Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance
Abstract
The recent development of organocatalyzed atom transfer radical polymerization (O‐ATRP) represents a significant advancement in the field of controlled radical polymerizations. A number of classes of photoredox catalysts have been employed thus far in O‐ATRP. Analysis of the proposed mechanism gives insight into the relevant photophysical and chemical properties that determine catalyst performance. Discussion of each of the classes of O‐ATRP catalysts highlights their previous uses, their roles in the development of O‐ATRP, and the distinctive properties that govern their polymerization behavior, leading to a set of design principles for O‐ATRP catalysts. Remaining challenges for O‐ATRP are presented, as well as prospects for further improvement in the application scope of O‐ATRP. image
- Authors:
-
- Department of Chemistry and Biochemistry University of Colorado Boulder Boulder Colorado 80309 United States
- Department of Chemistry and Biochemistry Materials Science and Engineering Program University of Colorado Boulder Boulder Colorado 80309 United States
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401302
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Macromolecular Rapid Communications
- Additional Journal Information:
- Journal Name: Macromolecular Rapid Communications Journal Volume: 38 Journal Issue: 13; Journal ID: ISSN 1022-1336
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Theriot, Jordan C., McCarthy, Blaine G., Lim, Chern‐Hooi, and Miyake, Garret M. Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance. Germany: N. p., 2017.
Web. doi:10.1002/marc.201700040.
Theriot, Jordan C., McCarthy, Blaine G., Lim, Chern‐Hooi, & Miyake, Garret M. Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance. Germany. https://doi.org/10.1002/marc.201700040
Theriot, Jordan C., McCarthy, Blaine G., Lim, Chern‐Hooi, and Miyake, Garret M. Mon .
"Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance". Germany. https://doi.org/10.1002/marc.201700040.
@article{osti_1401302,
title = {Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance},
author = {Theriot, Jordan C. and McCarthy, Blaine G. and Lim, Chern‐Hooi and Miyake, Garret M.},
abstractNote = {The recent development of organocatalyzed atom transfer radical polymerization (O‐ATRP) represents a significant advancement in the field of controlled radical polymerizations. A number of classes of photoredox catalysts have been employed thus far in O‐ATRP. Analysis of the proposed mechanism gives insight into the relevant photophysical and chemical properties that determine catalyst performance. Discussion of each of the classes of O‐ATRP catalysts highlights their previous uses, their roles in the development of O‐ATRP, and the distinctive properties that govern their polymerization behavior, leading to a set of design principles for O‐ATRP catalysts. Remaining challenges for O‐ATRP are presented, as well as prospects for further improvement in the application scope of O‐ATRP. image},
doi = {10.1002/marc.201700040},
journal = {Macromolecular Rapid Communications},
number = 13,
volume = 38,
place = {Germany},
year = {Mon Apr 03 00:00:00 EDT 2017},
month = {Mon Apr 03 00:00:00 EDT 2017}
}
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Works referenced in this record:
Phenoxazine Dyes for Dye‐Sensitized Solar Cells: Relationship Between Molecular Structure and Electron Lifetime
journal, April 2011
- Karlsson, Karl Martin; Jiang, Xiao; Eriksson, Susanna K.
- Chemistry – A European Journal, Vol. 17, Issue 23
Photoinduced Metal-Free Atom Transfer Radical Polymerization of Acrylonitrile
journal, January 2015
- Pan, Xiangcheng; Lamson, Melissa; Yan, Jiajun
- ACS Macro Letters, Vol. 4, Issue 2
Visible-Light-Induced Controlled Polymerization of Hydrophilic Monomers with Ir(ppy) 3 as a Photoredox Catalyst in Anisole
journal, April 2014
- Ma, Wenchao; Chen, Haochuan; Ma, Yuhong
- Macromolecular Chemistry and Physics, Vol. 215, Issue 10
Facile Synthesis of 5,10-Diaryl-5,10-dihydrophenazines and Application to EL Devices
journal, February 2003
- Okamoto, Toshihiro; Terada, Eriko; Kozaki, Masatoshi
- Organic Letters, Vol. 5, Issue 3
New Conjugated Polymers with Donor−Acceptor Architectures: Synthesis and Photophysics of Carbazole−Quinoline and Phenothiazine−Quinoline Copolymers and Oligomers Exhibiting Large Intramolecular Charge Transfer
journal, October 2001
- Jenekhe, Samson A.; Lu, Liangde; Alam, Maksudul M.
