Iron-Doped Sodium Vanadium Oxyflurophosphate Cathodes for Sodium-Ion Batteries—Electrochemical Characterization and In Situ Measurements of Heat Generation
Abstract
Sodium-ion batteries (NaIBs) are increasingly being envisioned for grid-scale energy-storage systems because of cost advantages. However, implementation of this vision has been challenged by the low-energy densities delivered by most NaIB cathodes. Toward addressing this challenge, the authors report the synthesis and characterization of a new iron-doped Na3Fe0.3V1.7O(PO4)2F2 cathode using a novel facile hydrothermal route. The synthesized material was characterized using scanning electron microscopy, X-ray diffraction, and Mössbauer spectroscopy techniques. The obtained discharge capacity in the half-cell configuration lies from 119 to 125 to 130 mA h/g at C/10 while tested using three different electrolyte formulations, dimethyl carbonate–ethylene carbonate (EC)–propylene carbonate (PC), diethyl carbonate–EC, and EC–PC, respectively. The synthesized cathodes were also evaluated in full-cell configurations, which delivered an initial discharge capacity of 80 mA h/g with NaTi2(PO4)3MWCNT as the anode. Ionic diffusivity and interfacial charge transfer kinetics were also evaluated as a function of temperature and sodium concentration, which revealed that electrochemical rate performances in this material were limited by charge-transfer kinetics. To understand the heat generation mechanism of the Na/Na3Fe0.3V1.7O(PO4)2F2 half-cell during charge and discharge processes, an electrochemical isothermal calorimetry measurement was carried out at different current rates for two different temperatures (25 and 45 °C). The resultsmore »
- Authors:
-
[1];
[2];
[2];
[4];
[3];
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Bredesen Center for Interdisciplinary Research and Graduate Education, Knoxville, TN (United States)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Hamad Bin Khalifa University, Doha (Qatar)
- University of Liege (Belgium)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Electricity (OE)
- OSTI Identifier:
- 1657957
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 37; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Sodium-ion batteries; in situ heat generation; full cell; oxyflurophosphate cathode; iron doping
Citation Formats
Belharouak, Ilias, Amin, Ruhul, Muralidharan, Nitin, Maher, Kenza, Abouimrane, Ali, Yahia, Hamdi Ben, Mahmoud, Abdelfattah, kumar, Ramesh, and Essehli, Rachid. Iron-Doped Sodium Vanadium Oxyflurophosphate Cathodes for Sodium-Ion Batteries—Electrochemical Characterization and In Situ Measurements of Heat Generation. United States: N. p., 2020.
Web. doi:10.1021/acsami.0c11616.
Belharouak, Ilias, Amin, Ruhul, Muralidharan, Nitin, Maher, Kenza, Abouimrane, Ali, Yahia, Hamdi Ben, Mahmoud, Abdelfattah, kumar, Ramesh, & Essehli, Rachid. Iron-Doped Sodium Vanadium Oxyflurophosphate Cathodes for Sodium-Ion Batteries—Electrochemical Characterization and In Situ Measurements of Heat Generation. United States. https://doi.org/10.1021/acsami.0c11616
Belharouak, Ilias, Amin, Ruhul, Muralidharan, Nitin, Maher, Kenza, Abouimrane, Ali, Yahia, Hamdi Ben, Mahmoud, Abdelfattah, kumar, Ramesh, and Essehli, Rachid. Tue .
"Iron-Doped Sodium Vanadium Oxyflurophosphate Cathodes for Sodium-Ion Batteries—Electrochemical Characterization and In Situ Measurements of Heat Generation". United States. https://doi.org/10.1021/acsami.0c11616. https://www.osti.gov/servlets/purl/1657957.
@article{osti_1657957,
title = {Iron-Doped Sodium Vanadium Oxyflurophosphate Cathodes for Sodium-Ion Batteries—Electrochemical Characterization and In Situ Measurements of Heat Generation},
author = {Belharouak, Ilias and Amin, Ruhul and Muralidharan, Nitin and Maher, Kenza and Abouimrane, Ali and Yahia, Hamdi Ben and Mahmoud, Abdelfattah and kumar, Ramesh and Essehli, Rachid},
abstractNote = {Sodium-ion batteries (NaIBs) are increasingly being envisioned for grid-scale energy-storage systems because of cost advantages. However, implementation of this vision has been challenged by the low-energy densities delivered by most NaIB cathodes. Toward addressing this challenge, the authors report the synthesis and characterization of a new iron-doped Na3Fe0.3V1.7O(PO4)2F2 cathode using a novel facile hydrothermal route. The synthesized material was characterized using scanning electron microscopy, X-ray diffraction, and Mössbauer spectroscopy techniques. The obtained discharge capacity in the half-cell configuration lies from 119 to 125 to 130 mA h/g at C/10 while tested using three different electrolyte formulations, dimethyl carbonate–ethylene carbonate (EC)–propylene carbonate (PC), diethyl carbonate–EC, and EC–PC, respectively. The synthesized cathodes were also evaluated in full-cell configurations, which delivered an initial discharge capacity of 80 mA h/g with NaTi2(PO4)3MWCNT as the anode. Ionic diffusivity and interfacial charge transfer kinetics were also evaluated as a function of temperature and sodium concentration, which revealed that electrochemical rate performances in this material were limited by charge-transfer kinetics. To understand the heat generation mechanism of the Na/Na3Fe0.3V1.7O(PO4)2F2 half-cell during charge and discharge processes, an electrochemical isothermal calorimetry measurement was carried out at different current rates for two different temperatures (25 and 45 °C). The results showed that the amount of heat generated was strongly affected by the operating charge/discharge state, C-rate, and temperature. Altogether, this work provides a new synthesis route for the development of iron-doped Na3Fe0.3V1.7O(PO4)2F2-based high-performance sodium cathode materials aimed at providing a viable pathway for the development and deployment of large-scale energy-storage based on sodium battery systems.},
doi = {10.1021/acsami.0c11616},
journal = {ACS Applied Materials and Interfaces},
number = 37,
volume = 12,
place = {United States},
year = {Tue Aug 18 00:00:00 EDT 2020},
month = {Tue Aug 18 00:00:00 EDT 2020}
}
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