Monolayer Ti3C2Tx as an Effective Co-catalyst for Enhanced Photocatalytic Hydrogen Production over TiO2
Abstract
Titanium dioxide (TiO2) represents a promising candidate for hydrogen production via photocatalysis. Yet, its large bandgap and fast charge recombination limits its efficiency. To overcome this limitation, we explored in this work two-dimensional titanium carbide MXene, Ti3C2Tx (Tx = O, OH, F), as feasible co-catalysts for hydrogen production with TiO2 as the photocatalyst. We synthesized a series of Ti3C2Tx/TiO2 composite photocatalysts with monolayer Ti3C2Tx as the co-catalyst to improve the separation of photoinduced electrons and holes. The physicochemical properties of the Ti3C2Tx/TiO2 composites were investigated by a variety of characterization techniques, and the effect of the monolayer Ti3C2Tx on the photocatalytic performance of the Ti3C2Tx/TiO2 composites is elucidated by comparison to the multilayer counterpart. The photocatalytic hydrogen evolution rate of the optimized monolayer Ti3C2Tx/TiO2 composite is over 9 times higher than that of the pure TiO2 and 2.5 times higher than the multilayer counterpart. The significantly enhanced activity is attributed to the superior electrical conductivity of monolayer Ti3C2Tx and charge-carrier separation at the MXene/TiO2 interface. A mechanism of photocatalytic hydrogen evolution over the Ti3C2Tx/TiO2 system is proposed. Our work reports on the potential of monolayer MXenes as effective co-catalysts for photocatalysis and further broadens the applications of the MXene familymore »
- Authors:
-
- Guangxi Univ., Nanning (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Tulane Univ., New Orleans, LA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); West Virginia Univ., Morgantown, WV (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Guangxi Univ., Nanning (China); Sun Yat-Sen Univ., Guangzhou, (China)
- Guangxi Univ., Nanning (China)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1545193
- Grant/Contract Number:
- AC05-00OR22725; DGE-1650044
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Energy Materials
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 7; Journal ID: ISSN 2574-0962
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN; monolayer titanium carbide; MXene; titanium dioxide; photocatalysis; hydrogen evolution
Citation Formats
Su, Tongming, Hood, Zachary D., Naguib, Michael, Bai, Lei, Luo, Si, Rouleau, Christopher M., Ivanov, Ilia N., Ji, Hongbing, Qin, Zuzeng, and Wu, Zili. Monolayer Ti3C2Tx as an Effective Co-catalyst for Enhanced Photocatalytic Hydrogen Production over TiO2. United States: N. p., 2019.
Web. doi:10.1021/acsaem.8b02268.
Su, Tongming, Hood, Zachary D., Naguib, Michael, Bai, Lei, Luo, Si, Rouleau, Christopher M., Ivanov, Ilia N., Ji, Hongbing, Qin, Zuzeng, & Wu, Zili. Monolayer Ti3C2Tx as an Effective Co-catalyst for Enhanced Photocatalytic Hydrogen Production over TiO2. United States. https://doi.org/10.1021/acsaem.8b02268
Su, Tongming, Hood, Zachary D., Naguib, Michael, Bai, Lei, Luo, Si, Rouleau, Christopher M., Ivanov, Ilia N., Ji, Hongbing, Qin, Zuzeng, and Wu, Zili. Fri .
"Monolayer Ti3C2Tx as an Effective Co-catalyst for Enhanced Photocatalytic Hydrogen Production over TiO2". United States. https://doi.org/10.1021/acsaem.8b02268. https://www.osti.gov/servlets/purl/1545193.
