Neutron diffraction study of magnetism in van der Waals layered MnBi2nTe3n+1

Ding, Lei; Hu, Chaowei; Feng, Erxi; Jiang, Chenyang; Kibalin, Iurii A.; Gukasov, Arsen; Chi, MiaoFang; Ni, Ni; Cao, Huibo

doi:10.1088/1361-6463/abe0dd

Title: Neutron diffraction study of magnetism in van der Waals layered MnBi_2nTe_3n+1

Abstract

Two-dimensional van der Waals MnBi_2nTe_3n+1 (n = 1, 2, 3, 4) compounds have been recently found to be intrinsic magnetic topological insulators rendering quantum anomalous Hall effect and diverse topological states. Here, we summarize and compare the crystal and magnetic structures of this family, and discuss the effects of chemical composition on their magnetism. We found that a considerable fraction of Bi occupies at the Mn sites in MnBi_2nTe_3n+1 (n = 1, 2, 3, 4) while there is no detectable Mn at the non-magnetic atomic sites within the resolution of neutron diffraction experiments. The occupancy of Mn monotonically decreases with the increase of n. The polarized neutron diffraction on the representative MnBi₄Te₇ reveals that its magnetization density is exclusively accumulated at the Mn site, in good agreement with the results from the unpolarized neutron diffraction. The defects of Bi at the Mn site naturally explain the continuously reduced saturated magnetic moments from n = 1 to n = 4. The experimentally estimated critical exponents of all the compounds generally suggest a three-dimensional character of magnetism. Our work provides material-specified structural parameters that may be useful for band structure calculations to understand the observed topological surface states and for designing quantummore »« less

Authors:

^[1]; Hu, Chaowei ^[2]; Feng, Erxi ^[1];

^[1];

^[3]; Gukasov, Arsen ^[3];

^[4]; Ni, Ni ^[2];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division
Univ. of California, Los Angeles, CA (United States)
Centre National de la Recherche Scientifique (CNRS), Gif-sur-Yvette (France)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Publication Date:: Tue Feb 16 00:00:00 EST 2021

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1767852

Grant/Contract Number:: AC05-00OR22725; SC0011978

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physics. D, Applied Physics

Additional Journal Information:: Journal Volume: 54; Journal Issue: 17; Journal ID: ISSN 0022-3727

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Ding, Lei, Hu, Chaowei, Feng, Erxi, Jiang, Chenyang, Kibalin, Iurii A., Gukasov, Arsen, Chi, MiaoFang, Ni, Ni, and Cao, Huibo. Neutron diffraction study of magnetism in van der Waals layered MnBi2nTe3n+1.  United States: N. p., 2021. 
Web.  doi:10.1088/1361-6463/abe0dd.

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                    Ding, Lei, Hu, Chaowei, Feng, Erxi, Jiang, Chenyang, Kibalin, Iurii A., Gukasov, Arsen, Chi, MiaoFang, Ni, Ni, & Cao, Huibo. Neutron diffraction study of magnetism in van der Waals layered MnBi2nTe3n+1.  United States.  https://doi.org/10.1088/1361-6463/abe0dd

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                    Ding, Lei, Hu, Chaowei, Feng, Erxi, Jiang, Chenyang, Kibalin, Iurii A., Gukasov, Arsen, Chi, MiaoFang, Ni, Ni, and Cao, Huibo. Tue .  
"Neutron diffraction study of magnetism in van der Waals layered MnBi2nTe3n+1".  United States.  https://doi.org/10.1088/1361-6463/abe0dd.  https://www.osti.gov/servlets/purl/1767852.

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@article{osti_1767852,

  title        = {Neutron diffraction study of magnetism in van der Waals layered MnBi2nTe3n+1},

  author       = {Ding, Lei and Hu, Chaowei and Feng, Erxi and Jiang, Chenyang and Kibalin, Iurii A. and Gukasov, Arsen and Chi, MiaoFang and Ni, Ni and Cao, Huibo},

