Amplified luminescence in organo-curium nanocrystal hybrids
Abstract
We present here the first report of ligand-sensitized, actinide luminescence in a lanthanide nanoparticle host. Amplified luminescence of 248Cm3+ doped in a NaGdF4 lattice is achieved through optical pumping of a surface-localized metal chelator, 3,4,3-LI(1,2-HOPO), capable of sensitizing Cm3+ excited states. The data suggest the possibility of using such materials in theranostic applications, with a ligand-sensitized actinide or radio-lanthanide serving the dual roles of a nuclear decay source for radiotherapeutics, and as a luminescent center or energy transfer conduit to another emissive metal ion, for biological imaging.
- Authors:
-
[4]
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Center for Electron Microscopy. Molecular Foundry
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Center for Electron Microscopy. Molecular Foundry; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Nuclear Engineering
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1510769
- Alternate Identifier(s):
- OSTI ID: 1506156
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 16; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
Citation Formats
Agbo, Peter, Müller, Alexander, Arnedo-Sanchez, Leticia, Ercius, Peter, Minor, Andrew M., and Abergel, Rebecca J. Amplified luminescence in organo-curium nanocrystal hybrids. United States: N. p., 2019.
Web. doi:10.1039/c9nr01360a.
Agbo, Peter, Müller, Alexander, Arnedo-Sanchez, Leticia, Ercius, Peter, Minor, Andrew M., & Abergel, Rebecca J. Amplified luminescence in organo-curium nanocrystal hybrids. United States. https://doi.org/10.1039/c9nr01360a
Agbo, Peter, Müller, Alexander, Arnedo-Sanchez, Leticia, Ercius, Peter, Minor, Andrew M., and Abergel, Rebecca J. Wed .
"Amplified luminescence in organo-curium nanocrystal hybrids". United States. https://doi.org/10.1039/c9nr01360a. https://www.osti.gov/servlets/purl/1510769.
@article{osti_1510769,
title = {Amplified luminescence in organo-curium nanocrystal hybrids},
author = {Agbo, Peter and Müller, Alexander and Arnedo-Sanchez, Leticia and Ercius, Peter and Minor, Andrew M. and Abergel, Rebecca J.},
abstractNote = {We present here the first report of ligand-sensitized, actinide luminescence in a lanthanide nanoparticle host. Amplified luminescence of 248Cm3+ doped in a NaGdF4 lattice is achieved through optical pumping of a surface-localized metal chelator, 3,4,3-LI(1,2-HOPO), capable of sensitizing Cm3+ excited states. The data suggest the possibility of using such materials in theranostic applications, with a ligand-sensitized actinide or radio-lanthanide serving the dual roles of a nuclear decay source for radiotherapeutics, and as a luminescent center or energy transfer conduit to another emissive metal ion, for biological imaging.},
doi = {10.1039/c9nr01360a},
journal = {Nanoscale},
number = 16,
volume = 11,
place = {United States},
year = {Wed Apr 10 00:00:00 EDT 2019},
month = {Wed Apr 10 00:00:00 EDT 2019}
}
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