@article{osti_1545193,
title = {Monolayer Ti3C2Tx as an Effective Co-catalyst for Enhanced Photocatalytic Hydrogen Production over TiO2},
author = {Su, Tongming and Hood, Zachary D. and Naguib, Michael and Bai, Lei and Luo, Si and Rouleau, Christopher M. and Ivanov, Ilia N. and Ji, Hongbing and Qin, Zuzeng and Wu, Zili},
abstractNote = {Titanium dioxide (TiO2) represents a promising candidate for hydrogen production via photocatalysis. Yet, its large bandgap and fast charge recombination limits its efficiency. To overcome this limitation, we explored in this work two-dimensional titanium carbide MXene, Ti3C2Tx (Tx = O, OH, F), as feasible co-catalysts for hydrogen production with TiO2 as the photocatalyst. We synthesized a series of Ti3C2Tx/TiO2 composite photocatalysts with monolayer Ti3C2Tx as the co-catalyst to improve the separation of photoinduced electrons and holes. The physicochemical properties of the Ti3C2Tx/TiO2 composites were investigated by a variety of characterization techniques, and the effect of the monolayer Ti3C2Tx on the photocatalytic performance of the Ti3C2Tx/TiO2 composites is elucidated by comparison to the multilayer counterpart. The photocatalytic hydrogen evolution rate of the optimized monolayer Ti3C2Tx/TiO2 composite is over 9 times higher than that of the pure TiO2 and 2.5 times higher than the multilayer counterpart. The significantly enhanced activity is attributed to the superior electrical conductivity of monolayer Ti3C2Tx and charge-carrier separation at the MXene/TiO2 interface. A mechanism of photocatalytic hydrogen evolution over the Ti3C2Tx/TiO2 system is proposed. Our work reports on the potential of monolayer MXenes as effective co-catalysts for photocatalysis and further broadens the applications of the MXene family of two-dimensional materials.},
doi = {10.1021/acsaem.8b02268},
journal = {ACS Applied Energy Materials},
number = 7,
volume = 2,
place = {United States},
year = {Fri May 10 00:00:00 EDT 2019},
month = {Fri May 10 00:00:00 EDT 2019}
}
Web of Science
Works referenced in this record:
Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting
journal, January 2014
- Hisatomi, Takashi; Kubota, Jun; Domen, Kazunari
- Chem. Soc. Rev., Vol. 43, Issue 22
Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%
journal, March 2016
- Wang, Qian; Hisatomi, Takashi; Jia, Qingxin
- Nature Materials, Vol. 15, Issue 6
g-C 3 N 4 -Based Heterostructured Photocatalysts
journal, September 2017
- Fu, Junwei; Yu, Jiaguo; Jiang, Chuanjia
- Advanced Energy Materials, Vol. 8, Issue 3
In-Plane Heterojunctions Enable Multiphasic Two-Dimensional (2D) MoS 2 Nanosheets As Efficient Photocatalysts for Hydrogen Evolution from Water Reduction
journal, September 2016
- Peng, Rui; Liang, Liangbo; Hood, Zachary D.
- ACS Catalysis, Vol. 6, Issue 10
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
journal, January 2015
- Moniz, Savio J. A.; Shevlin, Stephen A.; Martin, David James
- Energy & Environmental Science, Vol. 8, Issue 3
Role of Interfaces in Two-Dimensional Photocatalyst for Water Splitting
journal, January 2018
- Su, Tongming; Shao, Qian; Qin, Zuzeng
- ACS Catalysis, Vol. 8, Issue 3
Engineering disorder into exotic electronic 2D TiO 2 nanosheets for enhanced photocatalytic performance
journal, January 2016
- Yan, Bo; Zhou, Pengshang; Xu, Qun
- RSC Advances, Vol. 6, Issue 8
In situ synthesis of carbon doped TiO2 nanotubes with an enhanced photocatalytic performance under UV and visible light
journal, December 2017
- Ji, Lijun; Zhang, Yuheng; Miao, Shiyong
- Carbon, Vol. 125
A review on TiO 2 -based Z-scheme photocatalysts
journal, December 2017
- Qi, Kezhen; Cheng, Bei; Yu, Jiaguo
- Chinese Journal of Catalysis, Vol. 38, Issue 12
TiO2/MXene Ti3C2 composite with excellent photocatalytic CO2 reduction activity
journal, May 2018
- Low, Jingxiang; Zhang, Liuyang; Tong, Tong
- Journal of Catalysis, Vol. 361
Principles on design and fabrication of nanomaterials as photocatalysts for water-splitting
journal, May 2016
- Pan, Hui
- Renewable and Sustainable Energy Reviews, Vol. 57
