Hybrid Nanostructured Ni(OH)2/NiO for High Capacity Lithium–ion Battery Anodes
Abstract
A straightforward hydrothermal process followed by a controlled calcination technique is introduced for the synthesis of a Ni(OH)2 modified NiO nanohybrid structure. Conversion materials as Li-ion battery anodes, NiO in this case, suffer from capacity fade and structural/morphological instability during lithiation and delithiation. The novelty of this work is in utilizing this hybrid configuration to increase the specific capacity and enable reversible electrochemistry. Here, we study the lithiation/delithiation process of NiO using a suite of spectroscopy and microscopy techniques from the atomic to electrode scale. We propose a mechanism for a reversible redox couple behavior of the NiO electrode by means of a hybrid Ni(OH)2/NiO structure. The ultimate objective of this work is to guide the development of anode with rationally-designed heterogeneity to create high capacity Li-ion batteries with excellent cycling and rate performance.
- Authors:
-
- SLAC National Accelerator Lab., Menlo Park, CA (United States); Weifang Univ. (China)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- SLAC National Accelerator Lab., Menlo Park, CA (United States); Stanford Univ., CA (United States)
- Shanghai Jiao Tong Univ. (China)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1592170
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Electrochemical Energy Conversion and Storage
- Additional Journal Information:
- Journal Volume: 17; Journal Issue: 4; Journal ID: ISSN 2381-6872
- Publisher:
- ASME
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Ren, Yang, Ko, Jesse S., Kasse, Robert M., Song, Xuefeng, Toney, Michael F., and Weker, Johanna Nelson. Hybrid Nanostructured Ni(OH)2/NiO for High Capacity Lithium–ion Battery Anodes. United States: N. p., 2020.
Web. doi:10.1115/1.4046491.
Ren, Yang, Ko, Jesse S., Kasse, Robert M., Song, Xuefeng, Toney, Michael F., & Weker, Johanna Nelson. Hybrid Nanostructured Ni(OH)2/NiO for High Capacity Lithium–ion Battery Anodes. United States. https://doi.org/10.1115/1.4046491
Ren, Yang, Ko, Jesse S., Kasse, Robert M., Song, Xuefeng, Toney, Michael F., and Weker, Johanna Nelson. Fri .
"Hybrid Nanostructured Ni(OH)2/NiO for High Capacity Lithium–ion Battery Anodes". United States. https://doi.org/10.1115/1.4046491. https://www.osti.gov/servlets/purl/1592170.
@article{osti_1592170,
title = {Hybrid Nanostructured Ni(OH)2/NiO for High Capacity Lithium–ion Battery Anodes},
author = {Ren, Yang and Ko, Jesse S. and Kasse, Robert M. and Song, Xuefeng and Toney, Michael F. and Weker, Johanna Nelson},
abstractNote = {A straightforward hydrothermal process followed by a controlled calcination technique is introduced for the synthesis of a Ni(OH)2 modified NiO nanohybrid structure. Conversion materials as Li-ion battery anodes, NiO in this case, suffer from capacity fade and structural/morphological instability during lithiation and delithiation. The novelty of this work is in utilizing this hybrid configuration to increase the specific capacity and enable reversible electrochemistry. Here, we study the lithiation/delithiation process of NiO using a suite of spectroscopy and microscopy techniques from the atomic to electrode scale. We propose a mechanism for a reversible redox couple behavior of the NiO electrode by means of a hybrid Ni(OH)2/NiO structure. The ultimate objective of this work is to guide the development of anode with rationally-designed heterogeneity to create high capacity Li-ion batteries with excellent cycling and rate performance.},
doi = {10.1115/1.4046491},
journal = {Journal of Electrochemical Energy Conversion and Storage},
number = 4,
volume = 17,
place = {United States},
year = {Fri Feb 28 00:00:00 EST 2020},
month = {Fri Feb 28 00:00:00 EST 2020}
}
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