- Macromolecules, Vol. 34, Issue 21
An improved method for the rapid preparation of 2-Amino-4,4a-dihydro-4a,7-dimethyl-3H-phenoxazine-3-one, a Novel Antitumor Agent
journal, April 2001
- Tomoda, Akio; Arai, Sadao; Ishida, Ryoji
- Bioorganic & Medicinal Chemistry Letters, Vol. 11, Issue 8
Antitumor activity of a phenoxazine compound, 2-amino-4,4α-dihydro-4α,7-dimethyl-3H-phenoxazine-3-one against human B cell and T cell lymphoblastoid cell lines: induction of mixed types of cell death, apoptosis, and necrosis
journal, July 2002
- J., Koshibu-Koizumi; M., Akazawa; T., Iwamoto
- Journal of Cancer Research and Clinical Oncology, Vol. 128, Issue 7
Isolation and Synthesis of Biologically Active Carbazole Alkaloids
journal, November 2002
- Knölker, Hans-Joachim; Reddy, Kethiri R.
- Chemical Reviews, Vol. 102, Issue 11
Enhancement of external quantum efficiency through steric hindrance of phenazine derivative for white polymer light-emitting diode materials
journal, October 2013
- Song, Ho Jun; Lee, Eui Jin; Kim, Doo Hun
- Synthetic Metals, Vol. 181
Visible Light-Mediated Intermolecular C−H Functionalization of Electron-Rich Heterocycles with Malonates
journal, July 2010
- Furst, Laura; Matsuura, Bryan S.; Narayanam, Jagan M. R.
- Organic Letters, Vol. 12, Issue 13
Photocatalysis in organic and polymer synthesis
journal, January 2016
- Corrigan, Nathaniel; Shanmugam, Sivaprakash; Xu, Jiangtao
- Chemical Society Reviews, Vol. 45, Issue 22
Organocatalyzed Atom Transfer Radical Polymerization Using N -Aryl Phenoxazines as Photoredox Catalysts
journal, August 2016
- Pearson, Ryan M.; Lim, Chern-Hooi; McCarthy, Blaine G.
- Journal of the American Chemical Society, Vol. 138, Issue 35
On the constitution of murrayanine, a carbazole derivative isolated from Murraya koenigii Spreng
journal, January 1965
- Chakraborty, D. P.; Barman, B. K.; Bose, P. K.
- Tetrahedron, Vol. 21, Issue 2
A cyanobenzo[a]phenoxazine-based near infrared lysosome-tracker for in cellulo imaging
journal, January 2013
- Sun, Ru; Liu, Wu; Xu, Yu-Jie
- Chemical Communications, Vol. 49, Issue 91
Red-Light-Induced Cationic Photopolymerization: Perylene Derivatives as Efficient Photoinitiators
journal, August 2013
- Xiao, Pu; Dumur, Frédéric; Graff, Bernadette
- Macromolecular Rapid Communications, Vol. 34, Issue 18
Toward a Rational Design of Poly(2,7-Carbazole) Derivatives for Solar Cells
journal, January 2008
- Blouin, Nicolas; Michaud, Alexandre; Gendron, David
- Journal of the American Chemical Society, Vol. 130, Issue 2, p. 732-742
Copper-Mediated Living Radical Polymerization (Atom Transfer Radical Polymerization and Copper(0) Mediated Polymerization): From Fundamentals to Bioapplications
journal, November 2015
- Boyer, Cyrille; Corrigan, Nathaniel Alan; Jung, Kenward
- Chemical Reviews, Vol. 116, Issue 4
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
journal, March 2016
- Chen, Mao; Zhong, Mingjiang; Johnson, Jeremiah A.
- Chemical Reviews, Vol. 116, Issue 17
Advances in RAFT polymerization: the synthesis of polymers with defined end-groups
journal, September 2005
- Moad, Graeme; Chong, Y. K.; Postma, Almar
- Polymer, Vol. 46, Issue 19
Solution-Processable Field-Effect Transistors Fabricated Using Aryl Phenoxazine Based Polymers as the Active Layer
journal, October 2009
- Yoon, Hye-Seon; Lee, Woo-Hyung; Lee, Ji-Hoon
- Bulletin of the Korean Chemical Society, Vol. 30, Issue 10, p. 2371-2376
Cellular penetration and antisense activity by a phenoxazine-substituted heptanucleotide
journal, January 1999
- Flanagan, W. Michael; Wagner, Richard W.; Grant, Deborah
- Nature Biotechnology, Vol. 17, Issue 1
Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst
journal, July 2012
- Mosnáček, Jaroslav; Ilčíková, Markéta
- Macromolecules, Vol. 45, Issue 15
Molecular engineering of small molecules donor materials based on phenoxazine core unit for solution-processed organic solar cells
journal, January 2014
- Cheng, Ming; Yang, Xichuan; Chen, Cheng
- J. Mater. Chem. A, Vol. 2, Issue 27
Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence
journal, March 2014
- Zhang, Qisheng; Li, Bo; Huang, Shuping
- Nature Photonics, Vol. 8, Issue 4
Discovery of Novel Benzo[ a ]phenoxazine SSJ-183 as a Drug Candidate for Malaria
journal, July 2010
- Ge, Jian-Feng; Arai, Chika; Yang, Mei
- ACS Medicinal Chemistry Letters, Vol. 1, Issue 7
Shining Light on Photoredox Catalysis: Theory and Synthetic Applications
journal, January 2012
- Tucker, Joseph W.; Stephenson, Corey R. J.
