Homogeneity and elemental distribution in self-assembled bimetallic Pd–Pt aerogels prepared by a spontaneous one-step gelation process
Abstract
Pd–Pt aerogels prepared by a one-step gelation process exhibit alloy features with different elemental distributions over a broad length scale.
- Authors:
-
- Paul Scherrer Inst. (PSI), Villigen (Switzerland); Univ. of Oldenburg, Oldenburg (Germany)
- TU Dresden, Dresden (Germany)
- Paul Scherrer Inst. (PSI), Villigen (Switzerland)
- Yeshiva Univ., New York, NY (United States)
- AGH Univ. of Science and Technology, Krakow (Poland)
- Paul Scherrer Inst. (PSI), Villigen (Switzerland); ETH Zurich, Zurich (Switzerland)
- Publication Date:
- Research Org.:
- Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1439319
- Grant/Contract Number:
- FG02-03ER15476
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 18; Journal Issue: 30; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Oezaslan, Mehtap, Liu, W., Nachtegaal, M., Frenkel, A. I., Rutkowski, B., Werheid, M., Herrmann, A. -K., Laugier-Bonnaud, C., Yilmaz, H. -C., Gaponik, N., Czyrska-Filemonowicz, A., Eychmuller, A., and Schmidt, Thomas Justus. Homogeneity and elemental distribution in self-assembled bimetallic Pd–Pt aerogels prepared by a spontaneous one-step gelation process. United States: N. p., 2016.
Web. doi:10.1039/c6cp03527b.
Oezaslan, Mehtap, Liu, W., Nachtegaal, M., Frenkel, A. I., Rutkowski, B., Werheid, M., Herrmann, A. -K., Laugier-Bonnaud, C., Yilmaz, H. -C., Gaponik, N., Czyrska-Filemonowicz, A., Eychmuller, A., & Schmidt, Thomas Justus. Homogeneity and elemental distribution in self-assembled bimetallic Pd–Pt aerogels prepared by a spontaneous one-step gelation process. United States. https://doi.org/10.1039/c6cp03527b
Oezaslan, Mehtap, Liu, W., Nachtegaal, M., Frenkel, A. I., Rutkowski, B., Werheid, M., Herrmann, A. -K., Laugier-Bonnaud, C., Yilmaz, H. -C., Gaponik, N., Czyrska-Filemonowicz, A., Eychmuller, A., and Schmidt, Thomas Justus. Fri .
"Homogeneity and elemental distribution in self-assembled bimetallic Pd–Pt aerogels prepared by a spontaneous one-step gelation process". United States. https://doi.org/10.1039/c6cp03527b. https://www.osti.gov/servlets/purl/1439319.
@article{osti_1439319,
title = {Homogeneity and elemental distribution in self-assembled bimetallic Pd–Pt aerogels prepared by a spontaneous one-step gelation process},
author = {Oezaslan, Mehtap and Liu, W. and Nachtegaal, M. and Frenkel, A. I. and Rutkowski, B. and Werheid, M. and Herrmann, A. -K. and Laugier-Bonnaud, C. and Yilmaz, H. -C. and Gaponik, N. and Czyrska-Filemonowicz, A. and Eychmuller, A. and Schmidt, Thomas Justus},
abstractNote = {Pd–Pt aerogels prepared by a one-step gelation process exhibit alloy features with different elemental distributions over a broad length scale.},
doi = {10.1039/c6cp03527b},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 30,
volume = 18,
place = {United States},
year = {Fri Jul 01 00:00:00 EDT 2016},
month = {Fri Jul 01 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 20 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Preparation and electrochemical characterization of palladium single crystal electrodes in 0.1M H2SO4 and HClO4
journal, May 2007
- Hara, M.; Linke, U.; Wandlowski, Th.
- Electrochimica Acta, Vol. 52, Issue 18
Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts
journal, January 2012
- Frenkel, Anatoly I.
- Chemical Society Reviews, Vol. 41, Issue 24
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016
- Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol
- Chemical Reviews, Vol. 116, Issue 6
Characterization of High-Surface-Area Electrocatalysts Using a Rotating Disk Electrode Configuration
journal, January 1998
- Schmidt, T. J.; Gasteiger, H. A.; Stäb, G. D.
- Journal of The Electrochemical Society, Vol. 145, Issue 7, p. 2354-2358
CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects
journal, January 2007
- Maillard, Frédéric; Savinova, Elena R.; Stimming, Ulrich
- Journal of Electroanalytical Chemistry, Vol. 599, Issue 2
High-Performance Electrocatalysis on Palladium Aerogels
journal, April 2012
- Liu, Wei; Herrmann, Anne-Kristin; Geiger, Dorin
- Angewandte Chemie International Edition, Vol. 51, Issue 23
Anion adsorption on Pd–Pt(111) electrodes in sulphuric acid solution
journal, February 2001
- Álvarez, B.; Climent, V.; Rodes, A.
