Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis
Abstract
Water electrolysis can delay the operation of capacitive deionization (CDI) and membrane CDI (MCDI). Here, we investigate the overpotential limits of CDI and MCDI (OP-MCDI) for water electrolysis and desalination performance. For sodium chloride concentrations of ~28,460 ppm, MCDI with mesoporous carbon electrodes could be operated at up to 2.4 V without water electrolysis, and the salt-adsorption capacity of the OP-MCDI system at 2.4 V was about two times greater than that of the MCDI at 1.2 V. This study offers an opportunity to extend the applicability of conventional CDI and MCDI systems for desalination of low-salinity solutions.
- Authors:
-
[2];
[7]
- Georgia Inst. of Technology, Atlanta, GA (United States); Louisiana State Univ., Baton Rouge, LA (United States)
- Georgia Inst. of Technology, Atlanta, GA (United States); Tianjin Polytechnic Univ., (China); Chinese Academy of Sciences (CAS), Beijing (China)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Indian Institute of Technology Gandhinagar, Gujarat (India)
- Georgia Inst. of Technology, Atlanta, GA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Georgia Inst. of Technology, Atlanta, GA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1531237
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Separation Science and Technology
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 13; Journal ID: ISSN 0149-6395
- Publisher:
- Taylor & Francis
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Electrosorption; Capacitive deionization; Membrane capacitive deionization; Desalination; Overpotential membrane capacitive deionization
Citation Formats
Kim, Yong Ha, Tang, K., Chang, J., Sharma, K., Yiacoumi, S., Mayes, R. T., Bilheux, H. Z., Santodonato, L. J., and Tsouris, C. Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis. United States: N. p., 2019.
Web. doi:10.1080/01496395.2019.1608243.
Kim, Yong Ha, Tang, K., Chang, J., Sharma, K., Yiacoumi, S., Mayes, R. T., Bilheux, H. Z., Santodonato, L. J., & Tsouris, C. Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis. United States. https://doi.org/10.1080/01496395.2019.1608243
Kim, Yong Ha, Tang, K., Chang, J., Sharma, K., Yiacoumi, S., Mayes, R. T., Bilheux, H. Z., Santodonato, L. J., and Tsouris, C. Wed .
"Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis". United States. https://doi.org/10.1080/01496395.2019.1608243. https://www.osti.gov/servlets/purl/1531237.
@article{osti_1531237,
title = {Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis},
author = {Kim, Yong Ha and Tang, K. and Chang, J. and Sharma, K. and Yiacoumi, S. and Mayes, R. T. and Bilheux, H. Z. and Santodonato, L. J. and Tsouris, C.},
abstractNote = {Water electrolysis can delay the operation of capacitive deionization (CDI) and membrane CDI (MCDI). Here, we investigate the overpotential limits of CDI and MCDI (OP-MCDI) for water electrolysis and desalination performance. For sodium chloride concentrations of ~28,460 ppm, MCDI with mesoporous carbon electrodes could be operated at up to 2.4 V without water electrolysis, and the salt-adsorption capacity of the OP-MCDI system at 2.4 V was about two times greater than that of the MCDI at 1.2 V. This study offers an opportunity to extend the applicability of conventional CDI and MCDI systems for desalination of low-salinity solutions.},
doi = {10.1080/01496395.2019.1608243},
journal = {Separation Science and Technology},
number = 13,
volume = 54,
place = {United States},
year = {Wed May 08 00:00:00 EDT 2019},
month = {Wed May 08 00:00:00 EDT 2019}
}
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Works referenced in this record:
Water scarcity: Fact or fiction?
journal, February 2006
- Rijsberman, Frank R.
- Agricultural Water Management, Vol. 80, Issue 1-3
A Multiscalar Drought Index Sensitive to Global Warming: The Standardized Precipitation Evapotranspiration Index
journal, April 2010
- Vicente-Serrano, Sergio M.; Beguería, Santiago; López-Moreno, Juan I.
- Journal of Climate, Vol. 23, Issue 7
Reverse Osmosis Biofilm Dispersal by Osmotic Back-Flushing: Cleaning via Substratum Perforation
journal, December 2013
- Bar-Zeev, Edo; Elimelech, Menachem
- Environmental Science & Technology Letters, Vol. 1, Issue 2
Capacitive deionization as an electrochemical means of saving energy and delivering clean water. Comparison to present desalination practices: Will it compete?
journal, April 2010
- Anderson, Marc A.; Cudero, Ana L.; Palma, Jesus
- Electrochimica Acta, Vol. 55, Issue 12
Energy Issues in Desalination Processes
journal, November 2008
- Semiat, Raphael
- Environmental Science & Technology, Vol. 42, Issue 22
Transport of Ions in Mesoporous Carbon Electrodes during Capacitive Deionization of High-Salinity Solutions
journal, July 2014
- Sharma, K.; Kim, Y. -H.; Gabitto, J.
- Langmuir, Vol. 31, Issue 3
Modular Chemical Process Intensification: A Review
journal, June 2017
- Kim, Yong-ha; Park, Lydia K.; Yiacoumi, Sotira
- Annual Review of Chemical and Biomolecular Engineering, Vol. 8, Issue 1
Capacitive Deionization Technology™: An alternative desalination solution
journal, November 2005
- Welgemoed, T. J.; Schutte, C. F.
