCiD logo [1]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [1]
+ Show Author Affiliations
  1. Univ. of Notre Dame, IN (United States)
  2. Univ. of Notre Dame, IN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  3. Northwestern Univ., Evanston, IL (United States)
  4. Univ. of Chicago, IL (United States)
  5. Oregon State Univ., Corvallis, OR (United States)
Publication Date:
Research Org.:
University of Notre Dame, IN (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1886847
Grant/Contract Number:  
NA0003763
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 34; Journal Issue: 18; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Irradiation; Materials; Metal organic frameworks; Metals; Radiation

Citation Formats

Hastings, Ashley M., Fairley, Melissa, Wasson, Megan C., Campisi, Dario, Sarkar, Arup, Emory, Zoë C., Brunson, Kieran, Fast, Dylan B., Islamoglu, Timur, Nyman, May, Burns, Peter C., Gagliardi, Laura, Farha, Omar K., Hixon, Amy E., and LaVerne, Jay A. Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks. United States: N. p., 2022. Web. doi:10.1021/acs.chemmater.2c02170.
Copy to clipboard
Hastings, Ashley M., Fairley, Melissa, Wasson, Megan C., Campisi, Dario, Sarkar, Arup, Emory, Zoë C., Brunson, Kieran, Fast, Dylan B., Islamoglu, Timur, Nyman, May, Burns, Peter C., Gagliardi, Laura, Farha, Omar K., Hixon, Amy E., & LaVerne, Jay A. Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks. United States. https://doi.org/10.1021/acs.chemmater.2c02170
Copy to clipboard
Hastings, Ashley M., Fairley, Melissa, Wasson, Megan C., Campisi, Dario, Sarkar, Arup, Emory, Zoë C., Brunson, Kieran, Fast, Dylan B., Islamoglu, Timur, Nyman, May, Burns, Peter C., Gagliardi, Laura, Farha, Omar K., Hixon, Amy E., and LaVerne, Jay A. Fri . "Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks". United States. https://doi.org/10.1021/acs.chemmater.2c02170. https://www.osti.gov/servlets/purl/1886847.
Copy to clipboard
@article{osti_1886847,
title = {Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks},
author = {Hastings, Ashley M. and Fairley, Melissa and Wasson, Megan C. and Campisi, Dario and Sarkar, Arup and Emory, Zoë C. and Brunson, Kieran and Fast, Dylan B. and Islamoglu, Timur and Nyman, May and Burns, Peter C. and Gagliardi, Laura and Farha, Omar K. and Hixon, Amy E. and LaVerne, Jay A.},
abstractNote = {Robust and versatile metal–organic frameworks (MOFs) have emerged as sophisticated scaffolds to meet the critical needs of the nuclear community, but their performance depends on their underexplored structural integrities in high- radiation fields. The contributions of selected metal nodes in the radiation stability of MOFs within the isostructural M-UiO-66 series (where M = Zr, Ce, Hf, Th, and Pu; Zr-UiO-66 experiments were executed in a previous work) have been determined. Ce-, Hf-, and Th-UiO-66 MOF samples were irradiated via gamma and He-ion methodologies to obtain doses up to 3 MGy and 85 MGy, respectively, the latter strikingly higher than that obtained in most other studies. Appreciable self-irradiation constituted the total absorbed doses, up to 31 MGy of the gamma-irradiated Pu-UiO-66 samples. Structural degradation was ascertained by powder X-ray diffraction, X-ray total scattering, vibrational spectroscopy, and, where possible, N2 physisorption isotherms. Diffuse reflectance infrared Fourier transform spectroscopy provided atomic-level mechanistic insights to reveal that the node-linker connection was most susceptible to radiation damage. Density functional theory calculations were performed on cluster models to evaluate the binding energy of the linkers to each metal node. Here, while the isostructures disclosed the same breakdown signatures, distinct radiation sensitivity as a function of metal selection was evident and followed the trend Hf-UiO-66 ~ Zr-UiO-66 > Th-UiO-66 > Pu-UiO-66 > Ce-UiO-66. We anticipate that these endeavors will contribute to the rational design of radiation-resistant materials for targeted applications.},
doi = {10.1021/acs.chemmater.2c02170},
journal = {Chemistry of Materials},
number = 18,
volume = 34,
place = {United States},
year = {Fri Sep 09 00:00:00 EDT 2022},
month = {Fri Sep 09 00:00:00 EDT 2022}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.chemmater.2c02170
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Structural Features of Zirconium-Based Metal–Organic Frameworks Affecting Radiolytic Stability
journal, April 2020

