Operation Mechanism of Perovskite Quantum Dot Solar Cells Probed by Impedance Spectroscopy
Abstract
We fabricated perovskite quantum dot solar cells (PQDSCs) and varied the thickness of the QD layer by controlling the number of deposition cycles; the cells were systematically investigated with impedance spectroscopy. Despite the evident structural differences with respect to standard perovskite solar cells (PSCs), similar impedance spectra were obtained for PQDSCs, pointing to similar working principles in terms of the active layer. We distinguish two different regimes: At low illumination, recombination is ruled by multiple trapping with trap distributions and/or shunting. However, at higher light intensities, Shockley-Read-Hall recombination is observed. In addition, the low-frequency capacitance, CLF, of PQDSCs increases several orders of magnitude when the illumination is varied from dark to 1-sun conditions. This feature has not been observed in other kinds of photovoltaic devices and is characteristic of PSCs. Although there is no consensus about the exact mechanism responsible for CLF, the suggested models point to an ion migration origin. Its observation in thin-film and PQDSCs devices implies a similar effect in both.
- Authors:
-
- Univ. Jaume I, Castellon (Spain); Amirkabir Univ. of Technology, Tehran (Iran)
- Univ. Jaume I, Castellon (Spain)
- Amirkabir Univ. of Technology, Tehran (Iran)
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1491374
- Report Number(s):
- NREL/JA-5900-72790
Journal ID: ISSN 2380-8195
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 1; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; perovskite quantum dot solar cells; quantum dots; impedance spectroscopy
Citation Formats
Zolfaghari, Zahra, Hassanabadi, Ehsan, Pitarch-Tena, Didac, Yoon, Seog Joon, Shariatinia, Zahra, van de Lagemaat, Jao, Luther, Joseph M., and Mora-Seró, Iván. Operation Mechanism of Perovskite Quantum Dot Solar Cells Probed by Impedance Spectroscopy. United States: N. p., 2018.
Web. doi:10.1021/acsenergylett.8b02157.
Zolfaghari, Zahra, Hassanabadi, Ehsan, Pitarch-Tena, Didac, Yoon, Seog Joon, Shariatinia, Zahra, van de Lagemaat, Jao, Luther, Joseph M., & Mora-Seró, Iván. Operation Mechanism of Perovskite Quantum Dot Solar Cells Probed by Impedance Spectroscopy. United States. https://doi.org/10.1021/acsenergylett.8b02157
Zolfaghari, Zahra, Hassanabadi, Ehsan, Pitarch-Tena, Didac, Yoon, Seog Joon, Shariatinia, Zahra, van de Lagemaat, Jao, Luther, Joseph M., and Mora-Seró, Iván. Mon .
"Operation Mechanism of Perovskite Quantum Dot Solar Cells Probed by Impedance Spectroscopy". United States. https://doi.org/10.1021/acsenergylett.8b02157. https://www.osti.gov/servlets/purl/1491374.
@article{osti_1491374,
title = {Operation Mechanism of Perovskite Quantum Dot Solar Cells Probed by Impedance Spectroscopy},
author = {Zolfaghari, Zahra and Hassanabadi, Ehsan and Pitarch-Tena, Didac and Yoon, Seog Joon and Shariatinia, Zahra and van de Lagemaat, Jao and Luther, Joseph M. and Mora-Seró, Iván},
abstractNote = {We fabricated perovskite quantum dot solar cells (PQDSCs) and varied the thickness of the QD layer by controlling the number of deposition cycles; the cells were systematically investigated with impedance spectroscopy. Despite the evident structural differences with respect to standard perovskite solar cells (PSCs), similar impedance spectra were obtained for PQDSCs, pointing to similar working principles in terms of the active layer. We distinguish two different regimes: At low illumination, recombination is ruled by multiple trapping with trap distributions and/or shunting. However, at higher light intensities, Shockley-Read-Hall recombination is observed. In addition, the low-frequency capacitance, CLF, of PQDSCs increases several orders of magnitude when the illumination is varied from dark to 1-sun conditions. This feature has not been observed in other kinds of photovoltaic devices and is characteristic of PSCs. Although there is no consensus about the exact mechanism responsible for CLF, the suggested models point to an ion migration origin. Its observation in thin-film and PQDSCs devices implies a similar effect in both.},
doi = {10.1021/acsenergylett.8b02157},
journal = {ACS Energy Letters},
number = 1,
volume = 4,
place = {United States},
year = {Mon Dec 10 00:00:00 EST 2018},
month = {Mon Dec 10 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells
journal, March 2013
- Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck
- Nano Letters, Vol. 13, Issue 4, p. 1764-1769
Operating Mechanisms of Mesoscopic Perovskite Solar Cells through Impedance Spectroscopy and J – V Modeling
journal, December 2017
- Zarazúa, Isaac; Sidhik, Siraj; Lopéz-Luke, Tzarara
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 24
Recombination Study of Combined Halides (Cl, Br, I) Perovskite Solar Cells
journal, April 2014
- Suarez, Belen; Gonzalez-Pedro, Victoria; Ripolles, Teresa S.
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 10
Hierarchical Arrays of Cesium Lead Halide Perovskite Nanocrystals through Electrophoretic Deposition
journal, June 2018
- Ravi, Vikash Kumar; Scheidt, Rebecca A.; DuBose, Jeffrey
- Journal of the American Chemical Society, Vol. 140, Issue 28
Nontemplate Synthesis of CH 3 NH 3 PbBr 3 Perovskite Nanoparticles
journal, January 2014
- Schmidt, Luciana C.; Pertegás, Antonio; González-Carrero, Soranyel
- Journal of the American Chemical Society, Vol. 136, Issue 3
Prospects of Nanoscience with Nanocrystals
journal, January 2015
- Kovalenko, Maksym V.; Manna, Liberato; Cabot, Andreu
- ACS Nano, Vol. 9, Issue 2
Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells
journal, January 2014
- Juarez-Perez, Emilio J.; Wuβler, Michael; Fabregat-Santiago, Francisco
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 4, p. 680-685
Specific cation interactions as the cause of slow dynamics and hysteresis in dye and perovskite solar cells: a small-perturbation study
journal, January 2016
- Contreras, Lidia; Idígoras, Jesús; Todinova, Anna
- Physical Chemistry Chemical Physics, Vol. 18, Issue 45
Stability in Perovskite Photovoltaics: A Paradigm for Newfangled Technologies
journal, August 2018
- Christians, Jeffrey A.; Habisreutinger, Severin N.; Berry, Joseph J.
- ACS Energy Letters, Vol. 3, Issue 9
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells
journal, June 2017
- Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk
- Science, Vol. 356, Issue 6345
Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance
journal, August 2017
- Huang, He; Bodnarchuk, Maryna I.; Kershaw, Stephen V.
- ACS Energy Letters, Vol. 2, Issue 9
Ultrafast Electron Injection from Photoexcited Perovskite CsPbI 3 QDs into TiO 2 Nanoparticles with Injection Efficiency near 99%
journal, January 2018
- Liu, Feng; Zhang, Yaohong; Ding, Chao
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 2
Interfaces in Perovskite Solar Cells
journal, August 2017
- Fakharuddin, Azhar; Schmidt-Mende, Lukas; Garcia-Belmonte, Germà
- Advanced Energy Materials, Vol. 7, Issue 22
Understanding the rate-dependent J–V hysteresis, slow time component, and aging in CH 3 NH 3 PbI 3 perovskite solar cells: the role of a compensated electric field
journal, January 2015
- Tress, W.; Marinova, N.; Moehl, T.
- Energy & Environmental Science, Vol. 8, Issue 3
Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells
journal, December 2013
- Dualeh, Amalie; Moehl, Thomas; Tétreault, Nicolas
- ACS Nano, Vol. 8, Issue 1, p. 362-373
Light-Induced Space-Charge Accumulation Zone as Photovoltaic Mechanism in Perovskite Solar Cells
journal, January 2016
- Zarazua, Isaac; Bisquert, Juan; Garcia-Belmonte, Germà
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 3
Enhanced mobility CsPbI 3 quantum dot arrays for record-efficiency, high-voltage photovoltaic cells
journal, October 2017
- Sanehira, Erin M.; Marshall, Ashley R.; Christians, Jeffrey A.
- Science Advances, Vol. 3, Issue 10
Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability
journal, September 2015
- Bag, Monojit; Renna, Lawrence A.; Adhikari, Ramesh Y.
- Journal of the American Chemical Society, Vol. 137, Issue 40
Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014
- Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher
- Energy & Environmental Science, Vol. 7, Issue 3
Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy
journal, January 2011
- Fabregat-Santiago, Francisco; Garcia-Belmonte, Germà; Mora-Seró, Iván
- Physical Chemistry Chemical Physics, Vol. 13, Issue 20
Control of I – V Hysteresis in CH 3 NH 3 PbI 3 Perovskite Solar Cell
journal, October 2015
- Kim, Hui-Seon; Jang, In-Hyuk; Ahn, Namyoung
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
Band-Aligned Polymeric Hole Transport Materials for Extremely Low Energy Loss α-CsPbI3 Perovskite Nanocrystal Solar Cells
journal, November 2018
- Yuan, Jianyu; Ling, Xufeng; Yang, Di
- Joule, Vol. 2, Issue 11
Colloidal CsPbX 3 (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability
journal, February 2018
- Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii
- ACS Energy Letters, Vol. 3, Issue 3
Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers
journal, September 2016
- Bella, F.; Griffini, G.; Correa-Baena, J. -P.
- Science, Vol. 354, Issue 6309
Anomalous Hysteresis in Perovskite Solar Cells
journal, April 2014
- Snaith, Henry J.; Abate, Antonio; Ball, James M.
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
Quantum dot-induced phase stabilization of -CsPbI3 perovskite for high-efficiency photovoltaics
journal, October 2016
- Swarnkar, A.; Marshall, A. R.; Sanehira, E. M.
- Science, Vol. 354, Issue 6308
Characterization of Planar Lead Halide Perovskite Solar Cells by Impedance Spectroscopy, Open-Circuit Photovoltage Decay, and Intensity-Modulated Photovoltage/Photocurrent Spectroscopy
journal, February 2015
- Pockett, Adam; Eperon, Giles E.; Peltola, Timo
- The Journal of Physical Chemistry C, Vol. 119, Issue 7
Slow Dynamic Processes in Lead Halide Perovskite Solar Cells. Characteristic Times and Hysteresis
journal, June 2014
- Sanchez, Rafael S.; Gonzalez-Pedro, Victoria; Lee, Jin-Wook
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
Controlling the Phase Segregation in Mixed Halide Perovskites through Nanocrystal Size
journal, November 2018
- Gualdrón-Reyes, Andrés. F.; Yoon, Seog Joon; Barea, Eva M.
- ACS Energy Letters, Vol. 4, Issue 1
To Exchange or Not to Exchange . Suppressing Anion Exchange in Cesium Lead Halide Perovskites with PbSO 4 –Oleate Capping
journal, March 2018
- Ravi, Vikash Kumar; Scheidt, Rebecca A.; Nag, Angshuman
- ACS Energy Letters, Vol. 3, Issue 4
Insights into Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells Using Impedance Spectroscopy
journal, February 2015
- Pascoe, Alexander R.; Duffy, Noel W.; Scully, Andrew D.
- The Journal of Physical Chemistry C, Vol. 119, Issue 9
Impedance Spectroscopy Measurements in Perovskite Solar Cells: Device Stability and Noise Reduction
journal, March 2018
- Pitarch-Tena, Didac; Ngo, Thi Tuyen; Vallés-Pelarda, Marta
- ACS Energy Letters, Vol. 3, Issue 4
Perovskite Quantum Dot Photovoltaic Materials beyond the Reach of Thin Films: Full-Range Tuning of A-Site Cation Composition
journal, September 2018
- Hazarika, Abhijit; Zhao, Qian; Gaulding, E. Ashley
- ACS Nano, Vol. 12, Issue 10
Inorganic caesium lead iodide perovskite solar cells
journal, January 2015
- Eperon, Giles E.; Paternò, Giuseppe M.; Sutton, Rebecca J.
- Journal of Materials Chemistry A, Vol. 3, Issue 39
Targeted Ligand-Exchange Chemistry on Cesium Lead Halide Perovskite Quantum Dots for High-Efficiency Photovoltaics
journal, July 2018
- Wheeler, Lance M.; Sanehira, Erin M.; Marshall, Ashley R.
- Journal of the American Chemical Society, Vol. 140, Issue 33
Chemical Synthesis and Luminescence Applications of Colloidal Semiconductor Quantum Dots
journal, July 2017
- Owen, Jonathan; Brus, Louis
- Journal of the American Chemical Society, Vol. 139, Issue 32
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals
journal, November 2017
- Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I.
- Science, Vol. 358, Issue 6364
Reaction Order and Ideality Factor in Dye-Sensitized Nanocrystalline Solar Cells: A Theoretical Investigation
journal, May 2012
- Ansari-Rad, M.; Abdi, Y.; Arzi, E.
- The Journal of Physical Chemistry C, Vol. 116, Issue 20
Iodine chemistry determines the defect tolerance of lead-halide perovskites
journal, January 2018
- Meggiolaro, Daniele; Motti, Silvia G.; Mosconi, Edoardo
- Energy & Environmental Science, Vol. 11, Issue 3
Recent insights for achieving mixed halide perovskites without halide segregation
journal, October 2018
- Gualdrón-Reyes, Andrés Fabián; Yoon, Seog Joon; Mora-Seró, Iván
- Current Opinion in Electrochemistry, Vol. 11
Dependence of halide composition on the stability of highly efficient all-inorganic cesium lead halide perovskite quantum dot solar cells
journal, October 2018
- Ghosh, Dibyendu; Ali, Md. Yusuf; Chaudhary, Dhirendra K.
- Solar Energy Materials and Solar Cells, Vol. 185
High-Bandgap Perovskite Materials for Multijunction Solar Cells
journal, August 2018
- Yang, Terry Chien-Jen; Fiala, Peter; Jeangros, Quentin
- Joule, Vol. 2, Issue 8
Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite
journal, June 2015
- Conings, Bert; Drijkoningen, Jeroen; Gauquelin, Nicolas
- Advanced Energy Materials, Vol. 5, Issue 15
Bandgap-Tunable Cesium Lead Halide Perovskites with High Thermal Stability for Efficient Solar Cells
journal, February 2016
- Sutton, Rebecca J.; Eperon, Giles E.; Miranda, Laura
- Advanced Energy Materials, Vol. 6, Issue 8
Origin and Whereabouts of Recombination in Perovskite Solar Cells
journal, May 2017
- Contreras-Bernal, Lidia; Salado, Manuel; Todinova, Anna
- The Journal of Physical Chemistry C, Vol. 121, Issue 18
Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, I)
journal, July 2015
- Nedelcu, Georgian; Protesescu, Loredana; Yakunin, Sergii
- Nano Letters, Vol. 15, Issue 8
Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells
journal, December 2015
- Kulbak, Michael; Gupta, Satyajit; Kedem, Nir
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 1
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016
- Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
- Energy & Environmental Science, Vol. 9, Issue 6
Rationalizing the light-induced phase separation of mixed halide organic–inorganic perovskites
journal, August 2017
- Draguta, Sergiu; Sharia, Onise; Yoon, Seog Joon
- Nature Communications, Vol. 8, Issue 1
Electron Lifetime in Dye-Sensitized Solar Cells: Theory and Interpretation of Measurements
journal, August 2009
- Bisquert, Juan; Fabregat-Santiago, Francisco; Mora-Seró, Iván
- The Journal of Physical Chemistry C, Vol. 113, Issue 40
Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor
journal, January 2009
- Fabregat-Santiago, Francisco; Bisquert, Juan; Cevey, Le
- Journal of the American Chemical Society, Vol. 131, Issue 2
Phase Diagrams of Quasibinary Systems of the Type: ABX 3 — A′BX 3 ; ABX 3 — AB′X 3 , and ABX 3 — ABX′ 3 ; X = Halogen
journal, January 1992
- Sharma, Surendra; Weiden, Norbert; Weiss, Alarich
- Zeitschrift für Physikalische Chemie, Vol. 175, Issue Part_1
Semiconductor Clusters, Nanocrystals, and Quantum Dots
journal, February 1996
- Alivisatos, A. P.
- Science, Vol. 271, Issue 5251, p. 933-937
Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells
journal, June 2014
- Juarez-Perez, Emilio J.; Sanchez, Rafael S.; Badia, Laura
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 13
Properties of Contact and Bulk Impedances in Hybrid Lead Halide Perovskite Solar Cells Including Inductive Loop Elements
journal, April 2016
- Guerrero, Antonio; Garcia-Belmonte, Germà; Mora-Sero, Ivan
- The Journal of Physical Chemistry C, Vol. 120, Issue 15
Surface Recombination and Collection Efficiency in Perovskite Solar Cells from Impedance Analysis
journal, November 2016
- Zarazua, Isaac; Han, Guifang; Boix, Pablo P.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 24
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015
- Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.
- Nano Letters, Vol. 15, Issue 6
Electron injection and scaffold effects in perovskite solar cells
journal, January 2017
- Anaya, Miguel; Zhang, Wei; Hames, Bruno Clasen
- Journal of Materials Chemistry C, Vol. 5, Issue 3
The two faces of capacitance: New interpretations for electrical impedance measurements of perovskite solar cells and their relation to hysteresis
journal, December 2018
- Jacobs, Daniel A.; Shen, Heping; Pfeffer, Florian
- Journal of Applied Physics, Vol. 124, Issue 22
Works referencing / citing this record:
Soft interfaces within hybrid perovskite solar cells: real-time dynamic tracking of interfacial electrical property evolution by EIS
journal, January 2019
- Feng, Yulin; Bian, Jiming; Wang, Shi
- Journal of Materials Chemistry C, Vol. 7, Issue 27
Spray‐Coated Colloidal Perovskite Quantum Dot Films for Highly Efficient Solar Cells
journal, September 2019
- Yuan, Jifeng; Bi, Chenghao; Wang, Shixun
- Advanced Functional Materials, Vol. 29, Issue 49
Cesium Doping for Performance Improvement of Lead(II)-acetate-Based Perovskite Solar Cells
journal, January 2021
- Han, Min-Seok; Liu, Zhihai; Liu, Xuewen
- Materials, Vol. 14, Issue 2
Impedance analysis of perovskite solar cells: a case study
journal, January 2019
- Contreras-Bernal, Lidia; Ramos-Terrón, Susana; Riquelme, Antonio
- Journal of Materials Chemistry A, Vol. 7, Issue 19
High efficiency perovskite quantum dot solar cells with charge separating heterostructure
journal, June 2019
- Zhao, Qian; Hazarika, Abhijit; Chen, Xihan
- Nature Communications, Vol. 10, Issue 1
Carbon-based materials for stable, cheaper and large-scale processable perovskite solar cells
journal, January 2019
- Fagiolari, Lucia; Bella, Federico
- Energy & Environmental Science, Vol. 12, Issue 12
Kinetic and material properties of interfaces governing slow response and long timescale phenomena in perovskite solar cells
journal, January 2019
- Wang, Hongxia; Guerrero, Antonio; Bou, Agustín
- Energy & Environmental Science, Vol. 12, Issue 7
High efficiency perovskite quantum dot solar cells with charge separating heterostructure
journal, June 2019
- Zhao, Qian; Hazarika, Abhijit; Chen, Xihan
- Nature Communications, Vol. 10, Issue 1
Photoexcited carrier dynamics in colloidal quantum dot solar cells: insights into individual quantum dots, quantum dot solid films and devices
journal, January 2020
- Zhang, Yaohong; Wu, Guohua; Liu, Feng
- Chemical Society Reviews, Vol. 49, Issue 1
Chemical stability and instability of inorganic halide perovskites
journal, January 2019
- Zhou, Yuanyuan; Zhao, Yixin
- Energy & Environmental Science, Vol. 12, Issue 5
Quantum Dots for Hybrid Energy Harvesting: From Integration to Piezo‐Phototronics
journal, May 2019
- Cho, Yuljae; Pak, Sangyeon; An, Geon‐Hyoung
- Israel Journal of Chemistry, Vol. 59, Issue 8