- Desalination, Vol. 183, Issue 1-3
Enhanced desalination efficiency in capacitive deionization with an ion-selective membrane
journal, January 2010
- Kim, Yu-Jin; Choi, Jae-Hwan
- Separation and Purification Technology, Vol. 71, Issue 1
Mesoporous Carbon for Capacitive Deionization of Saline Water
journal, December 2011
- Tsouris, C.; Mayes, R.; Kiggans, J.
- Environmental Science & Technology, Vol. 45, Issue 23
3D porous graphene with ultrahigh surface area for microscale capacitive deionization
journal, January 2015
- Li, Zhuo; Song, Bo; Wu, Zhenkun
- Nano Energy, Vol. 11
Capacitive deionization (CDI) for desalination and water treatment — past, present and future (a review)
journal, August 2008
- Oren, Yoram
- Desalination, Vol. 228, Issue 1-3
Desalination of a thermal power plant wastewater by membrane capacitive deionization
journal, September 2006
- Lee, Jae-Bong; Park, Kwang-Kyu; Eum, Hee-Moon
- Desalination, Vol. 196, Issue 1-3
Capacitive Deionization of NaCl and NaNO[sub 3] Solutions with Carbon Aerogel Electrodes
journal, January 1996
- Farmer, Joseph C.
- Journal of The Electrochemical Society, Vol. 143, Issue 1
Electrosorption behavior of graphene in NaCl solutions
journal, January 2009
- Li, Haibo; Lu, Ting; Pan, Likun
- Journal of Materials Chemistry, Vol. 19, Issue 37
Using graphene nano-flakes as electrodes to remove ferric ions by capacitive deionization
journal, September 2010
- Li, Haibo; Zou, Linda; Pan, Likun
- Separation and Purification Technology, Vol. 75, Issue 1
Faradaic Reactions in Water Desalination by Batch-Mode Capacitive Deionization
journal, May 2016
- He, Di; Wong, Chi Eng; Tang, Wangwang
- Environmental Science & Technology Letters, Vol. 3, Issue 5
Capacitive deionization characteristics of nanostructured carbon aerogel electrodes synthesized via ambient drying
journal, October 2007
- Jung, Hae-Hyun; Hwang, Sung-Woo; Hyun, Sang-Hoon
- Desalination, Vol. 216, Issue 1-3, p. 377-385
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015
- Suo, L.; Borodin, O.; Gao, T.
- Science, Vol. 350, Issue 6263
Application of Capacitive Deionisation in water desalination: A review
journal, June 2014
- AlMarzooqi, Faisal A.; Al Ghaferi, Amal A.; Saadat, Irfan
- Desalination, Vol. 342
The bubble coverage of gas-evolving electrodes in stagnant electrolytes
journal, March 2005
- Vogt, H.; Balzer, R. J.
- Electrochimica Acta, Vol. 50, Issue 10
Review on the science and technology of water desalination by capacitive deionization
journal, October 2013
- Porada, S.; Zhao, R.; van der Wal, A.
- Progress in Materials Science, Vol. 58, Issue 8
Ultrahigh Desalinization Performance of Asymmetric Flow-Electrode Capacitive Deionization Device with an Improved Operation Voltage of 1.8 V
journal, December 2016
- Xu, Xingtao; Wang, Miao; Liu, Yong
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
Determination of the electrode potential causing Faradaic reactions in membrane capacitive deionization
journal, August 2014
- Choi, Jae-Hwan
- Desalination, Vol. 347
Enhanced capacitive deionization of graphene/mesoporous carbon composites
journal, January 2012
- Zhang, Dengsong; Wen, Xiaoru; Shi, Liyi
- Nanoscale, Vol. 4, Issue 17
Seawater desalination by over-potential membrane capacitive deionization: Opportunities and hurdles
journal, February 2019
- Tang, Kexin; Kim, Yong-ha; Chang, Junjun
- Chemical Engineering Journal, Vol. 357
Effective desalination by capacitive deionization with functional graphene nanocomposite as novel electrode material
journal, August 2012
- Wang, Zhuo; Dou, Baojuan; Zheng, Lu
- Desalination, Vol. 299
Modeling of advanced alkaline electrolyzers: a system simulation approach
journal, January 2003
- Ulleberg, O.
- International Journal of Hydrogen Energy, Vol. 28, Issue 1
Gas Evolution in Operating Lithium-Ion Batteries Studied In Situ by Neutron Imaging
journal, October 2015
- Michalak, Barbara; Sommer, Heino; Mannes, David
- Scientific Reports, Vol. 5, Issue 1
Neutron imaging of ion transport in mesoporous carbon materials
journal, January 2013
- Sharma, Ketki; Bilheux, Hassina Z.; Walker, Lakeisha M. H.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 28
Analysis and simulation of a blue energy cycle
journal, June 2016
- Sharma, K.; Kim, Y. -H.; Yiacoumi, S.