  • Hanna, Sylvia L.; Rademacher, David X.; Hanson, Donald J.
  • Industrial & Engineering Chemistry Research, Vol. 59, Issue 16
  • DOI: 10.1021/acs.iecr.9b06820

Unusual Metal–Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry
journal, October 2021

  • Gilson, Sara E.; Fairley, Melissa; Hanna, Sylvia L.
  • Journal of the American Chemical Society, Vol. 143, Issue 42
  • DOI: 10.1021/jacs.1c08854

Highly efficient functionalized MOF-LIC-1 for extraction of U(vi) and Th(iv) from aqueous solution: experimental and theoretical studies
journal, January 2022

  • Venkata Sravani, V.; Sengupta, Somnath; Sreenivasulu, B.
  • Dalton Transactions, Vol. 51, Issue 9
  • DOI: 10.1039/D1DT03317D

Stability of Solid Uranyl Peroxides under Irradiation
journal, September 2019

Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)
journal, October 2015

  • Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V.
  • Pure and Applied Chemistry, Vol. 87, Issue 9-10
  • DOI: 10.1515/pac-2014-1117

Metal organic framework MIL-101 for radioiodine capture and storage
journal, September 2017

Structural Transitions of the Metal-Oxide Nodes within Metal–Organic Frameworks: On the Local Structures of NU-1000 and UiO-66
journal, March 2016

  • Platero-Prats, Ana E.; Mavrandonakis, Andreas; Gallington, Leighanne C.
  • Journal of the American Chemical Society, Vol. 138, Issue 12
  • DOI: 10.1021/jacs.6b00069

Cerium(IV) vs Zirconium(IV) Based Metal–Organic Frameworks for Detoxification of a Nerve Agent
journal, March 2017

H 2 Production in the Radiolysis of Water on CeO 2 and ZrO 2
journal, January 2002

  • LaVerne, Jay A.; Tandon, Lav
  • The Journal of Physical Chemistry B, Vol. 106, Issue 2
  • DOI: 10.1021/jp013098s

Multifunctional Two-Dimensional Metal–Organic Frameworks for Radionuclide Sequestration and Detection
journal, September 2021

  • Surbella, Robert G.; Reilly, Dallas D.; Sinnwell, Michael A.
  • ACS Applied Materials & Interfaces, Vol. 13, Issue 38
  • DOI: 10.1021/acsami.1c11018

Identifying the Recognition Site for Selective Trapping of 99 TcO 4 – in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework
journal, October 2017

  • Zhu, Lin; Sheng, Daopeng; Xu, Chao
  • Journal of the American Chemical Society, Vol. 139, Issue 42
  • DOI: 10.1021/jacs.7b08632

Modulation of crystal growth and structure within cerium-based metal–organic frameworks
journal, January 2020

  • Wasson, Megan C.; Otake, Ken-ichi; Gong, Xinyi
  • CrystEngComm, Vol. 22, Issue 47
  • DOI: 10.1039/D0CE01223H

Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake
journal, May 2013

  • Xue, Dong-Xu; Cairns, Amy J.; Belmabkhout, Youssef
  • Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7660-7667
  • DOI: 10.1021/ja401429x

Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution
journal, November 2020

  • Li, Zi‐Jian; Ju, Yu; Lu, Huangjie
  • Chemistry – A European Journal, Vol. 27, Issue 4
  • DOI: 10.1002/chem.202003621

I2 and CH3I capture in a γ-radiation stable metal-organic framework: CAU-21-ODB
journal, August 2022

Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66
journal, September 2012

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66
journal, April 2020

  • Hastings, Ashley M.; Ray, Debmalya; Jeong, WooSeok
  • Journal of the American Chemical Society, Vol. 142, Issue 20
  • DOI: 10.1021/jacs.0c01895

Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory
journal, April 2011

  • Valenzano, Loredana; Civalleri, Bartolomeo; Chavan, Sachin
  • Chemistry of Materials, Vol. 23, Issue 7, p. 1700-1718
  • DOI: 10.1021/cm1022882

PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013

Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks
journal, January 2021

  • Martin, Corey R.; Leith, Gabrielle A.; Shustova, Natalia B.
  • Chemical Science, Vol. 12, Issue 21
  • DOI: 10.1039/D1SC01827B

Tetravalent Ce in the Nitrate-Decorated Hexanuclear Cluster [Ce 6 (μ 3 -O) 4 (μ 3 -OH) 4 ] 12+ : A Structural End Point for Ceria Nanoparticles
journal, January 2016

