Enhancing residual trapping of supercritical CO 2 via cyclic injections: Cyclic Injections Enhance scCO 2 Trapping

Herring, Anna L.; Andersson, Linnéa; Wildenschild, Dorthe

doi:10.1002/2016GL070304

Title: Enhancing residual trapping of supercritical CO ₂ via cyclic injections: Cyclic Injections Enhance scCO ₂ Trapping

Abstract

We utilize synchrotron x-ray tomographic imaging to investigate the pore-scale characteristics and residual trapping of supercritical CO₂ (scCO₂) over the course of multiple drainage-imbibition (D-I) cycles in Bentheimer sandstone cores. Capillary pressure measurements are paired with image-based saturation and connectivity metrics which describe the extent of drainage and subsequent residual (end of imbibition) scCO₂ trapping. For the first D-I cycle, residual scCO₂ trapping is suppressed due to high imbibition capillary number (Ca≈10^-6); however, residual scCO₂ trapping dramatically increases for subsequent D-I cycles carried out at the same Ca value. The magnitude of scCO₂ trapping increase is hysteretic and depends on the relative extent of the sequential drainage processes. Increased trapping as a function of D-I cycle has not been observed in other similar mutli-cycle experiments; this suggests that chemical/geochemical reactions specific to our scCO₂-brine-sandstone experimental system may play a factor in the observed flow, mobilization, and residual trapping of scCO₂.

Authors:

Herring, Anna L. ^[1]; Andersson, Linnéa ^[2]; Wildenschild, Dorthe ^[2]

Oregon State Univ., Corvallis, OR (United States); Australian National Univ., Canberra, ACT (Australia)
Oregon State Univ., Corvallis, OR (United States)

Publication Date:: Wed Aug 24 00:00:00 EDT 2016

Research Org.:: Univ. of Chicago, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

OSTI Identifier:: 1508036

Report Number(s):: DOE-UCHICAGO-14466-4
Journal ID: ISSN 0094-8276

Grant/Contract Number:: FG02-94ER14466

Resource Type:: Accepted Manuscript

Journal Name:: Geophysical Research Letters

Additional Journal Information:: Journal Volume: 43; Journal Issue: 18; Journal ID: ISSN 0094-8276

Publisher:: American Geophysical Union

Country of Publication:: United States

Language:: English

Subject:: 42 ENGINEERING; Synchrotron radiation

Citation Formats


                    Herring, Anna L., Andersson, Linnéa, and Wildenschild, Dorthe. Enhancing residual trapping of supercritical CO 2 via cyclic injections: Cyclic Injections Enhance scCO 2 Trapping.  United States: N. p., 2016. 
Web.  doi:10.1002/2016GL070304.

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                    Herring, Anna L., Andersson, Linnéa, & Wildenschild, Dorthe. Enhancing residual trapping of supercritical CO 2 via cyclic injections: Cyclic Injections Enhance scCO 2 Trapping.  United States.  https://doi.org/10.1002/2016GL070304

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                    Herring, Anna L., Andersson, Linnéa, and Wildenschild, Dorthe. Wed .  
"Enhancing residual trapping of supercritical CO 2 via cyclic injections: Cyclic Injections Enhance scCO 2 Trapping".  United States.  https://doi.org/10.1002/2016GL070304.  https://www.osti.gov/servlets/purl/1508036.

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@article{osti_1508036,

  title        = {Enhancing residual trapping of supercritical CO 2 via cyclic injections: Cyclic Injections Enhance scCO 2 Trapping},

  author       = {Herring, Anna L. and Andersson, Linnéa and Wildenschild, Dorthe},

  abstractNote = {We utilize synchrotron x-ray tomographic imaging to investigate the pore-scale characteristics and residual trapping of supercritical CO2 (scCO2) over the course of multiple drainage-imbibition (D-I) cycles in Bentheimer sandstone cores. Capillary pressure measurements are paired with image-based saturation and connectivity metrics which describe the extent of drainage and subsequent residual (end of imbibition) scCO2 trapping. For the first D-I cycle, residual scCO2 trapping is suppressed due to high imbibition capillary number (Ca≈10-6); however, residual scCO2 trapping dramatically increases for subsequent D-I cycles carried out at the same Ca value. The magnitude of scCO2 trapping increase is hysteretic and depends on the relative extent of the sequential drainage processes. Increased trapping as a function of D-I cycle has not been observed in other similar mutli-cycle experiments; this suggests that chemical/geochemical reactions specific to our scCO2-brine-sandstone experimental system may play a factor in the observed flow, mobilization, and residual trapping of scCO2.},

  doi          = {10.1002/2016GL070304},

  journal      = {Geophysical Research Letters},

  number       = 18,

  volume       = 43,

  place        = {United States},

  year         = {Wed Aug 24 00:00:00 EDT 2016},

  month        = {Wed Aug 24 00:00:00 EDT 2016}

}

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Title: Enhancing residual trapping of supercritical CO 2 via cyclic injections: Cyclic Injections Enhance scCO 2 Trapping

Abstract

Citation Formats

Screening and ranking of sedimentary basins for sequestration of CO2 in geological media in response to climate change journal, June 2003

Experimental Study of Crossover from Capillary to Viscous Fingering for Supercritical CO 2 –Water Displacement in a Homogeneous Pore Network journal, June 2012

Characterizing flow behavior for gas injection: Relative permeability of CO 2 -brine and N 2 -water in heterogeneous rocks : CHARACTERIZING FLOW BEHAVIOR FOR GAS INJECTION journal, December 2015

Hysteretic trapping and relative permeability of CO2 in sandstone at reservoir conditions journal, August 2014

An Experimental Study on the Influence of Sub-Core Scale Heterogeneities on CO2 Distribution in Reservoir Rocks journal, June 2009

Quantifying the flow dynamics of supercritical CO2–water displacement in a 2D porous micromodel using fluorescent microscopy and microscopic PIV journal, September 2016

The impact of reservoir conditions on the residual trapping of carbon dioxide in B erea sandstone journal, April 2015

Investigation of mechanisms of supercritical CO2 trapping in deep saline reservoirs using surrogate fluids at ambient laboratory conditions journal, October 2014

CO2 Sequestration in Deep Sedimentary Formations journal, October 2008

Pore-scale imaging of geological carbon dioxide storage under in situ conditions: PORE-SCALE IMAGING OF CARBON STORAGE journal, August 2013

Pore-by-pore capillary pressure measurements using X-ray microtomography at reservoir conditions: Curvature, snap-off, and remobilization of residual CO 2 journal, November 2014

Quantification of soil structure based on Minkowski functions journal, October 2010

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Measurements of Non-Wetting Phase Trapping Applied to Carbon Dioxide Storage journal, February 2009

Multiphase flow behaviour during CO2 geo-sequestration: Emphasis on the effect of cyclic CO2–brine flooding journal, November 2011

The Footprint of the CO2 Plume during Carbon Dioxide Storage in Saline Aquifers: Storage Efficiency for Capillary Trapping at the Basin Scale journal, June 2009

Contact angle measurement ambiguity in supercritical CO2–water–mineral systems: Mica as an example journal, December 2014

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Title: Enhancing residual trapping of supercritical CO ₂ via cyclic injections: Cyclic Injections Enhance scCO ₂ Trapping

Screening and ranking of sedimentary basins for sequestration of CO2 in geological media in response to climate change
journal, June 2003

Experimental Study of Crossover from Capillary to Viscous Fingering for Supercritical CO ₂ –Water Displacement in a Homogeneous Pore Network
journal, June 2012

Characterizing flow behavior for gas injection: Relative permeability of CO ₂ -brine and N ₂ -water in heterogeneous rocks : CHARACTERIZING FLOW BEHAVIOR FOR GAS INJECTION
journal, December 2015

Hysteretic trapping and relative permeability of CO2 in sandstone at reservoir conditions
journal, August 2014

An Experimental Study on the Influence of Sub-Core Scale Heterogeneities on CO2 Distribution in Reservoir Rocks
journal, June 2009

Quantifying the flow dynamics of supercritical CO2–water displacement in a 2D porous micromodel using fluorescent microscopy and microscopic PIV
journal, September 2016

The impact of reservoir conditions on the residual trapping of carbon dioxide in B erea sandstone
journal, April 2015

Investigation of mechanisms of supercritical CO2 trapping in deep saline reservoirs using surrogate fluids at ambient laboratory conditions
journal, October 2014

CO2 Sequestration in Deep Sedimentary Formations
journal, October 2008

Pore-scale imaging of geological carbon dioxide storage under in situ conditions: PORE-SCALE IMAGING OF CARBON STORAGE
journal, August 2013

Pore-by-pore capillary pressure measurements using X-ray microtomography at reservoir conditions: Curvature, snap-off, and remobilization of residual CO ₂
journal, November 2014

Quantification of soil structure based on Minkowski functions
journal, October 2010

Impact of Reservoir Conditions on CO2-brine Relative Permeability in Sandstones
journal, January 2014

Experimental study of gas evolution in heterogeneous shallow subsurface formations during leakage of stored CO2
journal, March 2014

Pore-scale observations of supercritical CO2 drainage in Bentheimer sandstone by synchrotron x-ray imaging
journal, June 2014

Wettability Evaluation of a CO ₂ /Water/Bentheimer Sandstone System: Contact Angle, Dissolution, and Bubble Size
journal, May 2014

Relative permeability hysteresis and capillary trapping characteristics of supercritical CO2/brine systems: An experimental study at reservoir conditions
journal, February 2013

Measurements of the capillary trapping of super-critical carbon dioxide in Berea sandstone: MEASUREMENT OF CARBON DIOXIDE ENTRAPMENT
journal, March 2011

Pore-scale displacement mechanisms as a source of hysteresis for two-phase flow in porous media: FLUID TOPOLOGY
journal, March 2016

Impact of relative permeability hysteresis on geological CO ₂ storage : IMPACT OF HYSTERESIS ON GEOLOGICAL CO
journal, December 2006

Simultaneous determination of capillary pressure and relative permeability curves from core-flooding experiments with various fluid pairs: Capillary Pressure and Relative Permeability Curves
journal, June 2013

Capillary Pressure Hysteresis Behavior of Three Sandstones Measured with a Multistep Outflow–Inflow Apparatus
journal, January 2014

Effects of in-situ conditions on relative permeability characteristics of CO2-brine systems
journal, July 2007

Quantitative Analysis of Flow Processes in a Sand Using Synchrotron-Based X-ray Microtomography
journal, February 2005

Measurements of non-wetting phase trapping applied to carbon dioxide storage
journal, March 2010

Relative permeability and trapping of CO ₂ and water in sandstone rocks at reservoir conditions : MULTIPHASE FLOW OF CO
journal, February 2012

Measurements of Non-Wetting Phase Trapping Applied to Carbon Dioxide Storage
journal, February 2009

Multiphase flow behaviour during CO2 geo-sequestration: Emphasis on the effect of cyclic CO2–brine flooding
journal, November 2011

The Footprint of the CO2 Plume during Carbon Dioxide Storage in Saline Aquifers: Storage Efficiency for Capillary Trapping at the Basin Scale
journal, June 2009

Contact angle measurement ambiguity in supercritical CO2–water–mineral systems: Mica as an example
journal, December 2014

Effect of fluid topology on residual nonwetting phase trapping: Implications for geologic CO2 sequestration
journal, December 2013

Pore-scale trapping of supercritical CO ₂ and the role of grain wettability and shape : PORE-SCALE CONTROLS ON TRAPPING OF s-CO
journal, August 2013

Two‐phase flow properties of a sandstone rock for the CO ₂ /water system: Core‐flooding experiments, and focus on impacts of mineralogical changes
journal, April 2015

From connected pathway flow to ganglion dynamics
journal, May 2015

Residual CO ₂ imaged with X-ray micro-tomography : RESIDUAL CO
journal, November 2011

Dewetting of Silica Surfaces upon Reactions with Supercritical CO ₂ and Brine: Pore-Scale Studies in Micromodels
journal, March 2012

Capillary Pressure–Saturation Relations for Supercritical CO ₂ and Brine in Limestone/Dolomite Sands: Implications for Geologic Carbon Sequestration in Carbonate Reservoirs
journal, June 2015

Experimental investigation of carbon dioxide trapping due to capillary retention in saline aquifers
journal, January 2015

Capillary pressure for the sand–CO2–water system under various pressure conditions. Application to CO2 sequestration
journal, November 2007

Residual CO ₂ Trapping in Indiana Limestone
journal, August 2012

Efficiently engineering pore-scale processes: The role of force dominance and topology during nonwetting phase trapping in porous media
journal, May 2015

Reservoir Simulation of CO<sub>2</sub> Storage in Aquifers
journal, September 2005

Wettability measurement under high P-T conditions using X-ray imaging with application to the brine-supercritical CO ₂ system : WETTABILITY MEASUREMENT USING X-RAY
journal, August 2015

Pore-scale displacement mechanisms as a source of hysteresis for two-phase flow in porous media
text, January 2016

Enhancement of CO 2 trapping efficiency in heterogeneous reservoirs by water-alternating gas injection : Original Research Article: Enhancement of CO
journal, July 2018

Topological Persistence for Relating Microstructure and Capillary Fluid Trapping in Sandstones
journal, January 2019

Capillary Trapping of CO ₂ in Sandstone Using Low Field NMR Relaxometry
journal, December 2019