- Renewable Energy, Vol. 91
Neutron scattering lengths and cross sections
journal, January 1992
- Sears, Varley F.
- Neutron News, Vol. 3, Issue 3
iMARS (iMaging Analysis Research Software)
journal, January 2015
- Bilheux, Jean-Christophe; Bilheux, Hassina
- Physics Procedia, Vol. 69
A novel approach to determine post mortem interval using neutron radiography
journal, June 2015
- Bilheux, Hassina Z.; Cekanova, Maria; Vass, Arpad A.
- Forensic Science International, Vol. 251
Electrode reactions and adsorption/desorption performance related to the applied potential in a capacitive deionization process
journal, August 2010
- Lee, Jae-Hun; Bae, Wi-Sup; Choi, Jae-Hwan
- Desalination, Vol. 258, Issue 1-3
Comparison of Faradaic reactions in capacitive deionization (CDI) and membrane capacitive deionization (MCDI) water treatment processes
journal, September 2017
- Tang, Wangwang; He, Di; Zhang, Changyong
- Water Research, Vol. 120
Theory of pH changes in water desalination by capacitive deionization
journal, August 2017
- Dykstra, J. E.; Keesman, K. J.; Biesheuvel, P. M.
- Water Research, Vol. 119
On the solubility of sodium chloride in water
journal, December 1982
- Langer, H.; Offermann, H.
- Journal of Crystal Growth, Vol. 60, Issue 2
Current status of ion exchange membranes for power generation from salinity gradients
journal, July 2008
- Dlugolecki, P.; Nymeijer, K.; Metz, S.
- Journal of Membrane Science, Vol. 319, Issue 1-2
Attractive forces in microporous carbon electrodes for capacitive deionization
journal, February 2014
- Biesheuvel, P. M.; Porada, S.; Levi, M.
- Journal of Solid State Electrochemistry, Vol. 18, Issue 5
Parametric study for saline water electrolysis: Part II—Chlorine evolution, selectivity and determination
journal, July 1993
- Abdelaal, H.; Sultan, S.; Hussein, I.
- International Journal of Hydrogen Energy, Vol. 18, Issue 7
Electric field effects on proton transfer between ionizable groups and water in ion exchange membranes
journal, February 1984
- Simons, R.
- Electrochimica Acta, Vol. 29, Issue 2
Water splitting in ion exchange membranes
journal, March 1985
- Simons, R.
- Electrochimica Acta, Vol. 30, Issue 3
On the resistances of membrane, diffusion boundary layer and double layer in ion exchange membrane transport
journal, March 2010
- Długołęcki, Piotr; Ogonowski, Piotr; Metz, Sybrand J.
- Journal of Membrane Science, Vol. 349, Issue 1-2
Electrosorption of Inorganic Salts from Aqueous Solution Using Carbon Aerogels
journal, July 2002
- Gabelich, Christopher J.; Tran, Tri D.; Suffet, I. H. “Mel”
- Environmental Science & Technology, Vol. 36, Issue 13
Combinatorial discovery of bifunctional oxygen reduction — water oxidation electrocatalysts for regenerative fuel cells
journal, June 2001
- Chen, Guoying; Delafuente, David A.; Sarangapani, S.
- Catalysis Today, Vol. 67, Issue 4
Electrocatalysis of proton-coupled electron-transfer reactions at glassy carbon electrodes
journal, April 1985
- Cabaniss, George E.; Diamantis, A. A.; Murphy, W. Rorer
- Journal of the American Chemical Society, Vol. 107, Issue 7
Elucidating Proton Involvement in the Rate-Determining Step for Pt/Pd-Based and Non-Precious-Metal Oxygen Reduction Reaction Catalysts Using the Kinetic Isotope Effect
journal, August 2016
- Tse, Edmund C. M.; Varnell, Jason A.; Hoang, Thao T. H.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 18
Kinetic Isotope Effect in the Hydrogenation and Deuteration of Graphene
journal, November 2012
- Paris, Alessio; Verbitskiy, Nikolay; Nefedov, Alexei
- Advanced Functional Materials, Vol. 23, Issue 13
Water Scarcity: Fact or Fiction
conference, January 2016
- Yu, Xiaomeng
- Proceedings of the 2016 International Conference on Education, Management and Computing Technology (ICEMCT-16)
Gas Evolution in Operating Lithium-Ion Batteries Studied in Situ by Neutron Imaging
text, January 2015
- Michalak, B.; Sommer, H.; Mannes, D.
- Karlsruhe
Kinetic isotope effect in the hydrogenation and deuteration of graphene
text, January 2012
- Nefedov, A.; Paris, A.; Verbitsky, N.
- Karlsruhe
Review on the science and technology of water desalination by capacitive deionization
other, January 2013
- Presser, Volker; Porada, S.; Zhao, R.
- Amsterdam : Elsevier
Attractive forces in microporous carbon electrodes for capacitive deionization
preprint, January 2013
- Biesheuvel, P. M.; Porada, S.; Levi, M.
- arXiv
Kinetic isotope effect in the hydrogenation and deuteration of graphene
text, January 2012
- Nefedov, A.; Paris, A.; Verbitsky, N.
- Karlsruhe