  abstractNote = {Two-dimensional van der Waals MnBi2nTe3n+1 (n = 1, 2, 3, 4) compounds have been recently found to be intrinsic magnetic topological insulators rendering quantum anomalous Hall effect and diverse topological states. Here, we summarize and compare the crystal and magnetic structures of this family, and discuss the effects of chemical composition on their magnetism. We found that a considerable fraction of Bi occupies at the Mn sites in MnBi2nTe3n+1 (n = 1, 2, 3, 4) while there is no detectable Mn at the non-magnetic atomic sites within the resolution of neutron diffraction experiments. The occupancy of Mn monotonically decreases with the increase of n. The polarized neutron diffraction on the representative MnBi4Te7 reveals that its magnetization density is exclusively accumulated at the Mn site, in good agreement with the results from the unpolarized neutron diffraction. The defects of Bi at the Mn site naturally explain the continuously reduced saturated magnetic moments from n = 1 to n = 4. The experimentally estimated critical exponents of all the compounds generally suggest a three-dimensional character of magnetism. Our work provides material-specified structural parameters that may be useful for band structure calculations to understand the observed topological surface states and for designing quantum magnetic materials through chemical doping.},

  doi          = {10.1088/1361-6463/abe0dd},

  journal      = {Journal of Physics. D, Applied Physics},

  number       = 17,

  volume       = 54,

  place        = {United States},

  year         = {Tue Feb 16 00:00:00 EST 2021},

  month        = {Tue Feb 16 00:00:00 EST 2021}

}

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Title: Neutron diffraction study of magnetism in van der Waals layered MnBi2nTe3n+1

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Magnetic structure of the quasi-two-dimensional antiferromagnet NiPS 3 journal, December 2015

Natural van der Waals heterostructural single crystals with both magnetic and topological properties journal, November 2019

Universal window for two-dimensional critical exponents journal, June 2008

Crystal structure and chemistry of topological insulators journal, January 2013

A van der Waals antiferromagnetic topological insulator with weak interlayer magnetic coupling journal, January 2020

Topological Materials: Quantum Anomalous Hall System journal, March 2018

Prediction and observation of an antiferromagnetic topological insulator journal, December 2019

Novel ternary layered manganese bismuth tellurides of the MnTe-Bi2Te3 system: Synthesis and crystal structure journal, June 2019

New insights on the microstructural characterisation of nickel hydroxides and correlation with electrochemical properties journal, January 2006

Title: Neutron diffraction study of magnetism in van der Waals layered MnBi_2nTe_3n+1

Gapless Surface Dirac Cone in Antiferromagnetic Topological Insulator ${MnBi}_{2} {Te}_{4}$
journal, November 2019

Realizing gapped surface states in the magnetic topological insulator $Mn {Bi}_{2 − x} {Sb}_{x} {Te}_{4}$
journal, September 2020

Dirac Surface States in Intrinsic Magnetic Topological Insulators EuSn 2 As 2 and MnBi 2 n Te 3 n + 1
journal, November 2019

Layered manganese bismuth tellurides with GeBi 4 Te 7 - and GeBi 6 Te 10 -type structures: towards multifunctional materials
journal, January 2019

Symmetry-Based Computational Tools for Magnetic Crystallography
journal, July 2015

Crystal Chemistry and Bonding Patterns of Bismuth-Based Topological Insulators
journal, February 2020

Quantized topological magnetoelectric effect of the zero-plateau quantum anomalous Hall state
journal, August 2015

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Crystal structure, properties and nanostructuring of a new layered chalcogenide semiconductor, Bi2MnTe4
journal, January 2013

Gapless Dirac surface states in the antiferromagnetic topological insulator ${MnBi}_{2} {Te}_{4}$
journal, April 2020

Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor
journal, May 2011

Spin scattering and noncollinear spin structure-induced intrinsic anomalous Hall effect in antiferromagnetic topological insulator $MnB i_{2} T e_{4}$
journal, August 2019

Competing Magnetic Interactions in the Antiferromagnetic Topological Insulator ${MnBi}_{2} {Te}_{4}$
journal, April 2020

The use of polarized neutrons in determining the magnetic scattering by iron and nickel
journal, July 1959

Topological Axion States in the Magnetic Insulator ${MnBi}_{2} {Te}_{4}$ with the Quantized Magnetoelectric Effect
journal, May 2019

Topological Electronic Structure and Its Temperature Evolution in Antiferromagnetic Topological Insulator MnBi 2 Te 4
journal, November 2019

Choreographed entanglement dances: Topological states of quantum matter
journal, February 2019

Tunable 3D/2D magnetism in the (MnBi2Te4)(Bi2Te3)m topological insulators family
journal, August 2020

Realization of an intrinsic ferromagnetic topological state in MnBi ₈ Te ₁₃
journal, July 2020

Intrinsic axion insulating behavior in antiferromagnetic ${MnBi}_{6} {Te}_{10}$
journal, July 2020

