Supercritical Drying of Wet Gel Layers Generated Inside ICF Ablator Shells
Abstract
Spherical ablator shells that contain a thin layer of ultralow-density polymer foam have recently attracted attention in the inertial confinement fusion (ICF) community as they can be used to bring dopants for diagnostics and nuclear physics experiments in direct contact with the deuterium-tritium (DT) fuel or to study new ignition regimes by enabling the formation of uniform liquid DT fuel layers. We developed a method to fabricate these foam-lined ablator shells using a prefabricated ablator as a mold to cast the foam liner within the shell. One crucial component of this new approach is the removal of solvent from the ablator shells without collapsing the ultralow-density porous polymer network. In this work, we report on a supercritical drying approach with liquid carbon dioxide that provides critical information on how to produce thin layers of low-density polymer foams in ablator shells for ICF experiments. Diffusion experiments were used to study the time required for complete solvent exchange in 2-mm-inner-diameter diamond shells and the data were used to demonstrate the fabrication of uniform porous polymer films inside ablator shells.
- Authors:
-
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1467819
- Report Number(s):
- LLNL-JRNL-735742
Journal ID: ISSN 1536-1055; 887862
- Grant/Contract Number:
- AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Fusion Science and Technology
- Additional Journal Information:
- Journal Volume: 73; Journal Issue: 2; Journal ID: ISSN 1536-1055
- Publisher:
- American Nuclear Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; 36 MATERIALS SCIENCE; Polymer films; hollow sphere; supercritical drying
Citation Formats
Braun, Tom, Kim, Sung Ho, Biener, Monika M., Hamza, Alex V., and Biener, Juergen. Supercritical Drying of Wet Gel Layers Generated Inside ICF Ablator Shells. United States: N. p., 2017.
Web. doi:10.1080/15361055.2017.1392203.
Braun, Tom, Kim, Sung Ho, Biener, Monika M., Hamza, Alex V., & Biener, Juergen. Supercritical Drying of Wet Gel Layers Generated Inside ICF Ablator Shells. United States. https://doi.org/10.1080/15361055.2017.1392203
Braun, Tom, Kim, Sung Ho, Biener, Monika M., Hamza, Alex V., and Biener, Juergen. Tue .
"Supercritical Drying of Wet Gel Layers Generated Inside ICF Ablator Shells". United States. https://doi.org/10.1080/15361055.2017.1392203. https://www.osti.gov/servlets/purl/1467819.
@article{osti_1467819,
title = {Supercritical Drying of Wet Gel Layers Generated Inside ICF Ablator Shells},
author = {Braun, Tom and Kim, Sung Ho and Biener, Monika M. and Hamza, Alex V. and Biener, Juergen},
abstractNote = {Spherical ablator shells that contain a thin layer of ultralow-density polymer foam have recently attracted attention in the inertial confinement fusion (ICF) community as they can be used to bring dopants for diagnostics and nuclear physics experiments in direct contact with the deuterium-tritium (DT) fuel or to study new ignition regimes by enabling the formation of uniform liquid DT fuel layers. We developed a method to fabricate these foam-lined ablator shells using a prefabricated ablator as a mold to cast the foam liner within the shell. One crucial component of this new approach is the removal of solvent from the ablator shells without collapsing the ultralow-density porous polymer network. In this work, we report on a supercritical drying approach with liquid carbon dioxide that provides critical information on how to produce thin layers of low-density polymer foams in ablator shells for ICF experiments. Diffusion experiments were used to study the time required for complete solvent exchange in 2-mm-inner-diameter diamond shells and the data were used to demonstrate the fabrication of uniform porous polymer films inside ablator shells.},
doi = {10.1080/15361055.2017.1392203},
journal = {Fusion Science and Technology},
number = 2,
volume = 73,
place = {United States},
year = {Tue Dec 19 00:00:00 EST 2017},
month = {Tue Dec 19 00:00:00 EST 2017}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Supercritical drying of aerogel: In situ analysis of concentration profiles inside the gel and derivation of the effective binary diffusion coefficient using Raman spectroscopy
journal, February 2016
- Quiño, Jaypee; Ruehl, Martin; Klima, Tobias
- The Journal of Supercritical Fluids, Vol. 108
Development of Divinylbenzene Foam Shells for Use as Inertial Fusion Energy Reactor Targets
journal, May 2003
- Streit, Jon; Schroen, Diana
- Fusion Science and Technology, Vol. 43, Issue 3
Process Development and Micro-Machining of MARBLE Foam-Cored Rexolite Hemi-Shell Ablator Capsules
journal, September 2016
- Randolph, Randall B.; Oertel, John A.; Schmidt, Derek W.