  • Estes, Shanna L.; Antonio, Mark R.; Soderholm, L.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 10
  • DOI: 10.1021/acs.jpcc.6b00644

Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np 6 O 8 } hexanuclear clusters
journal, January 2018

  • Martin, N. P.; März, J.; Feuchter, H.
  • Chemical Communications, Vol. 54, Issue 51
  • DOI: 10.1039/C8CC03121E

Robust and Radiation-Resistant Hofmann-Type Metal–Organic Frameworks for Record Xenon/Krypton Separation
journal, February 2022

  • Pei, Jiyan; Gu, Xiao-Wen; Liang, Cong-Cong
  • Journal of the American Chemical Society, Vol. 144, Issue 7
  • DOI: 10.1021/jacs.1c12873

Radioluminescence and radiation effects in metal organic framework materials
conference, September 2007

  • Doty, F. P.; Bauer, C. A.; Grant, P. G.
  • Optical Engineering + Applications, SPIE Proceedings
  • DOI: 10.1117/12.740829

Adsorptive separation of xenon/krypton mixtures using a zirconium-based metal-organic framework with high hydrothermal and radioactive stabilities
journal, December 2016

Synergistic Assembly of Heavy Metal Clusters and Luminescent Organic Bridging Ligands in Metal–Organic Frameworks for Highly Efficient X-ray Scintillation
journal, April 2014

  • Wang, Cheng; Volotskova, Olga; Lu, Kuangda
  • Journal of the American Chemical Society, Vol. 136, Issue 17
  • DOI: 10.1021/ja500671h

Sulfate-Rich Metal–Organic Framework for High Efficiency and Selective Removal of Barium from Nuclear Wastewater
journal, November 2017

  • Kang, Chufan; Peng, Yaguang; Tang, Yuanzhe
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 46
  • DOI: 10.1021/acs.iecr.7b02887

X-ray radiation-induced amorphization of metal–organic frameworks
journal, January 2019

  • Widmer, Remo N.; Lampronti, Giulio I.; Casati, Nicola
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 23
  • DOI: 10.1039/C9CP01463B

Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity
journal, January 2015

  • Lammert, Martin; Wharmby, Michael T.; Smolders, Simon
  • Chemical Communications, Vol. 51, Issue 63
  • DOI: 10.1039/C5CC02606G

Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework
journal, May 2017

  • Xie, Jian; Wang, Yaxing; Liu, Wei
  • Angewandte Chemie International Edition, Vol. 56, Issue 26
  • DOI: 10.1002/anie.201700919

Plurality of radiation-chemical steady states during the radiolysis of water coolant in nuclear reactor
journal, March 2016

Irradiation and isolation of fission products from uranium metal–organic frameworks
journal, March 2019

  • Dorhout, Jacquelyn M.; Wilkerson, Marianne P.; Czerwinski, Kenneth R.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 320, Issue 2
  • DOI: 10.1007/s10967-019-06478-w

SRIM – The stopping and range of ions in matter (2010)
journal, June 2010

  • Ziegler, James F.; Ziegler, M. D.; Biersack, J. P.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12
  • DOI: 10.1016/j.nimb.2010.02.091

Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook
journal, January 2017

  • Xiao, Chengliang; Silver, Mark A.; Wang, Shuao
  • Dalton Transactions, Vol. 46, Issue 47
  • DOI: 10.1039/C7DT03670A

Valence basis sets for relativistic energy-consistent small-core lanthanide pseudopotentials
journal, October 2001

  • Cao, Xiaoyan; Dolg, Michael
  • The Journal of Chemical Physics, Vol. 115, Issue 16
  • DOI: 10.1063/1.1406535

How does basis set superposition error change the potential surfaces for hydrogen‐bonded dimers?
journal, December 1996

  • Simon, Sílvia; Duran, Miquel; Dannenberg, J. J.
  • The Journal of Chemical Physics, Vol. 105, Issue 24
  • DOI: 10.1063/1.472902

Defect engineering in metal–organic frameworks: a new strategy to develop applicable actinide sorbents
journal, January 2018

  • Yuan, Liyong; Tian, Ming; Lan, Jianhui
  • Chemical Communications, Vol. 54, Issue 4
  • DOI: 10.1039/C7CC07527H

Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF
journal, October 2018

  • Andreo, Jacopo; Priola, Emanuele; Alberto, Gabriele
  • Journal of the American Chemical Society, Vol. 140, Issue 43
  • DOI: 10.1021/jacs.8b07113

Accurate Coulomb-fitting basis sets for H to Rn
journal, January 2006

  • Weigend, Florian
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 9
  • DOI: 10.1039/b515623h