- The Journal of Organic Chemistry, Vol. 77, Issue 4
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
journal, December 2001
- Hawker, Craig J.; Bosman, Anton W.; Harth, Eva
- Chemical Reviews, Vol. 101, Issue 12
Photoinitiators based on a phenazine scaffold: High performance systems upon near-UV or visible LED (385, 395 and 405 nm) irradiations
journal, May 2014
- Tehfe, Mohamad-Ali; Dumur, Frédéric; Xiao, Pu
- Polymer, Vol. 55, Issue 10
Visible-Light Organic Photocatalysis for Latent Radical-Initiated Polymerization via 2e – /1H + Transfers: Initiation with Parallels to Photosynthesis
journal, May 2014
- Aguirre-Soto, Alan; Lim, Chern-Hooi; Hwang, Albert T.
- Journal of the American Chemical Society, Vol. 136, Issue 20
Differences in electron densities of phenoxazine and phenothiazine derivatives—charge density studies
journal, January 2012
- Malińska, Maura; Nowacki, Jacek; Kapturkiewicz, Andrzej
- RSC Advances, Vol. 2, Issue 10
Phenothiazine photosensitizers for onium salt photoinitiated cationic polymerization
journal, January 2001
- Gomurashvili, Zaza; Crivello, James V.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 39, Issue 8
Photochemistry and Photophysics of Coordination Compounds: Iridium
book, January 2007
- Flamigni, Lucia; Barbieri, Andrea; Sabatini, Cristiana
- Photochemistry and Photophysics of Coordination Compounds II
Perylene-3,4,9,10-tetracarboxylic Acid Diimides: Synthesis, Physical Properties, and Use in Organic Electronics
journal, April 2011
- Huang, Chun; Barlow, Stephen; Marder, Seth R.
- The Journal of Organic Chemistry, Vol. 76, Issue 8
Effect of side-chain positions on morphology and photovoltaic properties of phenazine-based donor-acceptor copolymers
journal, April 2013
- Li, Ying; Fu, Yingying; Tong, Hui
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 51, Issue 13
Synthesis, characterisation and antimicrobial activity of new benzo[a]phenoxazine based fluorophores
journal, November 2007
- Frade, Vânia H. J.; Sousa, Maria J.; Moura, João C. V. P.
- Tetrahedron Letters, Vol. 48, Issue 47
Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts
journal, March 2011
- Nguyen, John D.; Tucker, Joseph W.; Konieczynska, Marlena D.
- Journal of the American Chemical Society, Vol. 133, Issue 12
Modifying organic phenoxazine dyes for efficient dye-sensitized solar cells
journal, January 2011
- Tian, Haining; Bora, Ilkay; Jiang, Xiao
- Journal of Materials Chemistry, Vol. 21, Issue 33
A Stable Radical-Substituted Radical Cation with Strongly Ferromagnetic Interaction: Nitronyl Nitroxide-Substituted 5,10-Diphenyl-5,10-dihydrophenazine Radical Cation
journal, January 2004
- Hiraoka, Shinsuke; Okamoto, Toshihiro; Kozaki, Masatoshi
- Journal of the American Chemical Society, Vol. 126, Issue 1
Simple Benchtop Approach to Polymer Brush Nanostructures Using Visible-Light-Mediated Metal-Free Atom Transfer Radical Polymerization
journal, January 2016
- Discekici, Emre H.; Pester, Christian W.; Treat, Nicolas J.
- ACS Macro Letters, Vol. 5, Issue 2
Phenothiazine-functionalized redox polymers for a new cathode-active material
journal, January 2015
- Golriz, Ali A.; Suga, Takeo; Nishide, Hiroyuki
- RSC Advances, Vol. 5, Issue 29
Synthesis of Carbazoles and Dibenzofurans via Cross-Coupling of o -Iodoanilines and o -Iodophenols with Silylaryl Triflates
journal, October 2004
- Liu, Zhijian; Larock, Richard C.
- Organic Letters, Vol. 6, Issue 21
Rylene and Related Diimides for Organic Electronics
journal, December 2010
- Zhan, Xiaowei; Facchetti, Antonio; Barlow, Stephen
- Advanced Materials, Vol. 23, Issue 2, p. 268-284
Functional polymers by atom transfer radical polymerization
journal, April 2001
- Coessens, Veerle; Pintauer, Tomislav; Matyjaszewski, Krzysztof
- Progress in Polymer Science, Vol. 26, Issue 3
Emission properties of aromatic amines in solution. Phenoxazine system
journal, May 1972
- Huber, J. Robert; Mantulin, W. W.