- Journal of Electroanalytical Chemistry, Vol. 497, Issue 1-2
Hydrogen bubbles template-directed synthesis of self-supported AuPt nanowire networks for improved ethanol oxidation and oxygen reduction reactions
journal, June 2016
- Liu, Lei; Chen, Li-Xian; Wang, Ai-Jun
- International Journal of Hydrogen Energy, Vol. 41, Issue 21
Short- and Long-Range Order Parameters in Disordered Solid Solutions
journal, December 1960
- Cowley, J. M.
- Physical Review, Vol. 120, Issue 5
An Approximate Theory of Order in Alloys
journal, March 1950
- Cowley, J. M.
- Physical Review, Vol. 77, Issue 5
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014
- Chen, C.; Kang, Y.; Huo, Z.
- Science, Vol. 343, Issue 6177
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs
journal, March 2005
- Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar
- Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35
Surface Composition Effects in Electrocatalysis: Kinetics of Oxygen Reduction on Well-Defined Pt 3 Ni and Pt 3 Co Alloy Surfaces
journal, November 2002
- Stamenković, V.; Schmidt, T. J.; Ross, P. N.
- The Journal of Physical Chemistry B, Vol. 106, Issue 46
Short-Range Order and Long-Range Order Parameters
journal, May 1965
- Cowley, J. M.
- Physical Review, Vol. 138, Issue 5A
Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges
journal, April 2012
- Rabis, Annett; Rodriguez, Paramaconi; Schmidt, Thomas J.
- ACS Catalysis, Vol. 2, Issue 5
Hydrogen Adsorption at Strained Pd Nanoshells
journal, May 2011
- Montes de Oca, M. G.; Kumarakuru, H.; Cherns, D.
- The Journal of Physical Chemistry C, Vol. 115, Issue 21
Engineering Ordered and Nonordered Porous Noble Metal Nanostructures: Synthesis, Assembly, and Their Applications in Electrochemistry
journal, July 2015
- Zhu, Chengzhou; Du, Dan; Eychmüller, Alexander
- Chemical Reviews, Vol. 115, Issue 16
Bimetallic Aerogels: High-Performance Electrocatalysts for the Oxygen Reduction Reaction
journal, July 2013
- Liu, Wei; Rodriguez, Paramaconi; Borchardt, Lars
- Angewandte Chemie International Edition, Vol. 52, Issue 37
Modeling the Structure and Composition of Nanoparticles by Extended X-Ray Absorption Fine-Structure Spectroscopy
journal, July 2011
- Frenkel, Anatoly I.; Yevick, Aaron; Cooper, Chana
- Annual Review of Analytical Chemistry, Vol. 4, Issue 1
Noble Metal Aerogels—Synthesis, Characterization, and Application as Electrocatalysts
journal, January 2015
- Liu, Wei; Herrmann, Anne-Kristin; Bigall, Nadja C.
- Accounts of Chemical Research, Vol. 48, Issue 2
Understanding the electrocatalysis of oxygen reduction on platinum and its alloys
journal, January 2012
- Stephens, Ifan E. L.; Bondarenko, Alexander S.; Grønbjerg, Ulrik
- Energy & Environmental Science, Vol. 5, Issue 5
Recent advances in porous Pt-based nanostructures: synthesis and electrochemical applications
journal, January 2014
- Xu, You; Zhang, Bin
- Chemical Society Reviews, Vol. 43, Issue 8
Trends in the Catalytic CO Oxidation Activity of Nanoparticles
journal, June 2008
- Falsig, Hanne; Hvolbæk, Britt; Kristensen, Iben S.
- Angewandte Chemie, Vol. 120, Issue 26
Aerogels and related porous materials
journal, June 1989
- Gesser, H. D.; Goswami, P. C.
- Chemical Reviews, Vol. 89, Issue 4
Pt-Based Core–Shell Catalyst Architectures for Oxygen Fuel Cell Electrodes
journal, September 2013
- Oezaslan, Mehtap; Hasché, Frédéric; Strasser, Peter
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 19
Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012
- Debe, Mark K.
- Nature, Vol. 486, Issue 7401
Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces
journal, October 2004
- Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A.
