Crystal growth and magnetic structure of MnBi2Te4

Yan, Jiaqiang; Zhang, Qiang; Heitmann, Thomas; Huang, Zengle; Chen, K. Y.; Cheng, J. -G.; Wu, Weida; Vaknin, David; Sales, Brian C.; McQueeney, Robert John

doi:10.1103/PhysRevMaterials.3.064202

Title: Crystal growth and magnetic structure of ${MnBi}_{2} {Te}_{4}$

Journal Article · 06 June 2019 · Physical Review Materials

DOI: https://doi.org/10.1103/PhysRevMaterials.3.064202 · OSTI ID:1524865

^[1];

^[1]; Heitmann, Thomas ^[2]; Huang, Zengle ^[3]; Chen, K. Y. ^[4]; Cheng, J. -G. ^[5]; Wu, Weida ^[3]; Vaknin, David ^[6];

^[1]; McQueeney, Robert John ^[6]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Missouri, Columbia, MO (United States)
Rutgers Univ., Piscataway, NJ (United States)
Chinese Academy of Sciences (CAS), Beijing (China)
Chinese Academy of Sciences (CAS), Beijing (China); Songshan Lake Materials Lab., Guangdong (China)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Millimeter-sized ${MnBi}_{2} {Te}_{4}$ single crystals are grown out of a Bi-Te flux and characterized using magnetic, transport, scanning tunneling microscopy, and spectroscopy measurements. The magnetic structure of ${MnBi}_{2} {Te}_{4}$ below T_N is determined by powder and single-crystal neutron diffraction measurements. Below T_N = 24 K, Mn²⁺ moments order ferromagnetically in the ab plane but antiferromagnetically along the crystallographic c axis. The ordered moment is 4.04(13)μ_B/Mn at 10 K and aligned along the crystallographic c axis in an A-type antiferromagnetic order. Below T_N, the electrical resistivity drops upon cooling or when going across the metamagnetic transition in increasing magnetic fields. A critical scattering effect is observed in the vicinity of T_N in the temperature dependence of thermal conductivity, indicating strong spin-lattice coupling in this compound. Yet, no anomaly is observed in the temperature dependence of thermopower around T_N. Fine tuning of the magnetism and/or electronic band structure is needed for the proposed topological properties of this compound. The growth protocol reported here might be applied to grow high-quality crystals where the electronic band structure and magnetism can be finely tuned by chemical substitutions.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division

Grant/Contract Number:: AC02-07CH11358; AC05-00OR22725

OSTI ID:: 1524865

Journal Information:: Physical Review Materials, Journal Name: Physical Review Materials Journal Issue: 6 Vol. 3; ISSN PRMHAR; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (26)

Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Competing rhombohedral and monoclinic crystal structures in MnPn 2 Ch 4 compounds: An ab-initio study Eremeev, S. V.; Otrokov, M. M.; Chulkov, E. V. Journal of Alloys and Compounds, Vol. 709 https://doi.org/10.1016/j.jallcom.2017.03.121	journal	June 2017
Crystal structure, properties and nanostructuring of a new layered chalcogenide semiconductor, Bi2MnTe4 Lee, Dong Sun; Kim, Tae-Hoon; Park, Cheol-Hee CrystEngComm, Vol. 15, Issue 27 https://doi.org/10.1039/c3ce40643a	journal	January 2013
Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples Canfield, Paul C.; Kong, Tai; Kaluarachchi, Udhara S. Philosophical Magazine, Vol. 96, Issue 1 https://doi.org/10.1080/14786435.2015.1122248	journal	December 2015
The thermal conductivity of NiO and CoO at the Neel temperature Lewis, F. B.; Saunders, N. H. Journal of Physics C: Solid State Physics, Vol. 6, Issue 15 https://doi.org/10.1088/0022-3719/6/15/012	journal	August 1973
Highly-ordered wide bandgap materials for quantized anomalous Hall and magnetoelectric effects Otrokov, M. M.; Menshchikova, T. V.; Vergniory, M. G. 2D Materials, Vol. 4, Issue 2 https://doi.org/10.1088/2053-1583/aa6bec	journal	April 2017
Thermal Conductivity of Ca F 2 , Mn F 2 , Co F 2 , and Zn F 2 Crystals Slack, Glen A. Physical Review, Vol. 122, Issue 5 https://doi.org/10.1103/PhysRev.122.1451	journal	June 1961
Magnon heat transport in ( Sr , Ca , La ) 14 Cu 24 O 41 Hess, C.; Baumann, C.; Ammerahl, U. Physical Review B, Vol. 64, Issue 18 https://doi.org/10.1103/PhysRevB.64.184305	journal	October 2001
Thermal conductivity in the stripe-ordered phase of cuprates and nickelates Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B. Physical Review B, Vol. 68, Issue 10 https://doi.org/10.1103/PhysRevB.68.104520	journal	September 2003
Development of ferromagnetism in the doped topological insulator Bi 2 − x Mn x Te 3 Hor, Y. S.; Roushan, P.; Beidenkopf, H. Physical Review B, Vol. 81, Issue 19 https://doi.org/10.1103/PhysRevB.81.195203	journal	May 2010
Antiferromagnetic topological insulators Mong, Roger S. K.; Essin, Andrew M.; Moore, Joel E. Physical Review B, Vol. 81, Issue 24 https://doi.org/10.1103/PhysRevB.81.245209	journal	June 2010
Contamination from magnetic starting materials in flux-grown single crystals of R FeAsO superconductors Yan, J. -Q.; Xing, Q.; Jensen, B. Physical Review B, Vol. 84, Issue 1 https://doi.org/10.1103/PhysRevB.84.012501	journal	July 2011
Ferromagnetism and spin-dependent transport in n -type Mn-doped bismuth telluride thin films Lee, Joon Sue; Richardella, Anthony; Rench, David W. Physical Review B, Vol. 89, Issue 17 https://doi.org/10.1103/PhysRevB.89.174425	journal	May 2014
Thermal Conductivity of MnO and NiO Slack, G. A.; Newman, R. Physical Review Letters, Vol. 1, Issue 10 https://doi.org/10.1103/PhysRevLett.1.359	journal	November 1958
Toward the Intrinsic Limit of the Topological Insulator Bi 2 Se 3 Dai, Jixia; West, Damien; Wang, Xueyun Physical Review Letters, Vol. 117, Issue 10 https://doi.org/10.1103/PhysRevLett.117.106401	journal	August 2016
Topological Axion States in the Magnetic Insulator MnBi 2 Te 4 with the Quantized Magnetoelectric Effect Zhang, Dongqin; Shi, Minji; Zhu, Tongshuai Physical Review Letters, Vol. 122, Issue 20 https://doi.org/10.1103/PhysRevLett.122.206401	journal	May 2019
Bipolar Conduction as the Possible Origin of the Electronic Transition in Pentatellurides: Metallic vs Semiconducting Behavior Shahi, P.; Singh, D. J.; Sun, J. P. Physical Review X, Vol. 8, Issue 2 https://doi.org/10.1103/PhysRevX.8.021055	journal	May 2018
Theory of Thermal Conductivity of Solids at Low Temperatures Carruthers, Peter Reviews of Modern Physics, Vol. 33, Issue 1 https://doi.org/10.1103/RevModPhys.33.92	journal	January 1961
Magnetic symmetry in the Bilbao Crystallographic Server: a computer program to provide systematic absences of magnetic neutron diffraction Gallego, Samuel V.; Tasci, Emre S.; de la Flor, Gemma Journal of Applied Crystallography, Vol. 45, Issue 6 https://doi.org/10.1107/S0021889812042185	journal	November 2012
Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups Aroyo, Mois I.; Kirov, Asen; Capillas, Cesar Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 2 https://doi.org/10.1107/S0108767305040286	journal	March 2006
Experimental Observation of the Quantum Anomalous Hall Effect in a Magnetic Topological Insulator Chang, C. -Z.; Zhang, J.; Feng, X. Science, Vol. 340, Issue 6129 https://doi.org/10.1126/science.1234414	journal	March 2013
Thermal Conductivity of KMnF ₃ , KCoF ₃ , KNiF ₃ , and KZnF ₃ Single Crystals Suemune, Yasutaka; Ikawa, Hyō Journal of the Physical Society of Japan, Vol. 19, Issue 9 https://doi.org/10.1143/JPSJ.19.1686	journal	September 1964
Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples Canfield, Paul C.; Kong, Tai; Kaluarachchi, Udhara S. arXiv https://doi.org/10.48550/arxiv.1509.08131	text	January 2015
Experimental Observation of the Quantum Anomalous Hall Effect in a Magnetic Topological Insulator Chang, Cui-Zu; Zhang, Jinsong; Feng, Xiao arXiv https://doi.org/10.48550/arxiv.1605.08829	text	January 2016
Bipolar Conduction is the Origin of the Electronic Transition in Pentatellurides: Metallic vs. Semiconducting Behavior Shahi, P.; Singh, D. J.; Sun, J. P. arXiv https://doi.org/10.48550/arxiv.1611.06370	text	January 2016
Magnon Heat Transport in (Sr,La)_14Cu_24O_41 Hess, C.; Baumannn, C.; Ammerahl, U. arXiv https://doi.org/10.48550/arxiv.cond-mat/0105407	text	January 2001