- Journal of the American Chemical Society, Vol. 94, Issue 11
Controlled Radical Polymerization of Acrylates Regulated by Visible Light
journal, May 2014
- Treat, Nicolas J.; Fors, Brett P.; Kramer, John W.
- ACS Macro Letters, Vol. 3, Issue 6
Spectroscopic studies of electron donor properties and radical cations of phenothiazine derivatives
journal, February 1975
- Dwivedi, P. C.; Rao, K. Gurudath; Bhat, S. N.
- Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 31, Issue 2
Intramolecular Radiative and Radiationless Charge Recombination Processes in Donor−Acceptor Carbazole Derivatives
journal, March 1997
- Kapturkiewicz, Andrzej; Herbich, Jerzy; Karpiuk, Jerzy
- The Journal of Physical Chemistry A, Vol. 101, Issue 12
Synthesis, Physical Properties, and Light-Emitting Diode Performance of Phenazine-Based Derivatives with Three, Five, and Nine Fused Six-Membered Rings
journal, February 2015
- Gu, Pei-Yang; Zhao, Yongbiao; He, Jing-Hui
- The Journal of Organic Chemistry, Vol. 80, Issue 6
Light-Emitting Carbazole Derivatives: Potential Electroluminescent Materials
journal, September 2001
- Justin Thomas, K. R.; Lin, Jiann T.; Tao, Yu-Tai
- Journal of the American Chemical Society, Vol. 123, Issue 38
Studies on Photoinduced ATRP in the Presence of Photoinitiator
journal, July 2011
- Tasdelen, Mehmet Atilla; Uygun, Mustafa; Yagci, Yusuf
- Macromolecular Chemistry and Physics, Vol. 212, Issue 18
Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst
journal, September 2012
- Konkolewicz, Dominik; Schröder, Kristin; Buback, Johannes
- ACS Macro Letters, Vol. 1, Issue 10
Synthesis and properties of perylene pigments
journal, May 1997
- Nagao, Yukinori
- Progress in Organic Coatings, Vol. 31, Issue 1-2
Atom Transfer Radical Polymerization
journal, September 2001
- Matyjaszewski, Krzysztof; Xia, Jianhui
- Chemical Reviews, Vol. 101, Issue 9
Transition Metal Complexes in Organic Synthesis, Part 70&#. Synthesis of Biologically Active Carbazole Alkaloids Using Organometallic Chemistry
journal, October 2004
- Knolker, Hans-Joachim
- Current Organic Synthesis, Vol. 1, Issue 4
Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp 3 )–C(sp 2 ) Cross-Coupling
journal, January 2016
- Luo, Jian; Zhang, Jian
- ACS Catalysis, Vol. 6, Issue 2
Highly Efficient New Hole Injection Materials for OLEDs Based on Dimeric Phenothiazine and Phenoxazine Derivatives
journal, February 2011
- Park, Youngil; Kim, Beomjin; Lee, Changjun
- The Journal of Physical Chemistry C, Vol. 115, Issue 11
Indolo[3,2- b ]carbazole-Based Thin-Film Transistors with High Mobility and Stability
journal, January 2005
- Wu, Yiliang; Li, Yuning; Gardner, Sandra
- Journal of the American Chemical Society, Vol. 127, Issue 2
Synthesis of Thiol-Reactive, Long-Wavelength Fluorescent Phenoxazine Derivatives for Biosensor Applications
journal, March 2006
- Sherman, Douglas B.; Pitner, J. Bruce; Ambroise, Arounaguiry
- Bioconjugate Chemistry, Vol. 17, Issue 2
Recent Advances in the Chemistry of 9H-Carbazoles
book, January 1984
- Joule, John A.
- Advances in Heterocyclic Chemistry
Controlled/living radical polymerization: Features, developments, and perspectives
journal, January 2007
- Braunecker, Wade A.; Matyjaszewski, Krzysztof
- Progress in Polymer Science, Vol. 32, Issue 1
Visible-Light-Controlled Living Radical Polymerization from a Trithiocarbonate Iniferter Mediated by an Organic Photoredox Catalyst
journal, April 2015
- Chen, Mao; MacLeod, Michelle J.; Johnson, Jeremiah A.
- ACS Macro Letters, Vol. 4, Issue 5
Poly(2,7-carbazole) and perylene tetracarboxydiimide: a promising donor/acceptor pair for polymer solar cells
journal, January 2006
- Li, Jiaoli; Dierschke, Frank; Wu, Jishan
- J. Mater. Chem., Vol. 16, Issue 1
Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence
journal, March 1988
- Juris, A.; Balzani, V.; Barigelletti, F.