Intrinsic magnetic topological insulators in van der Waals layered MnBi ₂ Te ₄ -family materials
journal, June 2019

Universal gapless Dirac cone and tunable topological states in ${(MnB i_{2} T e_{4})}_{m} {(B i_{2} T e_{3})}_{n}$ heterostructures
journal, April 2020

Local magnetic anisotropy by polarized neutron powder diffraction: Application of magnetically induced preferred crystallite orientation
journal, November 2019

Low-temperature crystal and magnetic structure of $α - {RuCl}_{3}$
journal, April 2016

Massive Dirac Fermion on the Surface of a Magnetically Doped Topological Insulator
journal, August 2010

Surface states and Rashba-type spin polarization in antiferromagnetic MnBi 2 Te 4 (0001)
journal, September 2019

Monoclinic crystal structure of $α - {RuCl}_{3}$ and the zigzag antiferromagnetic ground state
journal, December 2015

Magnetic topological insulators
journal, January 2019

Coexistence of Surface Ferromagnetism and a Gapless Topological State in ${MnBi}_{2} {Te}_{4}$
journal, September 2020

Toward 2D Magnets in the (MnBi ₂ Te ₄ )(Bi ₂ Te ₃ ) _n Bulk Crystal
journal, April 2020

Spin density in ${YTiO}_{3}$ : I. Joint refinement of polarized neutron diffraction and magnetic x-ray diffraction data leading to insights into orbital ordering
journal, August 2017

Evolution of structural, magnetic, and transport properties in ${MnBi}_{2 - x} {Sb}_{x} {Te}_{4}$
journal, September 2019

Chemical Aspects of the Candidate Antiferromagnetic Topological Insulator MnBi ₂ Te ₄
journal, March 2019

Experimental Observation of the Quantum Anomalous Hall Effect in a Magnetic Topological Insulator
journal, March 2013

DEMAND, a Dimensional Extreme Magnetic Neutron Diffractometer at the High Flux Isotope Reactor
journal, December 2018

High-temperature quantum anomalous Hall regime in a MnBi2Te4/Bi2Te3 superlattice
journal, August 2020

Colloquium: Topological insulators
journal, November 2010

Stacking-dependent topological phase in bilayer $M B i_{2} T e_{4} (M = Ge, Sn, Pb)$
journal, March 2020

The physics of quantum materials
journal, October 2017

Crystal growth and magnetic structure of ${MnBi}_{2} {Te}_{4}$
journal, June 2019

Robust $A$ -Type Order and Spin-Flop Transition on the Surface of the Antiferromagnetic Topological Insulator ${MnBi}_{2} {Te}_{4}$
journal, July 2020

Critical phenomena and renormalization-group theory
journal, October 2002

Trajectory of the anomalous Hall effect towards the quantized state in a ferromagnetic topological insulator
journal, August 2014

Intrinsic magnetic topological insulator phases in the Sb doped MnBi2Te4 bulks and thin flakes
journal, October 2019

Antiferromagnetic topological insulators
journal, June 2010

Realization of interlayer ferromagnetic interaction in $MnS b_{2} T e_{4}$ toward the magnetic Weyl semimetal state
journal, November 2019

Topological Electronic Structure and Intrinsic Magnetization in ${MnBi}_{4} {Te}_{7}$ : A ${Bi}_{2} {Te}_{3}$ Derivative with a Periodic Mn Sublattice
journal, December 2019

X‐Ray Interference in Partially Ordered Layer Lattices
journal, March 1942

Crystal and magnetic structures of magnetic topological insulators ${MnBi}_{2} {Te}_{4}$ and ${MnBi}_{4} {Te}_{7}$
journal, January 2020

Magnetic structure of the quasi-two-dimensional antiferromagnet ${NiPS}_{3}$
journal, December 2015

Natural van der Waals heterostructural single crystals with both magnetic and topological properties
journal, November 2019

Universal window for two-dimensional critical exponents
journal, June 2008

Crystal structure and chemistry of topological insulators
journal, January 2013

A van der Waals antiferromagnetic topological insulator with weak interlayer magnetic coupling
journal, January 2020

Topological Materials: Quantum Anomalous Hall System
journal, March 2018

Prediction and observation of an antiferromagnetic topological insulator
journal, December 2019

Novel ternary layered manganese bismuth tellurides of the MnTe-Bi2Te3 system: Synthesis and crystal structure
journal, June 2019

New insights on the microstructural characterisation of nickel hydroxides and correlation with electrochemical properties
journal, January 2006