Nonaqueous Synthesis of TiO 2 Nanocrystals Using TiF 4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity
journal, April 2012
- Gordon, Thomas R.; Cargnello, Matteo; Paik, Taejong
- Journal of the American Chemical Society, Vol. 134, Issue 15
Fabrication and Properties of a Free-Standing Two-Dimensional Titania
journal, October 2017
- Wang, Song Ling; Luo, Xin; Zhou, Xiong
- Journal of the American Chemical Society, Vol. 139, Issue 43
Efficient photocatalytic hydrogen production over Rh and Nb codoped TiO2 nanorods
journal, April 2018
- Huang, Jiquan; Li, Guojing; Zhou, Zhangfeng
- Chemical Engineering Journal, Vol. 337
Extended visible to near-infrared harvesting of earth-abundant FeS 2 –TiO 2 heterostructures for highly active photocatalytic hydrogen evolution
journal, January 2018
- Kuo, Tsung-Rong; Liao, Hsiang-Ju; Chen, Yu-Ting
- Green Chemistry, Vol. 20, Issue 7
Introducing Ti 3+ defects based on lattice distortion for enhanced visible light photoreactivity in TiO 2 microspheres
journal, January 2017
- Xu, Yunfan; Wu, Sujuan; Wan, Piaopiao
- RSC Advances, Vol. 7, Issue 52
Engineering the Absorption and Field Enhancement Properties of Au–TiO 2 Nanohybrids via Whispering Gallery Mode Resonances for Photocatalytic Water Splitting
journal, April 2016
- Zhang, Jianming; Jin, Xin; Morales-Guzman, Pablo I.
- ACS Nano, Vol. 10, Issue 4
M–Au/TiO 2 (M = Ag, Pd, and Pt) nanophotocatalyst for overall solar water splitting: role of interfaces
journal, January 2015
- Melvin, Ambrose A.; Illath, Kavya; Das, Tanmay
- Nanoscale, Vol. 7, Issue 32
Unraveling the Orientation of MoS 2 on TiO 2 for Photocatalytic Water Splitting
journal, July 2017
- Tang, Chao; Xu, Weiwei; Chen, Chongyang
- Advanced Materials Interfaces, Vol. 4, Issue 16
Facile in-situ design strategy to disperse TiO2 nanoparticles on graphene for the enhanced photocatalytic degradation of rhodamine 6G
journal, December 2017
- Pu, Shengyan; Zhu, Rongxin; Ma, Hui
- Applied Catalysis B: Environmental, Vol. 218
Reduced TiO 2 -Graphene Oxide Heterostructure As Broad Spectrum-Driven Efficient Water-Splitting Photocatalysts
journal, March 2016
- Li, Lihua; Yu, Lili; Lin, Zhaoyong
- ACS Applied Materials & Interfaces, Vol. 8, Issue 13
Bi 2 O 3 cocatalyst improving photocatalytic hydrogen evolution performance of TiO 2
journal, April 2017
- Xu, Difa; Hai, Yang; Zhang, Xiangchao
- Applied Surface Science, Vol. 400
Synergetic Effect of MoS 2 and Graphene as Cocatalysts for Enhanced Photocatalytic H 2 Production Activity of TiO 2 Nanoparticles
journal, April 2012
- Xiang, Quanjun; Yu, Jiaguo; Jaroniec, Mietek
- Journal of the American Chemical Society, Vol. 134, Issue 15
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011
- Naguib, Michael; Kurtoglu, Murat; Presser, Volker
- Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
Clay-Inspired MXene-Based Electrochemical Devices and Photo-Electrocatalyst: State-of-the-Art Progresses and Challenges
journal, January 2018
- Wang, Hou; Wu, Yan; Yuan, Xingzhong
- Advanced Materials, Vol. 30, Issue 12
Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production
journal, January 2017
- Ran, Jingrun; Gao, Guoping; Li, Fa-Tang
- Nature Communications, Vol. 8, Issue 1
Boosting the Photocatalytic Activity of P25 for Carbon Dioxide Reduction by using a Surface-Alkalinized Titanium Carbide MXene as Cocatalyst
journal, March 2018
- Ye, Minheng; Wang, Xin; Liu, Enzuo
- ChemSusChem, Vol. 11, Issue 10
The synergetic effects of Ti 3 C 2 MXene and Pt as co-catalysts for highly efficient photocatalytic hydrogen evolution over g-C 3 N 4
journal, January 2018
- An, Xiaoqiang; Wang, Wei; Wang, Jiangpeng
- Physical Chemistry Chemical Physics, Vol. 20, Issue 16
Formation of quasi-core-shell In2S3/anatase TiO2@metallic Ti3C2Tx hybrids with favorable charge transfer channels for excellent visible-light-photocatalytic performance
journal, October 2018
- Wang, Hou; Wu, Yan; Xiao, Tong
- Applied Catalysis B: Environmental, Vol. 233
One-Step Synthesis of Nb 2 O 5 /C/Nb 2 C (MXene) Composites and Their Use as Photocatalysts for Hydrogen Evolution
journal, January 2018
- Su, Tongming; Peng, Rui; Hood, Zachary D.