- Coordination Chemistry Reviews, Vol. 84
Steady-State and Time-Resolved Studies on Photoinduced Interaction of Phenothiazine and 10-Methylphenothiazine with Chloroalkanes
journal, July 1998
- Nath, Sukhendu; Pal, Haridas; Palit, Dipak K.
- The Journal of Physical Chemistry A, Vol. 102, Issue 29
Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
journal, November 2014
- Miyake, Garret M.; Theriot, Jordan C.
- Macromolecules, Vol. 47, Issue 23
A study on the laser flash photolysis of phenothiazine and its N-alkyl derivatives
journal, January 1996
- Guo, Qing-Xiang; Liang, Zhao-Xun; Liu, Bo
- Journal of Photochemistry and Photobiology A: Chemistry, Vol. 93, Issue 1
Rethinking 'secondary' metabolism: physiological roles for phenazine antibiotics
journal, January 2006
- Price-Whelan, Alexa; Dietrich, Lars E. P.; Newman, Dianne K.
- Nature Chemical Biology, Vol. 2, Issue 2
The photophysics of photoredox catalysis: a roadmap for catalyst design
journal, January 2016
- Arias-Rotondo, Daniela M.; McCusker, James K.
- Chemical Society Reviews, Vol. 45, Issue 21
Metal-Free Photocatalytic Radical Trifluoromethylation Utilizing Methylene Blue and Visible Light Irradiation
journal, July 2014
- Pitre, Spencer P.; McTiernan, Christopher D.; Ismaili, Hossein
- ACS Catalysis, Vol. 4, Issue 8
Update and challenges in organo-mediated polymerization reactions
journal, May 2016
- Ottou, Winnie Nzahou; Sardon, Haritz; Mecerreyes, David
- Progress in Polymer Science, Vol. 56
Redox-Active Antibiotics Control Gene Expression and Community Behavior in Divergent Bacteria
journal, August 2008
- Dietrich, L. E. P.; Teal, T. K.; Price-Whelan, A.
- Science, Vol. 321, Issue 5893
Preparation and magnetic properties of verdazyl-substituted dihydrophenazine radical cation tetrachloroferrate salts
journal, June 2009
- Masuda, Yuki; Kuratsu, Masato; Suzuki, Shuichi
- Polyhedron, Vol. 28, Issue 9-10
1,4-Benzoxazino[2,3- b ]phenoxazine and Its Sulfur Analogues: Synthesis, Properties, and Application to Organic Light-Emitting Diodes
journal, November 2005
- Okamoto, Toshihiro; Kozaki, Masatoshi; Doe, Matsumi
- Chemistry of Materials, Vol. 17, Issue 22
Free Radical Polymerization Initiated and Controlled by Visible Light Photocatalysis at Ambient Temperature
journal, October 2011
- Zhang, Guan; Song, In Young; Ahn, Kyo Han
- Macromolecules, Vol. 44, Issue 19
Photochemistry of phenoxazine. Flash-photolytic study
journal, August 1970
- Gegiou, Dina.; Huber, J. Robert.; Weiss, Karl.
- Journal of the American Chemical Society, Vol. 92, Issue 17
Organic Photoredox Catalysis
journal, June 2016
- Romero, Nathan A.; Nicewicz, David A.
- Chemical Reviews, Vol. 116, Issue 17
Chemoselective Radical Dehalogenation and C–C Bond Formation on Aryl Halide Substrates Using Organic Photoredox Catalysts
journal, June 2016
- Poelma, Saemi O.; Burnett, G. Leslie; Discekici, Emre H.
- The Journal of Organic Chemistry, Vol. 81, Issue 16
Phenazine Compounds in Fluorescent Pseudomonas Spp. Biosynthesis and Regulation
journal, September 2006
- Mavrodi, Dmitri V.; Blankenfeldt, Wulf; Thomashow, Linda S.
- Annual Review of Phytopathology, Vol. 44, Issue 1
Electrochemical and ab initio investigations to design a new phenothiazine based organic redox polymeric material for metal-ion battery cathodes
journal, January 2015
- Godet-Bar, T.; Leprêtre, J. -C.; Le Bacq, O.
- Phys. Chem. Chem. Phys., Vol. 17, Issue 38
Metal-Free Atom Transfer Radical Polymerization
journal, October 2014
- Treat, Nicolas J.; Sprafke, Hazel; Kramer, John W.
- Journal of the American Chemical Society, Vol. 136, Issue 45
New Ambipolar Organic Semiconductors. 1. Synthesis, Single-Crystal Structures, Redox Properties, and Photophysics of Phenoxazine-Based Donor−Acceptor Molecules
journal, July 2008
- Zhu, Yan; Kulkarni, Abhishek P.; Wu, Pei-Tzu
- Chemistry of Materials, Vol. 20, Issue 13
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
journal, March 2013
- Prier, Christopher K.; Rankic, Danica A.; MacMillan, David W. C.
