Current status and future directions of multivalent metal-ion batteries
Abstract
Batteries based on multivalent metals have the potential to meet the future needs of large-scale energy storage, due to the relatively high abundance of elements such as magnesium, calcium, aluminium and zinc in the Earth’s crust. However, the com- plexity of multivalent metal-ion chemistries has led to rampant confusions, technical challenges, and eventually doubts and uncertainties about the future of these technologies. In this Review, we clarify the key strengths as well as common misconceptions of multivalent metal-based batteries. We then examine the growth behaviour of metal anodes, which is crucial for their safety promises but hitherto unestablished. We further discuss scrutiny of anode efficiency and cathode storage mechanism pertaining to complications arising from electrolyte solutions. Lastly, we critically review existing cathode materials and discuss design strategies to enable genuine multivalent metal-ion-based energy storage materials with competitive performance.
- Authors:
-
- Univ. of Houston, TX (United States)
- Bar-Ilan Univ., Ramat-Gan (Israel)
- Publication Date:
- Research Org.:
- Univ. of Houston, TX (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office. Batteries for Advanced Transportation Technologies (BATT) Program
- OSTI Identifier:
- 1856674
- Grant/Contract Number:
- EE0008234
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Energy
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 9; Journal ID: ISSN 2058-7546
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Batteries; Electrochemistry; Energy storage
Citation Formats
Liang, Yanliang, Dong, Hui, Aurbach, Doron, and Yao, Yan. Current status and future directions of multivalent metal-ion batteries. United States: N. p., 2020.
Web. doi:10.1038/s41560-020-0655-0.
Liang, Yanliang, Dong, Hui, Aurbach, Doron, & Yao, Yan. Current status and future directions of multivalent metal-ion batteries. United States. https://doi.org/10.1038/s41560-020-0655-0
Liang, Yanliang, Dong, Hui, Aurbach, Doron, and Yao, Yan. Thu .
"Current status and future directions of multivalent metal-ion batteries". United States. https://doi.org/10.1038/s41560-020-0655-0. https://www.osti.gov/servlets/purl/1856674.
@article{osti_1856674,
title = {Current status and future directions of multivalent metal-ion batteries},
author = {Liang, Yanliang and Dong, Hui and Aurbach, Doron and Yao, Yan},
abstractNote = {Batteries based on multivalent metals have the potential to meet the future needs of large-scale energy storage, due to the relatively high abundance of elements such as magnesium, calcium, aluminium and zinc in the Earth’s crust. However, the com- plexity of multivalent metal-ion chemistries has led to rampant confusions, technical challenges, and eventually doubts and uncertainties about the future of these technologies. In this Review, we clarify the key strengths as well as common misconceptions of multivalent metal-based batteries. We then examine the growth behaviour of metal anodes, which is crucial for their safety promises but hitherto unestablished. We further discuss scrutiny of anode efficiency and cathode storage mechanism pertaining to complications arising from electrolyte solutions. Lastly, we critically review existing cathode materials and discuss design strategies to enable genuine multivalent metal-ion-based energy storage materials with competitive performance.},
doi = {10.1038/s41560-020-0655-0},
journal = {Nature Energy},
number = 9,
volume = 5,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}
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