- ChemSusChem, Vol. 11, Issue 4
Titania Composites with 2 D Transition Metal Carbides as Photocatalysts for Hydrogen Production under Visible-Light Irradiation
journal, May 2016
- Wang, Hui; Peng, Rui; Hood, Zachary D.
- ChemSusChem, Vol. 9, Issue 12
Synergistic effect of 2D Ti 2 C and g-C 3 N 4 for efficient photocatalytic hydrogen production
journal, January 2017
- Shao, Mengmeng; Shao, Yangfan; Chai, Jianwei
- Journal of Materials Chemistry A, Vol. 5, Issue 32
High efficiency photocatalytic hydrogen production over ternary Cu/TiO2@Ti3C2Tx enabled by low-work-function 2D titanium carbide
journal, November 2018
- Peng, Chao; Wei, Ping; Li, Xiaoyao
- Nano Energy, Vol. 53
Drastic Layer-Number-Dependent Activity Enhancement in Photocatalytic H 2 Evolution over n MoS 2 /CdS ( n ≥ 1) Under Visible Light
journal, March 2015
- Chang, Kun; Li, Mu; Wang, Tao
- Advanced Energy Materials, Vol. 5, Issue 10
Capacitive and resistive response of humidity sensors based on graphene decorated by PMMA and silver nanoparticles
journal, August 2018
- Rahim, Ishrat; Shah, Mutabar; Khan, Afzal
- Sensors and Actuators B: Chemical, Vol. 267
Pressure-induced shear and interlayer expansion in Ti 3 C 2 MXene in the presence of water
journal, January 2018
- Ghidiu, Michael; Kota, Sankalp; Drozd, Vadym
- Science Advances, Vol. 4, Issue 1
Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti 3 C 2 MXene Flakes
journal, November 2016
- Lipatov, Alexey; Alhabeb, Mohamed; Lukatskaya, Maria R.
- Advanced Electronic Materials, Vol. 2, Issue 12
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials
journal, December 2013
- Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W.
- Advanced Materials, Vol. 26, Issue 7, p. 992-1005
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
journal, November 2014
- Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang
- Nature, Vol. 516, Issue 7529
Atomic-Scale Recognition of Surface Structure and Intercalation Mechanism of Ti 3 C 2 X
journal, February 2015
- Wang, Xuefeng; Shen, Xi; Gao, Yurui
- Journal of the American Chemical Society, Vol. 137, Issue 7
Efficient thorium(IV) removal by two-dimensional Ti2CTx MXene from aqueous solution
journal, June 2019
- Li, Shuangxiao; Wang, Lin; Peng, Jing
- Chemical Engineering Journal, Vol. 366
High Electrical Conductivity 2D MXene Serves as Additive of Perovskite for Efficient Solar Cells
journal, October 2018
- Guo, Zhanglin; Gao, Liguo; Xu, Zhenhua
- Small, Vol. 14, Issue 47
g-C 3 N 4 /Ti 3 C 2 T x (MXenes) composite with oxidized surface groups for efficient photocatalytic hydrogen evolution
journal, January 2018
- Sun, Yuliang; Jin, Di; Sun, Yuan
- Journal of Materials Chemistry A, Vol. 6, Issue 19
Photocatalytic degradation of bisphenol A over Rh/TiO 2 suspensions in different water matrices
journal, April 2017
- Repousi, Vasiliki; Petala, Athanasia; Frontistis, Zacharias
- Catalysis Today, Vol. 284
Heterostructural TiO2/Ti3C2Tx (MXene) for photocatalytic degradation of antiepileptic drug carbamazepine
journal, October 2018
- Shahzad, Asif; Rasool, Kashif; Nawaz, Mohsin
- Chemical Engineering Journal, Vol. 349
One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes
journal, January 2014
- Naguib, Michael; Mashtalir, Olha; Lukatskaya, Maria R.
