Titania Composites with 2 D Transition Metal Carbides as Photocatalysts for Hydrogen Production under Visible-Light Irradiation

Wang, Hui; Peng, Rui; Hood, Zachary D.; Naguib, Michael; Adhikari, Shiba P.; Wu, Zili

doi:10.1002/cssc.201600165

Title: Titania Composites with 2 D Transition Metal Carbides as Photocatalysts for Hydrogen Production under Visible-Light Irradiation

Journal Article · Tue May 24 00:00:00 EDT 2016 · ChemSusChem

DOI: https://doi.org/10.1002/cssc.201600165 · OSTI ID:1257896

Wang, Hui ^[1]; Peng, Rui ^[1]; Hood, Zachary D. ^[2]; Naguib, Michael ^[3]; Adhikari, Shiba P. ^[4];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Georgia Inst. of Technology, Atlanta, GA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Materials Science Technology Division, Oak Ridge National Laboratory, Oak Ridge TN 37831 USA
Wake Forest Univ., Winston-Salem, NC (United States)

In the MXenes family of two-dimensional transition-metal carbides there were successful demonstrations of co-catalysts with rutile TiO₂ for visible-light-induced solar hydrogen production from water splitting. The physicochemical properties of Ti₃C₂T_x MXene coupled with TiO₂ were investigated by a variety of characterization techniques. The effect of the Ti₃C₂T_x loading on the photocatalytic performance of the TiO₂/Ti₃C₂T_x composites was elucidated. Moreover, with an optimized Ti₃C₂T_x content of 5 wt %, the TiO₂/Ti₃C₂T_x composite shows a 400 % enhancement in the photocatalytic hydrogen evolution reaction compared with that of pure rutile TiO₂. We also expanded our exploration to other MXenes (Nb₂CT_x and Ti₂CT_x) as co-catalysts coupled with TiO₂, and these materials also exhibited enhanced hydrogen production. These results manifest the generality of MXenes as effective co-catalysts for solar hydrogen production.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1257896

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 12 Vol. 9; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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