- Chemical Reviews, Vol. 113, Issue 7
Quenching mechanism in a highly exothermic region of the Rehm-Weller relationship for electron-transfer fluorescence quenching
journal, May 1993
- Kikuchi, Koichi; Niwa, Taeko; Takahashi, Yasutake
- The Journal of Physical Chemistry, Vol. 97, Issue 19
Carbazole Compounds as Host Materials for Triplet Emitters in Organic Light-Emitting Diodes: Tuning the HOMO Level without Influencing the Triplet Energy in Small Molecules
journal, May 2004
- Brunner, Klemens; van Dijken, Addy; Börner, Herbert
- Journal of the American Chemical Society, Vol. 126, Issue 19
A TDDFT study of the lowest excitation energies of polycyclic aromatic hydrocarbons
journal, July 2003
- Parac, Maja; Grimme, Stefan
- Chemical Physics, Vol. 292, Issue 1
Excited State Behavior of Aromatic Amines in Solution: Dihydrophenazine Derivatives
journal, December 1974
- Morris, J. V.; Brühlmann, U.; Serafimov, O.
- Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 78, Issue 12
Venezuelines A–G, new phenoxazine-based alkaloids and aminophenols from Streptomyces venezuelae and the regulation of gene target Nur77
journal, January 2013
- Ren, Jinwei; Liu, Dong; Tian, Li
- Bioorganic & Medicinal Chemistry Letters, Vol. 23, Issue 1
Novel hole transport materials based on N,N′-disubstituted-dihydrophenazine derivatives for electroluminescent diodes
journal, January 2014
- Zheng, Zhiwen; Dong, Qingchen; Gou, Liao
- J. Mater. Chem. C, Vol. 2, Issue 46
Phenoxazine-Based Conjugated Polymers: A New Class of Organic Semiconductors for Field-Effect Transistors
journal, September 2005
- Zhu, Yan; Babel, Amit; Jenekhe, Samson A.
- Macromolecules, Vol. 38, Issue 19
The Cation Radical Salts of Phenothiazine and Related Compounds
journal, March 1971
- Iida, Yôichi
- Bulletin of the Chemical Society of Japan, Vol. 44, Issue 3
Enlightening the Mechanism of Copper Mediated PhotoRDRP via High-Resolution Mass Spectrometry
journal, May 2015
- Frick, Elena; Anastasaki, Athina; Haddleton, David M.
- Journal of the American Chemical Society, Vol. 137, Issue 21
A review of airborne polycyclic aromatic hydrocarbons (PAHs) and their human health effects
journal, October 2013
- Kim, Ki-Hyun; Jahan, Shamin Ara; Kabir, Ehsanul
- Environment International, Vol. 60
Cation radicals of dihydrophenazine and its derivatives
journal, January 1972
- Gordienko, L. L.; Chukhlantseva, A. G.
- Theoretical and Experimental Chemistry, Vol. 5, Issue 6
Control of a Living Radical Polymerization of Methacrylates by Light
journal, July 2012
- Fors, Brett P.; Hawker, Craig J.
- Angewandte Chemie International Edition, Vol. 51, Issue 35
Tunable Organophotocatalysts for Polymerization Reactions Under Visible Lights.
journal, February 2012
- Tehfe, Mohamad-Ali; Lalevée, Jacques; Morlet-Savary, Fabrice
- Macromolecules, Vol. 45, Issue 4
Synthesis, optical properties and charge transport characteristics of a series of novel thiophene-fused phenazine derivatives
journal, January 2013
- Xie, Yongfa; Fujimoto, Takuya; Dalgleish, Simon
- Journal of Materials Chemistry C, Vol. 1, Issue 21
Thermally Activated Delayed Fluorescence Materials Towards the Breakthrough of Organoelectronics
journal, September 2014
- Tao, Ye; Yuan, Kai; Chen, Ting
- Advanced Materials, Vol. 26, Issue 47
Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids
journal, March 2012
- Schmidt, Arndt W.; Reddy, Kethiri R.; Knölker, Hans-Joachim
- Chemical Reviews, Vol. 112, Issue 6
Electrogenerated Chemiluminescence of Donor-Acceptor Molecules with Thermally Activated Delayed Fluorescence
journal, May 2014
- Ishimatsu, Ryoichi; Matsunami, Shigeyuki; Kasahara, Takashi
- Angewandte Chemie International Edition, Vol. 53, Issue 27
Phenothiazine derivatives for efficient organic dye-sensitized solar cells
journal, January 2007
- Tian, Haining; Yang, Xichuan; Chen, Ruikui
- Chemical Communications, Issue 36
A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations
journal, January 2015
- Discekici, Emre H.; Treat, Nicolas J.; Poelma, Saemi O.
