A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries

Fan, Xiulin; Wang, Fei; Ji, Xiao; Wang, Ruixing; Gao, Tao; Hou, Singyuk; Chen, Ji; Deng, Tao; Li, Xiaogang; Chen, Long; Luo, Chao; Wang, Luning; Wang, Chunsheng

doi:10.1002/anie.201803703

Title: A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries

Abstract

Abstract Low‐cost multivalent battery chemistries (Mg ²⁺ , Al ³⁺ ) have been extensively investigated for large‐scale energy storage applications. However, their commercialization is plagued by the poor power density and cycle life of cathodes. A universal polyimides@CNT (PI@CNT) cathode is now presented that can reversibly store various cations with different valences (Li ⁺ , Mg ²⁺ , Al ³⁺ ) at an extremely fast rate. The ion‐coordination charge storage mechanism of PI@CNT is systemically investigated. Full cells using PI@CNT cathodes and corresponding metal anodes exhibit long cycle life (>10000 cycles), fast kinetics (>20 C), and wide operating temperature range (−40 to 50 °C), making the low‐cost industrial polyimides universal cathodes for different multivalent metal batteries. The stable ion‐coordinated mechanism opens a new foundation for the development of high‐energy and high‐power multivalent batteries.

Authors:

Fan, Xiulin ^[1]; Wang, Fei ^[2]; Ji, Xiao ^[1]; Wang, Ruixing ^[3]; Gao, Tao ^[1]; Hou, Singyuk ^[1]; Chen, Ji ^[1]; Deng, Tao ^[1]; Li, Xiaogang ^[1]; Chen, Long ^[1]; Luo, Chao ^[1]; Wang, Luning ^[3];

^[1]

Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20742 USA
Electrochemistry Branch Sensor and Electron Devices Directorate Power and Energy Division U.S. Army Research Laboratory Adelphi MD 20783 USA
Department of Chemistry and Biochemistry University of Maryland College Park MD 20742 USA

Publication Date:: Mon May 14 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1437068

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 24; Journal ID: ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Fan, Xiulin, Wang, Fei, Ji, Xiao, Wang, Ruixing, Gao, Tao, Hou, Singyuk, Chen, Ji, Deng, Tao, Li, Xiaogang, Chen, Long, Luo, Chao, Wang, Luning, and Wang, Chunsheng. A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries.  Germany: N. p., 2018. 
Web.  doi:10.1002/anie.201803703.

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                    Fan, Xiulin, Wang, Fei, Ji, Xiao, Wang, Ruixing, Gao, Tao, Hou, Singyuk, Chen, Ji, Deng, Tao, Li, Xiaogang, Chen, Long, Luo, Chao, Wang, Luning, & Wang, Chunsheng. A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries.  Germany.  https://doi.org/10.1002/anie.201803703

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                    Fan, Xiulin, Wang, Fei, Ji, Xiao, Wang, Ruixing, Gao, Tao, Hou, Singyuk, Chen, Ji, Deng, Tao, Li, Xiaogang, Chen, Long, Luo, Chao, Wang, Luning, and Wang, Chunsheng. Mon .  
"A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries".  Germany.  https://doi.org/10.1002/anie.201803703.

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@article{osti_1437068,

  title        = {A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries},

  author       = {Fan, Xiulin and Wang, Fei and Ji, Xiao and Wang, Ruixing and Gao, Tao and Hou, Singyuk and Chen, Ji and Deng, Tao and Li, Xiaogang and Chen, Long and Luo, Chao and Wang, Luning and Wang, Chunsheng},