Cited By (23)

The Material Efforts for Quantized Hall Devices Based on Topological Insulators Fei, Fucong; Zhang, Shuai; Zhang, Minhao Advanced Materials https://doi.org/10.1002/adma.201904593	journal	December 2019
A van der Waals antiferromagnetic topological insulator with weak interlayer magnetic coupling Hu, Chaowei; Gordon, Kyle N.; Liu, Pengfei Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13814-x	journal	January 2020
Seeing is believing: visualization of antiferromagnetic domains Cheong, Sang-Wook; Fiebig, Manfred; Wu, Weida npj Quantum Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41535-019-0204-x	journal	January 2020
Robust axion insulator and Chern insulator phases in a two-dimensional antiferromagnetic topological insulator Liu, Chang; Wang, Yongchao; Li, Hao Nature Materials https://doi.org/10.1038/s41563-019-0573-3	journal	January 2020
Prediction and observation of an antiferromagnetic topological insulator Otrokov, M. M.; Klimovskikh, I. I.; Bentmann, H. Nature, Vol. 576, Issue 7787 https://doi.org/10.1038/s41586-019-1840-9	journal	December 2019
Antiferromagnetic topological insulator MnBi ₂ Te ₄ : synthesis and magnetic properties Li, Hao; Liu, Shengsheng; Liu, Chang Physical Chemistry Chemical Physics, Vol. 22, Issue 2 https://doi.org/10.1039/c9cp05634c	journal	January 2020
Signatures of temperature driven antiferromagnetic transition in the electronic structure of topological insulator MnBi ₂ Te ₄ Estyunin, D. A.; Klimovskikh, I. I.; Shikin, A. M. APL Materials, Vol. 8, Issue 2 https://doi.org/10.1063/1.5142846	journal	February 2020
Evolution of structural, magnetic, and transport properties in MnBi 2 − x Sb x Te 4 Yan, J. -Q.; Okamoto, S.; McGuire, M. A. Physical Review B, Vol. 100, Issue 10 https://doi.org/10.1103/physrevb.100.104409	journal	September 2019
Magnetically controllable topological quantum phase transitions in the antiferromagnetic topological insulator MnBi 2 Te 4 Li, Jiaheng; Wang, Chong; Zhang, Zetao Physical Review B, Vol. 100, Issue 12 https://doi.org/10.1103/physrevb.100.121103	journal	September 2019
Surface states and Rashba-type spin polarization in antiferromagnetic MnBi 2 Te 4 (0001) Vidal, R. C.; Bentmann, H.; Peixoto, T. R. F. Physical Review B, Vol. 100, Issue 12 https://doi.org/10.1103/physrevb.100.121104	journal	September 2019
In-plane magnetic-field-induced quantum anomalous Hall plateau transition Zhang, Jinlong; Liu, Zhaochen; Wang, Jing Physical Review B, Vol. 100, Issue 16 https://doi.org/10.1103/physrevb.100.165117	journal	October 2019
Realization of interlayer ferromagnetic interaction in MnS b 2 T e 4 toward the magnetic Weyl semimetal state Murakami, Taito; Nambu, Yusuke; Koretsune, Takashi Physical Review B, Vol. 100, Issue 19 https://doi.org/10.1103/physrevb.100.195103	journal	November 2019
Crystal and magnetic structures of magnetic topological insulators MnBi 2 Te 4 and MnBi 4 Te 7 Ding, Lei; Hu, Chaowei; Ye, Feng Physical Review B, Vol. 101, Issue 2 https://doi.org/10.1103/physrevb.101.020412	journal	January 2020
Suppression of the antiferromagnetic metallic state in the pressurized MnB i 2 T e 4 single crystal Chen, K. Y.; Wang, B. S.; Yan, J. -Q. Physical Review Materials, Vol. 3, Issue 9 https://doi.org/10.1103/physrevmaterials.3.094201	journal	September 2019
Spin scattering and noncollinear spin structure-induced intrinsic anomalous Hall effect in antiferromagnetic topological insulator MnB i 2 T e 4 Lee, Seng Huat; Zhu, Yanglin; Wang, Yu Physical Review Research, Vol. 1, Issue 1 https://doi.org/10.1103/physrevresearch.1.012011	journal	August 2019
Gapless Surface Dirac Cone in Antiferromagnetic Topological Insulator MnBi 2 Te 4 Hao, Yu-Jie; Liu, Pengfei; Feng, Yue Physical Review X, Vol. 9, Issue 4 https://doi.org/10.1103/physrevx.9.041038	journal	November 2019
Dirac Surface States in Intrinsic Magnetic Topological Insulators EuSn 2 As 2 and MnBi 2 n Te 3 n + 1 Li, Hang; Gao, Shun-Ye; Duan, Shao-Feng Physical Review X, Vol. 9, Issue 4 https://doi.org/10.1103/physrevx.9.041039	journal	November 2019
Topological Electronic Structure and Its Temperature Evolution in Antiferromagnetic Topological Insulator MnBi 2 Te 4 Chen, Y. J.; Xu, L. X.; Li, J. H. Physical Review X, Vol. 9, Issue 4 https://doi.org/10.1103/physrevx.9.041040	journal	November 2019
Natural van der Waals heterostructural single crystals with both magnetic and topological properties Wu, Jiazhen; Liu, Fucai; Sasase, Masato Science Advances, Vol. 5, Issue 11 https://doi.org/10.1126/sciadv.aax9989	journal	November 2019
Surface states and Rashba-type spin polarization in antiferromagnetic $MnBi_{2}Te_{4}$ (0001) Vidal, R. C.; Bentmann, H.; Peixoto, T. R. F. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-03496	text	January 2019
Seeing is believing: visualization of antiferromagnetic domains Cheong, Sang-Wook; Fiebig, Manfred; Wu, Weida ETH Zurich https://doi.org/10.3929/ethz-b-000400220	text	January 2020
Natural van der Waals heterostructural single crystals with both magnetic and topological properties Wu, Jiazhen; Liu, Fucai; Sasase, Masato arXiv https://doi.org/10.48550/arxiv.1905.02385	text	January 2019
Antiferromagnetic Topological Insulator MnBi2Te4: Synthesis and Magnetic properties Li, Hao; Liu, Shengsheng; Liu, Chang arXiv https://doi.org/10.48550/arxiv.1907.13018	text	January 2019

Similar Records

Spin correlation in trigonal

{EuMn}_{2} {As}_{2}

Journal Article · 2019 · Physical Review B · OSTI ID:1594103

Dahal, A.; Chen, Yiyao; Heitmann, T.; +4 more

Antiferromagnetic stacking of ferromagnetic layers and doping-controlled phase competition in

{Ca}_{1 - x} {Sr}_{x} {Co}_{2 - y} {As}_{2}

Journal Article · 2019 · Physical Review B · OSTI ID:1542872

Li, Bing; Sizyuk, Y.; Sangeetha, N. S.; +9 more

Two-dimensional ordering and collective magnetic excitations in the dilute ferromagnetic topological insulator

{({Bi}_{0.95} {Mn}_{0.05})}_{2} {Te}_{3}

Journal Article · 2019 · Physical Review B · OSTI ID:1545207

Vaknin, David; Pajerowski, Daniel M.; Schlagel, Deborah L.; +2 more

Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: Crystal growth and magnetic structure of MnBi 2 Te 4

Citation Formats

References (26)

Cited By (23)

Similar Records

Related Subjects

Title: Crystal growth and magnetic structure of ${MnBi}_{2} {Te}_{4}$