- Chemical Communications, Vol. 51, Issue 58
Pd-Catalyzed Intramolecular Oxidative C–H Amination: Synthesis of Carbazoles
journal, July 2011
- Youn, So Won; Bihn, Joon Hyung; Kim, Byung Seok
- Organic Letters, Vol. 13, Issue 14
Photosensitized cationic polymerization using allyl sulfonium salt
journal, April 1996
- Denizligil, Selcuk; Resul, Rezan; Yagci, Yusuf
- Macromolecular Chemistry and Physics, Vol. 197, Issue 4
The Chemistry of Phenothiazine.
journal, October 1954
- Massie, Samuel P.
- Chemical Reviews, Vol. 54, Issue 5
Nitroxide-mediated polymerization
journal, January 2013
- Nicolas, Julien; Guillaneuf, Yohann; Lefay, Catherine
- Progress in Polymer Science, Vol. 38, Issue 1
Organocatalyzed atom transfer radical polymerization driven by visible light
journal, March 2016
- Theriot, J. C.; Lim, C. -H.; Yang, H.
- Science, Vol. 352, Issue 6289
Metal and metal-free photocatalysts: mechanistic approach and application as photoinitiators of photopolymerization
journal, January 2014
- Lalevée, Jacques; Telitel, Sofia; Xiao, Pu
- Beilstein Journal of Organic Chemistry, Vol. 10
A comparative study on properties of two phenoxazine-based dyes for dye-sensitized solar cells
journal, February 2014
- Tan, Haijun; Pan, Chunyue; Wang, Gang
- Dyes and Pigments, Vol. 101
Highly efficient organic light-emitting diodes from delayed fluorescence
journal, December 2012
- Uoyama, Hiroki; Goushi, Kenichi; Shizu, Katsuyuki
- Nature, Vol. 492, Issue 7428
The effects of the number of anchoring groups and N-substitution on the performance of phenoxazine dyes in dye-sensitized solar cells
journal, March 2014
- Lee, Woosung; Yuk, Sim Bum; Choi, Jun
- Dyes and Pigments, Vol. 102
Organic photocatalysts for cleaner polymer synthesis
journal, May 2016
- Shanmugam, S.; Boyer, C.
- Science, Vol. 352, Issue 6289
Tailoring Excited-State Properties and Electroluminescence Performance of Donor–Acceptor Molecules through Tuning the Energy Level of the Charge-Transfer State
journal, July 2015
- Yao, Liang; Pan, Yuyu; Tang, Xiangyang
- The Journal of Physical Chemistry C, Vol. 119, Issue 31
Electron transfer reactions in chemistry. Theory and experiment
journal, July 1993
- Marcus, Rudolph A.
- Reviews of Modern Physics, Vol. 65, Issue 3, p. 599-610
Organic Catalysts for Photocontrolled Polymerizations
journal, January 2016
- Trotta, Jacob; Fors, Brett
- Synlett, Vol. 27, Issue 05
Intramolecular Charge Transfer and Ion Pairing in N,N -Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization
journal, December 2016
- Lim, Chern-Hooi; Ryan, Matthew D.; McCarthy, Blaine G.
- Journal of the American Chemical Society, Vol. 139, Issue 1
Phenazine Natural Products: Biosynthesis, Synthetic Analogues, and Biological Activity
journal, March 2004
- Laursen, Jane Buus; Nielsen, John
- Chemical Reviews, Vol. 104, Issue 3
Some Derivatives of Phenothiazine
journal, June 1944
- Gilman, Henry; Shirley, David A.
- Journal of the American Chemical Society, Vol. 66, Issue 6
The active role of excited states of phenothiazines in photoinduced metal free atom transfer radical polymerization: singlet or triplet excited states?
journal, January 2016
- Jockusch, Steffen; Yagci, Yusuf
- Polymer Chemistry, Vol. 7, Issue 39
Surface modification of nanodiamond through metal free atom transfer radical polymerization
journal, December 2016
- Zeng, Guangjian; Liu, Meiying; Shi, Kexin
- Applied Surface Science, Vol. 390
Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes
journal, May 2015
- Bachman, John C.; Kavian, Reza; Graham, Daniel J.
