Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy
Abstract
All-solid-state batteries have attracted attention owing to the potential high energy density and safety; however, little success has been made on practical applications of solid-state batteries, which is largely attributed to the solid–solid interface issues. A fundamental elucidation of electrode–electrolyte interface behaviors is of crucial significance but has proven difficult. The interfacial resistance and capacity fading issues in a solid-state battery were probed, revealing a heterogeneous phase transition evolution at solid–solid interfaces. The strain-induced interfacial change and the contact loss, as well as a dense metallic surface phase, deteriorate the electrochemical reaction in solid-state batteries. Furthermore, the in situ growth of electrolytes on secondary particles is proposed to fabricate robust solid–solid interface. Finally, our study enlightens new insights into the mechanism behind solid–solid interfacial reaction for optimizing advanced solid-state batteries.
- Authors:
-
[1];
- Harbin Inst. of Technology (China). School of Chemistry and Chemical Engineering, MIIT Key Lab. of Critical Materials Technology for New Energy Conversion and Storage
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Univ. of Western Ontario, London, ON (Canada). Dept. of Mechanical and Materials Engineering
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1577426
- Report Number(s):
- BNL-212376-2019-JAAM
Journal ID: ISSN 1433-7851; ANIE
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 51; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; electrochemistry; interfaces; lithium; solid-state batteries; sulfide electrolyte
Citation Formats
Sun, Nan, Liu, Qingsong, Cao, Yi, Lou, Shuaifeng, Ge, Mingyuan, Xiao, Xianghui, Lee, Wah-Keat, Gao, Yunzhi, Yin, Geping, Wang, Jiajun, and Sun, Xueliang. Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy. United States: N. p., 2019.
Web. doi:10.1002/anie.201910993.
Sun, Nan, Liu, Qingsong, Cao, Yi, Lou, Shuaifeng, Ge, Mingyuan, Xiao, Xianghui, Lee, Wah-Keat, Gao, Yunzhi, Yin, Geping, Wang, Jiajun, & Sun, Xueliang. Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy. United States. https://doi.org/10.1002/anie.201910993
Sun, Nan, Liu, Qingsong, Cao, Yi, Lou, Shuaifeng, Ge, Mingyuan, Xiao, Xianghui, Lee, Wah-Keat, Gao, Yunzhi, Yin, Geping, Wang, Jiajun, and Sun, Xueliang. Mon .
"Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy". United States. https://doi.org/10.1002/anie.201910993. https://www.osti.gov/servlets/purl/1577426.
@article{osti_1577426,
title = {Anisotropically Electrochemical-Mechanical Evolution in Solid-State Batteries and Interfacial Tailored Strategy},
author = {Sun, Nan and Liu, Qingsong and Cao, Yi and Lou, Shuaifeng and Ge, Mingyuan and Xiao, Xianghui and Lee, Wah-Keat and Gao, Yunzhi and Yin, Geping and Wang, Jiajun and Sun, Xueliang},
abstractNote = {All-solid-state batteries have attracted attention owing to the potential high energy density and safety; however, little success has been made on practical applications of solid-state batteries, which is largely attributed to the solid–solid interface issues. A fundamental elucidation of electrode–electrolyte interface behaviors is of crucial significance but has proven difficult. The interfacial resistance and capacity fading issues in a solid-state battery were probed, revealing a heterogeneous phase transition evolution at solid–solid interfaces. The strain-induced interfacial change and the contact loss, as well as a dense metallic surface phase, deteriorate the electrochemical reaction in solid-state batteries. Furthermore, the in situ growth of electrolytes on secondary particles is proposed to fabricate robust solid–solid interface. Finally, our study enlightens new insights into the mechanism behind solid–solid interfacial reaction for optimizing advanced solid-state batteries.},
doi = {10.1002/anie.201910993},
journal = {Angewandte Chemie (International Edition)},
number = 51,
volume = 58,
place = {United States},
year = {Mon Oct 14 00:00:00 EDT 2019},
month = {Mon Oct 14 00:00:00 EDT 2019}
}
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Figures / Tables:
Figure 1: Physical characterizations. (A) Crystal structure of triclinic Li7P3S11. (B) X-ray diffraction patterns of the neat Li7P3S11 electrolytes, commercial FeS2, and electrode composites. (C) XPS spectra of P and S for Li7P3S11. (D) The Raman spectra of the neat Li7P3S11 electrolytes, commercial FeS2, and electrode composites. (E) Nyquist plotmore »
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