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Title: Photoionization of metastable heliumlike C 4 + ( 1 s 2 s S 1 3 ) ions: Precision study of intermediate doubly excited states

Abstract

In a joint experimental and theoretical endeavor, photoionization of metastable C4+(1s2s3S1) ions via intermediate levels with hollow, double-K-vacancy configurations 2s2p, 2s3p, 2p3s, 2p3d, 2s4p, 2p4s, and 2p4d has been investigated. High-resolution photon-ion merged-beams measurements were carried out with the resolving power reaching up to 25 800 which is sufficient to separate the leading fine-structure components of the 2s2p 3P term. Many-body perturbation theory was employed to determine level-to-level cross sections for K-shell excitation with subsequent autoionization. The resonance energies were calculated with inclusion of electron correlation and radiative contributions. Their uncertainties are estimated to be below ±1 meV. Detailed balance confirms the present photoionization cross-section results by comparison with previous dielectronic-recombination measurements. Finally, the high accuracy of the theoretical transition energies together with the present experimental results qualify photoabsorption resonances in heliumlike ions as new, greatly improved energy-reference standards at synchrotron radiation facilities.

Authors:
 [1];  [2];  [3];  [1];  [4];  [1];  [5];  [6];  [3];  [7];  [8];  [9];  [1]
  1. Justus-Liebig-Univ., Giessen (Germany)
  2. Alba Nova Univ. Center, Stockholm (Sweden)
  3. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  4. GSI Helmholtzzentrum fur Schwerionenforschung, Darmstadt (Germany); Columbia Univ., New York, NY (United States)
  5. Sorbonne Univ., Paris (France)
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  7. Univ. Hamburg (Germany)
  8. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Helmholtz-Zentrum, Berlin (Germany)
  9. Justus-Liebig-Univ., Giessen (Germany); Max-Planck-Inst. fur Kernphysik, Heidelberg (Germany)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); Bundesministerium fur Bildung und Forschung; European Union (EU); Helmholtz Association; Swedish Research Council (SRC)
OSTI Identifier:
1604650
Grant/Contract Number:  
AC02-05CH11231; 05K10RG1; 05K10GUB; 05K16RG1; 05K16GUV; 654220; EMMI HA-216; 2016-03789
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review A
Additional Journal Information:
Journal Volume: 98; Journal Issue: 3; Journal ID: ISSN 2469-9926
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; atomic & molecular structure; autoionization & Auger processes; electronic structure of atoms & molecules; electronic transitions; relativistic & quantum electrodynamic effects in atoms, molecules, & ions; single- and few-photon ionization & excitation

Citation Formats

Müller, A., Lindroth, E., Bari, S., Borovik, A., Hillenbrand, P. -M., Holste, K., Indelicato, P., Kilcoyne, A. L. D., Klumpp, S., Martins, M., Viefhaus, J., Wilhelm, P., and Schippers, S. Photoionization of metastable heliumlike C4+(1s2sS13) ions: Precision study of intermediate doubly excited states. United States: N. p., 2018. Web. doi:10.1103/PhysRevA.98.033416.
Müller, A., Lindroth, E., Bari, S., Borovik, A., Hillenbrand, P. -M., Holste, K., Indelicato, P., Kilcoyne, A. L. D., Klumpp, S., Martins, M., Viefhaus, J., Wilhelm, P., & Schippers, S. Photoionization of metastable heliumlike C4+(1s2sS13) ions: Precision study of intermediate doubly excited states. United States. https://doi.org/10.1103/PhysRevA.98.033416
Müller, A., Lindroth, E., Bari, S., Borovik, A., Hillenbrand, P. -M., Holste, K., Indelicato, P., Kilcoyne, A. L. D., Klumpp, S., Martins, M., Viefhaus, J., Wilhelm, P., and Schippers, S. Tue . "Photoionization of metastable heliumlike C4+(1s2sS13) ions: Precision study of intermediate doubly excited states". United States. https://doi.org/10.1103/PhysRevA.98.033416. https://www.osti.gov/servlets/purl/1604650.
@article{osti_1604650,
title = {Photoionization of metastable heliumlike C4+(1s2sS13) ions: Precision study of intermediate doubly excited states},
author = {Müller, A. and Lindroth, E. and Bari, S. and Borovik, A. and Hillenbrand, P. -M. and Holste, K. and Indelicato, P. and Kilcoyne, A. L. D. and Klumpp, S. and Martins, M. and Viefhaus, J. and Wilhelm, P. and Schippers, S.},
abstractNote = {In a joint experimental and theoretical endeavor, photoionization of metastable C4+(1s2s3S1) ions via intermediate levels with hollow, double-K-vacancy configurations 2s2p, 2s3p, 2p3s, 2p3d, 2s4p, 2p4s, and 2p4d has been investigated. High-resolution photon-ion merged-beams measurements were carried out with the resolving power reaching up to 25 800 which is sufficient to separate the leading fine-structure components of the 2s2p 3P term. Many-body perturbation theory was employed to determine level-to-level cross sections for K-shell excitation with subsequent autoionization. The resonance energies were calculated with inclusion of electron correlation and radiative contributions. Their uncertainties are estimated to be below ±1 meV. Detailed balance confirms the present photoionization cross-section results by comparison with previous dielectronic-recombination measurements. Finally, the high accuracy of the theoretical transition energies together with the present experimental results qualify photoabsorption resonances in heliumlike ions as new, greatly improved energy-reference standards at synchrotron radiation facilities.},
doi = {10.1103/PhysRevA.98.033416},
journal = {Physical Review A},
number = 3,
volume = 98,
place = {United States},
year = {Tue Sep 25 00:00:00 EDT 2018},
month = {Tue Sep 25 00:00:00 EDT 2018}
}

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Works referencing / citing this record:

The photon‐ion merged‐beams experiment PIPE at PETRA III—The first five years
text, January 2020

  • Schippers, Stefan; Buhr, Ticia; Borovik, Alexander
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The photon‐ion merged‐beams experiment PIPE at PETRA III—The first five years
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Photoionization and photofragmentation of singly charged positive and negative Sc 3 N @ C 80 endohedral fullerene ions
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Photoionization and photofragmentation of singly charged positive and negative Sc$_3$N@C$_{80}$ endohedral fullerene ions
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The photon‐ion merged‐beams experiment PIPE at PETRA III—The first five years
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