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Title: Dynamic Field Modulation of the Octahedral Framework in Metal Oxide Heterostructures

Abstract

Control over the oxygen octahedral framework is widely recognized as key to the design of functional properties in perovskite oxide heterostructures. Although the oxygen octahedral framework can be manipulated during synthesis, the as-grown oxygen octahedra generally remain fixed, preventing the development of adaptive behavior in electronic and ionotronic systems. Here, it is demonstrated that the oxygen octahedral framework can be dynamically and reversibly manipulated by an electric field through the coupling with oxygen vacancies. Studying model WO3 heterostructures during ionic liquid gating with a combination of in situ X-ray scattering and spectroscopy, it is shown that large changes in electronic properties can arise due to the increased flexibility of the octahedral network at high vacancy concentrations. Furthermore, the results describe a generic framework for the construction of dynamic systems and devices with an array of field-tunable properties.

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [4];  [4];  [4];  [4]; ORCiD logo [4]
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  1. Argonne National Lab. (ANL), Argonne, IL (United States); A*STAR (Agency for Science, Technology and Research) (Singapore)
  2. Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Science and Technology of China, Anhui (China)
  3. Argonne National Lab. (ANL), Argonne, IL (United States); Huazhong Univ. of Science and Technology, Hubei (China)
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE
OSTI Identifier:
1490425
Alternate Identifier(s):
OSTI ID: 1479586
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 30; Journal Issue: 52; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; WO3; ionic liquid gating; metal-insulator transition; oxygen octahedral rotation; x-ray scattering and spectroscopy

Citation Formats

Liu, Huajun, Dong, Yongqi, Xu, Dongwei, Karapetrova, Evguenia, Lee, Sungsik, Stan, Liliana, Zapol, Peter, Zhou, Hua, and Fong, Dillon D. Dynamic Field Modulation of the Octahedral Framework in Metal Oxide Heterostructures. United States: N. p., 2018. Web. doi:10.1002/adma.201804775.
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Liu, Huajun, Dong, Yongqi, Xu, Dongwei, Karapetrova, Evguenia, Lee, Sungsik, Stan, Liliana, Zapol, Peter, Zhou, Hua, & Fong, Dillon D. Dynamic Field Modulation of the Octahedral Framework in Metal Oxide Heterostructures. United States. https://doi.org/10.1002/adma.201804775
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Liu, Huajun, Dong, Yongqi, Xu, Dongwei, Karapetrova, Evguenia, Lee, Sungsik, Stan, Liliana, Zapol, Peter, Zhou, Hua, and Fong, Dillon D. Mon . "Dynamic Field Modulation of the Octahedral Framework in Metal Oxide Heterostructures". United States. https://doi.org/10.1002/adma.201804775. https://www.osti.gov/servlets/purl/1490425.
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@article{osti_1490425,
title = {Dynamic Field Modulation of the Octahedral Framework in Metal Oxide Heterostructures},
author = {Liu, Huajun and Dong, Yongqi and Xu, Dongwei and Karapetrova, Evguenia and Lee, Sungsik and Stan, Liliana and Zapol, Peter and Zhou, Hua and Fong, Dillon D.},
abstractNote = {Control over the oxygen octahedral framework is widely recognized as key to the design of functional properties in perovskite oxide heterostructures. Although the oxygen octahedral framework can be manipulated during synthesis, the as-grown oxygen octahedra generally remain fixed, preventing the development of adaptive behavior in electronic and ionotronic systems. Here, it is demonstrated that the oxygen octahedral framework can be dynamically and reversibly manipulated by an electric field through the coupling with oxygen vacancies. Studying model WO3 heterostructures during ionic liquid gating with a combination of in situ X-ray scattering and spectroscopy, it is shown that large changes in electronic properties can arise due to the increased flexibility of the octahedral network at high vacancy concentrations. Furthermore, the results describe a generic framework for the construction of dynamic systems and devices with an array of field-tunable properties.},
doi = {10.1002/adma.201804775},
journal = {Advanced Materials},
number = 52,
volume = 30,
place = {United States},
year = {Mon Oct 29 00:00:00 EDT 2018},
month = {Mon Oct 29 00:00:00 EDT 2018}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adma.201804775
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Cited by: 13 works
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Figures / Tables:

Figure 1 Figure 1: Static and dynamic tuning of oxygen octahedral rotations. (a) Schematic depicting of changes in the degree of orbital overlap between the B-site cation and oxygen ions when oxygen octahedra are tilted (less overlap) or not tilted (greater overlap). Static tunings of oxygen octahedral rotations are shown in (b)more » for chemical doping (yellow ion), (c) for strain and interfacial coupling, and (d) for superlattice modulation in epitaxial thin films. The dynamic tuning of oxygen octahedra in WO3 by ionic liquid gating for negative and positive gate voltages are depicted in (e) and (f), respectively. Oxygen vacancies are generated during positive gating, altering the oxygen octahedral rotation angles.« less
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    Figure 5 (p. 15)figure
    Figure 6 (p. 18)figure
    Figure S1 (p. 31)figure
    Table S1 (p. 31)table
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