- Physical Review Letters, Vol. 93, Issue 15
Activity, stability and degradation of multi walled carbon nanotube (MWCNT) supported Pt fuel cell electrocatalysts
journal, January 2010
- Hasché, Frédéric; Oezaslan, Mehtap; Strasser, Peter
- Physical Chemistry Chemical Physics, Vol. 12, Issue 46
Just a Dream—or Future Reality?
journal, April 2009
- Gasteiger, Hubert A.; Marković, Nenad M
- Science, Vol. 324, Issue 5923, p. 48-49
Multimetallic Aerogels by Template-Free Self-Assembly of Au, Ag, Pt, and Pd Nanoparticles
journal, December 2013
- Herrmann, Anne-Kristin; Formanek, Petr; Borchardt, Lars
- Chemistry of Materials, Vol. 26, Issue 2
Role of Electronic Property of Pt and Pt Alloys on Electrocatalytic Reduction of Oxygen
journal, January 1998
- Toda, Takako
- Journal of The Electrochemical Society, Vol. 145, Issue 12
CO Chemisorption at Metal Surfaces and Overlayers
journal, March 1996
- Hammer, B.; Morikawa, Y.; Nørskov, J. K.
- Physical Review Letters, Vol. 76, Issue 12
Modification of the surface electronic and chemical properties of Pt(111) by subsurface 3d transition metals
journal, June 2004
- Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A.
- The Journal of Chemical Physics, Vol. 120, Issue 21
Short range order in bimetallic nanoalloys: An extended X-ray absorption fine structure study
journal, February 2013
- Frenkel, Anatoly I.; Wang, Qi; Sanchez, Sergio I.
- The Journal of Chemical Physics, Vol. 138, Issue 6
Enhanced electrocatalysis of oxygen reduction on platinum alloys in proton exchange membrane fuel cells
journal, October 1993
- Mukerjee, Sanjeev; Srinivasan, Supramaniam
- Journal of Electroanalytical Chemistry, Vol. 357, Issue 1-2, p. 201-224
Enhanced Electrocatalytic Performance of Processed, Ultrathin, Supported Pd–Pt Core–Shell Nanowire Catalysts for the Oxygen Reduction Reaction
journal, June 2011
- Koenigsmann, Christopher; Santulli, Alexander C.; Gong, Kuanping
- Journal of the American Chemical Society, Vol. 133, Issue 25
Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction
journal, May 2009
- Lim, B.; Jiang, M.; Camargo, P. H. C.
- Science, Vol. 324, Issue 5932, p. 1302-1305
Atomic Ensemble and Electronic Effects in Ag-Rich AgPd Nanoalloy Catalysts for Oxygen Reduction in Alkaline Media
journal, May 2012
- Slanac, Daniel A.; Hardin, William G.; Johnston, Keith P.
- Journal of the American Chemical Society, Vol. 134, Issue 23
The Particle Size Effect on the Oxygen Reduction Reaction Activity of Pt Catalysts: Influence of Electrolyte and Relation to Single Crystal Models
journal, November 2011
- Nesselberger, Markus; Ashton, Sean; Meier, Josef C.
- Journal of the American Chemical Society, Vol. 133, Issue 43
Hierarchically Structured Nanomaterials for Electrochemical Energy Conversion
journal, November 2015
- Trogadas, Panagiotis; Ramani, Vijay; Strasser, Peter
- Angewandte Chemie International Edition, Vol. 55, Issue 1
Aerogels—Airy Materials: Chemistry, Structure, and Properties
journal, February 1998
- Hüsing, Nicola; Schubert, Ulrich
- Angewandte Chemie International Edition, Vol. 37, Issue 1-2, p. 22-45
IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001
- Newville, Matthew
- Journal of Synchrotron Radiation, Vol. 8, Issue 2
Electrochemical properties of palladium adlayers on Pt(100) substrates
journal, December 2004
- Álvarez, B.; Berná, A.; Rodes, A.
- Surface Science, Vol. 573, Issue 1
Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co
journal, January 1999
- Toda, Takako; Igarashi, Hiroshi; Uchida, Hiroyuki
- Journal of The Electrochemical Society, Vol. 146, Issue 10, p. 3750-3756
Activity of dealloyed PtCo3 and PtCu3 nanoparticle electrocatalyst for oxygen reduction reaction in polymer electrolyte membrane fuel cell
journal, June 2011
- Oezaslan, Mehtap; Strasser, Peter
- Journal of Power Sources, Vol. 196, Issue 12
Correlations in palladium membranes for hydrogen separation: A review
journal, June 2011
- Yun, Samhun; Ted Oyama, S.
- Journal of Membrane Science, Vol. 375, Issue 1-2
Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007
- Stamenkovic, V. R.; Fowler, B.; Mun, B. S.
- Science, Vol. 315, Issue 5811, p. 493-497
Works referencing / citing this record:
Recent Developments in Electrocatalysts and Hybrid Electrocatalyst Support Systems for Polymer Electrolyte Fuel Cells
book, January 2017
- Sharma, Surbhi
- Electrocatalysts for Low Temperature Fuel Cells: Fundamentals and Recent Trends
Kinetics of Spontaneous Bimetallization between Silver and Noble Metal Nanoparticles
journal, June 2018
- Hirakawa, Kazutaka; Kaneko, Tetsuya; Toshima, Naoki
- Chemistry - An Asian Journal, Vol. 13, Issue 15