- Chem. Commun., Vol. 50, Issue 56
UV light assisted synthesis of ternary reduced graphene oxide hybrid materials and their photocatalytic performance
journal, January 2013
- Min, YuLin; He, GuangQiang; Xu, QunJie
- Dalton Transactions, Vol. 42, Issue 34
X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)
journal, January 2016
- Halim, Joseph; Cook, Kevin M.; Naguib, Michael
- Applied Surface Science, Vol. 362
Photoreaction of Ethanol on TiO 2 (110) Single-Crystal Surface
journal, February 2007
- Jayaweera, P. M.; Quah, E. L.; Idriss, H.
- The Journal of Physical Chemistry C, Vol. 111, Issue 4
Black TiO2 nanobelts/g-C3N4 nanosheets Laminated Heterojunctions with Efficient Visible-Light-Driven Photocatalytic Performance
journal, February 2017
- Shen, Liyan; Xing, Zipeng; Zou, Jinlong
- Scientific Reports, Vol. 7, Issue 1
Enhanced photocatalytic activity for degrading Rhodamine B solution of commercial Degussa P25 TiO2 and its mechanisms
journal, December 2009
- Qin, Xu; Jing, Liqiang; Tian, Guohui
- Journal of Hazardous Materials, Vol. 172, Issue 2-3
Enhanced Efficiency of Electron-Hole Separation in Bi 2 O 2 CO 3 for Photocatalysis via Acid Treatment
journal, March 2018
- Huang, Yongchao; Li, Kunshan; Lin, Ying
- ChemCatChem, Vol. 10, Issue 9
Preparation and characterization of Cu modified BiYO3 for carbon dioxide reduction to formic acid
journal, March 2017
- Su, Tongming; Tian, Hui; Qin, Zuzeng
- Applied Catalysis B: Environmental, Vol. 202
Efficient Charges Separation Using Advanced BiOI-Based Hollow Spheres Decorated with Palladium and Manganese Dioxide Nanoparticles
journal, December 2017
- Huang, Yongchao; Xu, Huimin; Yang, Haojie
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 2
Oxidation Stability of Colloidal Two-Dimensional Titanium Carbides (MXenes)
journal, May 2017
- Zhang, Chuanfang John; Pinilla, Sergio; McEvoy, Niall
- Chemistry of Materials, Vol. 29, Issue 11
Two-Dimensional Ultrathin MXene Ceramic Nanosheets for Photothermal Conversion
journal, December 2016
- Lin, Han; Wang, Xingang; Yu, Luodan
- Nano Letters, Vol. 17, Issue 1
Boosting the Photocatalytic Ability of Cu 2 O Nanowires for CO 2 Conversion by MXene Quantum Dots
journal, November 2018
- Zeng, Zhiping; Yan, Yibo; Chen, Jie
- Advanced Functional Materials, Vol. 29, Issue 2
Faster Electron Injection and More Active Sites for Efficient Photocatalytic H 2 Evolution in g-C 3 N 4 /MoS 2 Hybrid
journal, January 2018
- Shi, Xiaowei; Fujitsuka, Mamoru; Kim, Sooyeon
- Small, Vol. 14, Issue 11
Works referencing / citing this record:
An overview of photocatalysis facilitated by 2D heterojunctions
journal, September 2019
- Su, Tongming; Qin, Zuzeng; Ji, Hongbing
- Nanotechnology, Vol. 30, Issue 50
Water Splitting Performance Enhancement of the TiO 2 Nanorod Array Electrode with Ultrathin Black Phosphorus Nanosheets
journal, November 2019
- Xu, Yuanmei; Wang, Xin; Jin, Mingliang
- ChemElectroChem, Vol. 7, Issue 1
2D MXenes as Co-catalysts in Photocatalysis: Synthetic Methods
journal, September 2019
- Sun, Yuliang; Meng, Xing; Dall’Agnese, Yohan
- Nano-Micro Letters, Vol. 11, Issue 1