- Fusion Science and Technology, Vol. 70, Issue 2
First Liquid Layer Inertial Confinement Fusion Implosions at the National Ignition Facility
journal, December 2016
- Olson, R. E.; Leeper, R. J.; Kline, J. L.
- Physical Review Letters, Vol. 117, Issue 24
Aerogels
journal, August 1992
- Fricke, Jochen; Emmerling, Andreas
- Journal of the American Ceramic Society, Vol. 75, Issue 8
Foam materials for cryogenic targets of fast ignition realization experiment (FIREX)
journal, October 2005
- Nagai, Keiji; Azechi, H.; Ito, F.
- Nuclear Fusion, Vol. 45, Issue 11
Deterministic Control over High-Z Doping of Polydicyclopentadiene-Based Aerogel Coatings
journal, July 2013
- Kim, Sung Ho; Shin, Swanee J.; Lenhardt, Jeremy M.
- ACS Applied Materials & Interfaces, Vol. 5, Issue 16
Resorcinol/Formaldehyde Foam Shell Targets for ICF
journal, December 1995
- Overturf, George E.; Cook, Robert; Letts, Stephan A.
- Fusion Technology, Vol. 28, Issue 5
Alternative hot spot formation techniques using liquid deuterium-tritium layer inertial confinement fusion capsules
journal, September 2013
- Olson, R. E.; Leeper, R. J.
- Physics of Plasmas, Vol. 20, Issue 9
High-temperature and low-temperature supercritical drying of aerogels – structural investigations with SAXS
journal, October 1991
- Wang, P.; Emmerling, A.; Tappert, W.
- Journal of Applied Crystallography, Vol. 24, Issue 5
Target developments program to prepare LMJ campaigns
journal, August 2010
- Collier, R.; Bachelet, F.; Botrel, R.
- Journal of Physics: Conference Series, Vol. 244, Issue 3
Structure of Random Porous Materials: Silica Aerogel
journal, May 1986
- Schaefer, Dale W.; Keefer, Keith D.
- Physical Review Letters, Vol. 56, Issue 20, p. 2199-2202
Fabrication of hollow silica aerogel spheres by a droplet generation method and sol–gel processing
journal, May 1989
- Kim, N. K.; Kim, K.; Payne, D. A.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 7, Issue 3
Polyimide Aerogels by Ring-Opening Metathesis Polymerization (ROMP)
journal, April 2011
- Leventis, Nicholas; Sotiriou-Leventis, Chariklia; Mohite, Dhairyashil P.
- Chemistry of Materials, Vol. 23, Issue 8
Development and Fabrication of NIF-Scale Resorcinol Formaldehyde Foam Shells for ICF Experiments
journal, January 2011
- Paguio, R. R.; Jaison, D.; Saito, K. M.
- Fusion Science and Technology, Vol. 59, Issue 1
Diamond spheres for inertial confinement fusion
journal, September 2009
- Biener, J.; Ho, D. D.; Wild, C.
- Nuclear Fusion, Vol. 49, Issue 11
Wetted foam liquid fuel ICF target experiments
journal, May 2016
- Olson, R. E.; Leeper, R. J.; Yi, S. A.
- Journal of Physics: Conference Series, Vol. 717
Supercritical Fluid Technologies for Ceramic-Processing Applications
journal, June 1989
- Matson, Dean W.; Smith, Richard D.
- Journal of the American Ceramic Society, Vol. 72, Issue 6
Supercritical drying of aerogels using CO2: Effect of extraction time on the end material textural properties
journal, June 2012
- García-González, C. A.; Camino-Rey, M. C.; Alnaief, M.
- The Journal of Supercritical Fluids, Vol. 66
Summary Abstract: Characterization of low‐density foam materials for direct‐drive laser inertial confinement fusion targets
journal, May 1988
- Letts, S. A.; Buckley, S. R.; Chen, C.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 6, Issue 3
Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity
journal, January 1996
- Schwab, Peter; Grubbs, Robert H.; Ziller, Joseph W.
- Journal of the American Chemical Society, Vol. 118, Issue 1, p. 100-110
In Situ Real-Time Radiographic Study of Thin Film Formation Inside Rotating Hollow Spheres
journal, January 2016
- Braun, Tom; Walton, Christopher C.; Dawedeit, Christoph
- ACS Applied Materials & Interfaces, Vol. 8, Issue 4
Production of Silica Aerogel
journal, April 1981
- Henning, S.; Svensson, L.
- Physica Scripta, Vol. 23, Issue 4B
Direct drive cryogenic ICF capsules employing D-T wetted foam
journal, March 1987
- Sacks, R. A.; Darling, D. H.
