Application of Bottlebrush Block Copolymers as Photonic Crystals
Abstract
Brush block copolymers are a class of comb polymers that feature polymeric side chains densely grafted to a linear backbone. These polymers display interesting properties due to their dense functionality, low entanglement, and ability to rapidly self‐assemble to highly ordered nanostructures. The ability to prepare brush polymers with precise structures has been enabled by advancements in controlled polymerization techniques. This Feature Article highlights the development of brush block copolymers as photonic crystals that can reflect visible to near‐infrared wavelengths of light. Fabrication of these materials relies on polymer self‐assembly processes to achieve nanoscale ordering, which allows for the rapid preparation of photonic crystals from common organic chemical feedstocks. The characteristic physical properties of brush block copolymers are discussed, along with methods for their preparation. Strategies to induce self‐assembly at ambient temperatures and the use of blending techniques to tune photonic properties are emphasized. image
- Authors:
-
- California Inst. of Technology, Pasadena, CA (United States)
- Publication Date:
- Research Org.:
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF)
- OSTI Identifier:
- 1533189
- Alternate Identifier(s):
- OSTI ID: 1400844
- Grant/Contract Number:
- SC0001293; CHE-1048404; DE‐SC0001293
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Macromolecular Rapid Communications
- Additional Journal Information:
- Journal Volume: 38; Journal Issue: 13; Journal ID: ISSN 1022-1336
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; polymer science; photonic crystals; bottlebrush; block copolymers; self-assembly; structural color
Citation Formats
Liberman‐Martin, Allegra L., Chu, Crystal K., and Grubbs, Robert H. Application of Bottlebrush Block Copolymers as Photonic Crystals. United States: N. p., 2017.
Web. doi:10.1002/marc.201700058.
Liberman‐Martin, Allegra L., Chu, Crystal K., & Grubbs, Robert H. Application of Bottlebrush Block Copolymers as Photonic Crystals. United States. https://doi.org/10.1002/marc.201700058
Liberman‐Martin, Allegra L., Chu, Crystal K., and Grubbs, Robert H. Mon .
"Application of Bottlebrush Block Copolymers as Photonic Crystals". United States. https://doi.org/10.1002/marc.201700058. https://www.osti.gov/servlets/purl/1533189.
@article{osti_1533189,
title = {Application of Bottlebrush Block Copolymers as Photonic Crystals},
author = {Liberman‐Martin, Allegra L. and Chu, Crystal K. and Grubbs, Robert H.},
abstractNote = {Brush block copolymers are a class of comb polymers that feature polymeric side chains densely grafted to a linear backbone. These polymers display interesting properties due to their dense functionality, low entanglement, and ability to rapidly self‐assemble to highly ordered nanostructures. The ability to prepare brush polymers with precise structures has been enabled by advancements in controlled polymerization techniques. This Feature Article highlights the development of brush block copolymers as photonic crystals that can reflect visible to near‐infrared wavelengths of light. Fabrication of these materials relies on polymer self‐assembly processes to achieve nanoscale ordering, which allows for the rapid preparation of photonic crystals from common organic chemical feedstocks. The characteristic physical properties of brush block copolymers are discussed, along with methods for their preparation. Strategies to induce self‐assembly at ambient temperatures and the use of blending techniques to tune photonic properties are emphasized. image},
doi = {10.1002/marc.201700058},
journal = {Macromolecular Rapid Communications},
number = 13,
volume = 38,
place = {United States},
year = {Mon May 22 00:00:00 EDT 2017},
month = {Mon May 22 00:00:00 EDT 2017}
}
Web of Science
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