- Nature Communications, Vol. 6, Issue 1
Tuning of phenoxazine chromophores for efficient organic dye-sensitized solar cells
journal, January 2009
- Tian, Haining; Yang, Xichuan; Cong, Jiayan
- Chemical Communications, Issue 41
New core-pyrene π structure organophotocatalysts usable as highly efficient photoinitiators
journal, January 2013
- Telitel, Sofia; Dumur, Frédéric; Faury, Thomas
- Beilstein Journal of Organic Chemistry, Vol. 9
Metal-free photoinduced electron transfer–atom transfer radical polymerization (PET–ATRP) via a visible light organic photocatalyst
journal, January 2016
- Liu, Xiaodong; Zhang, Lifen; Cheng, Zhenping
- Polymer Chemistry, Vol. 7, Issue 3
Synthesis and applications of core-enlarged perylene dyes
journal, January 2010
- Avlasevich, Yuri; Li, Chen; Müllen, Klaus
- Journal of Materials Chemistry, Vol. 20, Issue 19
Efficient and stable dye-sensitized solar cells based on phenothiazine sensitizers with thiophene units
journal, January 2010
- Wu, Wenjun; Yang, Jiabao; Hua, Jianli
- Journal of Materials Chemistry, Vol. 20, Issue 9
Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies
journal, February 2016
- Pan, Xiangcheng; Fang, Cheng; Fantin, Marco
- Journal of the American Chemical Society, Vol. 138, Issue 7
Photoinitiated Metal-Free Controlled/Living Radical Polymerization Using Polynuclear Aromatic Hydrocarbons
journal, October 2016
- Allushi, Andrit; Jockusch, Steffen; Yilmaz, Gorkem
- Macromolecules, Vol. 49, Issue 20
Donor–acceptor copolymers based on benzo[1,2- b :4,5- b ′]dithiophene and pyrene-fused phenazine for high-performance polymer solar cells
journal, November 2014
- Fan, Qunping; Liu, Yu; Xiao, Manjun
- Organic Electronics, Vol. 15, Issue 11
The Preparation of Some 10-Substituted Phenoxazines 1
journal, July 1957
- Gilman, Henry; Moore, Leonard O.
- Journal of the American Chemical Society, Vol. 79, Issue 13
Transition Metal-Catalyzed Living Radical Polymerization: Toward Perfection in Catalysis and Precision Polymer Synthesis
journal, November 2009
- Ouchi, Makoto; Terashima, Takaya; Sawamoto, Mitsuo
- Chemical Reviews, Vol. 109, Issue 11
From Industrial Colorants to Single Photon Sources and Biolabels: The Fascination and Function of Rylene Dyes
journal, September 2006
- Herrmann, Andreas; Müllen, Klaus
- Chemistry Letters, Vol. 35, Issue 9
Photoinduced Metal-Free Atom Transfer Radical Polymerization of Biomass-Based Monomers
journal, October 2016
- Wang, Jifu; Yuan, Liang; Wang, Zhongkai
- Macromolecules, Vol. 49, Issue 20
A Remarkable Visible Light Effect on Atom-Transfer Radical Polymerization †
journal, September 2000
- Guan, Zhibin; Smart, Bruce
- Macromolecules, Vol. 33, Issue 18
Visible Light-Induced Atom Transfer Radical Polymerization
journal, May 2012
- Tasdelen, Mehmet Atilla; Ciftci, Mustafa; Yagci, Yusuf
- Macromolecular Chemistry and Physics, Vol. 213, Issue 13
Triplet Sensitized Red-to-Blue Photon Upconversion
journal, November 2009
- Singh-Rachford, Tanya N.; Castellano, Felix N.
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 1
Phenoxazine-based organic dyes with different chromophores for dye-sensitized solar cells
journal, November 2013
- Tan, Haijun; Pan, Chunyue; Wang, Gang
- Organic Electronics, Vol. 14, Issue 11
Radical addition–fragmentation chemistry in polymer synthesis
journal, March 2008
- Moad, Graeme; Rizzardo, Ezio; Thang, San H.
- Polymer, Vol. 49, Issue 5
Photocatalysts in Polymerization Reactions
journal, April 2016
- Zivic, Nicolas; Bouzrati-Zerelli, Mariem; Kermagoret, Anthony
- ChemCatChem, Vol. 8, Issue 9
Interstellar Polycyclic Aromatic Hydrocarbon Molecules
journal, September 2008
- Tielens, A. G. G. M.
- Annual Review of Astronomy and Astrophysics, Vol. 46, Issue 1
The photovoltaic effect in a poly(p-phenylenevinylene)/perylene heterojunction
journal, March 1997
- Halls, J. J. M.; Friend, R. H.
- Synthetic Metals, Vol. 85, Issue 1-3, p. 1307-1308
Visible light photoredox catalysis: applications in organic synthesis
journal, January 2011
- Narayanam, Jagan M. R.; Stephenson, Corey R. J.
- Chem. Soc. Rev., Vol. 40, Issue 1
Visible light photocatalysis as a greener approach to photochemical synthesis
journal, June 2010
- Yoon, Tehshik P.; Ischay, Michael A.; Du, Juana
- Nature Chemistry, Vol. 2, Issue 7