  abstractNote = {Abstract Low‐cost multivalent battery chemistries (Mg 2+ , Al 3+ ) have been extensively investigated for large‐scale energy storage applications. However, their commercialization is plagued by the poor power density and cycle life of cathodes. A universal polyimides@CNT (PI@CNT) cathode is now presented that can reversibly store various cations with different valences (Li + , Mg 2+ , Al 3+ ) at an extremely fast rate. The ion‐coordination charge storage mechanism of PI@CNT is systemically investigated. Full cells using PI@CNT cathodes and corresponding metal anodes exhibit long cycle life (>10000 cycles), fast kinetics (>20 C), and wide operating temperature range (−40 to 50 °C), making the low‐cost industrial polyimides universal cathodes for different multivalent metal batteries. The stable ion‐coordinated mechanism opens a new foundation for the development of high‐energy and high‐power multivalent batteries.},

  doi          = {10.1002/anie.201803703},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 24,

  volume       = 57,

  place        = {Germany},

  year         = {Mon May 14 00:00:00 EDT 2018},

  month        = {Mon May 14 00:00:00 EDT 2018}

}

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Title: A Universal Organic Cathode for Ultrafast Lithium and Multivalent Metal Batteries

Abstract

Citation Formats

A Rechargeable Al/S Battery with an Ionic-Liquid Electrolyte journal, July 2016

Reversible Aluminum-Ion Intercalation in Prussian Blue Analogs and Demonstration of a High-Power Aluminum-Ion Asymmetric Capacitor journal, November 2014

An aqueous, polymer-based redox-flow battery using non-corrosive, safe and low-cost materials journal, October 2015

Die Geburt der Lithiumionen-Batterie journal, February 2012

Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges journal, February 2017

A high capacity thiospinel cathode for Mg batteries journal, January 2016

High-Voltage Aqueous Magnesium Ion Batteries journal, September 2017

Layered TiS 2 Positive Electrode for Mg Batteries journal, June 2016

On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials † journal, February 2010

An ultrafast rechargeable aluminium-ion battery journal, April 2015

Polyimides: Promising Energy-Storage Materials journal, September 2010

Reversible Electrochemical Intercalation of Aluminum in Mo 6 S 8 journal, July 2015

Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life journal, January 2016

TiS2 nanotubes as the cathode materials of Mg-ion batteries journal, January 2004

Calcium-based multi-element chemistry for grid-scale electrochemical energy storage journal, March 2016

Enhancing the Reversibility of Mg/S Battery Chemistry through Li + Mediation journal, September 2015

Sustainability and in situ monitoring in battery development journal, December 2016

Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x journal, December 2016

Prototype systems for rechargeable magnesium batteries journal, October 2000

Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors journal, January 2010

Electrospun V 2 MoO 8 as a cathode material for rechargeable batteries with Mg metal anode journal, April 2017

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal, January 2013

Aqueous Mg-Ion Battery Based on Polyimide Anode and Prussian Blue Cathode journal, April 2017

Achieving High Aqueous Energy Storage via Hydrogen-Generation Passivation journal, July 2016

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A Rechargeable Al/S Battery with an Ionic-Liquid Electrolyte journal, July 2016

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The Birth of the Lithium-Ion Battery journal, February 2012

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Phase Stability of Post-spinel Compound AMn 2 O 4 (A = Li, Na, or Mg) and Its Application as a Rechargeable Battery Cathode journal, July 2013

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The rechargeable aluminum-ion battery journal, January 2011

Research Development on Sodium-Ion Batteries journal, October 2014

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Reversible Aluminum-Ion Intercalation in Prussian Blue Analogs and Demonstration of a High-Power Aluminum-Ion Asymmetric Capacitor
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An aqueous, polymer-based redox-flow battery using non-corrosive, safe and low-cost materials
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Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges
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High-Voltage Aqueous Magnesium Ion Batteries
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Sustainability and in situ monitoring in battery development
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Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x
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Prototype systems for rechargeable magnesium batteries
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Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors
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Electrospun V 2 MoO 8 as a cathode material for rechargeable batteries with Mg metal anode
journal, April 2017

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
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Aqueous Mg-Ion Battery Based on Polyimide Anode and Prussian Blue Cathode
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The Birth of the Lithium-Ion Battery
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