- Nuclear Fusion, Vol. 27, Issue 3
Development of foam shell with plastic ablator for cryogenic laser fusion target
journal, September 1993
- Takagi, M.; Ishihara, M.; Norimatsu, T.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 11, Issue 5
Polydicyclopentadiene based aerogel: a new insulation material
journal, July 2007
- Lee, Je Kyun; Gould, George L.
- Journal of Sol-Gel Science and Technology, Vol. 44, Issue 1
Optimization of Gelation to Prepare Hollow Foam Shell of Resorcinol-Formalin Using a Phase-Transfer Catalyst
journal, May 2006
- Ito, Fuyumi; Nagai, Keiji; Nakai, Mitsuo
- Fusion Science and Technology, Vol. 49, Issue 4
Hugoniot and release measurements in diamond shocked up to 26 Mbar
journal, April 2017
- Gregor, M. C.; Fratanduono, D. E.; McCoy, C. A.
- Physical Review B, Vol. 95, Issue 14
Exploration of the versatility of ring opening metathesis polymerization: an approach for gaining access to low density polymeric aerogels
journal, January 2012
- Ho Kim, Sung; Worsley, Marcus A.; Valdez, Carlos A.
- RSC Advances, Vol. 2, Issue 23
Diamond Ablators for Inertial Confinement Fusion
journal, May 2006
- Biener, Juergen; Mirkarimi, Paul B.; Tringe, Joseph W.
- Fusion Science and Technology, Vol. 49, Issue 4
Influence of supercritical drying fluid on structure and properties of organically modified silica aerogels
journal, June 1995
- Hüsing, Nicola; Schwertfeger, Fritz; Tappert, Wolfgang
- Journal of Non-Crystalline Solids, Vol. 186
Development of foam shells for cryogenic laser fusion target
journal, March 1991
- Chen, C.; Norimatsu, T.; Takagi, M.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 9, Issue 2
High-Energy-Density Laboratory Astrophysics Studies of Jets and Bow Shocks
journal, November 2005
- Foster, J. M.; Wilde, B. H.; Rosen, P. A.
- The Astrophysical Journal, Vol. 634, Issue 1
Fabrication and Properties of Overcoated Resorcinol-Formaldehyde Shells for OMEGA Experiments
journal, March 2004
- Nikroo, A.; Czechowicz, D.; Paguio, R.
- Fusion Science and Technology, Vol. 45, Issue 2
Technology and Developments for the Random Positioning Machine, RPM
journal, September 2008
- Borst, A. G.; van Loon, Jack J. W. A.
- Microgravity Science and Technology, Vol. 21, Issue 4
Developing one-dimensional implosions for inertial confinement fusion science
journal, January 2016
- Kline, J. L.; Yi, S. A.; Simakov, A. N.
- High Power Laser Science and Engineering, Vol. 4
Tuning the rheological properties of sols for low-density aerogel coating applications
journal, January 2012
- Dawedeit, Christoph; Kim, Sung Ho; Braun, Tom
- Soft Matter, Vol. 8, Issue 13
Preparation of multishell ICF target plastic foam cushion materials by thermally induced phase inversion processes
journal, April 1982
- Young, A. T.; Moreno, D. K.; Marsters, R. G.
- Journal of Vacuum Science and Technology, Vol. 20, Issue 4
A new approach to foam-lined indirect-drive NIF ignition targets
journal, April 2012
- Biener, J.; Dawedeit, C.; Kim, S. H.
- Nuclear Fusion, Vol. 52, Issue 6
Coherent Expanded Aerogels and Jellies
journal, May 1931
- Kistler, S. S.
- Nature, Vol. 127, Issue 3211
Cryogenic targets and related technologies at ILE Osaka University
journal, July 1994
- Norimatsu, T.; Chen, C. M.; Nakajima, K.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 12, Issue 4
Fabrication of low-density foam shells from resorcinol-formaldehyde aerogel
journal, September 1997
- Lambert, Stephen M.; Overturf, George E.; Wilemski, Gerald
- Journal of Applied Polymer Science, Vol. 65, Issue 11
Improving the Wall Uniformity of Resorcinol Formaldehyde Foam Shells by Modifying Emulsion Components
journal, May 2007
- Paguio, R. R.; Takagi, M.; Thi, M.
- Fusion Science and Technology, Vol. 51, Issue 4
Works referencing / citing this record:
Variable convergence liquid layer implosions on the National Ignition Facility
journal, May 2018
- Zylstra, A. B.; Yi, S. A.; Haines, B. M.
- Physics of Plasmas, Vol. 25, Issue 5
Robustness to hydrodynamic instabilities in indirectly driven layered capsule implosions
journal, January 2019
- Haines, Brian M.; Olson, R. E.; Sweet, W.
- Physics of Plasmas, Vol. 26, Issue 1
Figures / Tables found in this record: