DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A Techno-economic Analysis for Integrating an Electrochemical Reactor into a Lignocellulosic Biorefinery for Production of Industrial Chemicals and Hydrogen

Abstract

In this study, we present a techno-economic analysis for integrating an electrochemical reactor into a lignocellulosic biorefinery for the purpose of converting biorefinery lignin to higher-value industrial chemicals with co-generation of hydrogen. We consider how the electrochemical reactor impacts the manufacturing costs for producing biofuel and determine a break-even value for the lignin oxidation product stream, which is the minimum lignin conversion product stream value that renders the cost to produce biofuel the same as in the typical biorefinery concept. We conclude that at low extents of lignin conversion, the break-even product stream value is likely too high for the process to be feasible. However, at higher extents of lignin conversion, the break-even product stream value may be between 1.00 and 2.00/kg, depending on capital cost and other manufacturing costs like depreciation. Here the potential markets for the biomass conversion products include resin manufacturing, where the products would compete with petroleum-derived resin precursors.

Authors:
 [1];  [2];  [3];  [1];  [1]; ORCiD logo [1]
  1. Ohio Univ., Athens, OH (United States)
  2. Lakehead Univ., Thunder Bay, ON (Canada)
  3. Hexion Inc., Louisville, KY (United States)
Publication Date:
Research Org.:
Ohio Univ., Athens, OH (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office
OSTI Identifier:
1734537
Grant/Contract Number:  
EE0007105
Resource Type:
Accepted Manuscript
Journal Name:
Applied Biochemistry and Biotechnology
Additional Journal Information:
Journal Volume: 193; Journal Issue: 3; Journal ID: ISSN 0273-2289
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Lignin; Electrochemical; Conversion; Biorefinery; Economics

Citation Formats

NaderiNasrabadi, Mahtab, Rakshit, Sudip K., Viswanathan, Ganapathy, Chen, Zewei, Harrington, Peter B., and Staser, John A. A Techno-economic Analysis for Integrating an Electrochemical Reactor into a Lignocellulosic Biorefinery for Production of Industrial Chemicals and Hydrogen. United States: N. p., 2020. Web. doi:10.1007/s12010-020-03452-1.
NaderiNasrabadi, Mahtab, Rakshit, Sudip K., Viswanathan, Ganapathy, Chen, Zewei, Harrington, Peter B., & Staser, John A. A Techno-economic Analysis for Integrating an Electrochemical Reactor into a Lignocellulosic Biorefinery for Production of Industrial Chemicals and Hydrogen. United States. https://doi.org/10.1007/s12010-020-03452-1
NaderiNasrabadi, Mahtab, Rakshit, Sudip K., Viswanathan, Ganapathy, Chen, Zewei, Harrington, Peter B., and Staser, John A. Fri . "A Techno-economic Analysis for Integrating an Electrochemical Reactor into a Lignocellulosic Biorefinery for Production of Industrial Chemicals and Hydrogen". United States. https://doi.org/10.1007/s12010-020-03452-1. https://www.osti.gov/servlets/purl/1734537.
@article{osti_1734537,
title = {A Techno-economic Analysis for Integrating an Electrochemical Reactor into a Lignocellulosic Biorefinery for Production of Industrial Chemicals and Hydrogen},
author = {NaderiNasrabadi, Mahtab and Rakshit, Sudip K. and Viswanathan, Ganapathy and Chen, Zewei and Harrington, Peter B. and Staser, John A.},
abstractNote = {In this study, we present a techno-economic analysis for integrating an electrochemical reactor into a lignocellulosic biorefinery for the purpose of converting biorefinery lignin to higher-value industrial chemicals with co-generation of hydrogen. We consider how the electrochemical reactor impacts the manufacturing costs for producing biofuel and determine a break-even value for the lignin oxidation product stream, which is the minimum lignin conversion product stream value that renders the cost to produce biofuel the same as in the typical biorefinery concept. We conclude that at low extents of lignin conversion, the break-even product stream value is likely too high for the process to be feasible. However, at higher extents of lignin conversion, the break-even product stream value may be between 1.00 and 2.00/kg, depending on capital cost and other manufacturing costs like depreciation. Here the potential markets for the biomass conversion products include resin manufacturing, where the products would compete with petroleum-derived resin precursors.},
doi = {10.1007/s12010-020-03452-1},
journal = {Applied Biochemistry and Biotechnology},
number = 3,
volume = 193,
place = {United States},
year = {Fri Nov 13 00:00:00 EST 2020},
month = {Fri Nov 13 00:00:00 EST 2020}
}

Works referenced in this record:

Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014

  • Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
  • Science, Vol. 344, Issue 6185, p. 1246843-1246843
  • DOI: 10.1126/science.1246843

Oxidative pyrolysis of kraft lignin in a bubbling fluidized bed reactor with air
journal, May 2015


Comparison of some new pretreatment methods for second generation bioethanol production from wheat straw and water hyacinth
journal, March 2011


Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts
journal, April 2012


Hydrogen production from the gasification of lignin with nickel catalysts in supercritical water
journal, May 2007


Biomass conversion: attempted electrooxidation of lignin for vanillin production
journal, January 2000

  • Parpot, P.; Bettencourt, A. P.; Carvalho, A. M.
  • Journal of Applied Electrochemistry, Vol. 30, Issue 6, p. 727-731
  • DOI: 10.1023/A:1004003613883

Cellulosic biorefinery portfolio and diversification: Strategies to mitigate cellulosic biorefinery risks in US Corn Belt
journal, November 2016


Catalytic hydrodeoxygenation and hydrocracking of Alcell ® lignin in alcohol/formic acid mixtures using a Ru/C catalyst
journal, September 2015


Biomass-Depolarized Electrolysis
journal, January 2019

  • NaderiNasrabadi, Mahtab; Bateni, Fazel; Chen, Zewei
  • Journal of The Electrochemical Society, Vol. 166, Issue 10
  • DOI: 10.1149/2.1471910jes

Second generation biofuels and food crops: Co-products or competitors?
journal, July 2013


Catalysts of Ni/α-Al2O3 and Ni/La2O3-αAl2O3 for hydrogen production by steam reforming of bio-oil aqueous fraction with pyrolytic lignin retention
journal, February 2013


Electrochemical oxidation of lignin at IrO2-based oxide electrodes
journal, November 2010


Application of Generalized Standard Addition Method and Ultraviolet Spectroscopy to Quantify Electrolytic Depolymerization of Lignin
journal, January 2020

  • Chen, Zewei; NaderiNasrabadi, Mahtab; Staser, John A.
  • Journal of Analysis and Testing, Vol. 4, Issue 1
  • DOI: 10.1007/s41664-020-00119-y

Lignocellulosic biorefinery as a model for sustainable development of biofuels and value added products
journal, January 2018


Electrochemical oxidation of lignin by two typical electrodes: Ti/SbSnO2 and Ti/PbO2
journal, May 2014


Throughput, Reliability, and Yields of a Pilot-Scale Conversion Process for Production of Fermentable Sugars from Lignocellulosic Biomass: A Study on Feedstock Ash and Moisture
journal, January 2020

  • Sievers, David A.; Kuhn, Erik M.; Thompson, Vicki S.
  • ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 4
  • DOI: 10.1021/acssuschemeng.9b06550

Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates
journal, January 2012

  • Mettler, Matthew S.; Mushrif, Samir H.; Paulsen, Alex D.
  • Energy Environ. Sci., Vol. 5, Issue 1
  • DOI: 10.1039/C1EE02743C

Hydrothermal conversion of lignin compounds. A detailed study of fragmentation and condensation reaction pathways
journal, November 2012


Techno-economic analysis of an integrated biorefinery strategy based on one-pot biomass fractionation and furfural production
journal, July 2020


Supercritical water gasification of biomass for hydrogen production
journal, April 2014


Non-precious metal nanoparticle electrocatalysts for electrochemical modification of lignin for low-energy and cost-effective production of hydrogen
journal, April 2015


Review of Second-Generation Bioethanol Production from Residual Biomass
journal, January 2018


Biological valorization of natural gas for the production of lactic acid: Techno-economic analysis and life cycle assessment
journal, June 2020


Lignin-Augmented Water Electrolysis
journal, January 1992

  • Lalvani, S. B.
  • Journal of The Electrochemical Society, Vol. 139, Issue 1
  • DOI: 10.1149/1.2069212

Bioethanol from corn stover – a review and technical assessment of alternative biotechnologies
journal, July 2018

  • Zhao, Yan; Damgaard, Anders; Christensen, Thomas H.
  • Progress in Energy and Combustion Science, Vol. 67
  • DOI: 10.1016/j.pecs.2018.03.004