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This content will become publicly available on April 4, 2019

Title: Core–shell PdPb@Pd aerogels with multiply-twinned intermetallic nanostructures: facile synthesis with accelerated gelation kinetics and their enhanced electrocatalytic properties

Delicately engineering well-defined noble metal aerogels with favorable structural and compositional features is of vital importance for wide applications. Here, we reported a one-pot and facile method for synthesizing core–shell PdPb@Pd hydrogels/aerogels with multiply-twinned grains and an ordered intermetallic phase using sodium hypophosphite as a multifunctional reducing agent. Due to the accelerated gelation kinetics induced by increased reaction temperature and the specific function of sodium hypophosphite, the formation of hydrogels can be completed within 4 h. As a result, owing to their unique porous structure and favorable geometric and electronic effects, the optimized PdPb@Pd aerogels exhibit enhanced electrochemical performance towards ethylene glycol oxidation with a mass activity of 5.8 times higher than Pd black.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [2] ;  [2] ;  [1] ; ORCiD logo [3] ; ORCiD logo [4] ; ORCiD logo [2]
  1. Washington State Univ., Pullman, WA (United States); Central China Normal Univ., Wuhan (People's Republic of China)
  2. Washington State Univ., Pullman, WA (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
  4. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Publication Date:
Report Number(s):
BNL-203501-2018-JAAM
Journal ID: ISSN 2050-7488; JMCAET
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Electrocatalysis; Aerogel; Nanostructure; PdPb@Pd
OSTI Identifier:
1433968
Alternate Identifier(s):
OSTI ID: 1434119