Methyl functionalized Zr-Fum MOF with enhanced Xenon adsorption and separation
journal, May 2020

Scintillating Metal-Organic Frameworks: A New Class of Radiation Detection Materials
journal, January 2009

  • Doty, F. P.; Bauer, C. A.; Skulan, A. J.
  • Advanced Materials, Vol. 21, Issue 1, p. 95-101
  • DOI: 10.1002/adma.200801753

Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium
journal, June 1998

  • Weber, W. J.; Ewing, R. C.; Catlow, C. R. A.
  • Journal of Materials Research, Vol. 13, Issue 6
  • DOI: 10.1557/JMR.1998.0205

Thermochemical electronegativities of the elements
journal, April 2021

Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework
journal, July 2020

  • Gilson, Sara E.; Fairley, Melissa; Julien, Patrick
  • Journal of the American Chemical Society, Vol. 142, Issue 31
  • DOI: 10.1021/jacs.0c05272

Radiation-resistant metal-organic framework enables efficient separation of krypton fission gas from spent nuclear fuel
journal, June 2020

Tunable Rare Earth fcu -MOF Platform: Access to Adsorption Kinetics Driven Gas/Vapor Separations via Pore Size Contraction
journal, April 2015

  • Xue, Dong-Xu; Belmabkhout, Youssef; Shekhah, Osama
  • Journal of the American Chemical Society, Vol. 137, Issue 15
  • DOI: 10.1021/ja5131403

Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption
journal, March 2020

Isolating the Role of the Node-Linker Bond in the Compression of UiO-66 Metal–Organic Frameworks
journal, June 2020

Radiation chemical studies with heavy ions: oxidation of ferrous ion in the Fricke dosimeter
journal, October 1987

  • LaVerne, Jay A.; Schuler, Robert H.
  • The Journal of Physical Chemistry, Vol. 91, Issue 22
  • DOI: 10.1021/j100306a050

Water-Stable Metal–Organic Framework Material with Uncoordinated Terpyridine Site for Selective Th(IV)/Ln(III) Separation
journal, December 2018

H 2 Production in the Radiolysis of Water on UO 2 and Other Oxides
journal, December 2003

  • LaVerne, Jay A.; Tandon, Lav
  • The Journal of Physical Chemistry B, Vol. 107, Issue 49
  • DOI: 10.1021/jp035381s

Radiation-Induced Chemical Changes to Iron Oxides
journal, December 2014

  • Reiff, Sarah C.; LaVerne, Jay A.
  • The Journal of Physical Chemistry B, Vol. 119, Issue 24
  • DOI: 10.1021/jp510943j

Electronegativity values from thermochemical data
journal, June 1961

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
journal, November 2006

  • Zhao, Yan; Truhlar, Donald G.
  • The Journal of Chemical Physics, Vol. 125, Issue 19, Article No. 194101
  • DOI: 10.1063/1.2370993

Phonon confinement effects in the Raman scattering by TiO2 nanocrystals
journal, January 1998

  • Bersani, D.; Lottici, P. P.; Ding, Xing-Zhao
  • Applied Physics Letters, Vol. 72, Issue 1
  • DOI: 10.1063/1.120648

Raman spectroscopy: A tool to investigate alpha decay damage in a PuO 2 crystal lattice and determining sample age since calcination
journal, March 2019

  • Villa‐Aleman, Eliel; Houk, Amanda L.; Bridges, Nicholas J.
  • Journal of Raman Spectroscopy, Vol. 50, Issue 6
  • DOI: 10.1002/jrs.5591

Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H 2 O System
journal, February 2015

  • Falaise, Clément; Charles, Jean-Sébastien; Volkringer, Christophe
  • Inorganic Chemistry, Vol. 54, Issue 5
  • DOI: 10.1021/ic502725y

Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework
journal, January 2020

  • Knapp, Julia G.; Zhang, Xuan; Elkin, Tatyana
  • CrystEngComm, Vol. 22, Issue 11
  • DOI: 10.1039/C9CE02034A

Chemical, thermal and mechanical stabilities of metal–organic frameworks
journal, February 2016

Linker Contribution toward Stability of Metal–Organic Frameworks under Ionizing Radiation
journal, November 2021

A β-ray irradiation resistant MOF-based trap for efficient capture of Th(IV) ion
journal, September 2022

Radiation-modified natural zeolites for cleaning liquid nuclear waste (irradiation against radioactivity)
journal, October 2013

  • Yeritsyan, Hrant; Sahakyan, Aram; Harutyunyan, Vachagan
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02900

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Three-Dimensional MOF-Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U 6 O 8 )
journal, January 2013

  • Falaise, Clément; Volkringer, Christophe; Vigier, Jean-François
  • Chemistry - A European Journal, Vol. 19, Issue 17
  • DOI: 10.1002/chem.201203914

Kinetics of solid phase crystallization of amorphous silicon analyzed by Raman spectroscopy
journal, August 2013

  • Hong, Won-Eui; Ro, Jae-Sang
  • Journal of Applied Physics, Vol. 114, Issue 7
  • DOI: 10.1063/1.4818949

Rare-earth metal–organic frameworks: from structure to applications
journal, January 2020

  • Saraci, Felix; Quezada-Novoa, Victor; Donnarumma, P. Rafael
  • Chemical Society Reviews, Vol. 49, Issue 22
  • DOI: 10.1039/D0CS00292E

Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66
journal, July 2014

  • Shearer, Greig C.; Chavan, Sachin; Ethiraj, Jayashree
  • Chemistry of Materials, Vol. 26, Issue 14
  • DOI: 10.1021/cm501859p

Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions
journal, May 2015

  • Wang, Yanlong; Liu, Zhiyong; Li, Yuxiang
  • Journal of the American Chemical Society, Vol. 137, Issue 19
  • DOI: 10.1021/jacs.5b02480

Pore Size Reduction by Methyl Function in Aluminum-Based Metal–Organic Frameworks for Xenon/Krypton Separation
journal, November 2020

  • Yan, Zhaotong; Gong, Youjin; Yang, Chu-Ting
  • Crystal Growth & Design, Vol. 20, Issue 12
  • DOI: 10.1021/acs.cgd.0c01283

Effects of High Gamma Doses on the Structural Stability of Metal–Organic Frameworks
journal, July 2022

An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements
journal, November 2019

  • Ridenour, J. August; Surbella, Robert G.; Gelis, Artem V.
  • Angewandte Chemie International Edition, Vol. 58, Issue 46
  • DOI: 10.1002/anie.201909988

“Boarding-Up”: Radiation Damage and Radionuclide Leaching Kinetics in Linker-Capped Metal–Organic Frameworks
journal, July 2019

Unravelling the Redox-catalytic Behavior of Ce 4+ Metal-Organic Frameworks by X-ray Absorption Spectroscopy
journal, November 2017

  • Smolders, Simon; Lomachenko, Kirill A.; Bueken, Bart
  • ChemPhysChem, Vol. 19, Issue 4
  • DOI: 10.1002/cphc.201700967

Detailed Structure Analysis of Atomic Positions and Defects in Zirconium Metal–Organic Frameworks
journal, October 2014

  • Øien, Sigurd; Wragg, David; Reinsch, Helge
  • Crystal Growth & Design, Vol. 14, Issue 11
  • DOI: 10.1021/cg501386j

The calculation of small molecular interactions by the differences of separate total energies. Some procedures with reduced errors
journal, October 1970

Electron and ion irradiation of zeolites
journal, April 2000

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Segmented contraction scheme for small-core lanthanide pseudopotential basis sets
journal, April 2002

Stability of metal–organic frameworks under gamma irradiation
journal, January 2016

  • Volkringer, C.; Falaise, C.; Devaux, P.
  • Chemical Communications, Vol. 52, Issue 84
  • DOI: 10.1039/C6CC06878B

Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks
journal, January 2022

  • Wasson, Megan C.; Xie, Haomiao; Wang, Xingjie
  • CrystEngComm, Vol. 24, Issue 28
  • DOI: 10.1039/D2CE00650B

Vibrational Spectroscopic Characterization of Hematite, Maghemite, and Magnetite Thin Films Produced by Vapor Deposition
journal, September 2010

  • Jubb, Aaron M.; Allen, Heather C.
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 10
  • DOI: 10.1021/am1004943

Iodine Confinement into Metal–Organic Frameworks (MOFs): Low-Temperature Sintering Glasses To Form Novel Glass Composite Material (GCM) Alternative Waste Forms
journal, May 2011

  • Sava, Dorina F.; Garino, Terry J.; Nenoff, Tina M.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 2
  • DOI: 10.1021/ie200248g

A Trivalent Americium Organic Framework with Decent Structural Stability against Self‐Irradiation
journal, January 2022

  • Zhang, Yugang; Li, Kai; Zhang, Sida
  • Chinese Journal of Chemistry, Vol. 40, Issue 7
  • DOI: 10.1002/cjoc.202100724

Modeling the critical hydrogen concentration in the AECL test reactor
journal, January 2013

    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: