Supertough PLA-Silane Nanohybrids by in Situ Condensation and Grafting
Abstract
Brittleness is a key barrier for poly(lactic acid) (PLA) toward broader applications. Supertough PLA was achieved by simply mixing a low amount (0.5–1 wt %) of organoalkoxysilane with PLA. Three organosilanes, (3-aminopropyl)triethoxysilane (APTES), 3-(triethoxysilyl)propyl isocyanate (ICPTES), and trimethoxymethylsilane (MTMS), were selected for this study to understand how the functional group on a silane affects the behavior of the PLA-silane hybrids. Remarkable improvements in ultimate tensile strain (up to 12 folds) and tensile toughness (up to 10 folds) were observed in APTES- and ICPTES-modified PLA without any loss in tensile strength and modulus. Glass transition temperatures measured by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) did not show any obvious decrease. We propose that in situ condensation of organosilane and grafting of PLA to form a silica-PLA core–shell nanocomplex may be the reason for the improved mechanical properties. Scanning electron microscopy (SEM) showed evidence of nanofibrils at fractured surfaces. Dynamic light scattering (DLS) indicated nanoparticle formation (bimodal, 50–200 nm and <10 nm) in dilute solution, while transmission electron microscopy (TEM) provided clearer evidence of the nanosized silica formed in situ. Rheological studies also showed increased chain entanglement in the polymer melts, which contributed to 1 order of magnitude highermore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Mechanical, Aerospace, Biomedical Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Mechanical, Aerospace, Biomedical Engineering
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1474444
- Alternate Identifier(s):
- OSTI ID: 1476428
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Sustainable Chemistry & Engineering
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2168-0485
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; Alkoxysilane; Cross-linking; Mechanical property; PLA nanocomposites; Polylactide; Rheology; Sustainable material
Citation Formats
Meng, Xiangtao, Nguyen, Ngoc A., Tekinalp, Halil, Lara-Curzio, Edgar, and Ozcan, Soydan. Supertough PLA-Silane Nanohybrids by in Situ Condensation and Grafting. United States: N. p., 2017.
Web. doi:10.1021/acssuschemeng.7b03650.
Meng, Xiangtao, Nguyen, Ngoc A., Tekinalp, Halil, Lara-Curzio, Edgar, & Ozcan, Soydan. Supertough PLA-Silane Nanohybrids by in Situ Condensation and Grafting. United States. https://doi.org/10.1021/acssuschemeng.7b03650
Meng, Xiangtao, Nguyen, Ngoc A., Tekinalp, Halil, Lara-Curzio, Edgar, and Ozcan, Soydan. Wed .
"Supertough PLA-Silane Nanohybrids by in Situ Condensation and Grafting". United States. https://doi.org/10.1021/acssuschemeng.7b03650. https://www.osti.gov/servlets/purl/1474444.
@article{osti_1474444,
title = {Supertough PLA-Silane Nanohybrids by in Situ Condensation and Grafting},
author = {Meng, Xiangtao and Nguyen, Ngoc A. and Tekinalp, Halil and Lara-Curzio, Edgar and Ozcan, Soydan},
abstractNote = {Brittleness is a key barrier for poly(lactic acid) (PLA) toward broader applications. Supertough PLA was achieved by simply mixing a low amount (0.5–1 wt %) of organoalkoxysilane with PLA. Three organosilanes, (3-aminopropyl)triethoxysilane (APTES), 3-(triethoxysilyl)propyl isocyanate (ICPTES), and trimethoxymethylsilane (MTMS), were selected for this study to understand how the functional group on a silane affects the behavior of the PLA-silane hybrids. Remarkable improvements in ultimate tensile strain (up to 12 folds) and tensile toughness (up to 10 folds) were observed in APTES- and ICPTES-modified PLA without any loss in tensile strength and modulus. Glass transition temperatures measured by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) did not show any obvious decrease. We propose that in situ condensation of organosilane and grafting of PLA to form a silica-PLA core–shell nanocomplex may be the reason for the improved mechanical properties. Scanning electron microscopy (SEM) showed evidence of nanofibrils at fractured surfaces. Dynamic light scattering (DLS) indicated nanoparticle formation (bimodal, 50–200 nm and <10 nm) in dilute solution, while transmission electron microscopy (TEM) provided clearer evidence of the nanosized silica formed in situ. Rheological studies also showed increased chain entanglement in the polymer melts, which contributed to 1 order of magnitude higher complex viscosity and storage modulus. The simple PLA toughening strategy and the new mechanism revealed in this study will open a door to novel performance polymer materials and broader use of PLAs.},
doi = {10.1021/acssuschemeng.7b03650},
journal = {ACS Sustainable Chemistry & Engineering},
number = 1,
volume = 6,
place = {United States},
year = {Wed Dec 06 00:00:00 EST 2017},
month = {Wed Dec 06 00:00:00 EST 2017}
}
Web of Science
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